Crystallography Open Database

Information card for entry 2243974

Preview

Coordinates	2243974.cif
Structure factors	2243974.hkl
Original IUCr paper	HTML

Structure parameters

Common name	Tris[triphenylantimony(V)]-hexa-(μ-oxido)tellurate(VI)
Chemical name	Hexa-μ-oxido-1:2κ^4^<i>O</i>:<i>O</i>;1:3κ^4^<i>O</i>:<i>O</i>;1:4κ^4^<i>O</i>:<i>O</i>-nonaphenyl-2κ^3^<i>C</i>,3κ^3^<i>C</i>,4κ^3^<i>C</i>-triantimony(V)tellurium(VI)
Formula	C54 H45 O6 Sb3 Te
Calculated formula	C54 H45 O6 Sb3 Te
SMILES	[Te]123(O[Sb](O1)(c1ccccc1)(c1ccccc1)c1ccccc1)(O[Sb](O2)(c1ccccc1)(c1ccccc1)[c]1ccccc1)O[Sb](O3)(c1ccccc1)(c1ccccc1)c1ccccc1
Title of publication	Tris[triphenylantimony(V)]hexa(μ-oxido)tellurium(VI): a molecular complex with six Te—O—Sb bridges
Authors of publication	Domasevitch, Kostiantyn V.; Senchyk, Ganna A.
Journal of publication	Acta Crystallographica Section E
Year of publication	2021
Journal volume	77
Journal issue	12
Pages of publication	1229 - 1233
a	47.714 ± 0.002 Å
b	9.1176 ± 0.0004 Å
c	22.9324 ± 0.001 Å
α	90°
β	104.168 ± 0.004°
γ	90°
Cell volume	9673 ± 0.7 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	5
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0518
Residual factor for significantly intense reflections	0.0381
Weighted residual factors for significantly intense reflections	0.0914
Weighted residual factors for all reflections included in the refinement	0.0963
Goodness-of-fit parameter for all reflections included in the refinement	0.928
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	Yes

Version history

Revision	Date	Message	Files
271896 (current)	2022-01-07	cif/ hkl/ Adding structures of 2243974 via cif-deposit CGI script.	2243974.cif 2243974.hkl