#------------------------------------------------------------------------------ #$Date: 2021-08-11 05:15:44 +0300 (Wed, 11 Aug 2021) $ #$Revision: 268023 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/24/38/2243895.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2243895 loop_ _publ_author_name 'Whited, Matthew T.' 'Ball, Margaret A.' 'Block, Alison' 'Brewster, Benjamin A.' 'Ferrer, LouLou' 'Jin-Lee, Helen J.' 'King, Colby J.' 'North, Jamie D.' 'Shelton, Inger L.' 'Wilson, David G.' _publ_section_title ; Crystal structures of phosphine-supported (\h^5^-cyclopentadienyl)molybdenum(II) propionyl complexes ; _journal_coeditor_code JQ2008 _journal_issue 9 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first ; ; _journal_paper_doi 10.1107/S2056989021008008 _journal_volume 77 _journal_year 2021 _chemical_formula_iupac '[Mo (C5 H5) (C3 H5 O) (C18 H15 P) (C O)2]' _chemical_formula_moiety 'C28 H25 Mo O3 P' _chemical_formula_sum 'C28 H25 Mo O3 P' _chemical_formula_weight 536.39 _chemical_name_common CpMo(CO)2(PPh3)(COEt) _chemical_name_systematic Dicarbonyl(\h^5^-cyclopentadienyl)propionyl(triphenylphosphane-\kP)molybdenum(II) _space_group_crystal_system triclinic _space_group_IT_number 2 _space_group_name_Hall '-P 1' _space_group_name_H-M_alt 'P -1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _atom_sites_solution_secondary difmap _cell_angle_alpha 113.083(2) _cell_angle_beta 99.148(2) _cell_angle_gamma 99.380(2) _cell_formula_units_Z 2 _cell_length_a 9.1719(5) _cell_length_b 11.7493(7) _cell_length_c 12.6049(7) _cell_measurement_reflns_used 9085 _cell_measurement_temperature 170.(2) _cell_measurement_theta_max 33.1223 _cell_measurement_theta_min 2.6334 _cell_volume 1195.14(12) _computing_cell_refinement ; SAINT (Bruker, 2019) ; _computing_data_collection ; BIS (Bruker, 2019) ; _computing_data_reduction ; SAINT (Bruker, 2019) ; _computing_molecular_graphics ; Mercury (Macrae et al., 2020) ; _computing_publication_material ; publCIF (Westrip, 2010) ; _computing_structure_refinement ; SHELXL2018/3 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT2018/2 (Sheldrick, 2015a) ; _diffrn_ambient_temperature 170.(2) _diffrn_detector_area_resol_mean 7.3910 _diffrn_measured_fraction_theta_full 0.999 _diffrn_measured_fraction_theta_max 0.999 _diffrn_measurement_device 'Fixed--\c Diffractometer' _diffrn_measurement_device_type 'Bruker D8 QUEST ECO' _diffrn_measurement_method '\f and \w scans' _diffrn_radiation_monochromator 'Curved Graphite' _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0248 _diffrn_reflns_av_unetI/netI 0.0138 _diffrn_reflns_limit_h_max 12 _diffrn_reflns_limit_h_min -12 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_k_min -15 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_number 49481 _diffrn_reflns_theta_full 25.24 _diffrn_reflns_theta_max 28.28 _diffrn_reflns_theta_min 2.32 _diffrn_source 'sealed tube' _diffrn_source_current 20.0 _diffrn_source_power 1.00 _diffrn_source_voltage 50 _exptl_absorpt_coefficient_mu 0.643 _exptl_absorpt_correction_T_max 0.96 _exptl_absorpt_correction_T_min 0.89 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (Krause et al., 2015) ; _exptl_crystal_colour yellow _exptl_crystal_density_diffrn 1.491 _exptl_crystal_density_method 'not measured' _exptl_crystal_description prism _exptl_crystal_F_000 548 _exptl_crystal_size_max 0.160 _exptl_crystal_size_mid 0.160 _exptl_crystal_size_min 0.060 _refine_diff_density_max 0.337 _refine_diff_density_min -0.402 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.072 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 299 _refine_ls_number_reflns 5939 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.072 _refine_ls_R_factor_all 0.0201 _refine_ls_R_factor_gt 0.0189 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0220P)^2^+0.6108P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0500 _refine_ls_wR_factor_ref 0.0509 _reflns_number_gt 5674 _reflns_number_total 5939 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file jq2008sup1.cif _cod_data_source_block 1 _cod_database_code 2243895 _shelx_hkl_file ; -1 0 0 0.18 0.06 -1 0 0 0.33 0.05 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2 0 415.40 11.25 -4 -2 0 10.78 0.59 -4 -2 0 10.73 0.55 -4 -2 0 9.66 0.40 -4 -2 0 10.61 0.50 -4 -2 0 11.47 0.56 -4 -2 0 10.55 0.48 4 2 0 10.96 0.49 4 2 0 10.82 0.53 4 2 0 11.34 0.48 4 2 0 10.41 0.46 4 2 0 9.81 0.41 4 2 0 10.79 0.57 -5 -2 0 453.12 12.19 -5 -2 0 451.42 12.23 -5 -2 0 453.73 12.36 -5 -2 0 456.67 12.11 -5 -2 0 455.30 12.32 -5 -2 0 429.37 12.28 5 2 0 450.04 12.25 5 2 0 442.17 12.33 5 2 0 452.55 12.17 5 2 0 451.97 12.22 5 2 0 460.07 12.17 5 2 0 454.46 12.11 5 2 0 463.40 12.34 -6 -2 0 11.73 0.61 -6 -2 0 12.36 0.64 -6 -2 0 12.53 0.71 -6 -2 0 13.38 0.76 6 2 0 12.63 0.59 6 2 0 11.60 0.67 6 2 0 12.14 0.71 6 2 0 12.31 0.66 6 2 0 11.21 0.61 6 2 0 11.76 0.54 6 2 0 13.65 0.60 -7 -2 0 128.49 3.87 -7 -2 0 113.58 3.72 -7 -2 0 124.52 3.71 -7 -2 0 129.20 3.92 7 2 0 130.14 3.68 7 2 0 127.41 3.61 7 2 0 121.38 3.72 7 2 0 129.64 3.79 7 2 0 130.35 3.88 7 2 0 125.73 3.67 7 2 0 126.19 3.62 -8 -2 0 2.00 0.39 -8 -2 0 1.30 0.34 -8 -2 0 1.96 0.33 -8 -2 0 1.66 0.30 8 2 0 1.79 0.28 8 2 0 1.97 0.28 8 2 0 1.62 0.28 8 2 0 1.85 0.27 8 2 0 1.74 0.36 8 2 0 1.03 0.31 -9 -2 0 28.13 1.24 -9 -2 0 28.41 1.21 -9 -2 0 29.14 1.42 -9 -2 0 28.27 1.35 9 2 0 27.42 1.14 9 2 0 26.49 1.08 9 2 0 30.20 1.29 9 2 0 29.43 1.35 9 2 0 29.05 1.10 9 2 0 27.99 1.14 -10 -2 0 3.05 0.44 -10 -2 0 2.78 0.53 -10 -2 0 3.04 0.47 10 2 0 3.46 0.53 10 2 0 3.44 0.39 10 2 0 3.13 0.41 10 2 0 4.07 0.54 -11 -2 0 2.62 0.47 -11 -2 0 2.92 0.56 -11 -2 0 3.48 0.49 11 2 0 3.98 0.57 11 2 0 3.37 0.45 11 2 0 3.64 0.57 11 2 0 3.22 0.41 11 2 0 2.93 0.51 12 -3 0 4.73 0.60 12 -3 0 3.49 0.52 12 -3 0 3.89 0.57 12 -3 0 4.25 0.61 12 -3 0 3.79 0.61 12 -3 0 4.36 0.59 -12 3 0 5.34 0.68 11 -3 0 18.49 1.09 11 -3 0 20.60 1.09 11 -3 0 19.92 1.19 11 -3 0 19.91 1.09 11 -3 0 18.80 1.10 11 -3 0 20.58 1.05 -11 3 0 17.87 0.99 -11 3 0 19.18 1.09 10 -3 0 31.07 1.42 10 -3 0 33.72 1.50 10 -3 0 31.98 1.43 10 -3 0 31.18 1.39 10 -3 0 30.59 1.37 -10 3 0 30.66 1.30 -10 3 0 30.22 1.38 9 -3 0 64.97 2.23 9 -3 0 63.85 2.27 9 -3 0 64.23 2.27 9 -3 0 62.92 2.29 -9 3 0 63.10 2.12 -9 3 0 64.73 2.23 -9 3 0 61.81 2.13 8 -3 0 85.15 2.73 8 -3 0 79.16 2.59 8 -3 0 84.11 2.71 -8 3 0 80.86 2.54 -8 3 0 83.29 2.68 -8 3 0 77.66 2.63 -8 3 0 82.81 2.70 -8 3 0 82.07 2.57 7 -3 0 74.58 2.38 7 -3 0 72.42 2.38 7 -3 0 72.45 2.35 7 -3 0 67.82 2.27 7 -3 0 72.80 2.35 -7 3 0 70.26 2.35 -7 3 0 74.70 2.40 -7 3 0 70.95 2.21 -7 3 0 72.51 2.26 -7 3 0 73.28 2.31 -7 3 0 72.80 2.33 6 -3 0 125.91 3.65 6 -3 0 120.39 3.64 6 -3 0 121.12 3.56 6 -3 0 124.67 3.64 6 -3 0 112.12 3.60 6 -3 0 121.15 3.61 6 -3 0 126.24 3.65 -6 3 0 123.12 3.59 -6 3 0 128.41 3.68 -6 3 0 121.36 3.48 -6 3 0 120.61 3.54 -6 3 0 122.13 3.61 -6 3 0 124.64 3.65 5 -3 0 191.12 5.53 5 -3 0 197.50 5.56 5 -3 0 193.35 5.51 5 -3 0 195.13 5.54 5 -3 0 204.66 5.57 5 -3 0 193.16 5.48 5 -3 0 195.50 5.53 -5 3 0 195.89 5.49 -5 3 0 203.57 5.57 -5 3 0 197.60 5.52 -5 3 0 195.55 5.39 -5 3 0 205.09 5.59 -5 3 0 191.70 5.45 4 -3 0 179.30 4.82 4 -3 0 169.24 4.74 4 -3 0 167.81 4.80 4 -3 0 170.49 4.82 4 -3 0 173.02 4.81 4 -3 0 172.04 4.79 -4 3 0 169.73 4.75 -4 3 0 168.51 4.73 -4 3 0 157.06 4.63 -4 3 0 165.74 4.77 -4 3 0 176.79 4.79 -4 3 0 176.60 4.84 -4 3 0 175.58 4.82 3 -3 0 45.36 1.42 3 -3 0 43.80 1.43 3 -3 0 45.50 1.44 3 -3 0 43.37 1.26 3 -3 0 45.48 1.39 -3 3 0 46.17 1.40 -3 3 0 44.86 1.41 -3 3 0 46.11 1.45 -3 3 0 43.80 1.41 -3 3 0 44.79 1.26 -3 3 0 45.08 1.44 -3 3 0 44.53 1.37 2 -3 0 177.37 4.97 2 -3 0 183.77 4.97 2 -3 0 186.23 4.97 2 -3 0 182.05 4.94 2 -3 0 161.76 4.92 2 -3 0 182.99 4.97 -2 3 0 186.79 4.98 -2 3 0 175.75 4.96 -2 3 0 176.86 4.96 -2 3 0 177.94 4.98 -2 3 0 189.21 4.96 -2 3 0 185.05 4.93 1 -3 0 0.61 0.13 1 -3 0 0.42 0.13 1 -3 0 0.26 0.13 1 -3 0 0.51 0.12 1 -3 0 0.46 0.13 1 -3 0 0.76 0.17 -1 3 0 0.41 0.12 -1 3 0 0.46 0.07 -1 3 0 0.55 0.14 -1 3 0 0.37 0.13 -1 3 0 0.42 0.15 -1 3 0 0.56 0.07 -1 3 0 0.48 0.13 -1 3 0 0.30 0.11 0 -3 0 422.26 10.84 0 -3 0 417.22 10.84 0 -3 0 415.20 10.85 0 -3 0 419.51 10.94 0 -3 0 411.46 10.90 0 -3 0 364.18 10.86 0 -3 0 414.35 10.94 0 -3 0 412.76 10.90 0 3 0 413.59 10.91 0 3 0 405.03 10.89 0 3 0 407.69 10.94 0 3 0 391.64 10.92 0 3 0 393.45 10.84 0 3 0 412.12 10.90 -1 -3 0 76.12 2.15 -1 -3 0 74.48 2.09 -1 -3 0 73.50 2.07 -1 -3 0 70.81 2.14 -1 -3 0 74.49 2.08 -1 -3 0 74.96 1.97 -1 -3 0 72.35 2.06 1 3 0 64.09 2.06 1 3 0 73.94 2.07 1 3 0 73.12 2.15 1 3 0 70.76 2.13 1 3 0 73.02 2.11 -2 -3 0 102.53 2.91 -2 -3 0 105.49 2.94 -2 -3 0 104.04 3.02 -2 -3 0 102.87 2.98 -2 -3 0 105.06 2.91 -2 -3 0 104.50 3.03 2 3 0 105.02 2.91 2 3 0 103.04 2.93 2 3 0 103.92 2.98 2 3 0 106.03 3.03 -3 -3 0 299.07 8.77 -3 -3 0 329.99 8.91 -3 -3 0 326.36 8.81 -3 -3 0 324.42 8.93 -3 -3 0 335.96 8.96 -3 -3 0 331.05 8.84 3 3 0 319.57 8.93 3 3 0 326.41 8.88 3 3 0 336.34 8.95 3 3 0 332.85 8.83 3 3 0 328.69 8.79 -4 -3 0 148.30 4.16 -4 -3 0 152.99 4.24 -4 -3 0 146.90 4.32 -4 -3 0 151.21 4.36 -4 -3 0 150.51 4.20 -4 -3 0 148.40 4.32 4 3 0 156.16 4.37 4 3 0 147.40 4.35 4 3 0 150.24 4.28 4 3 0 151.06 4.18 4 3 0 149.45 4.22 -5 -3 0 138.55 3.90 -5 -3 0 139.89 3.94 -5 -3 0 132.34 4.07 -5 -3 0 132.36 4.02 -5 -3 0 140.26 4.05 5 3 0 134.76 3.74 5 3 0 140.21 3.75 5 3 0 138.42 3.86 5 3 0 137.87 3.98 5 3 0 138.86 3.86 5 3 0 140.51 4.07 5 3 0 132.66 4.05 5 3 0 131.69 3.91 -6 -3 0 12.89 0.74 -6 -3 0 11.70 0.75 -6 -3 0 12.28 0.64 -6 -3 0 11.05 0.60 6 3 0 12.07 0.49 6 3 0 11.31 0.61 6 3 0 11.75 0.73 6 3 0 11.31 0.66 6 3 0 11.68 0.56 6 3 0 12.09 0.59 6 3 0 11.86 0.49 -7 -3 0 50.80 1.92 -7 -3 0 53.27 1.78 -7 -3 0 45.21 1.68 -7 -3 0 52.86 1.90 7 3 0 51.84 1.82 7 3 0 52.82 1.57 7 3 0 46.25 1.87 7 3 0 51.96 1.67 7 3 0 50.63 1.66 7 3 0 51.17 1.56 7 3 0 51.20 1.89 -8 -3 0 1.82 0.40 -8 -3 0 1.87 0.34 -8 -3 0 0.93 0.36 -8 -3 0 1.61 0.31 8 3 0 1.80 0.24 8 3 0 2.02 0.36 8 3 0 1.38 0.21 8 3 0 1.37 0.26 8 3 0 1.56 0.38 8 3 0 0.96 0.23 -9 -3 0 0.60 0.34 -9 -3 0 1.30 0.31 -9 -3 0 1.05 0.30 -9 -3 0 0.94 0.33 9 3 0 1.47 0.23 9 3 0 0.89 0.36 9 3 0 1.36 0.27 9 3 0 1.25 0.34 9 3 0 1.36 0.27 9 3 0 1.04 0.20 -10 -3 0 13.75 1.02 -10 -3 0 10.44 0.79 -10 -3 0 11.16 0.76 10 3 0 11.88 0.90 10 3 0 11.45 0.68 10 3 0 11.82 0.95 10 3 0 11.72 0.84 10 3 0 10.61 0.56 12 -4 0 3.29 0.48 12 -4 0 2.44 0.51 12 -4 0 2.37 0.45 12 -4 0 2.56 0.48 12 -4 0 3.64 0.61 12 -4 0 3.11 0.49 -12 4 0 3.08 0.49 -12 4 0 2.74 0.51 11 -4 0 13.48 0.94 11 -4 0 14.03 0.83 11 -4 0 13.82 0.88 11 -4 0 13.48 0.90 11 -4 0 12.29 0.91 11 -4 0 14.81 1.00 -11 4 0 13.90 0.94 -11 4 0 12.24 0.81 10 -4 0 25.55 1.29 10 -4 0 25.49 1.28 10 -4 0 26.21 1.29 10 -4 0 24.86 1.20 -10 4 0 26.02 1.25 -10 4 0 24.73 1.14 -10 4 0 25.21 1.26 9 -4 0 32.03 1.40 9 -4 0 32.64 1.41 9 -4 0 32.03 1.41 -9 4 0 30.36 1.34 -9 4 0 29.83 1.19 -9 4 0 32.54 1.39 -9 4 0 30.44 1.26 -9 4 0 29.93 1.30 8 -4 0 66.55 2.30 8 -4 0 72.30 2.43 8 -4 0 72.11 2.41 -8 4 0 68.81 2.27 -8 4 0 70.54 2.43 -8 4 0 72.45 2.41 -8 4 0 70.87 2.37 -8 4 0 71.66 2.33 -8 4 0 69.60 2.19 7 -4 0 1.37 0.25 7 -4 0 1.79 0.31 7 -4 0 1.59 0.32 7 -4 0 1.36 0.28 -7 4 0 1.75 0.32 -7 4 0 2.16 0.26 -7 4 0 1.81 0.34 -7 4 0 1.41 0.28 -7 4 0 1.55 0.26 -7 4 0 2.11 0.30 6 -4 0 97.03 3.19 6 -4 0 109.71 3.21 6 -4 0 107.60 3.22 6 -4 0 97.62 3.14 6 -4 0 105.37 3.12 6 -4 0 104.96 3.21 6 -4 0 107.88 3.24 -6 4 0 111.99 3.25 -6 4 0 107.55 3.15 -6 4 0 106.19 2.99 -6 4 0 95.92 3.15 -6 4 0 111.68 3.27 -6 4 0 105.73 3.11 5 -4 0 22.85 0.96 5 -4 0 23.06 0.95 5 -4 0 24.10 0.98 5 -4 0 23.33 0.90 5 -4 0 22.64 0.96 5 -4 0 23.72 0.97 -5 4 0 23.25 0.93 -5 4 0 23.39 0.77 -5 4 0 24.41 0.96 -5 4 0 25.12 1.00 -5 4 0 23.42 0.89 -5 4 0 24.81 1.00 -5 4 0 24.96 0.93 4 -4 0 223.35 6.33 4 -4 0 231.27 6.34 4 -4 0 228.87 6.34 4 -4 0 232.11 6.32 4 -4 0 228.36 6.35 4 -4 0 217.24 6.09 4 -4 0 226.94 6.27 -4 4 0 225.43 6.09 -4 4 0 220.06 6.29 -4 4 0 227.65 6.36 -4 4 0 231.66 6.36 -4 4 0 226.87 6.28 -4 4 0 227.82 6.25 -4 4 0 235.92 6.32 3 -4 0 128.96 3.77 3 -4 0 131.13 3.81 3 -4 0 131.05 3.81 3 -4 0 139.25 3.83 3 -4 0 134.16 3.81 3 -4 0 132.20 3.77 -3 4 0 138.38 3.83 -3 4 0 133.22 3.75 -3 4 0 131.60 3.83 -3 4 0 135.50 3.81 -3 4 0 131.32 3.79 -3 4 0 135.64 3.78 2 -4 0 186.62 5.24 2 -4 0 196.71 5.26 2 -4 0 188.08 5.23 2 -4 0 192.07 5.23 2 -4 0 186.68 5.26 2 -4 0 187.97 5.26 -2 4 0 188.97 5.27 -2 4 0 195.10 5.25 -2 4 0 191.56 5.25 -2 4 0 183.84 5.24 -2 4 0 188.23 5.26 1 -4 0 594.67 15.57 1 -4 0 594.75 15.64 1 -4 0 593.63 15.62 1 -4 0 585.73 15.61 1 -4 0 579.34 15.57 1 -4 0 578.78 15.60 -1 4 0 602.75 15.57 -1 4 0 578.59 15.61 -1 4 0 566.76 15.46 -1 4 0 575.16 15.46 -1 4 0 578.94 15.62 -1 4 0 588.20 15.63 -1 4 0 583.85 15.59 -1 4 0 560.42 15.58 0 -4 0 659.40 17.51 0 -4 0 665.23 17.59 0 -4 0 670.43 17.52 0 -4 0 648.40 17.59 0 -4 0 659.90 17.65 0 -4 0 662.62 17.57 0 -4 0 659.72 17.64 0 4 0 644.14 17.64 0 4 0 658.16 17.59 0 4 0 654.02 17.65 0 4 0 666.45 17.60 0 4 0 659.61 17.61 -1 -4 0 395.02 10.77 -1 -4 0 401.31 10.69 -1 -4 0 405.02 10.55 -1 -4 0 401.72 10.68 -1 -4 0 395.95 10.66 -1 -4 0 395.44 10.68 -1 -4 0 399.38 10.55 -1 -4 0 391.11 10.76 1 4 0 397.50 10.68 1 4 0 400.40 10.78 1 4 0 403.94 10.69 1 4 0 382.56 10.75 1 4 0 393.06 10.72 -2 -4 0 13.04 0.58 -2 -4 0 12.48 0.52 -2 -4 0 12.94 0.52 -2 -4 0 12.34 0.54 -2 -4 0 12.39 0.62 -2 -4 0 11.29 0.60 2 4 0 12.38 0.53 2 4 0 11.87 0.52 2 4 0 12.04 0.62 2 4 0 11.92 0.61 2 4 0 12.39 0.58 -3 -4 0 234.04 6.72 -3 -4 0 246.33 6.62 -3 -4 0 242.07 6.58 -3 -4 0 242.26 6.75 -3 -4 0 243.56 6.69 -3 -4 0 239.97 6.55 3 4 0 239.66 6.67 3 4 0 229.99 6.71 3 4 0 235.91 6.60 3 4 0 247.19 6.75 3 4 0 245.03 6.57 -4 -4 0 -0.06 0.11 -4 -4 0 -0.14 0.10 -4 -4 0 -0.02 0.15 -4 -4 0 0.20 0.19 -4 -4 0 -0.05 0.14 -4 -4 0 -0.06 0.10 4 4 0 0.10 0.17 4 4 0 0.30 0.18 4 4 0 0.02 0.13 4 4 0 -0.08 0.12 4 4 0 -0.11 0.15 -5 -4 0 0.88 0.27 -5 -4 0 0.84 0.28 -5 -4 0 0.78 0.23 -5 -4 0 0.72 0.19 -5 -4 0 0.81 0.21 -5 -4 0 0.84 0.16 5 4 0 0.50 0.18 5 4 0 0.71 0.19 5 4 0 0.80 