#------------------------------------------------------------------------------ #$Date: 2024-05-23 04:50:14 +0300 (Thu, 23 May 2024) $ #$Revision: 292001 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/31/25/2312509.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2312509 loop_ _publ_author_name 'Abrahams, Brendan F.' 'Commons, Christopher J.' 'Hudson, Timothy A.' 'Sanchez-Arlt, Robin' _publ_section_title ; Supramolecular hydrogen-bonded networks formed from copper(II) carboxylate dimers. ; _journal_coeditor_code JX3083 _journal_issue 6 _journal_name_full 'Acta crystallographica. Section C, Structural chemistry' _journal_paper_doi 10.1107/S2053229624004534 _journal_volume 80 _journal_year 2024 _chemical_formula_iupac '[Cu2 (C7 H5 O3)4 (C4 H8 O2)2], 4C4 H8 O2' _chemical_formula_moiety 'C36 H36 Cu2 O16, 4(C4 H8 O2)' _chemical_formula_sum 'C52 H68 Cu2 O24' _chemical_formula_weight 1204.14 _chemical_name_systematic ; Tetrakis(\m-4-hydroxybenzoato)bis[(dioxane)copper(II)] dioxane tetrasolvate ; _space_group_crystal_system orthorhombic _space_group_IT_number 56 _space_group_name_Hall '-P 2ab 2ac' _space_group_name_H-M_alt 'P c c n' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _audit_creation_method ; Olex2 1.5 (compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928) ; _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 27.7701(8) _cell_length_b 21.2278(4) _cell_length_c 9.38880(10) _cell_measurement_reflns_used 4835 _cell_measurement_temperature 100.01(10) _cell_measurement_theta_max 74.7320 _cell_measurement_theta_min 5.1950 _cell_volume 5534.7(2) _computing_cell_refinement ; CrysAlis PRO (Rigaku OD, 2018) ; _computing_data_collection ; CrysAlis PRO (Rigaku OD, 2018) ; _computing_data_reduction ; CrysAlis PRO (Rigaku OD, 2018) ; _computing_molecular_graphics ; OLEX2 (Dolomanov et al., 2009) ; _computing_publication_material ; OLEX2 (Dolomanov et al., 2009) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT2014 (Sheldrick, 2015a) ; _diffrn_ambient_temperature 100.01(10) _diffrn_detector 'CCD plate' _diffrn_measured_fraction_theta_full 0.992 _diffrn_measured_fraction_theta_max 0.946 _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'Rigaku XtaLAB Synergy Dualflex diffractometer with a HyPix detector' _diffrn_measurement_method '\w scans' _diffrn_radiation_monochromator mirror _diffrn_radiation_probe x-ray _diffrn_radiation_type 'Cu K\a' _diffrn_radiation_wavelength 1.54184 _diffrn_reflns_av_R_equivalents 0.0492 _diffrn_reflns_av_unetI/netI 0.0477 _diffrn_reflns_limit_h_max 28 _diffrn_reflns_limit_h_min -35 _diffrn_reflns_limit_k_max 19 _diffrn_reflns_limit_k_min -26 _diffrn_reflns_limit_l_max 11 _diffrn_reflns_limit_l_min -11 _diffrn_reflns_number 18728 _diffrn_reflns_theta_full 67.684 _diffrn_reflns_theta_max 77.921 _diffrn_reflns_theta_min 2.620 _diffrn_source 'micro-focus sealed X-ray tube' _exptl_absorpt_coefficient_mu 1.659 _exptl_absorpt_correction_T_max 1.00000 _exptl_absorpt_correction_T_min 0.56692 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (CrysAlis PRO; Rigaku OD, 2018) ; _exptl_crystal_colour 'clear blue' _exptl_crystal_density_diffrn 1.445 _exptl_crystal_description irregular _exptl_crystal_F_000 2520 _exptl_crystal_size_max 0.14 _exptl_crystal_size_mid 0.126 _exptl_crystal_size_min 0.05 _refine_diff_density_max 0.470 _refine_diff_density_min -0.481 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.038 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 