#------------------------------------------------------------------------------ #$Date: 2020-11-25 07:11:19 +0200 (Wed, 25 Nov 2020) $ #$Revision: 259242 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/22/2022282.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2022282 loop_ _publ_author_name 'Rutherford, Ryan Noboru' 'Ura, Shinji' 'Chan, Tak-Hang' 'Fukumoto, Kozo' 'Nishioka, Takanori' 'Renzetti, Andrea' _publ_section_title ; Dibenzoate esters of cis-tetralin-2,3-diol as analogs of (--)-epigallocatechin gallate: synthesis and crystal structure of anticancer drug candidates ; _journal_coeditor_code OP3007 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229620014916 _journal_volume 76 _journal_year 2020 _chemical_formula_iupac 'C24 H14 F6 O4' _chemical_formula_moiety 'C24 H14 F6 O4' _chemical_formula_sum 'C24 H14 F6 O4' _chemical_formula_weight 480.35 _chemical_name_systematic ; (2R,3S)-1,2,3,4-Tetrahydronaphthalene-2,3-diyl bis(2,4,6-trifluorobenzoate) ; _space_group_crystal_system monoclinic _space_group_IT_number 15 _space_group_name_Hall '-I 2ya' _space_group_name_H-M_alt 'I 1 2/a 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _audit_creation_method ; Olex2 1.3 (compiled 2020.02.04 svn.rd84adfe8 for OlexSys, GUI svn.r6032) ; _cell_angle_alpha 90 _cell_angle_beta 112.62(3) _cell_angle_gamma 90 _cell_formula_units_Z 8 _cell_length_a 23.308(10) _cell_length_b 7.132(3) _cell_length_c 27.253(9) _cell_measurement_reflns_used 4856 _cell_measurement_temperature 193.4 _cell_measurement_theta_max 27.4479 _cell_measurement_theta_min 3.0091 _cell_volume 4182(3) _computing_cell_refinement ; CrystalClear (Rigaku, 2008) ; _computing_data_collection ; CrystalClear (Rigaku, 2008) ; _computing_data_reduction ; CrystalClear (Rigaku, 2008) ; _computing_molecular_graphics ; OLEX2 (Dolomanov et al., 2009) ; _computing_publication_material ; OLEX2 (Dolomanov et al., 2009) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT2018 (Sheldrick, 2015a) ; _diffrn_ambient_temperature 193.4 _diffrn_measured_fraction_theta_full 0.997 _diffrn_measured_fraction_theta_max 0.997 _diffrn_measurement_device ; Saturn724+ (2x2 bin mode) ; _diffrn_measurement_device_type 'Rigaku Saturn724+ (2x2 bin mode)' _diffrn_measurement_method dtprofit.ref _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71075 _diffrn_reflns_av_R_equivalents 0.0440 _diffrn_reflns_av_unetI/netI 0.0337 _diffrn_reflns_limit_h_max 28 _diffrn_reflns_limit_h_min -30 _diffrn_reflns_limit_k_max 9 _diffrn_reflns_limit_k_min -9 _diffrn_reflns_limit_l_max 35 _diffrn_reflns_limit_l_min -35 _diffrn_reflns_number 20765 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 27.448 _diffrn_reflns_theta_min 3.009 _exptl_absorpt_coefficient_mu 0.138 _exptl_absorpt_correction_T_max 1.0000 _exptl_absorpt_correction_T_min 0.7965 _exptl_absorpt_correction_type empirical _exptl_absorpt_process_details DTABSCOR _exptl_crystal_colour Colorless _exptl_crystal_density_diffrn 1.526 _exptl_crystal_description prism _exptl_crystal_F_000 1952 _exptl_crystal_size_max 0.238 _exptl_crystal_size_mid 0.116 _exptl_crystal_size_min 0.087 _refine_diff_density_max 0.220 _refine_diff_density_min -0.218 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.134 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 307 _refine_ls_number_reflns 4763 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.134 _refine_ls_R_factor_all 0.0620 _refine_ls_R_factor_gt 0.0464 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0582P)^2^+0.5393P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1131 _refine_ls_wR_factor_ref 0.1234 _reflns_number_gt 3880 _reflns_number_total 4763 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file op3007sup1.cif _cod_data_source_block 9 _cod_database_code 2022282 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; 1 -1 0 2.22 0.65 1 1 0 5.99 1.45 -1 1 0 1.06 0.41 -1 -1 0 1.04 0.40 1 -1 0 -0.26 0.37 -1 1 0 0.78 0.34 -1 1 0 0.82 0.87 -1 1 0 1.45 0.43 -2 0 4 1455.80 7.42 2 0 -4 1436.74 6.63 -2 0 4 1469.70 6.75 0 0 4 1.64 0.37 0 0 -4 2.27 0.65 0 0 -4 1.43 0.21 0 0 -4 1.54 0.39 0 0 4 1.92 0.21 0 0 4 1.34 0.37 -3 0 -1 0.18 0.25 3 0 1 0.47 0.44 3 0 1 -0.04 0.18 -3 0 -1 0.23 0.33 -3 0 -1 0.34 0.41 -1 -1 2 4740.68 264.08 1 1 -2 4609.76 256.82 -1 -1 2 4716.93 262.79 -1 1 2 4677.01 260.56 1 -1 -2 4435.79 17.27 -1 1 2 4658.46 259.48 1 1 -2 4803.47 267.59 -2 -1 1 1839.40 9.44 2 1 -1 1854.16 9.42 2 1 -1 1793.81 9.20 2 -1 -1 1891.56 9.82 4 0 -2 165.09 5.35 -4 0 2 169.66 5.59 4 0 -2 170.13 5.58 -1 -1 -2 1704.73 7.55 -1 1 -2 1642.48 9.27 1 1 2 1631.38 8.78 1 -1 2 1653.11 8.98 1 1 2 1709.22 8.93 1 1 2 1674.71 7.48 2 1 1 167.36 5.64 -2 -1 -1 157.99 5.43 2 1 1 160.36 5.14 -2 -1 -1 168.92 5.45 -2 1 -1 168.45 5.78 2 -1 1 165.71 5.75 -2 1 -1 159.47 5.23 2 -1 1 175.00 5.82 2 1 1 179.09 6.06 2 1 1 163.08 5.64 2 -1 1 158.86 5.38 -2 1 -1 156.84 5.44 0 1 -3 0.29 0.64 0 -1 3 0.62 0.48 0 -1 -3 0.34 0.31 0 1 3 0.26 0.49 0 -1 3 0.72 0.59 0 1 -3 0.52 0.56 0 1 -3 0.63 0.38 0 1 3 0.64 0.30 0 1 -3 0.56 0.55 0 -1 -3 0.49 0.52 0 1 3 0.54 0.29 2 1 -3 1.38 0.77 -2 -1 3 3.52 0.75 -2 1 3 2.57 0.40 2 1 -3 2.81 0.62 -2 1 3 2.55 0.68 2 -1 -3 3.90 1.18 -2 1 3 2.45 0.52 -2 -1 3 2.41 0.66 2 1 -3 3.05 0.62 -2 -1 3 3.03 0.74 -2 1 3 2.20 0.69 -2 1 3 2.85 0.61 -1 0 5 0.28 0.35 -1 0 5 0.28 0.54 1 0 -5 0.84 0.63 4 0 0 6.36 1.46 -4 0 0 6.33 1.49 4 0 0 6.74 1.01 -4 0 0 12.33 1.02 -4 0 0 5.59 1.12 4 0 0 7.33 1.31 3 1 -2 356.02 4.13 -3 -1 2 373.78 3.90 -3 -1 2 380.32 4.25 -3 -1 2 365.26 4.20 3 -1 -2 358.50 3.99 -3 1 2 362.38 4.20 -3 1 2 366.22 2.26 -3 1 2 378.39 4.24 3 -1 -2 364.60 4.16 4 0 -4 1855.72 8.30 -4 0 4 1820.00 8.24 4 0 -4 1771.03 9.23 -4 0 4 1871.45 9.66 -3 0 5 0.17 0.27 3 0 -5 0.17 0.48 -3 0 5 -0.20 0.55 3 0 -5 0.09 0.20 3 0 -5 0.37 0.60 -3 0 5 1.02 0.57 3 1 0 0.68 0.50 -3 -1 0 0.59 0.59 -3 -1 0 0.43 0.53 3 1 0 1.71 1.20 3 1 0 0.63 0.65 -3 -1 0 0.52 0.55 -3 1 0 0.27 0.58 -3 1 0 0.20 0.43 -3 1 0 0.34 0.48 3 -1 0 0.42 0.50 3 -1 0 0.40 0.40 3 -1 0 0.81 1.03 -1 1 4 1331.10 6.89 -1 -1 4 1348.98 8.32 1 -1 -4 1367.54 8.05 1 1 -4 1329.41 8.59 1 1 -4 1370.62 7.49 -1 -1 4 1347.19 8.83 1 -1 -4 1351.15 7.10 -2 0 -4 176.73 5.72 -2 0 -4 189.10 6.43 2 0 4 185.67 6.02 2 0 4 174.58 5.62 -2 0 -4 173.89 5.53 3 0 3 0.55 0.47 -3 0 -3 0.51 0.42 3 0 3 0.22 0.76 -3 0 -3 0.51 0.74 5 0 -3 0.71 0.63 5 0 -3 0.67 0.56 -5 0 3 0.26 0.50 -5 0 3 0.22 0.40 -5 0 3 0.35 0.58 -3 -1 4 144.24 5.17 3 1 -4 162.79 5.77 3 1 -4 169.87 6.00 -3 -1 4 163.59 5.89 -3 1 4 154.31 4.79 3 -1 -4 146.90 5.10 -3 1 4 152.23 5.28 3 -1 -4 146.56 5.51 3 -1 -4 157.04 4.90 2 0 -6 2152.14 10.50 2 0 -6 2174.56 10.27 -5 0 1 0.11 0.31 -5 0 1 0.11 0.98 -5 0 1 -0.16 0.51 5 0 -1 0.48 0.45 5 0 -1 0.13 0.41 1 0 5 0.57 0.58 -1 0 -5 0.43 0.57 1 0 5 0.17 0.28 -1 0 -5 0.41 0.76 -1 0 -5 0.16 0.27 -4 -1 1 1.25 0.62 4 1 -1 0.88 0.70 -4 -1 1 0.85 0.57 4 1 -1 1.28 0.97 -4 1 1 1.55 0.66 4 -1 -1 1.46 0.42 4 -1 -1 1.11 1.11 -4 1 1 0.68 0.29 2 1 3 997.44 6.93 -2 1 -3 1031.47 7.03 -2 -1 -3 1032.55 7.50 2 -1 3 988.17 6.72 -2 1 -3 1025.09 6.81 2 -1 3 1021.54 7.78 4 1 -3 2.93 0.54 4 1 -3 2.37 0.75 -4 -1 3 2.51 0.71 4 1 -3 2.72 0.76 -4 -1 3 2.35 0.77 4 -1 -3 2.68 0.77 -4 1 3 3.26 0.86 -4 0 -2 6403.93 356.72 4 0 2 6834.82 380.48 -4 0 -2 6751.45 375.86 -1 1 -4 787.40 6.34 1 -1 4 802.96 5.83 -1 1 -4 804.21 5.62 -1 -1 -4 840.60 4.65 1 1 4 793.95 4.73 -1 -1 -4 841.25 6.42 1 1 4 817.40 6.00 2 1 -5 2.23 0.78 -2 1 5 1.77 0.39 2 -1 -5 1.90 0.59 -2 -1 5 2.02 0.63 2 -1 -5 2.76 0.83 -2 1 5 2.68 0.79 2 1 -5 1.87 0.50 -2 -1 5 1.48 0.73 -2 1 5 2.14 0.52 -3 -1 -2 1512.59 6.20 3 1 2 1523.05 6.11 -3 1 -2 1497.48 9.40 -3 1 -2 1538.89 8.43 0 0 -6 74.35 2.80 0 0 -6 77.66 2.65 0 0 6 78.90 2.67 0 0 6 78.44 3.00 5 0 -5 0.25 0.77 5 0 -5 0.82 0.69 -5 0 5 -0.14 0.51 -5 0 5 0.58 1.00 -5 0 5 0.24 0.59 0 -1 5 93.95 3.86 0 1 -5 97.65 3.56 0 1 -5 94.13 3.41 0 1 -5 99.02 3.86 0 -1 -5 100.42 3.76 0 1 5 92.30 4.00 0 -1 -5 99.28 3.68 0 1 5 92.46 3.59 0 -1 -5 102.58 5.07 0 1 5 92.05 3.84 -4 -1 -1 201.42 6.37 4 1 1 203.25 6.38 -4 -1 -1 209.44 7.12 -4 1 -1 225.34 12.88 4 -1 1 192.04 6.41 4 -1 1 204.94 7.04 -4 1 -1 215.34 7.48 5 0 1 0.43 0.48 -5 0 -1 0.33 0.48 -5 0 -1 0.06 0.57 -5 0 -1 0.05 9.88 4 1 -5 105.10 3.82 -4 -1 5 111.45 4.15 -4 -1 5 106.22 4.20 4 -1 -5 107.09 4.74 -4 1 5 103.99 3.85 4 -1 -5 106.39 3.41 -4 1 5 95.02 3.00 4 1 -5 106.35 4.24 4 -1 -5 97.80 3.74 5 1 -2 51.80 2.49 -5 -1 2 57.15 2.84 -5 1 2 57.57 2.82 -5 1 2 55.64 2.01 5 -1 -2 55.93 2.25 5 -1 -2 58.03 2.87 -5 -1 2 56.65 2.49 3 0 -7 0.27 0.58 -3 0 7 0.46 0.56 -3 0 7 0.07 0.11 -6 0 2 2905.88 13.98 -6 0 4 1.37 0.60 -6 0 4 2.32 0.65 -6 0 4 0.80 0.50 6 0 -4 0.43 0.55 1 0 -7 0.10 0.13 1 0 -7 0.24 0.59 -1 0 7 0.16 0.11 1 0 -7 0.42 0.66 -1 0 7 0.84 0.84 -1 -1 6 114.64 4.51 1 1 -6 108.43 3.97 1 1 -6 121.93 4.98 1 1 -6 113.28 3.95 -1 1 6 108.63 4.07 1 -1 -6 114.56 4.67 -1 1 6 109.11 3.88 1 -1 -6 124.40 4.96 -1 1 6 112.15 3.96 1 -1 -6 113.84 4.42 3 1 -6 1440.86 7.65 -3 -1 6 1448.78 7.99 3 -1 -6 1444.01 9.32 -3 1 6 1430.58 8.38 -5 1 4 378.42 4.60 5 -1 -4 378.75 4.96 -5 -1 4 395.89 4.83 -5 -1 4 390.74 5.15 5 1 -4 397.53 5.19 -5 -1 0 70.12 2.61 5 1 0 71.81 3.20 -5 1 0 72.83 2.79 5 -1 0 70.21 2.65 5 -1 0 73.45 3.75 -5 1 0 72.33 3.16 -5 -1 0 72.54 3.31 5 1 0 68.98 2.49 -6 0 0 9.41 1.89 -6 0 0 7.77 1.01 -6 0 0 9.49 1.58 6 0 0 8.45 1.53 0 -2 0 4.47 1.06 0 -2 0 3.70 1.37 0 2 0 3.12 0.72 3 0 5 6.69 0.99 -3 0 -5 13.01 2.75 3 0 5 11.67 2.53 1 -2 -1 33.66 2.10 -1 -2 1 36.85 2.25 1 -2 -1 36.36 2.71 -1 -2 1 36.82 2.62 -1 2 1 38.52 2.02 1 2 -1 38.33 2.49 -3 1 -4 4393.01 18.73 3 -1 4 4340.36 19.23 -3 -1 -4 4715.28 262.93 -5 0 7 -0.86 1.05 -5 0 7 0.52 0.28 5 0 -7 -0.07 1.55 5 0 -7 -0.10 0.33 -5 0 7 -0.22 0.54 2 -1 5 48.55 2.24 2 -1 5 53.89 2.72 -2 1 -5 49.09 2.28 -2 1 -5 49.92 2.54 -2 -1 -5 49.74 3.04 2 1 5 46.29 1.72 -6 0 6 9999.00 556.87 -6 0 6 9608.63 534.98 6 0 -6 9454.94 526.42 1 -2 1 3632.88 18.87 0 2 -2 2058.23 12.57 0 -2 2 2060.15 13.35 0 -2 2 1921.92 13.05 -4 1 -3 3873.04 16.92 -4 -1 -3 3769.85 18.57 -4 -1 -3 3815.91 17.58 -4 1 -3 3757.61 16.81 2 1 -7 7.81 0.74 -2 1 7 8.54 1.94 -2 -1 7 11.92 2.09 2 -1 -7 9.47 1.38 -2 -1 7 7.57 1.13 2 -1 -7 8.62 0.95 2 1 -7 8.66 1.27 -2 1 7 9.02 0.77 -6 -1 3 200.68 7.02 -6 -1 3 217.09 7.37 6 1 -3 197.57 6.99 -6 1 3 192.39 6.80 6 -1 -3 197.01 7.64 6 -1 -3 191.37 5.98 -6 1 3 161.23 5.12 -2 0 8 45.06 3.03 2 0 -8 41.88 2.20 -1 1 -6 1655.38 8.67 -1 1 -6 1728.58 11.68 1 1 6 1657.10 7.72 1 1 6 1707.11 8.01 1 1 6 1646.61 9.28 2 -2 0 127.38 5.14 -2 -2 0 129.64 5.55 -2 -2 0 136.27 5.64 -2 2 0 127.27 5.07 2 2 0 123.28 4.84 -2 2 0 129.89 4.74 -5 -1 6 10.40 1.89 -5 -1 6 7.98 1.20 5 -1 -6 10.91 2.64 5 1 -6 6.35 1.15 5 1 -6 7.83 1.55 -5 1 6 8.13 1.62 5 -1 -6 8.98 1.08 -5 1 6 7.85 0.78 -2 -2 2 628.76 7.37 2 -2 -2 605.87 5.31 -2 2 2 641.58 5.68 2 2 -2 640.42 7.18 -2 2 2 595.96 7.08 -2 -2 2 632.05 6.92 -1 0 -7 2.54 0.71 1 0 7 -0.26 0.50 1 0 7 1.23 0.77 -5 0 -3 3.07 6.15 7 0 -3 0.17 0.29 -7 0 3 0.48 0.68 -7 0 3 -0.32 0.87 7 0 -3 0.33 0.54 -6 1 1 10.55 0.87 6 -1 -1 9.83 0.84 6 1 -1 11.64 1.50 -6 -1 1 13.33 1.04 6 -1 -1 10.80 1.22 6 1 -1 11.00 0.88 -6 -1 1 12.43 1.28 -6 1 1 11.21 1.19 -1 2 3 354.18 4.34 1 2 -3 358.07 8.96 -1 -2 3 353.31 6.01 -1 -2 3 350.96 5.60 1 -2 -3 321.76 4.67 4 1 -7 627.76 6.55 4 -1 -7 609.62 4.30 4 -1 -7 612.36 5.50 -4 1 7 622.06 5.38 4 1 -7 620.25 5.12 -4 -1 7 613.25 5.10 -5 1 -2 2630.79 13.93 -6 -1 5 80.42 3.46 -6 -1 5 83.05 3.37 6 1 -5 83.55 3.66 6 -1 -5 100.91 6.37 -6 1 5 103.06 4.34 -3 -2 1 3.58 0.87 3 2 -1 4.76 1.38 -3 -2 1 4.02 1.18 3 -2 -1 4.92 0.99 3 -2 -1 4.14 0.71 -3 2 1 4.65 0.74 -3 2 1 3.79 1.11 -7 0 5 0.79 0.69 7 0 -5 0.18 0.48 -7 0 5 0.87 1.09 -7 0 5 0.45 0.58 0 -1 7 29.24 1.93 0 -1 7 29.93 1.56 0 1 -7 31.09 2.22 0 1 -7 29.39 1.91 0 1 7 31.16 1.89 0 1 7 28.90 1.74 0 -1 -7 31.54 2.15 0 1 7 30.05 1.97 0 -1 -7 32.13 1.75 7 0 -1 0.28 0.23 -7 0 1 -0.02 0.85 -7 0 1 0.30 0.56 1 -2 3 1670.88 12.90 -1 2 -3 1648.37 11.53 -1 2 -3 1656.16 11.03 1 2 3 1700.47 11.33 2 2 2 12.73 1.42 -2 