0.26 5 4 0 0.97 0.26 -6 -4 0 45.60 1.54 -6 -4 0 45.26 1.75 -6 -4 0 45.36 1.72 -6 -4 0 45.47 1.59 6 4 0 46.38 1.51 6 4 0 46.08 1.73 6 4 0 45.47 1.57 6 4 0 44.26 1.48 6 4 0 45.34 1.66 -7 -4 0 1.18 0.35 -7 -4 0 1.11 0.36 -7 -4 0 0.60 0.26 -7 -4 0 0.83 0.24 7 4 0 0.61 0.28 7 4 0 0.53 0.21 7 4 0 0.72 0.32 7 4 0 0.75 0.20 -8 -4 0 68.08 2.27 -8 -4 0 70.47 2.52 -8 -4 0 69.59 2.34 -8 -4 0 69.16 2.56 8 4 0 70.85 2.21 8 4 0 66.27 2.17 8 4 0 69.03 2.41 8 4 0 71.16 2.53 -9 -4 0 3.97 0.62 -9 -4 0 3.77 0.47 -9 -4 0 2.99 0.43 9 4 0 3.20 0.38 9 4 0 3.67 0.57 9 4 0 3.07 0.42 9 4 0 2.52 0.48 -10 -4 0 52.61 1.99 -10 -4 0 51.82 2.24 -10 -4 0 50.87 1.91 10 4 0 55.40 2.21 10 4 0 55.64 2.28 10 4 0 51.69 1.78 10 4 0 47.78 2.03 12 -5 0 20.54 1.26 12 -5 0 23.44 1.32 12 -5 0 21.48 1.26 12 -5 0 21.47 1.23 12 -5 0 18.89 1.12 12 -5 0 21.29 1.07 -12 5 0 20.23 1.11 -12 5 0 23.14 1.29 11 -5 0 13.16 0.95 11 -5 0 13.13 0.86 11 -5 0 12.14 0.93 11 -5 0 11.14 0.73 11 -5 0 12.08 0.93 -11 5 0 12.24 0.89 -11 5 0 12.55 0.81 10 -5 0 16.63 1.02 10 -5 0 16.54 0.81 10 -5 0 16.87 1.04 10 -5 0 15.94 1.00 -10 5 0 15.57 0.91 -10 5 0 16.86 1.02 -10 5 0 15.66 0.88 -10 5 0 15.33 0.97 9 -5 0 56.88 2.16 9 -5 0 57.38 2.12 9 -5 0 58.62 2.14 -9 5 0 56.56 2.02 -9 5 0 56.95 2.13 -9 5 0 55.51 1.97 -9 5 0 55.51 2.08 8 -5 0 18.69 0.98 8 -5 0 17.45 0.95 -8 5 0 17.74 0.89 -8 5 0 17.51 0.73 -8 5 0 16.58 0.92 -8 5 0 17.22 0.84 -8 5 0 17.27 0.95 -8 5 0 17.69 0.98 7 -5 0 0.34 0.23 7 -5 0 0.15 0.19 7 -5 0 -0.04 0.16 -7 5 0 0.47 0.24 -7 5 0 0.20 0.13 -7 5 0 0.23 0.17 -7 5 0 0.11 0.21 -7 5 0 0.43 0.24 -7 5 0 0.21 0.17 6 -5 0 94.37 2.96 6 -5 0 92.02 2.85 6 -5 0 95.91 2.94 6 -5 0 99.56 3.29 -6 5 0 94.75 2.88 -6 5 0 94.46 2.98 -6 5 0 93.93 2.85 -6 5 0 93.33 2.93 -6 5 0 90.47 2.65 -6 5 0 95.39 3.00 5 -5 0 4.45 0.37 5 -5 0 5.14 0.45 5 -5 0 4.63 0.40 5 -5 0 3.94 0.22 5 -5 0 4.84 0.42 5 -5 0 4.78 0.41 5 -5 0 4.52 0.44 -5 5 0 4.48 0.38 -5 5 0 5.11 0.45 -5 5 0 3.95 0.21 -5 5 0 4.54 0.39 -5 5 0 4.22 0.42 -5 5 0 4.40 0.37 4 -5 0 152.10 4.30 4 -5 0 147.01 4.30 4 -5 0 148.01 4.24 4 -5 0 148.16 4.31 4 -5 0 148.49 4.27 4 -5 0 149.28 4.30 -4 5 0 150.20 4.33 -4 5 0 153.69 4.27 -4 5 0 142.78 4.27 -4 5 0 145.49 4.21 -4 5 0 154.75 4.33 -4 5 0 145.37 4.27 3 -5 0 123.95 3.63 3 -5 0 123.46 3.64 3 -5 0 120.30 3.58 3 -5 0 129.80 3.64 3 -5 0 126.82 3.62 3 -5 0 120.73 3.58 -3 5 0 127.36 3.64 -3 5 0 125.06 3.65 -3 5 0 128.04 3.61 -3 5 0 125.46 3.58 -3 5 0 124.20 3.62 -3 5 0 123.34 3.62 2 -5 0 104.45 3.01 2 -5 0 105.17 3.02 2 -5 0 102.04 3.02 2 -5 0 106.30 3.05 2 -5 0 105.00 3.06 2 -5 0 102.43 3.04 -2 5 0 102.75 3.06 -2 5 0 98.52 3.02 -2 5 0 104.99 3.01 -2 5 0 103.92 3.06 -2 5 0 105.21 3.05 -2 5 0 105.88 3.03 1 -5 0 153.01 4.17 1 -5 0 150.39 4.19 1 -5 0 149.95 4.23 1 -5 0 152.28 4.26 1 -5 0 148.11 4.22 1 -5 0 146.93 4.24 -1 5 0 147.11 4.06 -1 5 0 153.19 4.24 -1 5 0 150.02 4.26 -1 5 0 147.26 4.25 -1 5 0 149.17 4.21 -1 5 0 146.03 4.21 0 -5 0 227.48 5.98 0 -5 0 221.80 6.14 0 -5 0 225.92 6.09 0 -5 0 216.09 5.97 0 -5 0 222.21 6.15 0 -5 0 225.33 6.05 0 -5 0 215.94 6.07 0 5 0 212.80 6.12 0 5 0 217.92 6.06 0 5 0 223.61 6.09 0 5 0 218.99 6.14 0 5 0 222.54 6.10 0 5 0 213.02 5.99 -1 -5 0 10.61 0.59 -1 -5 0 9.93 0.56 -1 -5 0 10.33 0.37 -1 -5 0 10.14 0.50 -1 -5 0 10.73 0.38 -1 -5 0 10.71 0.52 -1 -5 0 10.25 0.49 -1 -5 0 10.33 0.49 1 5 0 9.42 0.56 1 5 0 9.91 0.50 1 5 0 9.60 0.57 1 5 0 9.95 0.54 1 5 0 10.08 0.49 -2 -5 0 0.15 0.15 -2 -5 0 0.08 0.12 -2 -5 0 -0.12 0.14 -2 -5 0 0.02 0.13 -2 -5 0 -0.03 0.12 -2 -5 0 -0.06 0.11 2 5 0 -0.05 0.10 2 5 0 0.14 0.15 2 5 0 -0.02 0.15 2 5 0 0.00 0.14 2 5 0 0.06 0.12 -3 -5 0 23.91 0.93 -3 -5 0 25.54 0.89 -3 -5 0 25.19 0.99 -3 -5 0 24.94 1.06 -3 -5 0 24.49 0.90 -3 -5 0 24.49 1.03 3 5 0 23.74 0.98 3 5 0 23.46 0.91 3 5 0 25.43 0.90 3 5 0 25.36 1.06 -4 -5 0 16.26 0.72 -4 -5 0 15.41 0.68 -4 -5 0 15.20 0.78 -4 -5 0 15.66 0.84 -4 -5 0 14.86 0.63 4 5 0 14.17 0.68 4 5 0 16.84 0.85 4 5 0 15.76 0.67 4 5 0 15.72 0.78 -5 -5 0 34.90 1.24 -5 -5 0 34.36 1.17 -5 -5 0 35.17 1.40 -5 -5 0 34.86 1.45 -5 -5 0 34.71 1.28 5 5 0 34.71 1.21 5 5 0 34.03 1.35 5 5 0 35.60 1.44 5 5 0 33.55 1.25 -6 -5 0 60.45 2.15 -6 -5 0 55.88 1.92 -6 -5 0 61.18 2.21 -6 -5 0 59.95 1.99 6 5 0 61.37 2.19 6 5 0 59.94 2.08 6 5 0 59.84 1.89 6 5 0 58.51 1.86 6 5 0 58.12 1.98 -7 -5 0 1.28 0.41 -7 -5 0 1.32 0.37 -7 -5 0 1.37 0.28 -7 -5 0 1.48 0.31 7 5 0 1.42 0.37 7 5 0 1.38 0.37 7 5 0 1.18 0.26 7 5 0 1.38 0.23 -8 -5 0 31.81 1.29 -8 -5 0 35.54 1.62 -8 -5 0 32.28 1.34 8 5 0 31.64 1.21 8 5 0 32.78 1.45 8 5 0 30.94 1.18 8 5 0 32.41 1.54 -9 -5 0 25.89 1.23 -9 -5 0 28.57 1.52 -9 -5 0 25.77 1.18 9 5 0 27.78 1.44 9 5 0 27.93 1.37 9 5 0 29.93 1.52 9 5 0 26.77 1.08 11 -6 0 19.49 0.92 11 -6 0 19.97 1.20 11 -6 0 20.66 1.20 11 -6 0 19.91 1.24 -11 6 0 20.84 1.06 -11 6 0 21.33 1.22 10 -6 0 8.28 0.76 10 -6 0 7.26 0.72 10 -6 0 7.17 0.70 10 -6 0 6.53 0.49 -10 6 0 6.45 0.63 -10 6 0 7.18 0.70 -10 6 0 7.12 0.72 -10 6 0 8.17 0.63 9 -6 0 20.35 1.09 9 -6 0 18.71 1.08 9 -6 0 20.13 1.13 9 -6 0 18.45 0.78 -9 6 0 18.14 0.94 -9 6 0 18.67 1.09 -9 6 0 18.02 1.03 -9 6 0 18.45 0.99 8 -6 0 2.09 0.40 8 -6 0 1.67 0.38 -8 6 0 1.91 0.38 -8 6 0 2.31 0.43 -8 6 0 1.94 0.34 -8 6 0 1.75 0.35 -8 6 0 1.59 0.31 7 -6 0 14.91 0.76 7 -6 0 16.45 0.90 7 -6 0 14.92 0.85 -7 6 0 13.82 0.77 -7 6 0 15.58 0.90 -7 6 0 14.33 0.76 -7 6 0 16.79 0.91 6 -6 0 36.86 1.49 6 -6 0 38.38 1.42 6 -6 0 42.51 1.51 6 -6 0 41.23 1.55 6 -6 0 38.19 1.20 -6 6 0 37.56 1.45 -6 6 0 41.90 1.57 -6 6 0 41.83 1.57 -6 6 0 40.91 1.47 -6 6 0 41.03 1.44 5 -6 0 33.59 1.47 5 -6 0 33.03 1.25 5 -6 0 35.47 1.35 5 -6 0 34.18 1.31 5 -6 0 35.65 1.50 5 -6 0 35.13 1.35 5 -6 0 34.08 1.46 -5 6 0 34.98 1.30 -5 6 0 33.95 1.36 -5 6 0 35.64 1.37 -5 6 0 34.05 1.30 -5 6 0 35.41 1.26 4 -6 0 181.44 5.22 4 -6 0 182.79 5.28 4 -6 0 187.21 5.29 4 -6 0 187.08 5.29 4 -6 0 180.49 5.24 4 -6 0 183.88 5.30 -4 6 0 188.10 5.25 -4 6 0 182.90 5.21 -4 6 0 186.45 5.32 -4 6 0 193.57 5.32 -4 6 0 176.84 5.25 -4 6 0 180.33 5.26 3 -6 0 92.24 2.78 3 -6 0 93.88 2.78 3 -6 0 89.92 2.74 3 -6 0 86.00 2.76 3 -6 0 88.46 2.72 3 -6 0 88.43 2.72 -3 6 0 95.78 2.78 -3 6 0 91.02 2.72 -3 6 0 90.80 2.79 -3 6 0 85.89 2.73 -3 6 0 89.53 2.77 -3 6 0 93.65 2.76 2 -6 0 34.06 1.26 2 -6 0 33.53 1.18 2 -6 0 33.10 1.23 2 -6 0 36.37 1.25 2 -6 0 34.44 1.23 2 -6 0 34.97 1.21 -2 6 0 36.35 1.22 -2 6 0 34.87 1.26 -2 6 0 35.35 1.26 -2 6 0 32.37 0.99 -2 6 0 34.82 1.22 -2 6 0 33.23 1.25 -2 6 0 33.63 1.00 -2 6 0 33.11 1.21 1 -6 0 199.74 5.50 1 -6 0 196.60 5.45 1 -6 0 201.09 5.42 1 -6 0 195.54 5.53 1 -6 0 195.17 5.49 1 -6 0 195.17 5.41 1 -6 0 199.57 5.55 -1 6 0 198.57 5.51 -1 6 0 186.96 5.46 -1 6 0 194.37 5.49 -1 6 0 197.29 5.54 -1 6 0 191.99 5.31 -1 6 0 188.34 5.52 0 -6 0 12.54 0.51 0 -6 0 12.77 0.59 0 -6 0 13.20 0.52 0 -6 0 13.28 0.62 0 -6 0 11.98 0.67 0 -6 0 13.15 0.62 0 -6 0 12.25 0.65 0 6 0 12.18 0.59 0 6 0 11.42 0.64 0 6 0 12.71 0.62 0 6 0 12.55 0.54 0 6 0 13.16 0.64 0 6 0 13.48 0.68 -1 -6 0 54.26 1.73 -1 -6 0 53.65 1.83 -1 -6 0 54.19 1.56 -1 -6 0 56.39 1.76 -1 -6 0 54.36 1.71 -1 -6 