354 _refine_ls_number_reflns 5586 _refine_ls_number_restraints 2 _refine_ls_restrained_S_all 1.037 _refine_ls_R_factor_all 0.0833 _refine_ls_R_factor_gt 0.0626 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0975P)^2^+4.3605P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1698 _refine_ls_wR_factor_ref 0.1865 _reflns_number_gt 4112 _reflns_number_total 5586 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file jx3083.cif _cod_data_source_block compound_1 _cod_database_code 2312509 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.801 _shelx_estimated_absorpt_t_max 0.922 _shelx_hkl_file ; 2 0 0 2761.47 132.43 3 0 0 0.07 0.39 4 0 0 1351.41 64.97 5 0 0 -0.15 0.70 6 0 0 4197.43 201.46 7 0 0 0.30 0.78 8 0 0 2244.15 107.98 9 0 0 0.22 0.91 10 0 0 39.06 2.56 -14 0 0 58.91 4.48 -15 0 0 0.19 1.84 -16 0 0 733.69 36.99 -17 0 0 -0.22 2.02 -18 0 0 397.52 21.22 -19 0 0 -1.28 2.35 -20 0 0 391.99 21.16 -21 0 0 -1.43 2.46 -22 0 0 227.35 13.54 -23 0 0 1.51 2.24 -24 0 0 14.58 2.89 -25 0 0 2.72 2.31 -26 0 0 2.41 2.06 -27 0 0 0.47 1.24 -28 0 0 2.25 1.24 -29 0 0 -0.35 1.20 -30 0 0 1.10 1.16 -31 0 0 1.16 1.04 -32 0 0 2.56 1.01 -33 0 0 0.97 0.81 -34 0 0 -1.30 0.69 -35 0 0 -0.29 0.43 -1 -1 0 14.79 0.85 2 1 0 0.09 0.28 3 1 0 17.44 1.06 4 1 0 0.21 0.53 5 1 0 0.67 0.66 6 1 0 -0.03 0.74 7 1 0 194.76 9.73 8 1 0 -1.04 0.92 -9 -1 0 15.85 2.00 9 1 0 18.59 1.56 -10 -1 0 1.40 1.60 10 1 0 0.36 0.90 -11 -1 0 39.26 3.12 11 1 0 35.82 2.45 12 1 0 -0.74 1.03 -12 -1 0 0.41 1.80 -13 -1 0 1.22 1.75 -14 -1 0 -0.17 1.82 -15 -1 0 27.34 3.04 -16 -1 0 0.99 1.89 -17 1 0 0.93 2.22 -17 -1 0 0.21 1.94 -18 -1 0 -1.37 1.93 -18 1 0 1.77 2.10 -19 1 0 0.27 2.35 -19 -1 0 -0.98 2.04 -20 -1 0 2.09 2.15 -20 1 0 0.86 2.31 -21 1 0 3.01 2.33 -21 -1 0 6.51 2.38 -22 1 0 -0.62 2.20 -22 -1 0 -1.67 2.38 -23 1 0 3.54 2.55 -23 -1 0 0.85 2.13 -24 1 0 1.30 2.30 -24 -1 0 -1.45 2.02 -25 -1 0 34.90 4.01 -25 1 0 34.08 4.15 -26 -1 0 -1.76 2.17 -26 -1 0 -0.79 1.17 -26 1 0 -0.31 2.03 -27 -1 0 4.68 1.32 -28 1 0 -1.15 1.30 -28 -1 0 0.07 1.19 -29 1 0 -0.50 1.21 -29 -1 0 -0.55 1.17 -30 -1 0 -0.13 1.08 -30 1 0 0.26 1.15 -31 1 0 3.34 1.12 -31 -1 0 3.29 1.09 -32 1 0 0.05 0.91 -32 -1 0 -0.15 0.87 -33 1 0 7.61 1.03 -33 -1 0 6.85 1.01 -34 1 0 0.26 0.65 -34 -1 0 -0.13 0.65 -35 -1 0 0.07 0.42 -35 1 0 0.36 0.42 0 -2 0 1582.37 76.00 -1 -2 0 -0.06 0.45 -2 -2 0 1376.79 66.19 3 2 0 0.12 0.47 4 2 0 1635.65 78.61 5 2 0 0.56 0.68 -5 -2 0 0.36 1.10 -6 -2 0 1029.64 47.90 6 2 0 964.56 47.63 7 2 0 -0.08 0.77 -7 -2 0 0.72 1.29 8 2 0 185.50 9.47 -8 -2 0 195.29 9.88 -9 -2 0 -0.85 1.58 9 2 0 1.05 0.86 -10 -2 0 16.74 2.13 10 2 0 16.35 1.50 11 2 0 0.07 0.89 -11 -2 0 0.95 1.56 -12 -2 0 8.01 1.94 12 2 0 8.27 1.21 -13 -2 0 0.87 1.62 13 2 0 -0.87 0.94 14 2 0 139.09 7.56 -14 -2 0 146.35 8.24 -15 -2 0 -0.69 1.74 -16 -2 0 175.98 10.11 -17 -2 0 0.82 1.94 -18 -2 0 272.06 15.02 -19 -2 0 0.46 1.94 -19 2 0 1.12 2.25 -20 2 0 274.46 15.39 -20 -2 0 256.38 14.75 -21 -2 0 1.52 2.06 -21 2 0 -0.64 2.60 -22 -2 0 45.71 4.36 -22 2 0 45.42 4.84 -23 2 0 -0.67 2.49 -23 -2 0 -0.56 2.12 -24 -2 0 30.63 2.32 -24 2 0 25.34 3.87 -24 -2 0 24.10 3.46 -25 -2 0 -1.15 2.13 -25 2 0 -1.03 2.68 -25 -2 0 1.86 1.26 -26 -2 0 9.09 1.55 -26 2 0 9.52 2.93 -27 -2 0 1.43 1.22 -28 -2 0 4.39 1.22 -29 2 0 0.66 1.25 -29 -2 0 0.74 1.12 -30 -2 0 -1.05 1.06 -30 2 0 -0.73 1.16 -31 -2 0 -1.28 1.01 -31 2 0 -1.18 1.05 -32 2 0 2.84 0.98 -32 -2 0 0.10 0.90 -33 -2 0 -0.57 0.75 -33 2 0 1.26 0.78 -34 2 0 1.59 0.69 -34 -2 0 2.37 0.69 -35 2 0 0.26 