2 -2 15.31 3.51 2 -2 2 17.62 4.04 2 2 2 11.90 2.69 -2 2 -2 12.10 1.25 -2 -2 -2 12.51 1.52 -2 -2 -2 11.64 1.24 -3 -2 3 39.14 3.91 -3 -2 3 41.95 3.14 3 2 -3 43.47 2.64 3 -2 -3 37.75 1.72 -3 2 3 38.79 2.46 -3 2 3 43.34 1.95 0 0 8 2.17 0.71 0 0 -8 2.92 0.67 0 0 8 2.72 0.38 0 0 -8 2.48 0.73 -6 0 -2 1194.57 6.99 -6 0 -2 1226.13 9.28 6 0 2 1223.72 6.93 -2 -2 4 30.08 5.08 2 2 -4 24.99 1.85 -2 -2 4 25.09 2.27 2 -2 -4 25.93 2.80 -2 2 4 28.03 1.57 2 -2 -4 25.86 1.74 0 2 4 3.44 0.95 0 2 -4 4.16 1.01 0 -2 -4 3.38 1.05 0 -2 4 4.86 1.52 3 -2 1 205.24 7.54 -3 -2 -1 185.51 6.44 -3 -2 -1 205.41 7.83 -3 2 -1 199.37 7.23 -3 2 -1 201.36 6.86 3 2 1 207.97 7.78 3 1 -8 27.76 1.35 3 -1 -8 27.63 1.54 -3 1 8 27.33 1.41 3 1 -8 30.74 2.27 -3 -1 8 30.18 2.80 -3 -1 8 29.83 2.48 -3 1 8 29.53 1.87 -3 1 8 26.26 1.66 -3 1 8 28.10 1.57 -6 -1 -1 324.76 3.03 -6 -1 -1 304.38 4.82 -6 -1 -1 340.99 5.90 6 -1 1 319.07 5.10 -4 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4.89 10 -2 16 15.21 2.96 -20 0 -2 194.08 18.54 -20 0 -2 203.46 9.88 12 5 5 107.75 7.20 -12 -5 -5 100.31 7.54 -12 5 -5 93.77 5.39 12 -5 5 94.13 6.81 -12 5 -5 91.22 6.34 -20 0 20 1.49 2.08 -20 0 20 0.99 1.14 9 -2 17 13.93 2.36 -9 -2 -17 11.28 4.15 -9 -2 -17 10.96 3.12 -9 2 -17 14.35 2.89 -9 2 -17 9.71 2.62 -10 4 -12 124.47 6.81 -10 4 -12 130.16 7.22 10 4 12 127.15 7.90 10 -4 12 135.54 7.74 -10 -4 -12 130.99 8.02 -2 2 24 80.07 4.72 -2 -2 24 86.45 5.93 2 2 -24 92.97 6.14 2 -2 -24 90.94 16.06 19 3 -16 76.91 5.72 -19 -3 16 80.31 5.91 -19 -3 16 70.40 10.76 -19 3 16 82.50 6.45 -19 3 16 77.92 5.39 5 5 -18 97.20 5.77 -5 -5 18 95.14 17.80 5 5 -18 99.38 6.50 5 -5 -18 84.01 6.25 -5 5 18 92.16 5.94 -5 5 18 86.39 5.02 -2 1 -23 10.37 3.94 -2 -1 -23 11.67 4.90 2 -1 23 6.42 1.73 -11 2 -15 47.50 11.29 -11 2 -15 56.28 4.49 -11 -2 -15 57.30 12.90 -11 -2 -15 52.99 4.84 11 -2 15 45.48 8.17 -7 -5 18 20.61 3.56 7 5 -18 19.31 3.60 7 5 -18 20.13 3.33 7 -5 -18 19.78 3.99 -7 5 18 18.37 2.89 9 -1 -26 1.60 1.65 9 1 -26 1.59 2.06 -9 -1 26 0.43 1.66 -9 1 26 1.98 2.43 -11 -6 5 4.95 1.78 -11 -6 5 7.13 2.92 11 6 -5 3.57 3.92 -11 6 5 3.45 2.63 11 -6 -5 7.51 3.19 12 3 -23 107.83 7.02 -12 3 23 96.73 6.65 -12 -3 23 112.50 13.39 -17 -4 15 9.89 2.38 17 4 -15 5.75 2.31 -17 -4 15 11.47 3.27 17 -4 -15 5.11 1.76 -17 4 15 9.07 2.64 -19 1 -4 0.56 0.90 -19 1 -4 0.52 1.35 -19 -1 -4 2.37 2.25 -9 -6 11 13.89 3.20 9 6 -11 12.95 3.36 -9 -6 11 14.54 3.73 -9 6 11 10.18 3.03 9 -6 -11 15.58 4.18 14 1 -25 117.25 6.45 -14 1 25 135.19 8.16 -14 -1 25 129.47 7.82 -6 4 -16 45.49 3.38 -6 4 -16 50.95 4.26 -6 -4 -16 47.42 4.35 6 -4 16 55.81 10.89 8 -2 18 13.50 4.14 -8 -2 -18 12.22 4.67 -8 2 -18 14.01 3.44 -8 -2 -18 15.89 4.71 -8 2 -18 15.63 3.10 -10 -1 -17 90.88 5.44 -10 1 -17 86.15 5.13 -10 1 -17 92.92 6.26 -10 -1 -17 90.29 18.90 14 2 -24 1.00 1.96 -14 2 24 0.78 1.59 -14 -2 24 0.53 1.71 15 3 8 5.16 3.03 -15 -3 -8 8.28 3.61 -15 3 -8 6.17 2.05 -15 3 -8 8.00 2.67 15 -3 8 4.47 1.55 -7 -1 26 2.50 1.58 7 1 -26 2.15 2.11 7 -1 -26 4.69 2.78 -7 1 26 3.16 1.53 -18 -4 12 12.29 2.76 -18 -4 12 10.93 3.09 18 4 -12 8.42 2.66 18 -4 -12 9.86 3.68 -18 4 12 9.66 2.70 0 6 -12 0.99 2.20 0 6 -12 3.76 3.16 0 -6 12 1.61 1.84 0 6 12 2.85 2.22 0 -6 -12 1.49 1.72 0 -6 -12 2.21 3.23 9 6 3 21.15 5.41 -9 -6 -3 19.60 4.57 -9 -6 -3 20.85 2.65 9 -6 3 25.29 3.83 -9 6 -3 14.36 4.53 -9 6 -3 14.09 5.24 -11 1 -16 2.14 1.84 -11 -1 -16 1.71 1.47 -11 -1 -16 1.14 1.75 -11 1 -16 0.87 1.02 12 0 -26 88.87 13.97 -12 0 26 111.18 7.42 14 5 1 80.15 15.78 -14 -5 -1 78.22 8.26 -14 5 -1 75.47 5.45 14 -5 1 66.07 9.82 -5 6 13 34.84 4.63 5 -6 -13 38.76 8.40 -5 -6 13 34.41 4.18 5 6 -13 37.43 4.27 5 6 -13 35.12 7.29 11 6 -3 3.80 3.30 -11 -6 3 2.29 1.93 -11 -6 3 2.76 2.85 -11 6 3 1.67 1.70 11 -6 -3 2.24 3.05 11 2 -25 3.19 2.24 11 -2 -25 0.83 1.06 -11 2 25 2.53 1.99 -11 -2 25 3.85 2.84 -9 -1 -18 2.05 1.38 -9 1 -18 2.34 1.55 -9 -1 -18 1.62 1.48 -9 1 -18 0.78 1.78 -8 -6 12 56.29 6.83 -8 -6 12 45.73 8.39 8 6 -12 53.09 4.66 -8 6 12 63.75 12.40 8 -6 -12 65.21 14.19 -11 -6 7 129.84 22.10 11 6 -7 124.08 16.83 -11 -6 7 128.23 7.93 -11 6 7 117.88 7.38 11 -6 -7 122.08 13.21 18 4 -4 6.19 2.68 -18 -4 4 5.40 2.05 -18 -4 4 3.34 2.06 -18 4 4 2.79 1.99 18 -4 -4 7.56 2.97 -12 -2 -14 30.56 8.50 -12 2 -14 27.96 5.80 -12 2 -14 22.03 7.92 -12 -2 -14 29.22 3.36 -17 -1 -8 13.36 3.54 -17 1 -8 11.37 2.67 -17 -1 -8 17.77 5.51 -17 1 -8 15.98 5.23 20 3 -5 48.14 7.46 -20 -3 5 39.90 4.73 -20 -3 5 42.55 8.91 20 -3 -5 52.28 9.27 -20 3 5 48.99 4.44 -16 0 -10 6.34 2.58 -16 0 -10 4.06 2.03 -20 -3 13 38.32 3.79 20 3 -13 41.15 4.35 -20 -3 13 40.78 3.71 20 -3 -13 41.85 8.44 -20 3 13 39.83 4.06 3 6 -13 313.37 13.96 -3 -6 13 300.56 14.28 3 6 -13 298.59 13.31 -3 6 13 281.69 12.53 -3 6 13 328.56 15.12 3 -6 -13 313.73 16.37 -11 -4 -11 51.20 4.66 11 4 11 54.69 4.87 11 -4 11 53.56 11.93 -11 4 -11 59.52 4.31 -11 4 -11 52.44 4.13 21 2 -15 3.37 2.78 -21 -2 15 5.41 2.00 -21 -2 15 5.32 2.86 -21 2 15 3.44 2.28 -21 2 15 6.18 2.66 -10 -6 10 14.52 4.40 10 6 -10 15.03 3.50 -10 -6 10 14.55 3.31 -10 6 10 11.28 3.16 10 -6 -10 14.88 3.11 15 0 -25 1.84 1.33 -15 0 25 1.99 1.71 -15 -5 2 73.80 11.25 -15 -5 2 67.29 4.06 15 5 -2 70.12 8.23 15 -5 -2 74.60 6.53 -15 5 2 68.50 5.03 3 4 -21 45.53 4.34 -3 -4 21 57.90 5.33 -3 4 21 54.66 3.74 3 -4 -21 42.46 10.32 -3 4 21 40.35 8.63 -12 1 -15 61.70 4.80 -12 -1 -15 59.95 12.76 -12 1 -15 54.78 10.57 -12 -1 -15 61.34 3.93 -2 3 -21 44.47 6.54 -2 -3 -21 48.24 10.58 -2 -3 -21 40.10 8.16 2 -3 21 44.05 4.05 -5 -2 25 14.46 3.00 5 -2 -25 10.84 3.58 5 2 -25 12.92 3.12 -5 2 25 13.42 2.36 -11 -1 26 6.68 2.62 -11 1 26 12.73 2.82 11 1 -26 12.60 2.59 11 -1 -26 9.67 2.07 -20 -2 0 0.80 1.69 20 -2 0 2.70 1.76 -20 2 0 0.53 1.38 20 2 0 3.10 2.97 -20 2 0 0.87 0.79 20 2 -18 11.00 2.62 -20 2 18 7.57 1.92 -20 2 18 6.42 2.29 -20 -2 18 5.51 2.04 -20 -2 18 6.71 2.67 -7 2 -19 136.07 7.89 -7 -2 -19 125.95 16.69 -7 2 -19 82.22 6.12 7 -2 19 129.90 6.79 -7 -2 -19 130.94 6.78 7 -5 12 2.83 2.65 -7 -5 -12 2.87 1.97 7 5 12 3.85 4.04 -7 5 -12 2.35 1.99 -7 5 -12 1.51 1.77 -8 -1 -19 5.90 2.44 -8 1 -19 4.26 2.73 -8 -1 -19 4.74 1.66 -8 1 -19 3.88 1.42 -11 -4 21 114.65 7.76 11 4 -21 134.44 15.86 -11 4 21 117.05 7.52 -11 4 21 121.59 7.85 -2 1 25 0.44 1.21 -2 -1 25 1.51 1.59 2 -1 -25 0.57 1.32 2 1 -25 1.31 1.59 -22 0 4 276.69 13.79 22 0 -4 316.48 13.53 -22 0 4 301.82 13.43 -8 5 -11 30.03 3.44 -8 5 -11 28.76 3.24 8 5 11 30.80 4.80 -8 -5 -11 31.90 6.13 8 -5 11 30.24 4.14 5 -4 17 1.46 1.43 -5 -4 -17 1.99 1.90 -5 4 -17 3.26 1.87 -5 -4 -17 1.99 1.69 -5 4 -17 2.31 2.26 3 5 -18 1.31 3.21 3 5 -18 2.22 1.87 -3 -5 18 4.29 3.24 -3 5 18 2.74 1.89 3 -5 -18 3.43 1.23 -3 5 18 0.59 1.26 0 -4 20 18.43 3.44 0 4 -20 17.48 2.81 0 -4 -20 14.31 4.88 0 -4 -20 13.08 4.82 -15 -4 -5 71.38 8.63 15 4 5 86.65 7.11 15 -4 5 80.53 5.51 -15 4 -5 65.21 10.50 -15 4 -5 74.43 5.45 21 1 -18 0.12 0.90 -21 1 18 0.94 0.93 -21 -1 18 1.11 1.34 -21 1 18 0.83 1.35 -21 -1 18 0.63 1.37 -6 5 -13 3.21 2.45 -6 5 -13 1.98 1.98 6 5 13 2.37 2.33 6 -5 13 3.50 2.60 -6 -5 -13 1.84 2.34 0 -5 17 17.08 4.22 0 5 -17 11.60 2.93 0 5 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33.10 3.54 -22 -1 15 31.37 4.65 9 5 10 110.28 8.20 -9 -5 -10 106.85 7.10 9 -5 10 103.65 7.10 -9 5 -10 89.08 14.89 -9 5 -10 91.88 5.83 -13 -1 -14 1.41 1.71 -13 1 -14 1.01 2.00 -13 -1 -14 0.49 1.23 -13 1 -14 0.22 1.05 -3 0 -23 0.36 0.96 -5 6 -9 4.61 1.65 5 -6 9 8.10 2.85 -5 -6 -9 4.48 1.34 -5 -6 -9 7.78 3.61 5 6 9 9.14 3.54 -5 6 -9 4.78 1.97 -19 -2 -3 25.84 6.37 19 -2 3 22.28 4.09 19 2 3 26.65 4.24 -19 2 -3 19.61 4.89 -19 2 -3 22.86 5.68 -7 -3 24 192.75 10.30 7 3 -24 197.82 25.17 7 -3 -24 168.36 15.93 -7 3 24 177.82 8.75 -12 -4 -10 21.30 3.80 12 4 10 23.06 3.72 -12 4 -10 20.41 3.30 12 -4 10 26.25 6.14 -12 4 -10 22.59 3.18 1 0 -25 1.74 2.11 -1 0 25 2.42 1.83 -19 0 -5 0.05 1.31 -19 0 -5 1.48 1.61 5 -5 14 181.56 20.69 -5 5 -14 170.81 9.25 -5 5 -14 165.94 8.19 5 5 14 165.46 9.10 -5 -5 -14 156.33 9.83 -6 6 -8 102.18 6.96 -6 6 -8 102.72 6.14 6 6 8 99.11 15.74 -6 -6 -8 92.90 13.44 -6 -6 -8 85.72 4.86 6 -6 8 98.05 6.98 -4 0 26 1.56 1.43 4 0 -26 0.10 1.15 -11 -6 1 167.71 10.25 -11 -6 1 167.65 17.57 11 6 -1 175.89 9.76 11 -6 -1 160.19 9.20 -11 6 1 155.09 17.04 -9 3 24 0.83 1.63 9 3 -24 1.46 2.28 9 -3 -24 1.91 1.28 -9 -3 24 1.86 2.45 13 5 4 5.50 2.55 -13 -5 -4 3.19 2.02 -13 5 -4 2.39 1.24 13 -5 4 3.80 2.44 -13 5 -4 3.95 3.04 -21 -2 3 71.15 7.12 21 2 -3 73.11 6.03 21 -2 -3 61.01 10.62 -21 2 3 72.68 5.42 -21 0 19 1.30 1.24 -21 0 19 1.99 1.98 -2 -3 23 80.64 13.27 2 3 -23 73.01 5.98 2 -3 -23 62.25 16.69 11 6 -9 116.08 7.86 -11 -6 9 109.74 7.35 -11 -6 9 109.11 11.79 -11 6 9 116.94 7.28 11 -6 -9 102.83 16.45 -7 -1 -20 108.05 6.15 -7 -1 -20 131.66 21.21 -7 1 -20 128.38 7.91 19 3 0 120.77 12.20 -19 -3 0 120.98 14.43 -19 3 0 124.92 14.41 19 -3 0 122.39 16.76 -5 1 26 0.85 0.92 -5 -1 26 1.42 2.07 5 1 -26 1.75 1.67 5 -1 -26 2.09 2.17 4 6 10 2.52 2.46 -4 -6 -10 1.86 1.70 4 -6 10 4.05 3.26 -4 6 -10 1.28 1.36 -4 6 -10 2.36 2.23 -4 -6 -10 1.25 1.23 1 6 -13 148.98 8.39 1 6 -13 145.41 8.19 -1 -6 13 132.85 8.69 1 -6 -13 134.56 9.27 1 -6 -13 145.01 15.04 -1 6 13 124.53 9.59 10 6 2 35.57 4.17 -10 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0.86 1.64 -29 1 20 2.13 1.85 -29 -1 20 0.79 1.13 -29 1 20 1.74 1.79 -29 -1 20 1.68 1.89 25 5 -10 19.34 5.60 -25 -5 10 8.62 6.33 25 -5 -10 10.17 5.10 -25 5 10 11.92 3.71 -19 3 -14 1.02 1.67 -19 -3 -14 3.67 2.69 -19 3 -14 3.12 2.98 19 3 14 2.32 3.19 -22 3 29 19.45 5.17 -22 -3 29 21.97 6.26 -10 -3 33 1.75 1.52 10 3 -33 1.01 1.47 -22 -5 -3 9.18 7.31 22 5 3 12.32 4.39 22 -5 3 9.26 3.69 -22 5 -3 5.18 2.20 11 7 -22 1.91 2.03 11 -7 -22 0.72 1.50 -11 -7 22 1.50 2.12 12 3 -33 0.02 1.20 -12 3 33 1.30 1.26 -12 -3 33 0.88 1.97 -25 -2 -5 1.94 2.18 -25 2 -5 2.25 1.88 25 2 5 0.30 1.51 -29 -1 6 3.26 2.57 -29 1 6 3.38 2.28 -17 3 32 1.00 1.20 -17 -3 32 2.08 2.49 17 3 -32 1.01 1.34 16 6 10 10.97 4.41 -16 -6 -10 12.07 4.39 16 -6 10 8.27 2.73 -16 6 -10 7.41 2.90 -26 -2 26 21.48 6.15 -26 2 26 21.80 6.06 -5 -9 0 1.16 1.32 -5 -9 0 1.90 1.98 5 9 0 1.66 1.57 5 -9 0 2.42 2.92 -5 9 0 0.31 2.12 19 -7 -12 3.40 2.20 -19 -7 12 2.56 1.71 -19 -7 12 2.89 2.33 19 7 -12 3.23 2.92 -19 7 12 4.19 2.55 -23 -1 -10 2.15 2.32 -23 1 -10 3.20 2.68 -23 -1 -10 2.35 1.91 24 5 -3 5.80 3.72 -24 -5 3 3.70 2.61 24 -5 -3 0.90 1.34 -24 5 3 1.14 1.82 -23 0 31 -0.07 1.56 5 -8 -17 0.20 1.11 -5 -8 17 4.07 3.28 5 8 -17 0.56 1.79 5 8 -17 1.37 2.12 -5 8 17 0.25 1.35 -29 0 21 2.45 1.61 -29 0 21 1.89 1.85 -14 -8 2 1.41 1.60 14 8 -2 2.68 3.35 -14 8 2 2.43 2.01 14 -8 -2 3.17 2.37 -22 0 -12 27.57 6.68 -22 0 -12 14.89 8.32 -15 -6 25 13.13 8.75 15 6 -25 17.55 7.09 -15 6 25 26.81 6.91 -25 0 29 1.69 2.29 -28 0 24 18.78 5.35 -17 -1 34 2.30 2.07 -17 1 34 4.32 2.63 -11 0 35 0.77 1.79 11 0 -35 1.73 1.77 -13 -8 13 3.12 2.77 13 8 -13 2.54 2.21 -13 -8 13 2.40 2.81 13 -8 -13 3.14 2.25 -13 8 13 3.06 2.82 -29 0 5 1.79 2.19 24 4 -24 3.11 2.17 -24 4 24 6.57 3.31 -24 -4 24 5.77 2.80 -20 2 -14 1.96 2.12 -20 -2 -14 1.83 2.16 -20 -2 -14 3.50 2.72 -20 2 -14 1.33 1.19 -28 -3 17 7.42 2.83 -28 -3 17 8.32 2.63 -28 3 17 6.02 3.02 -28 3 17 6.89 2.22 6 5 -29 0.90 1.60 -6 -5 29 -0.57 1.49 -20 2 32 21.96 12.19 -20 -2 32 30.44 7.68 10 -8 -16 36.00 17.20 10 8 -16 56.79 13.20 -10 8 16 52.55 11.92 -10 -8 16 56.79 12.97 -29 2 17 1.27 1.28 -29 -2 17 1.42 1.92 -29 2 17 2.36 2.00 -29 -2 17 3.43 2.43 7 -8 -17 1.60 1.53 -7 -8 17 4.99 3.31 -7 8 17 3.26 2.15 7 8 -17 6.06 2.84 -14 -2 34 1.18 1.44 -14 2 34 1.34 1.31 14 2 -34 0.90 1.64 -24 -3 27 14.16 5.20 -24 3 27 12.43 4.14 -26 -4 4 1.46 2.05 26 4 -4 3.80 2.74 26 -4 -4 1.94 2.01 -26 4 4 2.30 2.26 -29 2 9 5.69 2.21 -29 2 9 4.97 2.62 -29 -2 9 5.04 2.16 -18 -5 27 2.44 2.84 18 5 -27 1.78 2.16 -18 5 27 1.07 1.37 12 7 11 2.83 3.73 -12 -7 -11 0.82 2.50 12 -7 11 0.72 1.30 -12 7 -11 3.07 2.57 22 6 -4 4.63 2.86 -22 -6 4 0.74 1.74 -22 6 4 0.52 1.67 22 -6 -4 -0.25 1.20 -3 -7 22 1.40 1.92 3 7 -22 0.70 1.72 -10 0 -26 0.56 1.66 22 5 -23 1.63 1.66 -22 -5 23 1.87 2.38 -22 5 23 1.46 1.74 -17 0 -19 1.91 1.78 25 5 -14 10.94 4.11 -25 -5 14 16.53 4.73 -25 