0 54.28 1.57 -1 -6 0 55.29 1.85 1 6 0 53.95 1.73 1 6 0 54.31 1.73 1 6 0 52.29 1.82 1 6 0 54.49 1.79 1 6 0 54.75 1.85 -2 -6 0 35.76 1.36 -2 -6 0 36.88 1.23 -2 -6 0 36.35 1.26 -2 -6 0 32.41 1.34 -2 -6 0 36.79 1.22 -2 -6 0 35.88 1.27 2 6 0 31.68 1.33 2 6 0 36.75 1.25 2 6 0 37.58 1.24 2 6 0 34.65 1.30 2 6 0 34.78 1.34 -3 -6 0 26.36 1.01 -3 -6 0 27.65 1.19 -3 -6 0 27.48 1.00 -3 -6 0 27.84 1.11 -3 -6 0 28.93 1.07 3 6 0 27.62 1.12 3 6 0 27.30 1.03 3 6 0 26.76 1.18 3 6 0 27.75 1.02 -4 -6 0 14.28 0.65 -4 -6 0 15.59 0.71 -4 -6 0 15.23 0.74 -4 -6 0 15.42 0.82 -4 -6 0 15.92 0.89 4 6 0 14.87 0.71 4 6 0 15.37 0.69 4 6 0 15.63 0.82 4 6 0 15.88 0.88 -5 -6 0 104.32 3.27 -5 -6 0 96.31 3.10 -5 -6 0 104.23 3.08 -5 -6 0 97.63 2.98 5 6 0 99.92 3.09 5 6 0 105.34 3.03 5 6 0 105.26 3.35 5 6 0 105.88 3.25 -6 -6 0 15.31 0.92 -6 -6 0 16.40 0.78 -6 -6 0 14.43 0.67 -6 -6 0 15.05 0.97 -6 -6 0 15.76 0.81 6 6 0 15.90 0.73 6 6 0 15.72 0.91 6 6 0 15.98 0.98 -7 -6 0 6.51 0.72 -7 -6 0 6.41 0.55 -7 -6 0 6.41 0.52 7 6 0 6.09 0.70 7 6 0 6.26 0.44 7 6 0 6.35 0.48 7 6 0 6.72 0.64 -8 -6 0 13.66 1.03 -8 -6 0 13.30 0.77 -8 -6 0 13.24 0.81 8 6 0 14.35 1.00 8 6 0 14.16 1.02 8 6 0 13.05 0.79 8 6 0 13.71 0.92 8 6 0 12.83 0.67 -9 -6 0 0.35 0.22 -9 -6 0 -0.28 0.21 -9 -6 0 0.33 0.33 9 6 0 0.23 0.32 9 6 0 -0.11 0.26 9 6 0 -0.22 0.18 9 6 0 0.23 0.33 11 -7 0 0.07 0.29 11 -7 0 -0.24 0.27 11 -7 0 0.11 0.32 11 -7 0 0.34 0.20 11 -7 0 -0.39 0.24 -11 7 0 0.06 0.27 -11 7 0 0.16 0.27 -11 7 0 0.74 0.31 10 -7 0 34.63 1.57 10 -7 0 35.93 1.67 10 -7 0 32.84 1.17 10 -7 0 33.53 1.60 10 -7 0 30.95 1.52 -10 7 0 32.69 1.46 -10 7 0 34.60 1.62 -10 7 0 33.43 1.44 9 -7 0 1.21 0.39 9 -7 0 0.23 0.29 9 -7 0 0.83 0.34 9 -7 0 0.96 0.35 -9 7 0 0.43 0.33 -9 7 0 0.93 0.31 -9 7 0 0.79 0.30 8 -7 0 91.90 3.06 8 -7 0 92.66 3.06 8 -7 0 88.99 2.59 8 -7 0 93.07 3.10 8 -7 0 94.75 3.15 -8 7 0 91.49 2.99 -8 7 0 92.75 2.95 -8 7 0 91.45 3.12 7 -7 0 58.96 2.11 7 -7 0 57.58 2.12 7 -7 0 59.71 2.10 -7 7 0 59.68 2.05 -7 7 0 58.06 2.16 -7 7 0 56.72 1.99 -7 7 0 58.79 2.17 6 -7 0 92.41 2.98 6 -7 0 85.96 2.86 6 -7 0 93.52 2.96 6 -7 0 89.84 2.92 -6 7 0 94.00 3.01 -6 7 0 91.62 3.00 -6 7 0 92.79 2.86 -6 7 0 92.46 2.90 5 -7 0 25.85 1.14 5 -7 0 25.44 1.14 5 -7 0 27.09 1.13 5 -7 0 26.28 1.08 -5 7 0 27.63 1.19 -5 7 0 27.40 1.18 -5 7 0 25.90 1.11 -5 7 0 23.72 1.08 -5 7 0 27.11 1.08 4 -7 0 104.28 3.22 4 -7 0 108.23 3.22 4 -7 0 104.77 3.25 4 -7 0 108.45 3.26 4 -7 0 101.16 3.18 -4 7 0 107.21 3.29 -4 7 0 102.42 3.22 -4 7 0 103.14 3.17 -4 7 0 105.40 3.24 -4 7 0 108.81 3.24 3 -7 0 29.40 1.10 3 -7 0 25.91 1.06 3 -7 0 26.92 1.08 3 -7 0 27.37 1.12 3 -7 0 29.47 1.15 3 -7 0 24.67 1.09 -3 7 0 28.48 1.09 -3 7 0 29.61 1.14 -3 7 0 27.06 1.12 -3 7 0 24.09 1.10 -3 7 0 27.76 1.10 2 -7 0 9.71 0.56 2 -7 0 9.37 0.57 2 -7 0 9.89 0.58 2 -7 0 10.05 0.63 2 -7 0 9.67 0.53 2 -7 0 10.56 0.56 2 -7 0 9.74 0.58 -2 7 0 9.07 0.38 -2 7 0 10.12 0.62 -2 7 0 10.02 0.57 -2 7 0 9.83 0.60 -2 7 0 10.15 0.61 -2 7 0 10.11 0.57 1 -7 0 232.91 6.47 1 -7 0 230.34 6.57 1 -7 0 237.95 6.65 1 -7 0 244.47 6.60 1 -7 0 233.56 6.53 1 -7 0 241.48 6.48 1 -7 0 227.27 6.61 -1 7 0 239.87 6.60 -1 7 0 232.40 6.38 -1 7 0 238.66 6.59 -1 7 0 228.70 6.63 -1 7 0 243.03 6.66 -1 7 0 218.13 6.54 0 -7 0 -0.02 0.19 0 -7 0 0.11 0.16 0 -7 0 0.14 0.11 0 -7 0 -0.01 0.16 0 -7 0 0.09 0.12 0 -7 0 0.07 0.18 0 7 0 0.23 0.17 0 7 0 -0.01 0.17 0 7 0 -0.22 0.15 0 7 0 -0.09 0.11 0 7 0 0.32 0.20 0 7 0 0.12 0.15 -1 -7 0 137.47 4.04 -1 -7 0 135.38 3.87 -1 -7 0 136.14 3.91 -1 -7 0 134.61 3.68 -1 -7 0 133.70 3.89 -1 -7 0 131.80 3.68 1 7 0 132.03 3.85 1 7 0 135.41 3.97 1 7 0 121.68 3.86 1 7 0 136.37 3.90 1 7 0 136.08 4.04 -2 -7 0 15.33 0.74 -2 -7 0 14.86 0.70 -2 -7 0 14.96 0.70 -2 -7 0 17.00 0.88 2 7 0 14.03 0.69 2 7 0 15.16 0.73 2 7 0 14.29 0.70 2 7 0 14.02 0.82 2 7 0 14.34 0.78 -3 -7 0 101.02 3.24 -3 -7 0 105.66 3.08 -3 -7 0 98.98 2.99 -3 -7 0 101.53 3.01 3 7 0 97.12 3.03 3 7 0 101.15 3.16 3 7 0 101.62 3.01 3 7 0 96.80 3.22 -4 -7 0 46.59 1.55 -4 -7 0 47.59 1.84 -4 -7 0 45.66 1.59 -4 -7 0 48.09 1.66 4 7 0 44.54 1.62 4 7 0 46.33 1.57 4 7 0 47.35 1.84 4 7 0 46.80 1.76 -5 -7 0 49.63 1.65 -5 -7 0 49.71 1.78 -5 -7 0 49.96 2.00 -5 -7 0 50.37 1.73 5 7 0 51.30 2.00 5 7 0 50.54 1.68 5 7 0 53.63 1.93 -6 -7 0 45.35 1.59 -6 -7 0 45.51 1.89 -6 -7 0 41.24 1.45 -6 -7 0 45.15 1.64 6 7 0 42.45 1.74 6 7 0 43.08 1.84 6 7 0 41.82 1.78 6 7 0 43.44 1.50 -7 -7 0 11.25 0.93 -7 -7 0 10.56 0.66 -7 -7 0 10.66 0.70 7 7 0 11.36 0.88 7 7 0 10.88 0.60 7 7 0 9.91 0.57 7 7 0 10.31 0.86 7 7 0 11.24 0.84 -8 -7 0 7.66 0.64 -8 -7 0 8.31 0.86 -8 -7 0 6.90 0.59 8 7 0 8.59 0.78 8 7 0 8.81 0.83 8 7 0 9.37 0.55 8 7 0 8.08 0.85 11 -8 0 5.44 0.74 11 -8 0 5.25 0.73 11 -8 0 5.71 0.78 11 -8 0 5.19 0.74 -11 8 0 4.47 0.69 -11 8 0 4.65 0.61 -11 8 0 5.76 0.62 10 -8 0 39.93 1.78 10 -8 0 40.64 1.82 10 -8 0 42.11 1.79 10 -8 0 39.41 1.85 -10 8 0 39.09 1.63 -10 8 0 37.37 1.81 -10 8 0 38.94 1.66 9 -8 0 1.39 0.38 9 -8 0 1.94 0.44 9 -8 0 1.47 0.43 9 -8 0 2.00 0.45 -9 8 0 2.14 0.40 -9 8 0 1.71 0.44 -9 8 0 1.59 0.37 8 -8 0 46.98 1.93 8 -8 0 47.18 1.91 8 -8 0 47.52 1.88 8 -8 0 47.03 1.86 -8 8 0 45.99 1.80 -8 8 0 46.88 1.94 -8 8 0 46.75 1.77 7 -8 0 12.05 0.80 7 -8 0 11.26 0.83 7 -8 0 12.77 0.85 7 -8 0 12.21 0.84 -7 8 0 11.10 0.72 -7 8 0 11.91 0.86 -7 8 0 12.19 0.77 6 -8 0 69.84 2.40 6 -8 0 70.73 2.45 6 -8 0 69.27 2.42 -6 8 0 71.33 2.39 -6 8 0 71.14 2.34 -6 8 0 69.33 2.48 5 -8 0 17.08 0.92 5 -8 0 17.23 0.93 5 -8 0 17.23 0.89 5 -8 0 16.13 0.90 -5 8 0 18.24 0.87 -5 8 0 16.68 0.93 -5 8 0 16.80 0.88 4 -8 0 13.13 0.77 4 -8 0 12.70 0.75 4 -8 0 13.66 0.81 4 -8 0 13.64 0.76 -4 8 0 14.29 0.79 -4 8 0 14.37 0.82 -4 8 0 13.00 0.74 3 -8 0 12.91 0.73 3 -8 0 14.50 0.78 3 -8 0 14.50 0.81 3 -8 0 14.35 0.72 3 -8 0 14.62 0.74 -3 8 0 14.92 0.80 -3 8 0 14.07 0.96 -3 8 0 13.53 0.74 -3 8 0 14.65 0.81 2 -8 0 2.57 0.33 2 -8 0 2.79 0.31 2 -8 0 3.35 0.45 2 -8 0 2.50 0.35 2 -8 0 2.39 0.32 2 -8 0 2.77 0.37 -2 8 0 2.64 0.38 -2 8 0 3.20 0.39 -2 8 0 2.76 0.21 -2 8 0 2.56 0.39 1 -8 0 49.43 1.76 1 -8 0 57.08 1.85 1 -8 0 53.70 1.71 1 -8 0 52.16 1.81 1 -8 0 55.03 1.72 1 -8 0 53.86 1.90 -1 8 0 53.60 1.85 -1 8 0 50.96 1.79 -1 8 0 53.02 1.62 -1 8 0 55.82 1.92 -1 8 0 48.28 1.81 0 -8 0 94.82 2.82 0 -8 0 89.71 2.84 0 -8 0 88.86 2.67 0 -8 0 93.39 2.68 0 -8 0 93.95 2.97 0 -8 0 85.70 2.83 0 8 0 93.08 2.97 0 8 0 89.77 2.82 0 8 0 93.88 2.91 0 8 0 95.52 2.87 0 8 0 91.53 2.72 -1 -8 0 24.58 1.14 -1 -8 0 23.81 0.99 -1 -8 0 23.68 1.02 -1 -8 0 23.91 0.81 -1 -8 0 24.30 1.01 -1 -8 0 23.61 0.80 1 8 0 24.10 1.08 1 8 0 23.25 0.96 1 8 0 25.59 1.04 1 8 0 24.61 1.14 1 8 0 22.48 0.98 -2 -8 0 45.75 1.69 -2 -8 0 46.94 1.70 -2 -8 0 53.65 1.94 -2 -8 0 53.38 1.79 2 8 0 50.91 1.92 2 8 0 50.91 1.76 2 8 0 50.25 1.85 2 8 0 52.59 1.74 2 8 0 52.00 1.94 -3 -8 0 22.15 0.99 -3 -8 0 22.12 1.14 -3 -8 0 20.42 0.93 -3 -8 0 19.03 0.89 3 8 0 21.95 0.94 3 8 0 21.18 1.01 3 8 0 22.28 1.14 3 8 0 21.38 1.06 -4 -8 0 22.09 0.98 -4 -8 0 24.95 1.10 -4 -8 0 25.77 1.06 -4 -8 0 25.86 1.29 4 8 0 25.91 1.29 4 8 0 24.42 1.02 4 8 0 25.29 1.18 4 8 0 