0.40 -35 -2 0 -0.11 0.40 0 -3 0 0.63 0.68 -1 -3 0 125.03 6.32 -2 -3 0 -0.17 0.72 -3 -3 0 17.96 1.41 4 3 0 0.08 0.68 -5 -3 0 367.34 17.34 5 3 0 341.86 17.13 -6 -3 0 0.79 1.15 6 3 0 -0.32 0.79 -7 -3 0 -0.77 1.24 7 3 0 0.09 0.79 8 3 0 0.34 0.79 -8 -3 0 0.24 1.29 -9 -3 0 7.46 1.58 9 3 0 8.00 1.09 10 3 0 0.24 0.87 -10 -3 0 3.52 1.47 11 3 0 27.05 2.01 -11 -3 0 28.11 2.59 -12 -3 0 -0.77 1.66 12 3 0 1.08 0.94 -13 -3 0 294.69 15.22 13 3 0 288.99 14.63 -14 -3 0 -0.15 1.60 14 3 0 0.76 0.89 15 3 0 3.49 1.08 -15 -3 0 3.64 1.72 -16 -3 0 -1.07 1.78 -17 -3 0 25.13 2.83 -18 -3 0 2.26 1.81 -19 -3 0 46.55 4.09 -20 3 0 0.31 2.47 -20 -3 0 0.24 1.80 -21 -3 0 0.25 1.75 -21 3 0 3.99 2.71 -22 3 0 -1.04 2.48 -22 -3 0 0.79 1.92 -22 -3 0 0.43 1.08 -23 -3 0 15.03 2.81 -23 3 0 17.44 3.47 -23 -3 0 12.67 1.56 -24 -3 0 0.23 1.18 -24 3 0 0.72 2.54 -25 3 0 40.77 4.96 -25 -3 0 51.01 3.20 -26 -3 0 0.68 1.17 -26 3 0 2.46 2.36 -27 -3 0 2.06 1.21 -28 -3 0 0.07 1.14 -29 -3 0 2.77 1.17 -30 -3 0 1.27 1.05 -30 3 0 0.13 1.15 -31 -3 0 0.43 0.91 -31 3 0 1.24 1.05 -32 3 0 -0.05 0.89 -32 -3 0 -0.19 0.85 -33 -3 0 1.52 0.76 -33 3 0 -1.19 0.79 -34 3 0 -1.69 0.65 -34 -3 0 0.55 0.60 -35 3 0 -0.12 0.37 -35 -3 0 0.04 0.39 0 -4 0 3627.77 174.20 -1 -4 0 -1.35 1.02 -2 -4 0 1586.17 76.42 -3 -4 0 0.38 0.97 4 4 0 522.79 25.36 5 4 0 -0.26 0.71 6 4 0 370.41 18.13 7 4 0 0.38 0.85 -8 -4 0 260.72 12.77 8 4 0 242.87 12.42 9 4 0 0.68 0.87 -9 -4 0 2.99 1.46 10 4 0 0.50 0.82 -10 -4 0 0.41 1.36 11 4 0 -0.13 0.88 -11 -4 0 -0.56 1.38 -12 -4 0 11.46 1.96 12 4 0 15.00 1.44 -13 -4 0 -0.13 1.50 13 4 0 0.47 0.84 -14 -4 0 51.81 3.80 14 4 0 51.10 3.26 15 4 0 -0.09 0.88 -15 -4 0 0.65 1.56 -16 -4 0 23.57 2.62 -17 -4 0 1.53 1.78 -18 -4 0 162.84 9.63 -19 -4 0 -0.36 0.91 -19 -4 0 -0.88 1.62 -20 -4 0 7.78 2.36 -20 -4 0 10.45 1.30 -21 -4 0 -1.28 1.05 -21 4 0 -1.72 2.71 -22 4 0 5.82 2.90 -22 -4 0 2.61 1.17 -23 -4 0 -0.07 1.12 -23 4 0 0.38 2.67 -24 4 0 23.07 4.10 -24 -4 0 33.83 2.43 -25 4 0 -1.87 2.50 -25 -4 0 0.15 1.14 -26 -4 0 1.34 1.19 -26 4 0 3.28 2.58 -27 -4 0 1.15 1.18 -28 -4 0 0.07 1.12 -29 -4 0 -0.19 1.09 -30 -4 0 5.34 1.16 -31 4 0 0.35 1.06 -31 -4 0 0.89 0.93 -32 -4 0 -1.08 0.85 -32 4 0 -0.30 0.91 -33 -4 0 0.70 0.71 -33 4 0 -0.56 0.78 -34 4 0 -0.26 0.58 -34 -4 0 -0.17 0.57 0 -5 0 0.11 1.02 -1 -5 0 16.94 1.65 -2 -5 0 0.87 1.09 -3 -5 0 1.41 1.13 -4 -5 0 0.67 1.08 5 5 0 285.34 14.07 6 5 0 0.14 0.78 7 5 0 0.67 0.82 8 5 0 0.51 0.89 9 5 0 94.17 5.09 10 5 0 0.78 0.92 11 5 0 1.47 0.93 12 5 0 0.07 0.88 13 5 0 36.87 2.51 14 5 0 -0.68 0.88 15 5 0 223.69 11.53 16 5 0 -0.28 0.87 -17 -5 0 4.47 0.93 -18 -5 0 1.58 0.86 -19 -5 0 17.75 1.58 -20 -5 0 0.64 0.96 -21 -5 0 10.16 1.37 -22 -5 0 -0.84 1.06 -22 5 0 1.13 2.60 -23 -5 0 108.66 5.94 -23 5 0 110.36 8.55 -24 -5 0 -0.96 1.12 -24 5 0 -0.80 2.65 -25 -5 0 14.50 1.62 -25 5 0 10.57 3.40 -26 -5 0 -0.66 1.18 -26 5 0 0.38 2.68 -27 -5 0 7.15 1.37 -28 -5 0 1.01 1.11 -29 -5 0 16.12 1.63 -30 -5 0 -0.11 0.98 -31 5 0 2.00 1.08 -31 -5 0 0.60 0.89 -32 -5 0 0.64 0.80 -32 5 0 0.43 0.89 -33 5 0 0.34 0.73 -33 -5 0 2.00 0.71 -34 -5 0 0.05 0.52 -34 5 0 -0.03 0.52 0 -6 0 414.74 20.47 -1 -6 0 1.50 1.28 1 -6 0 -1.07 1.12 -2 -6 0 141.70 7.47 -3 -6 0 0.57 1.19 -4 -6 0 146.21 7.76 -5 -6 0 0.78 1.23 5 6 0 1.70 0.93 6 6 0 199.55 10.05 7 6 0 -0.11 0.85 8 6 0 14.13 1.43 9 6 0 0.27 0.92 10 6 0 22.84 1.83 11 6 0 -0.52 0.88 12 6 0 41.91 2.75 13 6 0 0.57 0.88 14 6 0 1.12 0.89 15 6 0 0.27 0.88 -16 -6 0 1.70 0.79 16 6 0 1.58 0.88 -17 -6 0 0.11 0.80 -18 -6 0 43.29 2.68 -19 -6 0 