5 14 13.94 4.51 25 -5 -14 12.85 6.71 -13 0 35 -0.17 1.36 3 9 4 3.12 2.14 3 9 4 4.00 3.87 -3 9 -4 3.16 2.71 3 -9 4 3.75 3.35 -3 -9 -4 2.60 1.90 16 7 -19 4.53 3.13 16 -7 -19 4.63 2.55 -16 -7 19 5.93 3.47 2 -9 5 8.53 3.24 -2 -9 -5 3.53 2.03 2 9 5 5.83 2.86 -2 9 -5 3.38 1.50 2 9 5 7.65 4.11 -2 9 -5 5.92 3.46 -15 -7 20 4.11 4.47 15 7 -20 1.61 2.06 15 -7 -20 4.26 2.55 -15 7 20 3.67 2.35 2 -1 -33 32.70 7.81 2 1 -33 25.74 12.36 4 5 25 9.35 2.91 4 -5 25 5.27 2.43 -4 5 -25 3.27 2.35 -21 -3 30 1.02 1.75 -21 3 30 1.23 1.62 21 3 -30 1.22 1.68 -7 -4 -25 1.27 1.49 -7 4 -25 3.76 2.39 -18 0 34 2.32 2.22 -17 4 -15 1.05 1.51 -17 -4 -15 1.81 1.48 17 4 15 2.86 2.21 8 2 -34 13.04 4.18 -30 0 14 28.53 16.93 -30 0 14 22.36 11.09 5 -7 18 2.12 2.29 -5 7 -18 1.14 2.02 -5 -7 -18 2.24 2.73 -22 -6 16 19.25 5.55 -22 -6 16 15.02 7.10 22 6 -16 22.29 6.47 -22 6 16 11.12 3.96 22 -6 -16 14.80 7.80 -27 -4 13 12.73 4.49 27 4 -13 10.04 3.12 -27 4 13 11.00 4.04 -27 4 13 9.17 2.76 24 5 -19 8.70 3.29 -24 -5 19 6.68 3.08 -24 -5 19 5.64 2.88 -24 5 19 7.74 2.61 -24 5 19 7.41 3.04 15 4 -31 0.01 1.30 -15 -4 31 3.13 2.90 -15 4 31 1.77 1.50 -4 9 -3 2.81 3.24 4 9 3 1.70 1.93 -4 -9 -3 2.37 2.02 -4 -9 -3 0.79 1.75 4 -9 3 2.24 2.82 27 4 -11 1.33 1.79 -27 -4 11 2.69 2.33 -27 4 11 2.41 2.27 27 -4 -11 2.25 2.28 -25 -5 8 2.11 2.31 25 5 -8 0.54 1.93 -25 5 8 0.30 1.68 25 -5 -8 2.25 1.33 2 -9 -7 4.38 2.46 -2 -9 7 1.83 1.89 2 9 -7 0.49 0.93 2 9 -7 2.23 2.27 -2 9 7 2.45 2.48 5 1 -34 15.14 4.69 5 -1 -34 9.26 4.65 -6 -9 3 6.41 3.07 -6 -9 3 2.26 2.97 -6 9 3 2.53 2.29 6 -9 -3 4.57 2.67 6 9 -3 3.13 2.25 -1 9 -6 2.71 2.32 1 9 6 2.09 3.19 -1 9 -6 1.59 2.77 -1 -9 -6 2.82 2.35 1 -9 6 2.89 3.11 2 4 -30 0.68 1.58 2 -4 -30 0.09 0.87 -30 0 12 1.30 2.05 0 -7 21 2.78 2.81 0 7 -21 -0.49 1.76 -23 4 -5 5.75 2.59 -23 -4 -5 11.09 5.21 23 4 5 7.78 3.25 -19 -7 4 0.59 1.66 19 7 -4 0.04 2.19 19 -7 -4 2.47 1.72 -19 7 4 4.07 3.06 5 -9 -6 1.41 1.52 -5 -9 6 2.39 1.87 -5 9 6 2.48 3.60 5 9 -6 4.02 2.62 5 9 -6 2.77 2.68 -8 -3 33 4.66 2.60 8 3 -33 6.61 4.23 3 -6 23 3.79 2.50 -3 6 -23 3.67 2.54 3 6 23 4.02 2.24 -28 2 22 0.34 1.00 -28 -2 22 1.63 2.41 -28 2 22 3.50 2.12 3 8 -17 5.21 2.42 -3 -8 17 9.61 4.41 3 8 -17 6.53 2.65 -3 8 17 8.62 3.28 1 6 -25 8.65 3.95 -1 -6 25 6.27 4.15 19 6 5 0.08 2.84 -19 -6 -5 -0.04 1.79 -19 6 -5 1.08 1.67 19 -6 5 -0.06 1.27 -4 -6 26 1.99 2.10 4 6 -26 5.10 3.13 0 8 -16 1.47 1.60 0 8 -16 3.98 2.82 0 -8 16 1.10 2.73 0 8 16 3.14 2.42 12 8 4 8.10 4.15 -12 8 -4 8.02 3.00 -12 -8 -4 7.98 4.81 12 -8 4 4.57 2.73 -9 0 35 2.84 2.16 9 0 -35 -0.04 1.00 -22 0 32 2.10 2.81 6 -9 -1 3.75 2.50 -6 -9 1 6.66 2.93 -6 -9 1 1.84 3.34 6 9 -1 3.82 2.40 -6 9 1 5.35 3.04 -21 -6 19 26.79 6.67 -21 -6 19 19.11 6.68 21 6 -19 31.51 8.19 21 -6 -19 22.56 10.51 -21 6 19 24.63 6.30 -21 -4 -9 45.25 10.81 21 4 9 40.78 10.02 -21 4 -9 24.74 13.43 -18 -5 -11 7.83 3.48 18 5 11 4.07 2.91 -18 5 -11 2.46 1.82 -14 -3 33 1.16 2.05 14 3 -33 1.53 1.36 -26 0 28 6.87 2.79 -4 9 7 4.74 2.67 -4 -9 7 7.94 3.11 4 -9 -7 6.28 2.46 4 9 -7 3.59 2.22 4 9 -7 7.76 4.05 -17 -7 18 0.47 1.52 17 -7 -18 1.62 1.59 -17 -7 18 1.42 2.38 17 7 -18 1.25 2.19 -17 7 18 0.41 1.32 -7 8 -11 25.36 10.39 -7 8 -11 27.06 6.51 7 -8 11 42.63 10.33 7 8 11 33.56 8.11 -7 -8 -11 28.11 15.17 -27 1 26 2.60 2.33 -27 -1 26 0.90 1.16 -20 1 -15 0.30 1.71 -20 -1 -15 1.14 2.13 -20 1 -15 0.96 1.56 -20 -1 -15 2.01 1.88 14 7 -21 18.49 5.58 -14 -7 21 19.35 5.71 -14 7 21 14.16 8.28 14 -7 -21 18.07 6.66 -6 8 -12 11.10 5.44 6 -8 12 12.35 6.27 -6 8 -12 10.03 2.81 -6 -8 -12 9.94 4.72 -20 1 33 15.37 4.91 -20 -1 33 22.39 6.34 -30 0 16 6.43 3.69 -30 0 16 3.61 5.16 -14 -5 29 4.46 3.76 -14 5 29 4.28 2.16 14 5 -29 4.17 2.40 -5 -4 31 10.27 3.55 5 4 -31 18.41 5.80 -5 -9 -2 11.17 10.25 5 9 2 8.12 5.12 5 -9 2 17.54 5.28 -5 9 -2 9.62 6.31 -5 -9 -2 13.57 4.04 6 -9 -5 4.06 2.47 6 9 -5 2.82 2.70 -6 9 5 1.21 2.28 -6 -9 5 2.63 2.16 -5 2 -29 1.95 2.50 -5 -2 -29 0.99 1.72 -26 -4 20 0.30 1.39 -26 -4 20 1.10 1.60 26 4 -20 3.13 2.24 -26 4 20 0.95 1.14 -26 4 20 2.16 3.10 4 0 -34 2.59 1.73 -8 -8 -10 45.45 22.77 8 -8 10 65.79 14.43 -8 8 -10 40.42 16.45 8 8 10 52.85 12.02 -5 3 -28 2.47 2.90 -5 -3 -28 1.03 1.44 -18 -4 30 3.22 2.71 -18 4 30 0.67 1.29 18 4 -30 1.44 1.72 27 4 -15 0.00 0.98 -27 4 15 0.71 1.90 -27 4 15 3.28 2.39 -28 -3 7 3.17 2.40 28 3 -7 2.33 2.12 -28 3 7 3.65 2.07 -28 3 7 4.62 2.29 12 1 -35 3.36 2.07 -12 1 35 3.76 2.29 -16 -7 -5 1.45 1.84 16 7 5 1.31 1.99 -16 7 -5 2.41 2.24 16 -7 5 0.72 1.75 0 -9 7 10.04 4.00 0 9 -7 11.81 4.65 0 9 7 10.75 5.33 0 -9 -7 7.78 3.71 -3 0 -31 1.66 1.59 14 8 -12 10.13 3.79 -14 -8 12 12.24 6.77 -14 -8 12 8.89 3.44 -14 8 12 10.71 3.05 14 -8 -12 10.42 3.50 13 7 10 5.06 2.66 -13 -7 -10 2.81 2.51 -13 7 -10 1.81 1.59 13 -7 10 0.60 1.29 -25 -3 26 1.24 1.61 -25 3 26 0.04 1.62 5 -8 13 2.67 2.04 -5 8 -13 4.25 3.04 -5 -8 -13 7.68 3.81 5 8 13 7.00 3.10 27 -4 -9 3.88 1.70 -27 -4 9 1.58 2.14 27 4 -9 1.29 1.43 -27 4 9 0.48 1.29 -9 0 -27 0.27 1.64 -27 -3 22 2.39 2.24 -27 3 22 0.60 1.43 -27 3 22 2.28 2.12 -9 -8 17 1.35 1.98 9 -8 -17 2.15 1.77 9 8 -17 2.41 2.03 9 8 -17 3.18 2.80 -9 8 17 1.13 1.57 -18 0 -18 14.18 7.71 -15 -8 7 14.19 6.09 15 8 -7 12.60 4.84 15 -8 -7 19.84 7.19 -15 8 7 13.38 4.78 -6 1 -29 2.91 2.40 -6 -1 -29 2.53 2.29 -10 1 35 3.45 1.94 10 1 -35 2.85 2.06 19 7 -14 3.30 3.24 -19 -7 14 4.10 2.16 -19 -7 14 2.79 2.49 19 -7 -14 3.05 2.54 -19 7 14 3.21 2.21 -28 -1 1 -0.31 1.68 -28 1 1 0.50 1.51 28 1 -1 1.79 2.32 -15 0 35 1.69 2.35 26 3 1 15.68 5.66 -26 3 -1 6.81 3.76 -26 -3 -1 7.66 5.06 -30 0 10 2.06 2.55 -8 -7 23 45.63 11.20 8 7 -23 32.92 8.27 1 0 -33 1.60 2.24 -9 8 -9 20.61 6.07 9 -8 9 16.38 10.16 9 8 9 17.11 4.84 -9 -8 -9 17.27 9.22 -4 7 -19 -0.16 1.38 4 -7 19 1.34 2.27 4 7 19 3.61 2.19 -4 -7 -19 0.75 1.47 -25 0 -7 2.90 2.39 -30 1 13 17.68 4.92 -30 -1 13 22.10 5.67 -30 1 13 15.61 4.45 -15 8 5 17.38 5.55 15 8 -5 20.63 6.56 -15 -8 5 16.19 6.44 15 -8 -5 17.85 9.57 17 6 9 3.65 3.03 -17 -6 -9 4.77 2.86 17 -6 9 4.17 2.61 -17 6 -9 2.77 2.11 -27 -1 -2 4.86 2.75 27 1 2 2.00 1.89 -27 1 -2 3.10 1.81 -20 -3 -13 11.29 7.69 -20 3 -13 9.77 4.71 20 3 13 18.72 5.84 -20 3 -13 8.96 6.27 25 5 -16 3.08 2.31 -25 -5 16 0.18 0.98 -25 -5 16 0.95 1.51 -25 5 16 1.79 1.50 25 -5 -16 1.40 1.12 3 -3 -32 1.24 1.54 3 3 -32 0.33 1.49 -3 -3 32 0.39 1.21 -17 -5 28 1.62 2.67 17 5 -28 1.88 1.63 -17 5 28 1.72 1.71 3 2 -33 1.70 2.22 3 -2 -33 2.54 1.96 -20 -3 31 4.58 3.19 20 3 -31 1.58 1.41 -3 -9 8 1.31 2.55 3 -9 -8 1.22 2.11 3 9 -8 0.48 1.43 -3 9 8 2.03 2.97 3 9 -8 2.39 2.70 -30 -1 15 0.19 1.33 -30 1 15 -0.03 1.22 23 5 -22 2.94 2.22 -23 -5 22 2.24 2.19 -23 5 22 1.53 2.16 -21 -5 -6 6.20 3.56 21 -5 6 2.20 2.37 21 5 6 2.81 3.97 -21 5 -6 3.43 1.79 -6 9 -1 6.75 3.80 -6 -9 -1 15.41 7.73 -6 -9 -1 6.81 3.53 6 -9 1 18.02 5.25 -15 -8 9 0.80 1.49 -15 -8 9 1.17 1.48 -15 8 9 2.18 3.08 15 -8 -9 3.81 2.42 -6 -7 23 4.32 3.59 6 7 -23 0.23 1.74 -27 -3 2 2.75 2.55 -27 3 2 1.21 2.09 -14 -8 0 2.79 1.99 -14 8 0 5.95 2.97 14 -8 0 4.85 3.23 -4 8 -14 0.82 1.38 -4 8 -14 2.49 2.47 -4 -8 -14 0.53 1.45 -23 -6 11 10.65 3.42 23 -6 -11 8.76 3.39 -18 -4 -14 1.85 1.66 -23 -3 -8 15.60 5.07 23 3 8 11.70 5.66 0 0 0 0.00 0.00 _computing_structure_solution 'SHELXT2018 (Sheldrick, 2015a)' ; _shelx_hkl_checksum 49983 _shelx_res_file ; TITL shelx_trans_a.res in I2/a shelx_trans.res created by SHELXL-2018/3 at 15:12:22 on 20-Oct-2020 REM Old TITL RNR-2A REM SHELXT solution in I2/a: R1 0.183, Rweak 0.379, Alpha 0.036 REM 0.999 for 354 systematic absences, Orientation as input REM Formula found by SHELXT: C13 F6 O7 CELL 0.71075 23.3083 7.1321 27.2533 90 112.621 90 ZERR 8 0.0098 0.0027 0.0088 0 0.027 0 LATT 2 SYMM 0.5-X,+Y,-Z SFAC C H F O UNIT 192 112 48 32 L.S. 30 PLAN 5 TEMP -79.75 CONF BOND list 4 MORE -1 BOND $H fmap 2 53 acta REM REM REM WGHT 0.058200 0.539300 FVAR 0.25881 F6 3 -0.595381 -0.863401 -0.252295 11.00000 0.05313 0.03378 = 0.06321 -0.00358 0.03588 0.00337 F3 3 -0.699609 -0.656244 -0.394735 11.00000 0.04465 0.02920 = 0.07651 0.00054 0.00092 0.00441 F5 3 -0.736575 -1.008922 -0.174736 11.00000 0.06884 0.04198 = 0.07206 0.01022 0.04324 -0.00539 O1 4 -0.654447 -0.323404 -0.378652 11.00000 0.02926 0.03131 = 0.04017 -0.00861 0.00934 0.00004 O3 4 -0.597196 -0.510446 -0.280896 11.00000 0.04553 0.03615 = 0.03833 -0.00401 0.01977 -0.01096 F4 3 -0.679056 -0.385948 -0.180566 11.00000 0.10006 0.02978 = 0.09940 -0.00532 0.07375 0.00339 O4 4 -0.580175 -0.326473 -0.209717 11.00000 0.05953 0.03579 = 0.05123 -0.01204 0.02717 -0.01394 F2 3 -0.893139 -0.744036 -0.530195 11.00000 0.05968 0.06568 = 0.06981 -0.02062 0.00517 -0.02730 O2 4 -0.725124 -0.101410 -0.384621 11.00000 0.04157 0.03325 = 0.07468 -0.01365 0.01189 0.00546 F1 3 -0.823408 -0.138329 -0.479049 11.00000 0.06512 0.03393 = 0.11460 0.01936 -0.02141 -0.00129 C18 1 -0.601162 -0.467226 -0.234449 11.00000 0.03266 0.02991 = 0.03731 -0.00169 0.01279 0.00054 C11 1 -0.711935 -0.252808 -0.396752 11.00000 0.03362 0.02668 = 0.04124 0.00100 0.01471 0.00044 C19 1 -0.635208 -0.614329 -0.217844 11.00000 0.03236 0.02927 = 0.03479 0.00082 0.01204 0.00062 C12 1 -0.757729 -0.385786 -0.433689 11.00000 0.03305 0.02990 = 0.03587 0.00094 0.01389 -0.00326 C2 1 -0.563963 -0.381048 -0.301942 11.00000 0.03327 0.03106 = 0.03569 -0.00002 0.01247 -0.00598 AFIX 13 H2 2 -0.528538 -0.323624 -0.271892 11.00000 -1.20000 AFIX 0 C4 1 -0.514102 -0.379767 -0.368769 11.00000 0.02937 0.03901 = 0.03245 0.00153 0.00812 0.00112 C24 1 -0.632883 -0.805303 -0.227983 11.00000 0.03276 0.03281 = 0.03602 -0.00158 0.01483 0.00319 C1 1 -0.606872 -0.227518 -0.334424 11.00000 0.03216 0.02898 = 0.03842 -0.00906 0.01165 -0.00350 AFIX 13 H1 2 -0.626082 -0.159152 -0.312525 11.00000 -1.20000 AFIX 0 C3 1 -0.538963 -0.498497 -0.335580 11.00000 0.03542 0.03041 = 0.04100 0.00301 0.01421 0.00396 AFIX 23 H3A 2 -0.505325 -0.580416 -0.312073 11.00000 -1.20000 H3B 2 -0.572576 -0.580005 -0.359305 11.00000 -1.20000 AFIX 0 C5 1 -0.529625 -0.189952 -0.378659 11.00000 0.03139 0.03738 = 0.03683 0.00262 0.00834 -0.00205 C17 1 -0.751121 -0.579722 -0.430764 11.00000 0.03630 0.03265 = 0.04118 -0.00159 0.01368 -0.00066 C6 1 -0.570574 -0.092773 -0.354791 11.00000 0.03779 0.02864 = 0.04726 0.00004 0.01343 -0.00227 AFIX 23 H6A 2 -0.600234 -0.010341 -0.382039 11.00000 -1.20000 H6B 2 -0.544278 -0.012360 -0.325027 11.00000 -1.20000 AFIX 0 C20 1 -0.673210 -0.567492 -0.190761 11.00000 0.04964 0.02776 = 0.04578 0.00011 0.02334 0.00479 C22 1 -0.702684 -0.879754 -0.188043 11.00000 0.04058 0.03595 = 0.04130 0.00961 0.01683 -0.00121 C23 1 -0.665413 -0.939922 -0.213395 11.00000 0.04414 0.02845 = 0.04466 0.00110 0.01827 -0.00037 AFIX 43 H23 2 -0.662217 -1.069007 -0.220563 11.00000 -1.20000 AFIX 0 C21 1 -0.707778 -0.695193 -0.175806 11.00000 0.04794 0.03847 = 0.04580 0.00551 0.02630 0.00641 AFIX 43 H21 2 -0.733785 -0.657632 -0.157963 11.00000 -1.20000 AFIX 0 C13 1 -0.813664 -0.322749 -0.472036 11.00000 0.04110 0.03308 = 0.05162 0.00861 0.00981 -0.00386 C7 1 -0.476075 -0.463175 -0.391671 11.00000 0.04050 0.05241 = 0.04352 0.00290 0.01701 0.00816 AFIX 43 H7 2 -0.465397 -0.591903 -0.385128 11.00000 -1.20000 AFIX 0 C15 1 -0.848872 -0.626419 -0.498600 11.00000 0.04373 0.04899 = 0.04196 -0.01013 0.01411 -0.01765 C16 1 -0.795802 -0.702132 -0.462187 11.00000 0.04906 0.03390 = 0.05731 -0.01005 0.01692 -0.00722 AFIX 43 H16 2 -0.789935 -0.834012 -0.458670 11.00000 -1.20000 AFIX 0 C10 1 -0.506511 -0.089226 -0.410961 11.00000 0.04226 0.05091 = 0.04875 0.01388 0.01453 -0.00100 AFIX 43 H10 2 -0.516759 0.039693 -0.417708 11.00000 -1.20000 AFIX 0 C14 1 -0.859539 -0.438574 -0.504939 11.00000 0.03950 0.05252 = 0.04254 0.00591 0.00607 -0.00867 AFIX 43 H14 2 -0.896844 -0.389864 -0.530823 11.00000 -1.20000 AFIX 0 C9 1 -0.469041 -0.173513 -0.433274 11.00000 0.05464 0.08074 = 0.05540 0.02086 0.02941 0.00172 AFIX 43 H9 2 -0.453709 -0.102928 -0.455201 11.00000 -1.20000 AFIX 0 C8 1 -0.453842 -0.361308 -0.423617 11.00000 0.04964 0.08094 = 0.05373 0.00840 0.02944 0.00992 AFIX 43 H8 2 -0.428125 -0.419917 -0.438983 11.00000 -1.20000 AFIX 0 HKLF 4 REM shelx_trans_a.res