26.21 1.22 -5 -8 0 -0.02 0.17 -5 -8 0 0.52 0.25 -5 -8 0 0.55 0.24 -5 -8 0 0.56 0.34 5 8 0 0.19 0.20 5 8 0 0.28 0.28 5 8 0 0.39 0.29 5 8 0 0.57 0.32 -6 -8 0 22.44 1.05 -6 -8 0 22.12 1.29 -6 -8 0 19.56 0.87 -6 -8 0 21.66 1.00 6 8 0 21.06 1.20 6 8 0 23.59 1.29 6 8 0 22.11 1.18 6 8 0 22.22 0.94 -7 -8 0 12.64 0.74 -7 -8 0 12.68 1.02 -7 -8 0 11.64 0.76 7 8 0 11.00 0.93 7 8 0 12.53 0.98 7 8 0 11.25 0.63 7 8 0 11.97 0.90 -8 -8 0 1.45 0.31 -8 -8 0 1.18 0.34 -8 -8 0 1.48 0.51 8 8 0 0.73 0.22 8 8 0 1.15 0.45 8 8 0 1.27 0.44 11 -9 0 1.42 0.47 11 -9 0 2.08 0.53 11 -9 0 2.08 0.52 11 -9 0 2.38 0.55 -11 9 0 2.15 0.45 -11 9 0 1.77 0.43 -11 9 0 1.44 0.44 10 -9 0 31.59 1.61 10 -9 0 32.95 1.58 10 -9 0 32.76 1.68 10 -9 0 31.23 1.57 -10 9 0 33.28 1.68 -10 9 0 31.05 1.47 -10 9 0 33.03 1.48 9 -9 0 2.21 0.50 9 -9 0 2.86 0.53 9 -9 0 1.96 0.45 9 -9 0 2.28 0.50 -9 9 0 3.52 0.58 -9 9 0 1.65 0.41 -9 9 0 2.92 0.48 8 -9 0 12.04 0.88 8 -9 0 10.46 0.86 8 -9 0 11.69 0.90 8 -9 0 13.78 0.92 -8 9 0 12.33 0.83 -8 9 0 13.55 0.83 -8 9 0 12.34 0.94 7 -9 0 -0.08 0.23 7 -9 0 -0.05 0.22 7 -9 0 0.23 0.29 7 -9 0 0.02 0.25 -7 9 0 0.30 0.28 -7 9 0 0.33 0.22 -7 9 0 -0.09 0.18 6 -9 0 14.66 0.92 6 -9 0 13.95 0.89 6 -9 0 13.85 0.90 6 -9 0 15.13 0.89 -6 9 0 14.00 0.94 -6 9 0 16.35 0.88 5 -9 0 9.47 0.71 5 -9 0 9.56 0.69 5 -9 0 8.82 0.67 5 -9 0 9.85 0.74 -5 9 0 10.09 0.75 -5 9 0 9.11 0.68 -5 9 0 9.52 0.67 4 -9 0 0.18 0.22 4 -9 0 0.04 0.24 4 -9 0 -0.02 0.18 -4 9 0 -0.07 0.18 -4 9 0 0.07 0.20 -4 9 0 0.05 0.22 3 -9 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1.64 0.51 0 10 -16 0.73 0.23 0 10 -16 0.88 0.43 0 -10 16 0.74 0.35 0 -10 16 0.68 0.38 3 9 -16 41.04 1.63 3 9 -16 41.35 1.89 3 9 -16 38.46 1.65 3 9 -16 37.67 1.88 -3 -9 16 38.65 1.82 -3 -9 16 36.89 1.45 2 9 -16 1.07 0.41 2 9 -16 1.63 0.28 2 9 -16 1.40 0.35 2 9 -16 0.71 0.30 2 9 -16 1.50 0.47 2 9 -16 1.94 0.30 -2 -9 16 1.61 0.43 -2 -9 16 1.24 0.36 1 9 -16 23.90 1.06 1 9 -16 24.16 1.03 1 9 -16 23.38 1.06 1 9 -16 25.35 1.08 1 9 -16 25.20 1.41 1 9 -16 25.54 1.46 -1 -9 16 23.31 1.17 -1 -9 16 25.27 1.36 0 9 -16 0.94 0.22 0 9 -16 0.43 0.39 0 9 -16 0.40 0.19 0 9 -16 0.42 0.37 0 9 -16 -0.12 0.23 0 9 -16 0.38 0.27 0 -9 16 0.59 0.33 0 -9 16 0.22 0.32 -1 9 -16 10.69 0.99 -1 9 -16 11.04 0.88 -1 9 -16 9.78 0.78 -1 9 -16 12.53 0.82 1 -9 16 11.00 0.89 1 -9 16 9.21 0.84 4 8 -16 26.28 1.52 4 8 -16 26.97 1.35 4 8 -16 26.55 1.28 4 8 -16 26.16 1.47 -4 -8 16 24.72 1.44 3 8 -16 27.01 1.49 3 8 -16 24.37 0.98 3 8 -16 26.92 1.51 3 8 -16 25.25 0.97 3 8 -16 26.41 1.21 3 8 -16 25.94 1.28 -3 -8 16 28.24 1.49 2 8 -16 -0.26 0.31 2 8 -16 0.29 0.20 2 8 -16 0.11 0.31 2 8 -16 0.20 0.24 2 8 -16 0.08 0.21 2 8 -16 0.20 0.22 -2 -8 16 -0.01 0.22 -2 -8 16 -0.20 0.25 1 8 -16 13.79 0.70 1 8 -16 12.38 0.97 1 8 -16 13.89 0.80 1 8 -16 11.85 1.02 1 8 -16 12.82 0.73 1 8 -16 12.19 0.75 -1 -8 16 13.09 0.82 -1 -8 16 12.10 0.96 0 8 -16 5.81 0.43 0 8 -16 6.50 0.80 0 8 -16 4.91 0.38 0 8 -16 5.86 0.61 0 8 -16 6.21 0.74 0 8 -16 6.10 0.59 0 -8 16 5.96 0.72 0 -8 16 5.65 0.64 -1 8 -16 1.22 0.46 -1 8 -16 2.01 0.43 -1 8 -16 1.53 0.42 -1 8 -16 1.73 0.39 1 -8 16 1.61 0.43 1 -8 16 1.34 0.45 5 7 -16 9.80 0.95 5 7 -16 9.33 0.79 5 7 -16 8.64 0.89 5 7 -16 8.68 0.82 -5 -7 16 9.99 0.92 4 7 -16 0.36 0.35 4 7 -16 0.64 0.34 4 7 -16 0.28 0.16 4 7 -16 -0.03 0.18 4 7 -16 -0.23 0.21 4 7 -16 0.30 0.34 -4 -7 16 0.02 0.27 3 7 -16 12.77 0.80 3 7 -16 12.23 1.01 3 7 -16 12.40 1.02 3 7 -16 12.54 0.66 3 7 -16 11.97 0.84 3 7 -16 12.21 0.68 -3 -7 16 13.15 1.01 2 7 -16 7.01 0.55 2 7 -16 7.23 0.82 2 7 -16 6.90 0.78 2 7 -16 5.24 0.57 2 7 -16 6.71 0.54 2 7 -16 6.34 0.53 -2 -7 16 5.65 0.51 -2 -7 16 8.12 0.82 1 7 -16 12.47 0.78 1 7 -16 12.67 1.04 1 7 -16 12.87 0.68 1 7 -16 12.47 0.78 1 7 -16 11.84 0.71 1 7 -16 12.79 0.96 -1 -7 16 12.30 0.98 -1 -7 16 13.82 0.80 0 7 -16 20.66 0.85 0 7 -16 23.34 1.40 0 7 -16 20.09 0.80 0 7 -16 22.63 1.13 0 7 -16 20.99 1.18 0 7 -16 20.87 1.09 0 -7 16 19.43 1.07 0 -7 16 23.78 1.33 -1 7 -16 10.72 0.99 -1 7 -16 8.91 0.77 -1 7 -16 9.85 0.79 -1 7 -16 10.21 0.81 1 -7 16 9.40 0.87 1 -7 16 10.32 0.81 5 6 -16 24.41 1.43 5 6 -16 22.68 0.90 5 6 -16 23.75 1.42 5 6 -16 24.24 1.32 -5 -6 16 24.42 1.27 -5 -6 16 24.05 1.43 4 6 -16 6.44 0.71 4 6 -16 9.43 0.92 4 6 -16 9.99 0.58 4 6 -16 9.40 0.91 4 6 -16 9.27 0.55 -4 -6 16 7.88 0.86 3 6 -16 18.45 0.89 3 6 -16 18.22 0.89 3 6 -16 18.70 1.24 3 6 -16 18.74 1.04 3 6 -16 18.72 1.20 -3 -6 16 19.90 1.23 2 6 -16 34.75 1.48 2 6 -16 37.69 1.47 2 6 -16 40.07 1.87 2 6 -16 37.85 1.44 2 6 -16 37.81 1.74 2 6 -16 36.30 1.47 -2 -6 16 36.99 1.78 1 6 -16 19.23 0.87 1 6 -16 21.55 1.34 1 6 -16 20.53 1.19 1 6 -16 19.18 0.93 1 6 -16 20.76 1.05 1 6 -16 20.68 1.07 -1 -6 16 20.25 0.98 -1 -6 16 21.08 1.28 0 6 -16 29.91 1.60 0 6 -16 28.62 1.06 0 6 -16 27.84 1.36 0 6 -16 28.49 1.32 0 6 -16 25.03 1.29 0 6 -16 26.00 0.98 0 -6 16 28.35 1.51 0 -6 16 28.69 1.28 -1 6 -16 25.85 1.33 -1 6 -16 25.44 1.26 -1 6 -16 26.14 1.32 -1 6 -16 25.41 1.51 1 -6 16 25.05 1.27 1 -6 16 25.79 1.45 5 5 -16 29.99 1.64 5 5 -16 32.54 1.20 5 5 -16 29.36 1.15 5 5 -16 32.37 1.67 5 5 -16 33.35 1.58 -5 -5 16 32.39 1.68 -5 -5 16 31.07 1.48 4 5 -16 9.18 0.89 4 5 -16 9.67 0.61 4 5 -16 9.30 0.93 4 5 -16 9.93 0.63 4 5 -16 7.95 0.75 -4 -5 16 9.84 0.90 -4 -5 16 9.08 0.75 3 5 -16 16.79 0.90 3 5 -16 18.98 1.04 3 5 -16 17.73 0.92 3 5 -16 19.16 1.17 3 5 -16 17.81 1.23 -3 -5 16 18.84 1.22 -3 -5 16 18.30 0.98 2 5 -16 22.81 1.25 2 5 -16 20.35 1.33 2 5 -16 21.78 1.06 2 5 -16 20.73 1.05 2 5 -16 21.02 1.06 -2 -5 16 21.83 1.01 -2 -5 16 21.01 1.29 1 5 -16 10.73 0.98 1 5 -16 10.96 0.79 1 5 -16 11.55 0.86 1 5 -16 11.38 0.70 1 5 -16 11.17 0.80 -1 -5 16 13.88 1.04 -1 -5 16 11.36 0.71 0 5 -16 9.15 0.50 0 5 -16 10.74 0.80 0 5 -16 9.33 0.58 0 5 -16 9.31 0.95 0 5 -16 10.11 0.80 0 5 -16 10.68 0.80 0 -5 16 10.00 0.72 0 -5 16 11.16 0.95 -1 5 -16 3.11 0.46 -1 5 -16 4.11 0.59 -1 5 -16 3.91 0.67 -1 5 -16 4.54 0.59 1 -5 16 3.82 0.62 1 -5 16 2.86 0.51 5 4 -16 26.70 1.12 5 4 -16 26.27 1.42 5 4 -16 28.49 1.57 5 4 -16 25.41 1.49 5 4 -16 27.19 1.14 -5 -4 16 28.37 1.37 -5 -4 16 27.27 1.53 4 4 -16 6.30 0.79 4 4 -16 4.72 0.66 4 4 -16 5.33 0.65 4 4 -16 4.19 0.48 4 4 -16 4.18 0.51 -4 -4 16 6.35 0.62 -4 -4 16 4.71 0.69 3 4 -16 6.08 0.81 3 4 -16 6.83 0.60 3 4 -16 6.53 0.59 3 4 -16 7.20 0.68 3 4 -16 6.04 0.74 -3 -4 16 7.61 0.81 -3 -4 16 6.58 0.60 2 4 -16 0.77 0.32 2 4 -16 1.80 0.36 2 4 -16 1.21 0.35 2 4 -16 1.33 0.39 2 4 -16 0.68 0.39 -2 -4 16 1.47 0.32 -2 -4 16 1.08 0.42 1 4 -16 2.09 0.41 1 4 -16 1.06 0.31 1 4 -16 2.27 0.45 1 4 -16 1.32 0.47 1 4 -16 2.21 0.43 -1 -4 16 1.61 0.31 -1 -4 16 1.58 0.32 -1 -4 16 1.71 0.48 0 4 -16 11.22 0.65 0 4 -16 10.47 0.83 0 4 -16 10.98 0.83 0 4 -16 10.13 0.76 0 -4 16 10.33 0.74 0 -4 16 10.91 0.98 -1 4 -16 11.06 0.99 -1 4 -16 11.18 0.76 -1 4 -16 11.59 0.90 -1 4 -16 12.32 0.93 1 -4 16 12.75 0.87 1 -4 16 12.54 1.05 5 3 -16 12.30 1.02 5 3 -16 11.57 0.72 5 3 -16 11.89 0.76 5 3 -16 13.45 1.08 -5 -3 16 12.10 0.88 -5 -3 16 10.77 0.91 4 3 -16 13.73 0.84 4 3 -16 15.01 1.06 4 3 -16 15.68 0.89 4 3 -16 13.59 