0.37 0.91 -20 -6 0 1.55 0.93 -21 -6 0 -1.42 1.03 -22 -6 0 11.32 1.42 -23 6 0 2.84 3.29 -23 -6 0 0.94 1.11 -24 -6 0 34.74 2.49 -24 6 0 31.53 4.74 -25 -6 0 0.22 1.12 -25 6 0 -2.45 3.06 -26 -6 0 5.03 1.28 -27 -6 0 1.25 1.11 -28 -6 0 4.38 1.21 -29 -6 0 1.27 1.05 -30 -6 0 3.35 1.05 -31 -6 0 0.66 0.88 -31 6 0 -0.11 1.02 -32 -6 0 0.20 0.73 -32 6 0 -0.41 0.86 -33 -6 0 -0.20 0.64 -33 6 0 -0.24 0.68 -34 -6 0 0.64 0.50 -34 6 0 1.24 0.49 0 -7 0 0.08 1.27 1 -7 0 4.28 1.32 -1 -7 0 4.52 1.42 -2 -7 0 -0.94 1.32 -3 -7 0 12.11 1.73 -4 -7 0 0.53 1.35 -5 -7 0 2.71 1.34 6 7 0 1.07 0.93 7 7 0 1.53 0.87 8 7 0 1.09 0.94 9 7 0 285.75 14.34 10 7 0 -0.83 0.94 11 7 0 5.69 1.13 12 7 0 0.66 0.89 13 7 0 21.31 1.81 14 7 0 2.46 0.92 15 7 0 40.08 2.76 -16 -7 0 0.52 0.76 -17 -7 0 -0.61 0.83 -18 -7 0 0.06 0.86 -19 -7 0 3.24 0.99 -20 -7 0 0.46 0.98 -21 -7 0 8.49 1.29 -22 -7 0 -0.85 1.13 -23 -7 0 4.49 1.20 -24 7 0 3.81 3.07 -24 -7 0 1.39 1.13 -25 -7 0 5.72 1.31 -25 7 0 5.46 3.21 -26 -7 0 -0.71 1.16 -27 -7 0 2.90 1.17 -28 -7 0 -0.76 1.07 -29 -7 0 1.84 0.99 -30 -7 0 0.51 0.89 -31 -7 0 3.59 0.91 -32 -7 0 1.03 0.72 -32 7 0 0.04 0.80 -33 -7 0 0.09 0.58 -33 7 0 -0.56 0.63 -34 -7 0 0.28 0.39 -34 7 0 0.08 0.37 0 -8 0 3595.16 173.10 -1 -8 0 1.08 1.38 1 -8 0 1.16 1.30 2 -8 0 134.63 7.71 -2 -8 0 160.00 7.98 -3 -8 0 -0.10 1.46 -4 -8 0 41.56 3.08 -5 -8 0 1.16 1.36 6 8 0 22.67 1.86 7 8 0 0.59 0.90 8 8 0 59.82 3.59 9 8 0 1.60 0.98 10 8 0 200.26 10.34 11 8 0 -0.43 0.94 12 8 0 89.73 5.09 13 8 0 0.63 0.90 14 8 0 68.19 4.08 -15 -8 0 -0.21 0.76 -16 -8 0 141.47 7.29 -17 -8 0 -0.46 0.87 -18 -8 0 119.48 6.31 -19 -8 0 -0.06 0.97 -20 -8 0 8.78 1.28 -21 -8 0 -1.53 1.04 -22 -8 0 26.22 2.08 -23 -8 0 -1.52 1.12 -24 8 0 2.59 2.98 -24 -8 0 8.63 1.39 -25 -8 0 0.71 1.11 -26 -8 0 0.62 1.11 -27 -8 0 0.91 1.09 -28 -8 0 1.87 1.06 -29 -8 0 -2.46 1.04 -30 -8 0 2.88 0.98 -31 -8 0 -1.15 0.82 -32 -8 0 3.08 0.74 -32 8 0 1.92 0.79 -33 -8 0 -0.33 0.54 -33 8 0 0.40 0.53 0 -9 0 -0.79 1.61 -1 -9 0 8.28 1.76 1 -9 0 10.34 1.71 -2 -9 0 0.23 1.46 2 -9 0 -1.42 1.36 -3 -9 0 7.03 1.68 3 -9 0 5.09 1.42 -4 -9 0 1.43 1.62 -5 -9 0 19.99 2.27 6 9 0 0.71 1.04 7 9 0 34.62 2.48 8 9 0 1.12 0.98 9 9 0 10.03 1.41 10 9 0 0.46 0.99 11 9 0 89.83 5.14 12 9 0 -0.19 0.89 13 9 0 27.95 2.20 -14 -9 0 0.41 0.76 -15 -9 0 0.44 0.83 -16 -9 0 -0.75 0.93 -17 -9 0 11.19 1.29 -18 -9 0 -0.38 0.94 -19 -9 0 14.37 1.48 -20 -9 0 -0.21 0.98 -21 -9 0 18.01 1.72 -22 -9 0 -1.44 1.12 -23 -9 0 0.22 1.14 -24 -9 0 0.14 1.07 -25 -9 0 -0.49 1.16 -26 -9 0 -1.60 1.14 -27 -9 0 5.49 1.24 -28 -9 0 0.35 1.02 -29 -9 0 6.11 1.11 -30 -9 0 1.16 0.87 -31 -9 0 3.52 0.81 -32 -9 0 -0.51 0.63 -32 9 0 0.07 0.65 -33 -9 0 0.59 0.46 -33 9 0 -0.11 0.42 0 -10 0 216.19 11.55 1 -10 0 1.86 1.56 -1 -10 0 -0.26 1.56 -2 -10 0 41.05 3.32 2 -10 0 35.46 2.93 -3 -10 0 -0.14 1.57 3 -10 0 0.11 1.34 -4 -10 0 1156.28 53.43 4 -10 0 1037.77 53.11 -5 -10 0 0.42 1.59 6 10 0 443.08 22.15 7 10 0 -0.29 1.04 8 10 0 159.25 8.50 9 10 0 0.81 1.06 10 10 0 1098.85 53.54 11 10 0 1.13 1.09 12 10 0 342.98 18.22 -12 -10 0 373.40 17.84 -13 -10 0 -0.21 0.78 14 -10 0 268.05 13.76 -14 -10 0 287.83 13.81 15 -10 0 1.83 0.95 -15 -10 0 -1.27 0.89 16 -10 0 153.61 8.15 -16 -10 0 166.79 8.25 -17 -10 0 0.57 0.90 17 -10 0 0.54 0.93 -18 -10 0 61.70 3.41 18 -10 0 52.57 3.28 -19 -10 0 0.48 1.04 -20 -10 0 61.30 3.67 -21 -10 0 0.07 1.07 -22 -10 0 15.31 1.61 -23 -10 0 -0.14 1.09 -24 -10 0 13.83 1.60 -25 -10 0 0.07 1.08 -26 -10 0 17.95 1.71 -27 -10 0 -0.72 1.08 -28 -10 0 13.66 1.47 -29 -10 0 1.44 0.92 -30 -10 0 9.31 1.09 -31 -10 0 -0.33 0.70 -32 10 0 0.46 0.55 -32 -10 0 0.26 0.56 0 -11 0 -1.73 1.76 -1 -11 0 19.36 2.53 1 -11 0 25.12 2.68 2 -11 0 0.28 1.49 -2 -11 0 -0.15 1.67 -3 -11 0 8.77 1.95 3 -11 0 7.96 1.73 -4 -11 0 1.25 1.74 4 -11 0 0.91 1.39 5 -11 0 20.48 2.27 -5 -11 0 21.01 2.61 6 11 0 -0.35 1.19 7 11 0 32.01 2.58 8 11 0 -0.78 1.10 9 11 0 1.13 1.12 10 11 0 2.14 1.09 -11 -11 0 16.50 1.43 -12 -11 0 1.03 0.80 12 -11 0 -0.05 1.01 13 -11 0 3.81 0.99 -13 -11 0 1.53 0.88 -14 -11 0 -0.12 0.90 14 -11 0 0.55 0.99 15 -11 0 6.60 1.17 -15 -11 0 6.11 1.08 16 -11 0 -0.74 1.01 -16 -11 0 0.44 0.94 17 -11 0 1.53 1.01 -17 -11 0 -0.53 1.01 18 -11 0 1.46 1.03 -18 -11 0 -0.27 1.05 19 -11 0 45.48 2.86 -19 -11 0 47.36 2.95 -20 -11 0 0.14 1.08 -21 -11 0 2.22 1.15 -22 -11 0 1.43 1.10 -23 -11 0 8.13 1.35 -24 -11 0 -0.07 1.11 -25 -11 0 0.20 1.07 -26 -11 0 0.12 1.05 -27 -11 0 30.05 2.17 -28 -11 0 0.37 0.92 -29 -11 0 2.95 0.90 -30 -11 0 0.67 0.77 -31 -11 0 0.58 0.64 -32 -11 0 -0.12 0.47 -32 11 0 0.02 0.39 0 -12 0 15.05 2.22 1 -12 0 -0.64 1.68 -1 -12 0 0.84 1.65 2 -12 0 182.21 10.46 -2 -12 0 196.63 10.59 3 -12 0 -0.15 1.53 -3 -12 0 -1.56 1.89 4 -12 0 201.36 11.39 -4 -12 0 224.06 11.75 5 -12 0 0.45 1.54 -5 -12 0 0.18 1.76 6 -12 0 2210.97 101.53 6 12 0 1994.38 101.27 7 -12 0 0.92 1.54 7 12 0 1.01 1.26 8 12 0 624.71 31.02 -9 -12 0 0.33 0.87 9 -12 0 0.05 0.97 9 12 0 -0.88 1.18 -10 -12 0 390.64 19.45 10 -12 0 400.48 19.46 11 -12 0 0.88 1.09 -11 -12 0 -0.70 0.89 12 -12 0 514.91 25.15 -12 -12 0 512.61 25.16 13 -12 0 0.57 1.08 -13 -12 0 -0.12 0.94 14 -12 0 445.35 21.68 -14 -12 0 435.79 21.69 15 -12 0 2.18 1.07 -15 -12 0 1.39 1.05 -16 -12 0 65.94 3.74 16 -12 0 60.75 3.67 17 -12 0 0.88 1.08 -17 -12 0 -0.35 1.06 -18 -12 0 64.52 3.65 18 -12 0 56.60 3.51 19 -12 0 -0.23 0.96 -19 -12 0 0.79 1.09 -20 -12 0 1.67 1.13 -21 -12 0 0.29 1.09 -22 -12 0 6.41 1.33 -23 -12 0 -1.13 1.16 -24 -12 0 31.11 2.32 -25 -12 0 0.39 1.08 -26 -12 0 10.46 1.38 -27 -12 0 0.33 0.97 -28 -12 0 2.68 0.95 -29 -12 0 1.02 0.78 -30 -12 0 3.55 0.81 -31 -12 0 -0.06 0.54 0 -13 0 -0.73 1.76 -1 -13 0 20.18 2.68 1 -13 0 23.54 2.65 -2 -13 0 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0 0.36 1.03 19 -13 0 10.40 1.34 -19 -13 0 10.80 1.49 20 -13 0 -0.49 0.99 -20 -13 0 -0.82 1.15 -21 -13 0 19.27 1.86 -22 -13 0 -1.50 1.18 -23 -13 0 16.36 1.73 -24 -13 0 0.79 1.07 -25 -13 0 -0.25 1.05 -26 -13 0 -0.79 1.00 -27 -13 0 1.43 0.95 -28 -13 0 0.18 0.81 -29 -13 0 0.74 0.72 -30 -13 0 -1.66 0.66 0 -14 0 58.44 3.60 0 -14 0 68.15 4.33 1 -14 0 1.39 1.71 -1 -14 0 -1.21 1.76 -1 -14 0 0.62 1.04 1 -14 0 -0.20 1.88 -2 -14 0 295.81 13.37 -2 -14 0 225.97 11.70 2 -14 0 288.75 13.23 -2 -14 0 202.31 11.67 2 -14 0 255.73 12.27 3 -14 0 0.61 1.86 -3 -14 0 0.72 1.00 -3 -14 0 -0.21 1.87 3 -14 0 1.38 1.87 -3 -14 0 0.63 1.83 -3 -14 0 0.54 1.10 3 -14 0 0.56 1.02 4 -14 0 28.91 2.22 4 -14 0 33.65 2.94 -4 -14 0 34.87 2.33 -4 -14 0 33.51 3.48 -4 -14 0 30.80 2.25 4 -14 0 40.26 3.41 -4 -14 0 38.41 3.13 -5 -14 0 0.57 1.15 -5 -14 0 -0.40 0.95 -5 -14 0 3.94 1.87 5 -14 0 0.78 1.65 -5 -14 0 1.11 1.87 5 -14 0 1.54 1.93 5 -14 0 0.29 1.07 6 -14 0 277.66 13.66 -6 -14 0 256.04 12.87 6 -14 0 240.38 12.79 -6 -14 0 257.37 12.43 -6 -14 0 235.50 12.37 6 14 0 224.79 13.08 6 -14 0 241.87 12.31 7 -14 0 -0.72 1.96 7 14 0 -1.69 1.44 -7 -14 0 0.51 2.03 7 -14 0 0.24 1.07 7 -14 0 1.91 1.66 -7 -14 0 -0.48 0.99 -7 -14 0 1.61 1.29 8 -14 0 688.64 32.33 8 -14 0 604.30 31.49 -8 -14 0 654.11 31.18 -8 -14 0 616.00 31.47 8 -14 0 655.52 31.11 -8 -14 0 619.61 31.13 9 -14 0 1.54 1.90 -9 -14 0 -1.12 1.12 9 -14 0 -0.20 1.62 9 -14 0 0.25 1.18 -9 -14 0 1.11 1.93 -9 -14 0 -2.12 1.09 -9 -14 0 -0.21 1.29 10 -14 0 490.14 23.93 -10 -14 0 488.52 22.77 -10 -14 0 455.68 22.77 -10 -14 0 449.83 23.00 -10 -14 0 426.38 22.63 10 -14 0 489.77 22.71 10 -14 0 447.33 23.05 11 -14 0 1.02 1.63 -11 -14 0 0.41 1.05 -11 -14 0 -0.15 1.31 11 -14 0 -1.20 1.17 -11 -14 0 -0.07 1.10 12 -14 0 118.42 6.15 -12 -14 0 124.01 6.24 12 -14 0 123.26 7.38 -12 -14 0 115.37 6.24 -12 -14 0 98.42 6.11 -13 -14 0 1.47 1.16 -13 -14 0 1.19 1.29 13 -14 0 -0.19 1.18 14 -14 0 263.83 13.44 -14 -14 0 272.69 13.55 15 -14 0 0.96 1.14 -15 -14 0 0.83 1.17 -16 -14 0 27.01 2.16 16 -14 0 24.70 2.02 17 -14 0 0.37 1.07 -17 -14 0 0.76 1.13 -18 -14 0 9.25 1.49 18 -14 0 11.41 1.43 -19 -14 0 3.03 1.23 19 -14 0 -0.81 1.05 20 -14 0 11.33 1.43 -20 -14 0 16.78 1.69 -21 -14 0 0.87 1.16 -22 -14 0 24.29 2.06 -23 -14 0 -0.94 1.13 -24 -14 0 2.90 1.01 -24 -14 0 2.26 1.09 -25 -14 0 -0.82 1.03 -26 -14 0 9.58 1.26 -27 -14 0 0.81 0.87 -28 -14 0 4.48 0.90 -29 -14 0 0.71 0.67 -30 -14 0 -0.27 0.47 0 -15 0 3.48 1.93 0 -15 0 1.26 2.07 0 -15 0 1.44 1.09 -1 -15 0 23.36 2.00 1 -15 0 20.56 2.77 -1 -15 0 26.53 3.04 1 -15 0 30.12 3.19 -2 -15 0 -1.57 2.01 -2 -15 0 0.97 1.14 2 -15 0 1.08 1.79 2 -15 0 -0.11 2.04 -3 -15 0 9.35 1.47 -3 -15 0 9.53 2.26 -3 -15 0 8.66 1.39 3 -15 0 11.61 2.28 -3 -15 0 10.02 2.28 3 -15 0 7.88 2.14 4 -15 0 0.13 1.06 -4 -15 0 0.23 2.03 4 -15 0 1.52 1.78 -4 -15 0 -0.07 1.18 4 -15 0 -2.62 2.19 -4 -15 0 0.47 1.80 -4 -15 0 0.30 1.08 5 -15 0 6.05 2.11 -5 -15 0 4.59 2.08 5 -15 0 2.88 1.87 -5 -15 0 4.86 1.37 5 -15 0 4.66 1.28 5 15 0 -0.36 1.42 -5 -15 0 3.25 1.23 -6 -15 0 -0.14 1.23 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0 1.82 1.18 -16 -15 0 0.66 1.14 -16 -15 0 -1.12 1.23 16 -15 0 -0.23 1.54 17 -15 0 11.00 1.41 -17 -15 0 6.94 1.37 -17 -15 0 9.95 1.54 17 -15 0 5.26 1.90 -18 -15 0 1.09 1.12 18 -15 0 2.50 1.59 18 -15 0 0.85 1.13 -18 -15 0 0.55 1.23 19 -15 0 135.81 6.88 -19 -15 0 154.72 7.13 -20 -15 0 -0.37 1.22 -20 -15 0 -0.67 1.06 20 -15 0 1.65 1.02 -21 -15 0 1.51 1.20 -21 -15 0 1.06 0.96 21 -15 0 2.30 1.00 -22 -15 0 0.75 1.11 -23 -15 0 4.02 1.19 -24 -15 0 0.36 1.03 -25 -15 0 16.94 1.57 -26 -15 0 0.30 0.88 -27 -15 0 5.57 0.95 -28 -15 0 0.78 0.69 -29 -15 0 0.48 0.51 0 -16 0 1.64 2.28 0 -16 0 0.24 1.76 0 -16 0 3.30 1.26 1 -16 0 -0.23 1.73 -1 -16 0 1.77 1.25 1 -16 0 -2.01 2.35 -1 -16 0 0.71 1.76 -2 -16 0 -3.13 2.05 -2 -16 0 0.07 1.24 2 -16 0 1.13 2.32 2 -16 0 1.46 1.85 -3 -16 0 0.13 2.29 3 -16 0 -2.12 2.00 -3 -16 0 -0.22 1.29 3 -16 0 1.38 2.12 -3 -16 0 0.49 1.94 4 -16 0 6.52 1.97 -4 -16 0 7.24 1.41 4 -16 0 6.62 2.41 -4 -16 0 3.53 2.29 -4 -16 0 6.81 2.26 4 -16 0 5.55 1.35 -4 -16 0 4.90 1.34 -5 -16 0 1.25 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1.27 16 -16 0 10.22 2.20 -16 -16 0 10.72 1.58 16 -16 0 7.80 1.42 -16 -16 0 5.18 1.11 -17 -16 0 -1.51 0.94 -17 -16 0 1.32 1.31 17 -16 0 1.01 1.17 -18 -16 0 10.01 1.26 -18 -16 0 14.99 1.72 18 -16 0 13.73 1.48 -19 -16 0 -0.50 0.81 19 -16 0 0.17 1.06 -19 -16 0 -1.86 1.27 20 -16 0 0.87 0.99 -20 -16 0 -0.67 1.22 21 -16 0 -0.68 0.90 -21 -16 0 -1.34 1.20 -22 -16 0 3.94 1.22 -23 -16 0 1.37 1.06 -24 -16 0 -1.65 1.07 -25 -16 0 -0.51 0.90 -26 -16 0 -1.28 0.85 -27 -16 0 -0.84 0.70 -28 -16 0 1.95 0.56 0 -17 0 -0.54 2.43 0 -17 0 -0.76 1.93 0 -17 0 -0.77 1.41 -1 -17 0 24.95 3.16 1 -17 0 27.69 3.30 1 -17 0 22.79 3.05 -1 -17 0 27.58 2.34 -2 -17 0 -1.28 1.86 2 -17 0 -0.25 1.85 