in I2/a REM wR2 = 0.1234, GooF = S = 1.134, Restrained GooF = 1.134 for all data REM R1 = 0.0464 for 3880 Fo > 4sig(Fo) and 0.0620 for all 4763 data REM 307 parameters refined using 0 restraints END WGHT 0.0582 0.5393 REM Highest difference peak 0.220, deepest hole -0.218, 1-sigma level 0.038 Q1 1 -0.8207 -0.1308 -0.4383 11.00000 0.05 0.22 Q2 1 -0.6338 -0.6989 -0.2234 11.00000 0.05 0.18 Q3 1 -0.8419 -0.3775 -0.4823 11.00000 0.05 0.16 Q4 1 -0.7981 -0.1542 -0.4804 11.00000 0.05 0.16 Q5 1 -0.5263 -0.2944 -0.3759 11.00000 0.05 0.14 ; _shelx_res_checksum 32059 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, y, -z' 'x+1/2, y+1/2, z+1/2' '-x+1, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y, z' '-x+1/2, -y+1/2, -z+1/2' 'x, -y+1/2, z+1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group F F6 -0.59538(4) -0.86340(12) -0.25229(4) 0.0460(3) Uani d 1 . . F F3 -0.69961(5) -0.65624(13) -0.39473(4) 0.0569(3) Uani d 1 . . F F5 -0.73657(5) -1.00892(14) -0.17474(4) 0.0561(3) Uani d 1 . . O O1 -0.65445(5) -0.32340(14) -0.37865(4) 0.0348(3) Uani d 1 . . O O3 -0.59720(5) -0.51045(15) -0.28090(4) 0.0389(3) Uani d 1 . . F F4 -0.67906(6) -0.38595(14) -0.18057(5) 0.0658(3) Uani d 1 . . O O4 -0.58017(6) -0.32647(15) -0.20972(5) 0.0471(3) Uani d 1 . . F F2 -0.89314(5) -0.74404(17) -0.53019(5) 0.0710(4) Uani d 1 . . O O2 -0.72512(5) -0.10141(16) -0.38462(5) 0.0530(3) Uani d 1 . . F F1 -0.82341(6) -0.13833(14) -0.47905(6) 0.0881(5) Uani d 1 . . C C18 -0.60116(7) -0.4672(2) -0.23445(6) 0.0335(3) Uani d 1 . . C C11 -0.71193(7) -0.2528(2) -0.39675(6) 0.0338(3) Uani d 1 . . C C19 -0.63521(7) -0.6143(2) -0.21784(6) 0.0324(3) Uani d 1 . . C C12 -0.75773(7) -0.3858(2) -0.43369(6) 0.0327(3) Uani d 1 . . C C2 -0.56396(7) -0.3810(2) -0.30194(6) 0.0336(3) Uani d 1 . . H H2 -0.528538 -0.323624 -0.271892 0.040 Uiso calc 1 . . C C4 -0.51410(7) -0.3798(2) -0.36877(6) 0.0347(3) Uani d 1 . . C C24 -0.63288(7) -0.8053(2) -0.22798(6) 0.0334(3) Uani d 1 . . C C1 -0.60687(7) -0.2275(2) -0.33442(6) 0.0338(3) Uani d 1 . . H H1 -0.626082 -0.159152 -0.312525 0.041 Uiso calc 1 . . C C3 -0.53896(7) -0.4985(2) -0.33558(6) 0.0358(3) Uani d 1 . . H H3A -0.505325 -0.580416 -0.312073 0.043 Uiso calc 1 . . H H3B -0.572576 -0.580005 -0.359305 0.043 Uiso calc 1 . . C C5 -0.52963(7) -0.1900(2) -0.37866(6) 0.0366(4) Uani d 1 . . C C17 -0.75112(7) -0.5797(2) -0.43076(6) 0.0371(4) Uani d 1 . . C C6 -0.57057(7) -0.0928(2) -0.35479(7) 0.0388(4) Uani d 1 . . H H6A -0.600234 -0.010341 -0.382039 0.047 Uiso calc 1 . . H H6B -0.544278 -0.012360 -0.325027 0.047 Uiso calc 1 . . C C20 -0.67321(8) -0.5675(2) -0.19076(6) 0.0396(4) Uani d 1 . . C C22 -0.70268(7) -0.8798(2) -0.18804(6) 0.0389(4) Uani d 1 . . C C23 -0.66541(7) -0.9399(2) -0.21340(6) 0.0387(4) Uani d 1 . . H H23 -0.662217 -1.069007 -0.220563 0.046 Uiso calc 1 . . C C21 -0.70778(8) -0.6952(2) -0.17581(7) 0.0416(4) Uani d 1 . . H H21 -0.733785 -0.657632 -0.157963 0.050 Uiso calc 1 . . C C13 -0.81366(8) -0.3227(2) -0.47204(7) 0.0443(4) Uani d 1 . . C C7 -0.47607(8) -0.4632(3) -0.39167(7) 0.0452(4) Uani d 1 . . H H7 -0.465397 -0.591903 -0.385128 0.054 Uiso calc 1 . . C C15 -0.84887(8) -0.6264(2) -0.49860(7) 0.0456(4) Uani d 1 . . C C16 -0.79580(8) -0.7021(2) -0.46219(7) 0.0478(4) Uani d 1 . . H H16 -0.789935 -0.834012 -0.458670 0.057 Uiso calc 1 . . C C10 -0.50651(8) -0.0892(3) -0.41096(7) 0.0482(4) Uani d 1 . . H H10 -0.516759 0.039693 -0.417708 0.058 Uiso calc 1 . . C C14 -0.85954(8) -0.4386(3) -0.50494(7) 0.0478(4) Uani d 1 . . H H14 -0.896844 -0.389864 -0.530823 0.057 Uiso calc 1 . . C C9 -0.46904(9) -0.1735(3) -0.43327(8) 0.0611(5) Uani d 1 . . H H9 -0.453709 -0.102928 -0.455201 0.073 Uiso calc 1 . . C C8 -0.45384(9) -0.3613(3) -0.42362(8) 0.0586(5) Uani d 1 . . H H8 -0.428125 -0.419917 -0.438983 0.070 Uiso calc 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 F6 0.0531(6) 0.0338(5) 0.0632(6) 0.0034(4) 0.0359(5) -0.0036(4) F3 0.0447(6) 0.0292(5) 0.0765(8) 0.0044(4) 0.0009(5) 0.0005(5) F5 0.0688(7) 0.0420(6) 0.0721(7) -0.0054(5) 0.0432(6) 0.0102(5) O1 0.0293(5) 0.0313(5) 0.0402(6) 0.0000(4) 0.0093(5) -0.0086(4) O3 0.0455(6) 0.0362(6) 0.0383(6) -0.0110(5) 0.0198(5) -0.0040(5) F4 0.1001(9) 0.0298(5) 0.0994(9) 0.0034(5) 0.0737(8) -0.0053(5) O4 0.0595(7) 0.0358(6) 0.0512(7) -0.0139(5) 0.0272(6) -0.0120(5) F2 0.0597(7) 0.0657(8) 0.0698(8) -0.0273(6) 0.0052(6) -0.0206(6) O2 0.0416(7) 0.0333(6) 0.0747(9) 0.0055(5) 0.0119(6) -0.0136(6) F1 0.0651(8) 0.0339(6) 0.1146(11) -0.0013(5) -0.0214(7) 0.0194(6) C18 0.0327(8) 0.0299(7) 0.0373(8) 0.0005(6) 0.0128(6) -0.0017(6) C11 0.0336(8) 0.0267(7) 0.0412(9) 0.0004(6) 0.0147(7) 0.0010(6) C19 0.0324(7) 0.0293(7) 0.0348(8) 0.0006(6) 0.0120(6) 0.0008(6) C12 0.0330(7) 0.0299(7) 0.0359(8) -0.0033(6) 0.0139(6) 0.0009(6) C2 0.0333(8) 0.0311(7) 0.0357(8) -0.0060(6) 0.0125(7) 0.0000(6) C4 0.0294(7) 0.0390(8) 0.0325(8) 0.0011(6) 0.0081(6) 0.0015(6) C24 0.0328(8) 0.0328(8) 0.0360(8) 0.0032(6) 0.0148(7) -0.0016(6) C1 0.0322(7) 0.0290(7) 0.0384(8) -0.0035(6) 0.0116(7) -0.0091(6) C3 0.0354(8) 0.0304(8) 0.0410(9) 0.0040(6) 0.0142(7) 0.0030(6) C5 0.0314(8) 0.0374(8) 0.0368(9) -0.0021(6) 0.0083(7) 0.0026(6) C17 0.0363(8) 0.0326(8) 0.0412(9) -0.0007(6) 0.0137(7) -0.0016(7) C6 0.0378(8) 0.0286(7) 0.0473(9) -0.0023(6) 0.0134(7) 0.0000(7) C20 0.0496(9) 0.0278(8) 0.0458(9) 0.0048(6) 0.0233(8) 0.0001(7) C22 0.0406(9) 0.0359(8) 0.0413(9) -0.0012(7) 0.0168(7) 0.0096(7) C23 0.0441(9) 0.0285(7) 0.0447(9) -0.0004(6) 0.0183(8) 0.0011(7) C21 0.0479(9) 0.0385(9) 0.0458(10) 0.0064(7) 0.0263(8) 0.0055(7) C13 0.0411(9) 0.0331(8) 0.0516(10) -0.0039(7) 0.0098(8) 0.0086(7) C7 0.0405(9) 0.0524(10) 0.0435(10) 0.0082(7) 0.0170(8) 0.0029(8) C15 0.0437(10) 0.0490(10) 0.0420(10) -0.0177(8) 0.0141(8) -0.0101(8) C16 0.0491(10) 0.0339(8) 0.0573(11) -0.0072(7) 0.0169(9) -0.0100(8) C10 0.0423(9) 0.0509(10) 0.0487(10) -0.0010(8) 0.0145(8) 0.0139(8) C14 0.0395(9) 0.0525(10) 0.0425(10) -0.0087(8) 0.0061(8) 0.0059(8) C9 0.0546(11) 0.0807(15) 0.0554(12) 0.0017(10) 0.0294(10) 0.0209(11) C8 0.0496(11) 0.0809(15) 0.0537(12) 0.0099(10) 0.0294(10) 0.0084(10) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag C11 O1 C1 . . 