1.13 -4 -3 16 14.46 0.97 -4 -3 16 14.96 1.12 -4 -3 16 16.41 0.96 3 3 -16 6.10 0.70 3 3 -16 5.80 0.60 3 3 -16 6.30 0.63 3 3 -16 4.61 0.69 -3 -3 16 5.99 0.59 -3 -3 16 5.74 0.80 -3 -3 16 6.49 0.66 2 3 -16 8.64 0.79 2 3 -16 9.97 0.97 2 3 -16 10.73 0.79 2 3 -16 10.39 0.78 -2 -3 16 10.52 0.96 -2 -3 16 9.47 0.68 -2 -3 16 11.13 0.77 1 3 -16 -0.53 0.22 1 3 -16 0.03 0.28 1 3 -16 0.44 0.38 1 3 -16 0.21 0.26 -1 -3 16 -0.31 0.24 -1 -3 16 0.27 0.24 -1 -3 16 -0.06 0.32 0 3 -16 19.86 1.03 0 3 -16 20.52 1.17 0 3 -16 21.93 1.35 0 3 -16 20.03 1.17 0 -3 16 21.78 1.36 0 -3 16 17.93 0.83 0 -3 16 21.25 0.96 0 -3 16 19.64 1.02 4 2 -16 9.88 0.74 4 2 -16 10.71 0.79 4 2 -16 9.95 1.01 4 2 -16 10.59 0.90 -4 -2 16 9.39 0.77 3 2 -16 0.01 0.26 3 2 -16 -0.03 0.33 3 2 -16 0.10 0.27 3 2 -16 -0.21 0.26 -3 -2 16 0.40 0.28 -3 -2 16 0.32 0.26 2 2 -16 26.91 1.33 2 2 -16 26.65 1.52 2 2 -16 23.04 1.24 2 2 -16 25.04 1.30 -2 -2 16 24.60 1.14 -2 -2 16 24.86 1.22 -2 -2 16 27.45 1.52 1 2 -16 3.76 0.59 1 2 -16 2.38 0.45 1 2 -16 3.54 0.57 1 2 -16 3.92 0.69 -1 -2 16 3.47 0.62 -1 -2 16 2.71 0.44 -1 -2 16 4.16 0.47 0 0 0 0.00 0.00 ; _shelx_hkl_checksum 22316 _shelx_res_file ; TITL CC2107_0m_a.res in P-1 CC2107_0m.res created by SHELXL-2018/3 at 10:05:16 on 20-Jul-2021 REM Old TITL CC2107_0m in P-1 REM SHELXT solution in P-1: R1 0.067, Rweak 0.009, Alpha 0.055 REM 0.000 for 0 systematic absences, Orientation as input REM Formula found by SHELXT: C28 Mo O3 P CELL 0.71073 9.1719 11.7493 12.6049 113.083 99.148 99.380 ZERR 2.000 0.0005 0.0007 0.0007 0.002 0.002 0.002 LATT 1 SFAC C H MO O P UNIT 56 50 2 6 2 ACTA TEMP -103.150 SIZE 0.06 0.16 0.16 L.S. 10 BOND $H CONF LIST 4 FMAP 2 OMIT 0 1 0 OMIT 0 0 1 OMIT 0 -1 1 OMIT -1 -1 1 EQIV $1 -x+1, -y+1, -z+1 HTAB C12 O2_$1 EQIV $2 -x, -y+1, -z HTAB C6 O1_$2 PLAN 20 WGHT 0.022000 0.610800 FVAR 0.24428 MO1 3 0.218512 0.458127 0.239605 11.00000 0.02476 0.01872 = 0.01856 0.01018 0.00643 0.00571 P1 5 0.322464 0.693217 0.333703 11.00000 0.01821 0.01985 = 0.01678 0.00879 0.00409 0.00582 O1 4 0.226528 0.504132 0.012955 11.00000 0.04944 0.03486 = 0.02214 0.01553 0.00903 0.01067 O2 4 0.546865 0.482646 0.374041 11.00000 0.03969 0.04130 = 0.04073 0.02200 0.00141 0.01872 O3 4 0.237123 0.186161 0.087621 11.00000 0.06112 0.02304 = 0.05251 0.01182 0.02143 0.01169 C1 1 0.229496 0.489275 0.098615 11.00000 0.02629 0.02033 = 0.02143 0.00777 0.00481 0.00532 C2 1 0.427351 0.475552 0.322216 11.00000 0.03681 0.02465 = 0.02375 0.01290 0.00885 0.01315 C3 1 0.305154 0.295563 0.118879 11.00000 0.03991 0.02537 = 0.02306 0.01045 0.00726 0.01327 C4 1 0.447836 0.320804 0.074486 11.00000 0.04813 0.03544 = 0.03607 0.01124 0.01992 0.01882 AFIX 23 H4A 2 0.428632 0.366718 0.024555 11.00000 -1.20000 H4B 2 0.533049 0.377870 0.144096 11.00000 -1.20000 AFIX 0 C5 1 0.497045 0.202608 0.003278 11.00000 0.06309 0.04749 = 0.04106 0.00966 0.02183 0.02985 AFIX 137 H5A 2 0.420288 0.151328 -0.072025 11.00000 -1.50000 H5B 2 0.507534 0.152040 0.048824 11.00000 -1.50000 H5C 2 0.595154 0.227972 -0.013045 11.00000 -1.50000 AFIX 0 C6 1 -0.050437 0.420107 0.213814 11.00000 0.02477 0.04876 = 0.04945 0.03268 0.01044 0.00411 AFIX 13 H6 2 -0.121988 0.444525 0.162697 11.00000 -1.20000 AFIX 0 C7 1 0.016303 0.491816 0.336448 11.00000 0.03381 0.03354 = 0.04596 0.01832 0.02348 0.00907 AFIX 13 H7 2 0.001080 0.576933 0.387033 11.00000 -1.20000 AFIX 0 C8 1 0.097015 0.419224 0.378079 11.00000 0.04087 0.04114 = 0.02815 0.01937 0.01645 0.00563 AFIX 13 H8 2 0.146453 0.442892 0.463005 11.00000 -1.20000 AFIX 0 C9 1 0.083551 0.302362 0.280553 11.00000 0.04624 0.02902 = 0.04157 0.02363 0.01934 0.00707 AFIX 13 H9 2 0.118582 0.227614 0.284712 11.00000 -1.20000 AFIX 0 C10 1 -0.007918 0.302836 0.178500 11.00000 0.03781 0.03376 = 0.03362 0.01423 0.01089 -0.00709 AFIX 13 H10 2 -0.047308 0.228557 0.098522 11.00000 -1.20000 AFIX 0 C11 1 0.294839 0.773863 0.483734 11.00000 0.01980 0.02292 = 0.01887 0.00830 0.00484 0.00427 C12 1 0.325192 0.718902 0.562252 11.00000 0.03928 0.03094 = 0.02307 0.01359 0.00947 0.01368 AFIX 43 H12 2 0.360821 0.643324 0.537306 11.00000 -1.20000 AFIX 0 C13 1 0.303903 0.773437 0.676452 11.00000 0.04376 0.03660 = 0.02204 0.01495 0.00857 0.00643 AFIX 43 H13 2 0.325727 0.735596 0.729406 11.00000 -1.20000 AFIX 0 C14 1 0.250875 0.882950 0.713085 11.00000 0.03745 0.03170 = 0.02171 0.00517 0.01170 0.00003 AFIX 43 H14 2 0.235238 0.919963 0.790907 11.00000 -1.20000 AFIX 0 C15 1 0.220733 0.938307 0.636039 11.00000 0.03325 0.02429 = 0.02963 0.00500 0.01197 0.00569 AFIX 43 H15 2 0.184400 1.013525 0.661221 11.00000 -1.20000 AFIX 0 C16 1 0.243272 0.884542 0.521628 11.00000 0.02312 0.02209 = 0.02384 0.00851 0.00542 0.00339 AFIX 43 H16 2 0.223316 0.923696 0.469530 11.00000 -1.20000 AFIX 0 C17 1 0.255042 0.787366 0.259289 11.00000 0.02088 0.02097 = 0.01760 0.00958 0.00575 0.00691 C18 1 0.104755 0.747510 0.191780 11.00000 0.02172 0.02478 = 0.02649 0.01304 0.00406 0.00470 AFIX 43 H18 2 0.041175 0.669342 0.180761 11.00000 -1.20000 AFIX 0 C19 1 0.047652 0.821744 0.140557 11.00000 0.02720 0.03299 = 0.03075 0.01628 -0.00024 0.00915 AFIX 43 H19 2 -0.055523 0.795183 0.096435 11.00000 -1.20000 AFIX 0 C20 1 0.140755 0.934385 0.153645 11.00000 0.04300 0.02659 = 0.02704 0.01528 0.00601 0.01442 AFIX 43 H20 2 0.101594 0.984707 0.118267 11.00000 -1.20000 AFIX 0 C21 1 0.290819 0.973273 0.218363 11.00000 0.03824 0.02151 = 0.02787 0.01271 0.00835 0.00543 AFIX 43 H21 2 0.355199 1.049602 0.226151 11.00000 -1.20000 AFIX 0 C22 1 0.347739 0.900996 0.272061 11.00000 0.02440 0.02263 = 0.02454 0.01068 0.00407 0.00334 AFIX 43 H22 2 0.450298 0.929118 0.317696 11.00000 -1.20000 AFIX 0 C23 1 0.529093 0.737199 0.354369 11.00000 0.01917 0.02120 = 0.02232 0.00957 0.00425 0.00641 C24 1 0.586063 0.696088 0.252798 11.00000 0.02178 0.02856 = 0.02293 0.00805 0.00426 0.00427 AFIX 43 H24 2 0.517700 0.656619 0.176174 11.00000 -1.20000 AFIX 0 C25 1 0.741109 0.712500 0.263167 11.00000 0.02551 0.03424 = 0.03352 0.00971 0.01189 0.00902 AFIX 43 H25 2 0.779018 0.684060 0.193800 11.00000 -1.20000 AFIX 0 C26 1 0.841829 0.770702 0.375232 11.00000 0.01870 0.03476 = 0.04416 0.01580 0.00499 0.00792 AFIX 43 H26 2 0.948349 0.781057 0.382243 11.00000 -1.20000 AFIX 0 C27 1 0.787433 0.813247 0.475830 11.00000 0.02502 0.03253 = 0.03022 0.01323 -0.00290 0.00369 AFIX 43 H27 2 0.856515 0.853859 0.552162 11.00000 -1.20000 AFIX 0 C28 1 0.630681 0.796815 0.465909 11.00000 0.02539 0.02805 = 0.02311 0.00958 0.00287 0.00632 AFIX 43 H28 2 0.593438 0.826442 0.535530 11.00000 -1.20000 REM ##### AFIX 0 HKLF 4 REM CC2107_0m_a.res in P-1 REM wR2 = 0.050861, GooF = S = 1.07219, Restrained GooF = 1.07219 for all data REM R1 = 0.018853 for 5674 Fo > 4sig(Fo) and 0.020104 for all 5939 data REM 299 parameters refined using 0 restraints END WGHT 0.0221 0.6114 REM Highest difference peak 0.337, deepest hole -0.402, 1-sigma level 0.052 Q1 1 0.2846 0.7521 0.2964 11.00000 0.05 0.34 Q2 1 0.2605 0.8207 0.5033 11.00000 0.05 0.33 Q3 1 -0.0092 0.4692 0.2750 11.00000 0.05 