117.70(11) ? C18 O3 C2 . . 117.80(11) ? O3 C18 C19 . . 111.34(12) ? O4 C18 O3 . . 124.07(14) ? O4 C18 C19 . . 124.59(14) ? O1 C11 C12 . . 111.43(12) ? O2 C11 O1 . . 124.25(14) ? O2 C11 C12 . . 124.32(14) ? C24 C19 C18 . . 124.24(13) ? C20 C19 C18 . . 120.94(13) ? C20 C19 C24 . . 114.82(14) ? C17 C12 C11 . . 123.98(14) ? C17 C12 C13 . . 114.49(14) ? C13 C12 C11 . . 121.37(14) ? O3 C2 H2 . . 109.5 ? O3 C2 C1 . . 110.85(12) ? O3 C2 C3 . . 105.94(11) ? C1 C2 H2 . . 109.5 ? C3 C2 H2 . . 109.5 ? C3 C2 C1 . . 111.52(12) ? C5 C4 C3 . . 121.86(14) ? C7 C4 C3 . . 118.99(14) ? C7 C4 C5 . . 119.12(15) ? F6 C24 C19 . . 118.62(13) ? F6 C24 C23 . . 117.48(13) ? C23 C24 C19 . . 123.87(14) ? O1 C1 C2 . . 105.38(11) ? O1 C1 H1 . . 110.5 ? O1 C1 C6 . . 110.38(12) ? C2 C1 H1 . . 110.5 ? C2 C1 C6 . . 109.57(12) ? C6 C1 H1 . . 110.5 ? C2 C3 H3A . . 109.2 ? C2 C3 H3B . . 109.2 ? C4 C3 C2 . . 112.25(12) ? C4 C3 H3A . . 109.2 ? C4 C3 H3B . . 109.2 ? H3A C3 H3B . . 107.9 ? C4 C5 C6 . . 121.25(14) ? C10 C5 C4 . . 119.04(15) ? C10 C5 C6 . . 119.72(15) ? F3 C17 C12 . . 119.68(13) ? F3 C17 C16 . . 116.60(14) ? C16 C17 C12 . . 123.69(15) ? C1 C6 H6A . . 108.9 ? C1 C6 H6B . . 108.9 ? C5 C6 C1 . . 113.52(13) ? C5 C6 H6A . . 108.9 ? C5 C6 H6B . . 108.9 ? H6A C6 H6B . . 107.7 ? F4 C20 C19 . . 118.46(14) ? F4 C20 C21 . . 117.33(14) ? C21 C20 C19 . . 124.14(15) ? F5 C22 C23 . . 118.13(14) ? F5 C22 C21 . . 118.30(14) ? C23 C22 C21 . . 123.57(15) ? C24 C23 H23 . . 121.5 ? C22 C23 C24 . . 117.04(14) ? C22 C23 H23 . . 121.5 ? C20 C21 H21 . . 121.7 ? C22 C21 C20 . . 116.52(15) ? C22 C21 H21 . . 121.7 ? F1 C13 C12 . . 118.88(14) ? F1 C13 C14 . . 116.82(15) ? C14 C13 C12 . . 124.26(16) ? C4 C7 H7 . . 119.5 ? C8 C7 C4 . . 120.96(17) ? C8 C7 H7 . . 119.5 ? F2 C15 C16 . . 118.30(16) ? F2 C15 C14 . . 118.20(16) ? C14 C15 C16 . . 123.50(16) ? C17 C16 H16 . . 121.3 ? C15 C16 C17 . . 117.31(16) ? C15 C16 H16 . . 121.3 ? C5 C10 H10 . . 119.4 ? C9 C10 C5 . . 121.16(18) ? C9 C10 H10 . . 119.4 ? C13 C14 H14 . . 121.6 ? C15 C14 C13 . . 116.74(16) ? C15 C14 H14 . . 121.6 ? C10 C9 H9 . . 120.1 ? C10 C9 C8 . . 119.80(17) ? C8 C9 H9 . . 120.1 ? C7 C8 C9 . . 119.93(18) ? C7 C8 H8 . . 120.0 ? C9 C8 H8 . . 120.0 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag F6 C24 . 1.3492(17) ? F3 C17 . 1.3404(19) ? F5 C22 . 1.3508(18) ? O1 C11 . 1.3356(19) ? O1 C1 . 1.4567(18) ? O3 C18 . 1.3401(19) ? O3 C2 . 1.4569(17) ? F4 C20 . 1.3422(18) ? O4 C18 . 1.2032(18) ? F2 C15 . 1.3514(19) ? O2 C11 . 1.2033(18) ? F1 C13 . 1.3359(19) ? C18 C19 . 1.487(2) ? C11 C12 . 1.492(2) ? C19 C24 . 1.395(2) ? C19 C20 . 1.394(2) ? C12 C17 . 1.391(2) ? C12 C13 . 1.395(2) ? C2 H2 . 1.0000 ? C2 C1 . 1.517(2) ? C2 C3 . 1.514(2) ? C4 C3 . 1.508(2) ? C4 C5 . 1.400(2) ? C4 C7 . 1.398(2) ? C24 C23 . 1.374(2) ? C1 H1 . 1.0000 ? C1 C6 . 1.519(2) ? C3 H3A . 0.9900 ? C3 H3B . 0.9900 ? C5 C6 . 1.514(2) ? C5 C10 . 1.395(2) ? C17 C16 . 1.376(2) ? C6 H6A . 0.9900 ? C6 H6B . 0.9900 ? C20 C21 . 1.377(2) ? C22 C23 . 1.370(2) ? C22 C21 . 1.374(2) ? C23 H23 . 0.9500 ? C21 H21 . 0.9500 ? C13 C14 . 1.376(2) ? C7 H7 . 0.9500 ? C7 C8 . 1.379(3) ? C15 C16 . 1.365(3) ? C15 C14 . 1.361(3) ? C16 H16 . 0.9500 ? C10 H10 . 0.9500 ? C10 C9 . 1.379(3) ? C14 H14 . 0.9500 ? C9 H9 . 0.9500 ? C9 C8 . 1.385(3) ? C8 H8 . 0.9500 ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag F6 C24 C23 C22 . . . . 179.08(14) ? F3 C17 C16 C15 . . . . 179.17(15) ? F5 C22 C23 C24 . . . . 178.04(14) ? F5 C22 C21 C20 . . . . -179.03(15) ? O1 C11 C12 C17 . . . . 29.2(2) ? O1 C11 C12 C13 . . . . -155.60(15) ? O1 C1 C6 C5 . . . . -69.26(16) ? O3 C18 C19 C24 . . . . 34.0(2) ? O3 C18 C19 C20 . . . . -145.29(14) ? O3 C2 C1 O1 . . . . -62.45(15) ? O3 C2 C1 C6 . . . . 178.80(11) ? O3 C2 C3 C4 . . . . 168.80(11) ? F4 C20 C21 C22 . . . . 178.04(15) ? O4 C18 C19 C24 . . . . -146.54(16) ? O4 C18 C19 C20 . . . . 34.2(2) ? F2 C15 C16 C17 . . . . 179.43(15) ? F2 C15 C14 C13 . . . . 179.77(16) ? O2 C11 C12 C17 . . . . -150.50(17) ? O2 C11 C12 C13 . . . . 24.7(2) ? F1 C13 C14 C15 . . . . 178.46(17) ? C18 O3 C2 C1 . . . . -86.51(15) ? C18 O3 C2 C3 . . . . 152.36(12) ? C18 C19 C24 F6 . . . . 3.1(2) ? C18 C19 C24 C23 . . . . -178.71(15) ? C18 C19 C20 F4 . . . . 0.8(2) ? C18 C19 C20 C21 . . . . 177.64(15) ? C11 O1 C1 C2 . . . . 145.89(13) ? C11 O1 C1 C6 . . . . -95.90(15) ? C11 C12 C17 F3 . . . . -3.5(2) ? C11 C12 C17 C16 . . . . 174.61(15) ? C11 C12 C13 F1 . . . . 6.6(2) ? C11 C12 C13 C14 . . . . -175.62(16) ? C19 C24 C23 C22 . . . . 0.9(2) ? C19 C20 C21 C22 . . . . 1.2(3) ? C12 C17 C16 C15 . . . . 1.0(3) ? C12 C13 C14 C15 . . . . 0.6(3) ? C2 O3 C18 O4 . . . . 1.7(2) ? C2 O3 C18 C19 . . . . -178.84(12) ? C2 C1 C6 C5 . . . . 46.35(17) ? C4 C5 C6 C1 . . . . -17.0(2) ? C4 C5 C10 C9 . . . . 0.2(3) ? C4 C7 C8 C9 . . . . 0.2(3) ? C24 C19 C20 F4 . . . . -178.49(14) ? C24 C19 C20 C21 . . . . -1.7(2) ? C1 O1 C11 O2 . . . . 11.7(2) ? C1 O1 C11 C12 . . . . -168.05(12) ? C1 C2 C3 C4 . . . . 48.10(16) ? C3 C2 C1 O1 . . . . 55.33(15) ? C3 C2 C1 C6 . . . . -63.42(15) ? C3 C4 C5 C6 . . . . 2.1(2) ? C3 C4 C5 C10 . . . . -178.16(14) ? C3 C4 C7 C8 . . . . 178.03(16) ? C5 C4 C3 C2 . . . . -17.6(2) ? C5 C4 C7 C8 . . . . 0.0(2) ? C5 C10 C9 C8 . . . . 0.0(3) ? C17 C12 C13 F1 . . . . -177.79(16) ? C17 C12 C13 C14 . . . . 0.0(3) ? C6 C5 C10 C9 . . . . 179.94(16) ? C20 C19 C24 F6 . . . . -177.58(13) ? C20 C19 C24 C23 . . . . 0.6(2) ? C23 C22 C21 C20 . . . . 0.5(3) ? C21 C22 C23 C24 . . . . -1.5(2) ? C13 C12 C17 F3 . . . . -178.94(14) ? C13 C12 C17 C16 . . . . -0.9(2) ? C7 C4 C3 C2 . . . . 164.44(14) ? C7 C4 C5 C6 . . . . -179.92(14) ? C7 C4 C5 C10 . . . . -0.2(2) ? C16 C15 C14 C13 . . . . -0.5(3) ? C10 C5 C6 C1 . . . . 163.33(14) ? C10 C9 C8 C7 . . . . -0.1(3) ? C14 C15 C16 C17 . . . . -0.3(3) ? _cod_database_fobs_code 2022282