0.33 Q4 1 0.0441 0.4572 0.3587 11.00000 0.05 0.32 Q5 1 0.6628 0.6877 0.2534 11.00000 0.05 0.32 Q6 1 0.5641 0.7178 0.3077 11.00000 0.05 0.31 Q7 1 0.5801 0.7631 0.4082 11.00000 0.05 0.31 Q8 1 0.3117 0.9405 0.2441 11.00000 0.05 0.31 Q9 1 0.7823 0.7424 0.3212 11.00000 0.05 0.30 Q10 1 0.2282 0.8985 0.5773 11.00000 0.05 0.30 Q11 1 0.2972 0.8453 0.2601 11.00000 0.05 0.30 Q12 1 0.2966 0.7439 0.5167 11.00000 0.05 0.29 Q13 1 0.8034 0.7655 0.4231 11.00000 0.05 0.29 Q14 1 0.2244 0.8989 0.6688 11.00000 0.05 0.28 Q15 1 0.1804 0.7791 0.2328 11.00000 0.05 0.28 Q16 1 0.3024 0.2043 0.1354 11.00000 0.05 0.28 Q17 1 0.3138 0.7436 0.4194 11.00000 0.05 0.27 Q18 1 0.2989 0.8408 0.7016 11.00000 0.05 0.27 Q19 1 0.0759 0.3561 0.3320 11.00000 0.05 0.26 Q20 1 0.0794 0.7924 0.1781 11.00000 0.05 0.26 ; _shelx_res_checksum 62358 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, -y, -z' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Mo Mo1 0.21851(2) 0.45813(2) 0.23960(2) 0.01978(4) Uani d 1 . . P P1 0.32246(3) 0.69322(3) 0.33370(3) 0.01786(6) Uani d 1 . . O O1 0.22653(14) 0.50413(11) 0.01296(9) 0.0343(2) Uani d 1 . . O O2 0.54687(13) 0.48265(11) 0.37404(11) 0.0391(3) Uani d 1 . . O O3 0.23712(16) 0.18616(11) 0.08762(12) 0.0459(3) Uani d 1 . . C C1 0.22950(15) 0.48927(12) 0.09861(11) 0.0233(2) Uani d 1 . . C C2 0.42735(17) 0.47555(13) 0.32222(12) 0.0267(3) Uani d 1 . . C C3 0.30515(18) 0.29556(13) 0.11888(12) 0.0288(3) Uani d 1 . . C C4 0.4478(2) 0.32080(16) 0.07449(15) 0.0390(4) Uani d 1 . . H H4A 0.428632 0.366718 0.024555 0.047 Uiso calc 1 . . H H4B 0.533049 0.37787 0.144096 0.047 Uiso calc 1 . . C C5 0.4970(2) 0.20261(19) 0.00328(17) 0.0504(5) Uani d 1 . . H H5A 0.420288 0.151328 -0.072025 0.076 Uiso calc 1 . . H H5B 0.507534 0.15204 0.048824 0.076 Uiso calc 1 . . H H5C 0.595154 0.227972 -0.013045 0.076 Uiso calc 1 . . C C6 -0.05044(17) 0.42011(17) 0.21381(16) 0.0377(4) Uani d 1 . . H H6 -0.121988 0.444525 0.162697 0.045 Uiso calc 1 . . C C7 0.01630(18) 0.49182(16) 0.33645(15) 0.0356(3) Uani d 1 . . H H7 0.00108 0.576933 0.387033 0.043 Uiso calc 1 . . C C8 0.09701(19) 0.41922(16) 0.37808(14) 0.0348(3) Uani d 1 . . H H8 0.146453 0.442892 0.463005 0.042 Uiso calc 1 . . C C9 0.08355(19) 0.30236(15) 0.28055(15) 0.0354(3) Uani d 1 . . H H9 0.118582 0.227614 0.284712 0.042 Uiso calc 1 . . C C10 -0.00792(19) 0.30284(16) 0.17850(15) 0.0369(3) Uani d 1 . . H H10 -0.047308 0.228557 0.098522 0.044 Uiso calc 1 . . C C11 0.29484(14) 0.77386(12) 0.48373(11) 0.0209(2) Uani d 1 . . C C12 0.32519(18) 0.71890(14) 0.56225(12) 0.0296(3) Uani d 1 . . H H12 0.360821 0.643324 0.537306 0.035 Uiso calc 1 . . C C13 0.30390(19) 0.77344(15) 0.67645(13) 0.0337(3) Uani d 1 . . H H13 0.325727 0.735596 0.729406 0.04 Uiso calc 1 . . C C14 0.25087(18) 0.88295(15) 0.71309(13) 0.0329(3) Uani d 1 . . H H14 0.235238 0.919963 0.790907 0.039 Uiso calc 1 . . C C15 0.22073(17) 0.93831(14) 0.63604(13) 0.0309(3) Uani d 1 . . H H15 0.1844 1.013525 0.661221 0.037 Uiso calc 1 . . C C16 0.24327(15) 0.88454(12) 0.52163(12) 0.0238(2) Uani d 1 . . H H16 0.223316 0.923696 0.46953 0.029 Uiso calc 1 . . C C17 0.25504(14) 0.78737(12) 0.25929(11) 0.0190(2) Uani d 1 . . C C18 0.10476(15) 0.74751(13) 0.19178(12) 0.0240(2) Uani d 1 . . H H18 0.041175 0.669342 0.180761 0.029 Uiso calc 1 . . C C19 0.04765(17) 0.82174(14) 0.14056(13) 0.0302(3) Uani d 1 . . H H19 -0.055523 0.795183 0.096435 0.036 Uiso calc 1 . . C C20 0.14075(18) 0.93438(14) 0.15365(13) 0.0305(3) Uani d 1 . . H H20 0.101594 0.984707 0.118267 0.037 Uiso calc 1 . . C C21 0.29082(18) 0.97327(13) 0.21836(13) 0.0287(3) Uani d 1 . . H H21 0.355199 1.049602 0.226151 0.034 Uiso calc 1 . . C C22 0.34774(15) 0.90100(12) 0.27206(12) 0.0242(3) Uani d 1 . . H H22 0.450298 0.929118 0.317696 0.029 Uiso calc 1 . . C C23 0.52909(14) 0.73720(12) 0.35437(11) 0.0207(2) Uani d 1 . . C C24 0.58606(15) 0.69609(13) 0.25280(12) 0.0258(3) Uani d 1 . . H H24 0.5177 0.656619 0.176174 0.031 Uiso calc 1 . . C C25 0.74111(16) 0.71250(15) 0.26317(14) 0.0319(3) Uani d 1 . . H H25 0.779018 0.68406 0.1938 0.038 Uiso calc 1 . . C C26 0.84183(16) 0.77070(15) 0.37523(15) 0.0331(3) Uani d 1 . . H H26 0.948349 0.781057 0.382243 0.04 Uiso calc 1 . . C C27 0.78743(16) 0.81325(14) 0.47583(13) 0.0310(3) Uani d 1 . . H H27 0.856515 0.853859 0.552162 0.037 Uiso calc 1 . . C C28 0.63068(16) 0.79681(13) 0.46591(12) 0.0264(3) Uani d 1 . . H H28 0.593438 0.826442 0.53553 0.032 Uiso calc 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Mo1 0.02476(6) 0.01872(6) 0.01856(6) 0.00571(4) 0.00643(4) 0.01018(4) P1 0.01821(14) 0.01985(14) 0.01678(14) 0.00582(11) 0.00409(11) 0.00879(11) O1 0.0494(6) 0.0349(6) 0.0221(5) 0.0107(5) 0.0090(4) 0.0155(4) O2 0.0397(6) 0.0413(6) 0.0407(6) 0.0187(5) 0.0014(5) 0.0220(5) O3 0.0611(8) 0.0230(5) 0.0525(7) 0.0117(5) 0.0214(6) 0.0118(5) C1 0.0263(6) 0.0203(6) 0.0214(6) 0.0053(5) 0.0048(5) 0.0078(5) C2 0.0368(7) 0.0246(6) 0.0237(6) 0.0131(5) 0.0088(5) 0.0129(5) C3 0.0399(8) 0.0254(6) 0.0231(6) 0.0133(6) 0.0073(6) 0.0105(5) C4 0.0481(9) 0.0354(8) 0.0361(8) 0.0188(7) 0.0199(7) 0.0112(7) C5 0.0631(12) 0.0475(10) 0.0411(9) 0.0299(9) 0.0218(9) 0.0097(8) C6 0.0248(7) 0.0488(9) 0.0495(9) 0.0041(6) 0.0104(6) 0.0327(8) C7 0.0338(8) 0.0335(8) 0.0460(9) 0.0091(6) 0.0235(7) 0.0183(7) C8 0.0409(8) 0.0411(8) 0.0281(7) 0.0056(7) 0.0165(6) 0.0194(6) C9 0.0462(9) 0.0290(7) 0.0416(8) 0.0071(6) 0.0193(7) 0.0236(7) C10 0.0378(8) 0.0338(8) 0.0336(8) -0.0071(6) 0.0109(6) 0.0142(6) C11 0.0198(5) 0.0229(6) 0.0189(5) 0.0043(5) 0.0048(4) 0.0083(5) C12 0.0393(8) 0.0309(7) 0.0231(6) 0.0137(6) 0.0095(6) 0.0136(6) C13 0.0438(8) 0.0366(8) 0.0220(6) 0.0064(6) 0.0086(6) 0.0149(6) C14 0.0375(8) 0.0317(7) 0.0217(6) 0.0000(6) 0.0117(6) 0.0052(5) C15 0.0332(7) 0.0243(6) 0.0296(7) 0.0057(5) 0.0120(6) 0.0050(5) C16 0.0231(6) 0.0221(6) 0.0238(6) 0.0034(5) 0.0054(5) 0.0085(5) C17 0.0209(5) 0.0210(6) 0.0176(5) 0.0069(4) 0.0057(4) 0.0096(5) C18 0.0217(6) 0.0248(6) 0.0265(6) 0.0047(5) 0.0041(5) 0.0130(5) C19 0.0272(7) 0.0330(7) 0.0308(7) 0.0092(6) -0.0002(5) 0.0163(6) C20 0.0430(8) 0.0266(7) 0.0270(7) 0.0144(6) 0.0060(6) 0.0153(6) C21 0.0382(7) 0.0215(6) 0.0279(7) 0.0054(5) 0.0083(6) 0.0127(5) C22 0.0244(6) 0.0226(6) 0.0245(6) 0.0033(5) 0.0041(5) 0.0107(5) C23 0.0192(5) 0.0212(6) 0.0223(6) 0.0064(4) 0.0043(5) 0.0096(5) C24 0.0218(6) 0.0286(7) 0.0229(6) 0.0043(5) 0.0043(5) 0.0080(5) C25 0.0255(7) 0.0342(7) 0.0335(7) 0.0090(6) 0.0119(6) 0.0097(6) C26 0.0187(6) 0.0348(7) 0.0442(8) 0.0079(5) 0.0050(6) 0.0158(7) C27 0.0250(6) 0.0325(7) 0.0302(7) 0.0037(5) -0.0029(5) 0.0132(6) C28 0.0254(6) 0.0281(6) 0.0231(6) 0.0063(5) 0.0029(5) 0.0096(5) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag C1 Mo1 C2 . . 107.83(6) y C1 Mo1 C3 . . 74.37(5) y C2 Mo1 C3 . . 72.47(5) y C1 Mo1 C9 . . 136.85(6) ? C2 Mo1 C9 . . 100.67(6) ? C3 Mo1 C9 . . 84.47(6) ? C1 Mo1 C10 . . 103.82(6) ? C2 Mo1 C10 . . 133.28(6) ? C3 Mo1 C10 . . 84.30(6) ? C9 Mo1 C10 . . 35.73(6) ? C1 Mo1 C8 . . 155.48(6) ? C2 Mo1 C8 . . 96.57(6) ? C3 Mo1 C8 . . 116.63(6) ? C9 Mo1 C8 . . 35.06(6) ? C10 Mo1 C8 . . 58.45(6) ? C1 Mo1 C6 . . 97.82(6) ? C2 Mo1 C6 . . 154.34(6) ? C3 Mo1 C6 . . 116.12(6) ? C9 Mo1 C6 . . 58.55(6) ? C10 Mo1 C6 . . 34.97(6) ? C8 Mo1 C6 . . 57.79(6) ? C1 Mo1 C7 . . 123.06(6) ? C2 Mo1 C7 . . 123.54(6) ? C3 Mo1 C7 . . 140.20(6) ? C9 Mo1 C7 . . 58.03(6) ? C10 Mo1 C7 . . 57.85(6) ? C8 Mo1 C7 . . 34.56(6) ? C6 Mo1 C7 . . 34.42(6) ? C1 Mo1 P1 . . 79.34(4) y C2 Mo1 P1 . . 78.28(4) y C3 Mo1 P1 . . 131.76(4) y C9 Mo1 P1 . . 139.01(4) ? C10 Mo1 P1 . . 141.74(5) ? C8 Mo1 P1 . . 103.97(4) ? C6 Mo1 P1 . . 106.91(4) ? C7 Mo1 P1 . . 88.01(4) ? C17 P1 C23 . . 102.95(6) ? C17 P1 C11 . . 102.96(6) ? C23 P1 C11 . . 103.95(6) ? C17 P1 Mo1 . . 119.32(4) ? C23 P1 Mo1 . . 111.87(4) ? C11 P1 Mo1 . . 114.09(4) ? O1 C1 Mo1 . . 175.81(12) ? O2 C2 Mo1 . . 176.43(13) ? O3 C3 C4 . . 118.46(14) ? O3 C3 Mo1 . . 119.78(12) ? C4 C3 Mo1 . . 121.76(10) ? C5 C4 C3 . . 115.02(15) ? C5 C4 H4A . . 108.5 ? C3 C4 H4A . . 108.5 ? C5 C4 H4B . . 108.5 ? C3 C4 H4B . . 108.5 ? H4A C4 H4B . . 107.5 ? C4 C5 H5A . . 109.5 ? C4 C5 H5B . . 109.5 ? H5A C5 H5B . . 109.5 ? C4 C5 H5C . . 109.5 ? H5A C5 H5C . . 109.5 ? H5B C5 H5C . . 109.5 ? C7 C6 C10 . . 107.44(14) ? C7 C6 Mo1 . . 72.83(9) ? C10 C6 Mo1 . . 70.27(9) ? C7 C6 H6 . . 126.2 ? C10 C6 H6 . . 126.2 ? Mo1 C6 H6 . . 126.2 ? C6 C7 C8 . . 108.81(15) ? C6 C7 Mo1 . . 72.75(9) ? C8 C7 Mo1 . . 71.97(8) ? C6 C7 H7 . . 125.5 ? C8 C7 H7 . . 125.5 ? Mo1 C7 H7 . . 125.5 ? C7 C8 C9 . . 107.89(14) ? C7 C8 Mo1 . . 73.47(8) ? C9 C8 Mo1 . . 70.63(8) ? C7 C8 H8 . . 125.9 ? C9 C8 H8 . . 125.9 ? Mo1 C8 H8 . . 125.9 ? C8 C9 C10 . . 107.75(14) ? C8 C9 Mo1 . . 74.31(8) ? C10 C9 Mo1 . . 72.43(8) ? C8 C9 H9 . . 125.8 ? C10 C9 H9 . . 125.8 ? Mo1 C9 H9 . . 125.8 ? C6 C10 C9 . . 108.10(15) ? C6 C10 Mo1 . . 74.76(9) ? C9 C10 Mo1 . . 71.83(9) ? C6 C10 H10 . . 125.7 ? C9 C10 H10 . . 125.7 ? Mo1 C10 H10 . . 125.7 ? C16 C11 C12 . . 118.96(12) ? C16 C11 P1 . . 123.40(10) ? C12 C11 P1 . . 117.64(10) ? C13 C12 C11 . . 120.73(14) ? C13 C12 H12 . . 119.6 ? C11 C12 H12 . . 119.6 ? C14 C13 C12 . . 119.95(14) ? C14 C13 H13 . . 120.0 ? C12 C13 H13 . . 120.0 ? C15 C14 C13 . . 119.77(13) ? C15 C14 H14 . . 120.1 ? C13 C14 H14 . . 120.1 ? C14 C15 C16 . . 120.48(14) ? C14 C15 H15 . . 119.8 ? C16 C15 H15 . . 119.8 ? C11 C16 C15 . . 120.10(13) ? C11 C16 H16 . . 119.9 ? C15 C16 H16 . . 119.9 ? C18 C17 C22 . . 118.98(12) ? C18 C17 P1 . . 119.14(9) ? C22 C17 P1 . . 121.83(10) ? C19 C18 C17 . . 120.29(12) ? C19 C18 H18 . . 119.9 ? C17 C18 H18 . . 119.9 ? C20 C19 C18 . . 120.26(13) ? C20 C19 H19 . . 119.9 ? C18 C19 H19 . . 119.9 ? C21 C20 C19 . . 119.83(13) ? C21 C20 H20 . . 120.1 ? C19 C20 H20 . . 120.1 ? C20 C21 C22 . . 120.23(13) ? C20 C21 H21 . . 119.9 ? C22 C21 H21 . . 119.9 ? C21 C22 C17 . . 120.39(12) ? C21 C22 H22 . . 119.8 ? C17 C22 H22 . . 119.8 ? C28 C23 C24 . . 119.14(12) ? C28 C23 P1 . . 122.88(10) ? C24 C23 P1 . . 117.61(10) ? C25 C24 C23 . . 120.42(13) ? C25 C24 H24 . . 119.8 ? C23 C24 H24 . . 119.8 ? C24 C25 C26 . . 120.02(14) ? C24 C25 H25 . . 120.0 ? C26 C25 H25 . . 120.0 ? C27 C26 C25 . . 120.14(13) ? C27 C26 H26 . . 119.9 ? C25 C26 H26 . . 119.9 ? C26 C27 C28 . . 120.10(13) ? C26 C27 H27 . . 120.0 ? C28 C27 H27 . . 120.0 ? C23 C28 C27 . . 120.16(13) ? C23 C28 H28 . . 119.9 ? C27 C28 H28 . . 119.9 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Mo1 P1 . 2.4816(4) y Mo1 C1 . 1.9640(13) y Mo1 C2 . 1.9662(15) y Mo1 C3 . 2.2794(14) y Mo1 C9 . 2.3138(14) ? Mo1 C10 . 2.3216(15) ? Mo1 C8 . 2.3612(14) ? Mo1 C6 . 2.3795(15) ? Mo1 C7 . 2.3805(15) ? P1 C17 . 1.8270(12) ? P1 C23 . 1.8289(13) ? P1 C11 . 1.8341(13) ? O1 C1 . 1.1563(17) ? O2 C2 . 1.1555(18) ? O3 C3 . 1.2083(19) ? C3 C4 . 1.533(2) ? C4 C5 . 1.514(2) ? C4 H4A . 0.99 ? C4 H4B . 0.99 ? C5 H5A . 0.98 ? C5 H5B . 0.98 ? C5 H5C . 0.98 ? C6 C7 . 1.408(2) ? C6 C10 . 1.414(3) ? C6 H6 . 1.0 ? C7 C8 . 1.409(2) ? C7 H7 . 1.0 ? C8 C9 . 1.409(2) ? C8 H8 . 1.0 ? C9 C10 . 1.422(2) ? C9 H9 . 1.0 ? C10 H10 . 1.0 ? C11 C16 . 1.3886(18) ? C11 C12 . 1.3951(18) ? C12 C13 . 1.388(2) ? C12 H12 . 0.95 ? C13 C14 . 1.384(2) ? C13 H13 . 0.95 ? C14 C15 . 1.382(2) ? C14 H14 . 0.95 ? C15 C16 . 1.3945(19) ? C15 H15 . 0.95 ? C16 H16 . 0.95 ? C17 C18 . 1.3956(17) ? C17 C22 . 1.3961(18) ? C18 C19 . 1.3910(18) ? C18 H18 . 0.95 ? C19 C20 . 1.387(2) ? C19 H19 . 0.95 ? C20 C21 . 1.384(2) ? C20 H20 . 0.95 ? C21 C22 . 1.3909(19) ? C21 H21 . 0.95 ? C22 H22 . 0.95 ? C23 C28 . 1.3907(18) ? C23 C24 . 1.3984(18) ? C24 C25 . 1.3814(19) ? C24 H24 . 0.95 ? C25 C26 . 1.392(2) ? C25 H25 . 0.95 ? C26 C27 . 1.376(2) ? C26 H26 . 0.95 ? C27 C28 . 1.398(2) ? C27 H27 . 0.95 ? C28 H28 . 0.95 ? loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag C12 H12 O2 2_666 0.95 2.36 3.1188(18) 136.8 y C6 H6 O1 2_565 1.00 2.60 3.545(2) 158.1 y loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag O3 C3 C4 C5 . . . . -5.3(2) ? Mo1 C3 C4 C5 . . . . 175.31(12) y C10 C6 C7 C8 . . . . -1.24(17) ? Mo1 C6 C7 C8 . . . . -63.38(11) ? C10 C6 C7 Mo1 . . . . 62.13(10) ? C6 C7 C8 C9 . . . . 1.22(17) ? Mo1 C7 C8 C9 . . . . -62.66(10) ? C6 C7 C8 Mo1 . . . . 63.88(11) ? C7 C8 C9 C10 . . . . -0.72(17) ? Mo1 C8 C9 C10 . . . . -65.22(10) ? C7 C8 C9 Mo1 . . . . 64.51(11) ? C7 C6 C10 C9 . . . . 0.79(17) ? Mo1 C6 C10 C9 . . . . 64.59(11) ? C7 C6 C10 Mo1 . . . . -63.80(10) ? C8 C9 C10 C6 . . . . -0.05(17) ? Mo1 C9 C10 C6 . . . . -66.52(10) ? C8 C9 C10 Mo1 . . . . 66.48(11) ? C17 P1 C11 C16 . . . . -3.65(12) ? C23 P1 C11 C16 . . . . 103.45(12) ? Mo1 P1 C11 C16 . . . . -134.44(10) ? C17 P1 C11 C12 . . . . 175.23(11) ? C23 P1 C11 C12 . . . . -77.66(12) ? Mo1 P1 C11 C12 . . . . 44.44(12) ? C16 C11 C12 C13 . . . . 0.2(2) ? P1 C11 C12 C13 . . . . -178.74(12) ? C11 C12 C13 C14 . . . . 0.5(2) ? C12 C13 C14 C15 . . . . -0.6(2) ? C13 C14 C15 C16 . . . . 0.0(2) ? C12 C11 C16 C15 . . . . -0.8(2) ? P1 C11 C16 C15 . . . . 178.09(10) ? C14 C15 C16 C11 . . . . 0.7(2) ? C23 P1 C17 C18 . . . . 157.21(10) ? C11 P1 C17 C18 . . . . -94.93(11) ? Mo1 P1 C17 C18 . . . . 32.63(12) ? C23 P1 C17 C22 . . . . -25.50(12) ? C11 P1 C17 C22 . . . . 82.36(11) ? Mo1 P1 C17 C22 . . . . -150.08(9) ? C22 C17 C18 C19 . . . . -1.5(2) ? P1 C17 C18 C19 . . . . 175.84(11) ? C17 C18 C19 C20 . . . . 1.6(2) ? C18 C19 C20 C21 . . . . -0.3(2) ? C19 C20 C21 C22 . . . . -1.2(2) ? C20 C21 C22 C17 . . . . 1.3(2) ? C18 C17 C22 C21 . . . . 0.1(2) ? P1 C17 C22 C21 . . . . -177.21(10) ? C17 P1 C23 C28 . . . . 118.22(11) ? C11 P1 C23 C28 . . . . 11.11(13) ? Mo1 P1 C23 C28 . . . . -112.46(11) ? C17 P1 C23 C24 . . . . -68.86(11) ? C11 P1 C23 C24 . . . . -175.97(10) ? Mo1 P1 C23 C24 . . . . 60.46(11) ? C28 C23 C24 C25 . . . . 1.1(2) ? P1 C23 C24 C25 . . . . -172.08(11) ? C23 C24 C25 C26 . . . . -0.2(2) ? C24 C25 C26 C27 . . . . -0.7(2) ? C25 C26 C27 C28 . . . . 0.8(2) ? C24 C23 C28 C27 . . . . -1.1(2) ? P1 C23 C28 C27 . . . . 171.76(11) ? C26 C27 C28 C23 . . . . 0.1(2) ? _cod_database_fobs_code 2243895