2 -17 0 -0.40 2.45 -2 -17 0 0.39 1.34 3 -17 0 7.09 2.52 3 -17 0 9.99 2.37 -3 -17 0 9.74 2.66 -3 -17 0 10.13 1.71 -3 -17 0 8.89 2.40 -4 -17 0 -2.28 2.32 4 -17 0 -0.25 1.92 4 -17 0 -1.06 1.32 4 -17 0 -1.99 2.44 -4 -17 0 -1.02 1.44 5 -17 0 8.32 2.55 5 -17 0 11.79 1.67 -5 -17 0 11.99 2.65 -5 -17 0 7.14 1.64 6 -17 0 1.26 1.86 -6 -17 0 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0.76 6 6 10 0.20 0.61 6 -6 10 0.12 0.69 6 -6 10 0.83 0.85 7 6 10 6.18 0.78 7 -6 10 5.48 1.00 8 6 10 3.21 0.68 8 -6 10 3.71 0.92 9 6 10 0.95 0.55 9 -6 10 0.67 0.81 10 6 10 3.33 0.60 10 -6 10 3.18 0.87 11 -6 -10 -1.27 0.92 11 6 10 0.20 0.52 11 -6 10 0.08 0.76 12 6 10 0.29 0.45 12 -6 10 -0.74 0.71 13 6 10 0.10 0.40 13 -6 10 0.23 0.67 14 -6 10 1.24 0.60 15 -6 10 0.36 0.50 16 -6 10 1.54 0.43 0 7 10 0.95 0.60 0 -7 10 1.43 0.68 -1 7 10 10.62 0.96 1 7 10 10.43 0.93 -1 -7 10 9.55 1.00 1 -7 10 10.17 0.98 -2 7 10 11.76 1.02 -2 -7 10 10.24 1.03 2 7 10 9.78 0.93 2 -7 10 11.00 1.01 -3 7 10 0.18 0.65 -3 -7 10 0.79 0.72 3 7 10 1.19 0.57 3 -7 10 0.66 0.66 -4 -7 10 10.44 1.03 4 7 10 9.87 0.87 4 -7 10 9.61 0.98 -5 -7 10 25.67 1.74 5 7 10 24.41 1.58 5 -7 10 26.23 1.69 6 7 10 9.76 0.90 6 -7 10 11.51 1.03 7 7 10 6.92 0.72 7 -7 10 6.81 0.85 7 -7 10 8.29 1.05 8 7 10 11.86 0.97 8 -7 10 13.80 1.09 9 7 10 0.05 0.46 9 -7 10 1.15 0.81 10 -7 -10 13.55 1.40 10 -7 10 15.77 1.27 11 -7 -10 4.92 0.91 11 -7 10 6.21 0.90 12 -7 10 20.80 1.45 13 -7 10 8.41 0.90 14 -7 10 7.19 0.76 15 -7 10 2.33 0.40 15 -7 10 3.01 0.54 16 -7 10 3.56 0.45 0 -8 10 14.00 1.11 -1 -8 10 0.96 0.68 1 -8 10 0.27 0.60 -2 -8 10 16.28 1.24 2 -8 10 16.65 1.22 -3 -8 10 0.48 0.66 3 -8 10 0.36 0.60 -4 -8 10 23.64 1.55 4 -8 10 21.76 1.47 5 -8 10 20.11 1.37 5 -8 10 21.39 1.55 6 -8 10 37.32 2.29 6 -8 10 47.31 2.51 7 -8 10 4.22 0.73 7 -8 10 6.01 0.94 -8 -8 -10 43.65 2.70 8 -8 -10 40.04 2.61 8 -8 10 37.94 2.26 8 -8 10 45.81 2.47 -9 -8 -10 1.13 1.12 9 -8 -10 1.33 1.10 9 -8 10 -0.19 0.57 9 -8 10 0.75 0.76 10 -8 -10 45.95 2.74 10 -8 10 43.18 2.52 11 -8 10 1.27 0.51 11 -8 10 -0.24 0.71 11 -8 -10 1.75 0.79 12 -8 10 19.17 1.28 12 -8 10 28.16 1.52 13 -8 10 0.34 0.35 13 -8 10 0.11 0.57 14 -8 10 15.13 1.04 15 -8 10 0.44 0.40 0 -9 10 0.47 0.58 -1 -9 10 12.24 1.02 1 -9 10 11.94 1.00 -2 -9 10 0.03 0.61 2 -9 10 -0.03 0.54 -3 -9 10 -0.49 0.59 3 -9 10 -0.29 0.53 4 -9 10 -0.22 0.54 -5 -9 -10 0.43 1.35 5 -9 -10 0.93 1.29 5 -9 10 0.75 0.55 -6 -9 -10 5.79 1.38 6 -9 -10 2.83 1.25 6 -9 10 2.35 0.58 6 -9 10 3.53 0.83 -7 -9 -10 17.97 1.63 7 -9 -10 15.65 1.56 7 -9 10 14.26 1.05 7 -9 10 17.06 1.29 -8 -9 -10 11.57 1.39 8 -9 -10 10.39 1.34 8 -9 10 10.74 0.86 8 -9 10 12.52 1.10 9 -9 -10 7.86 1.11 9 -9 10 8.55 0.94 10 -9 10 3.94 0.75 10 -9 -10 4.34 0.90 11 -9 10 2.03 0.63 12 -9 10 7.49 0.77 13 -9 10 1.26 0.51 14 -9 10 1.52 0.46 15 -9 10 -0.14 0.31 0 -10 -10 33.66 2.49 1 -10 -10 1.41 1.38 2 -10 -10 19.73 1.87 -3 -10 -10 0.18 1.37 3 -10 -10 1.80 1.29 -4 -10 -10 50.88 3.17 4 -10 -10 48.90 3.09 -5 -10 -10 1.48 1.29 5 -10 -10 0.80 1.20 -6 -10 -10 37.28 2.43 6 -10 -10 32.44 2.32 -7 -10 -10 6.84 1.33 7 -10 -10 4.25 1.20 -8 -10 -10 28.42 1.96 8 -10 -10 27.16 1.91 9 -10 -10 3.65 0.93 11 -10 10 -0.24 0.53 12 -10 10 31.22 1.79 13 -10 10 5.56 0.59 0 -11 -10 1.25 1.24 1 -11 -10 0.84 1.21 2 -11 -10 5.54 1.35 -3 -11 -10 -1.72 1.30 3 -11 -10 0.37 1.15 -4 -11 -10 -0.22 1.22 4 -11 -10 0.86 1.19 -5 -11 -10 2.96 1.22 5 -11 -10 2.54 1.11 -6 -11 -10 0.33 1.11 6 -11 -10 2.70 1.02 -7 -11 -10 -0.08 0.93 7 -11 -10 -0.72 0.97 8 -11 -10 0.27 0.81 9 -11 -10 2.62 0.75 0 -12 -10 0.86 1.14 1 -12 -10 3.36 1.17 2 -12 -10 5.07 1.23 -3 -12 -10 0.74 1.17 3 -12 -10 0.19 1.03 -4 -12 -10 4.48 1.22 4 -12 -10 4.90 1.15 -5 -12 -10 1.77 1.04 5 -12 -10 0.83 1.00 -6 -12 -10 8.94 1.14 6 -12 -10 5.30 1.07 -7 -12 -10 0.86 0.81 7 -12 -10 0.69 0.82 0 -13 -10 -0.83 1.05 1 -13 -10 2.41 1.02 2 -13 -10 0.71 1.02 -3 -13 -10 2.79 1.08 3 -13 -10 3.44 1.00 -4 -13 -10 -0.16 0.91 4 -13 -10 -0.04 0.85 -5 -13 -10 0.86 0.82 5 -13 -10 1.39 0.78 -6 -13 -10 1.41 0.77 6 -13 -10 0.53 0.73 0 -14 -10 13.80 1.29 1 -14 -10 0.94 0.81 2 -14 -10 11.64 1.13 -3 -14 -10 5.78 0.92 3 -14 -10 6.55 0.92 4 -14 -10 5.38 0.82 0 0 11 0.45 0.64 -1 0 11 -0.39 0.67 1 0 11 0.75 0.68 -2 0 11 0.32 0.65 2 0 11 0.14 0.65 -3 0 11 0.36 0.67 3 0 11 0.51 0.64 -4 0 11 -0.11 0.66 4 0 11 0.20 0.63 5 0 11 -0.30 0.64 6 0 11 0.29 0.60 7 0 11 0.13 0.62 8 0 11 0.06 0.60 9 0 11 -0.40 0.57 10 0 11 0.50 0.52 11 0 11 -0.12 0.46 12 0 11 -0.14 0.43 13 0 11 0.76 0.33 0 1 11 1.07 0.68 0 -1 11 -0.59 0.65 -1 1 11 30.91 1.87 -1 -1 11 30.12 1.87 1 1 11 31.03 1.87 1 -1 11 31.19 1.88 -2 1 11 0.35 0.68 -2 -1 11 0.85 0.68 2 1 11 0.70 0.66 2 -1 11 0.51 0.65 -3 1 11 62.84 3.34 -3 -1 11 58.09 3.32 3 1 11 62.95 3.31 3 -1 11 63.60 3.32 -4 1 11 0.43 0.69 -4 -1 11 2.10 0.73 4 1 11 1.57 0.65 4 -1 11 1.67 0.69 5 1 11 56.61 3.05 5 -1 11 56.40 3.06 6 1 11 2.80 0.70 6 -1 11 2.15 0.68 7 1 11 44.20 2.39 7 -1 11 41.26 2.41 8 1 11 0.79 0.60 8 -1 11 1.77 0.63 9 1 11 14.16 1.06 9 -1 11 14.05 1.06 10 1 11 0.48 0.49 10 -1 11 0.50 0.54 11 1 11 9.03 0.78 11 -1 11 10.10 0.81 12 1 11 0.09 0.40 12 -1 11 0.30 0.42 13 -1 11 13.08 0.84 0 2 11 0.47 0.66 0 -2 11 -0.14 0.64 -1 2 11 0.88 0.65 -1 -2 11 0.31 0.65 1 2 11 -0.23 0.60 1 -2 11 0.07 0.62 -2 2 11 1.10 0.69 -2 -2 11 1.45 0.67 2 2 11 0.87 0.64 2 -2 11 1.10 0.66 -3 2 11 0.42 0.66 -3 -2 11 0.24 0.66 3 2 11 0.83 0.61 3 -2 11 -0.46 0.63 -4 -2 11 -0.35 0.66 4 2 11 0.72 0.58 4 -2 11 -0.49 0.63 5 2 11 5.75 0.75 5 -2 11 5.53 0.76 6 2 11 -0.18 0.58 6 -2 11 -0.16 0.62 7 2 11 0.23 0.57 7 -2 11 -0.03 0.60 8 2 11 4.11 0.63 8 -2 11 3.25 0.66 9 2 11 1.74 0.53 9 -2 11 1.18 0.58 10 2 11 2.65 0.51 10 -2 11 1.75 0.55 11 2 11 1.17 0.45 11 -2 11 2.13 0.50 12 2 11 1.79 0.38 12 -2 11 1.91 0.43 13 -2 11 -0.05 0.30 0 3 11 0.42 0.64 -1 3 11 35.75 2.15 1 3 11 39.12 2.15 -2 3 11 3.19 0.71 2 3 11 3.64 0.69 -3 3 11 23.68 1.58 3 3 11 25.06 1.53 4 3 11 0.47 0.60 5 3 11 14.89 1.10 6 3 11 1.94 0.58 7 3 11 13.92 1.03 8 3 11 2.32 0.56 9 3 11 13.11 0.92 10 3 11 1.06 0.42 11 3 11 3.92 0.46 0 4 11 -0.33 0.56 -1 4 11 0.27 0.61 1 4 11 -0.49 0.61 -2 4 11 0.88 0.61 2 4 11 0.23 0.58 3 4 11 3.14 0.64 4 4 11 5.50 0.67 5 4 11 4.20 0.61 6 4 11 -0.93 0.49 7 4 11 0.74 0.47 8 4 11 9.73 0.75 8 -4 11 10.06 0.85 9 4 11 1.06 0.38 9 -4 11 0.54 0.50 10 -4 11 1.36 0.47 11 -4 11 3.12 0.45 12 -4 11 4.95 0.48 0 5 11 1.25 0.55 0 -5 11 -0.03 0.57 1 5 11 11.12 0.90 -1 -5 11 11.62 0.96 1 -5 11 11.53 0.95 -2 -5 11 1.49 0.61 2 5 11 1.44 0.52 2 -5 11 1.21 0.57 -3 -5 11 -0.18 0.58 3 5 11 0.05 0.48 3 -5 11 -0.14 0.54 4 5 11 1.81 0.50 4 -5 11 0.71 0.55 5 5 11 0.97 0.48 5 -5 11 2.16 0.57 6 5 11 5.96 0.61 6 -5 11 6.49 0.70 7 5 11 1.21 0.40 7 -5 11 1.47 0.50 8 -5 -11 2.20 0.74 8 -5 11 0.54 0.46 9 -5 11 -0.02 0.42 10 -5 11 4.04 0.50 11 -5 11 0.53 0.32 0 -6 11 0.82 0.58 -1 -6 11 0.25 0.53 1 -6 11 0.30 0.52 -2 -6 11 1.46 0.55 2 -6 11 0.66 0.52 3 -6 11 2.50 0.55 4 -6 11 1.88 0.52 5 -6 11 1.24 0.49 -6 -6 -11 3.63 1.00 6 -6 -11 3.46 0.90 6 -6 11 4.00 0.54 -7 -6 -11 0.67 0.81 7 -6 -11 -0.73 0.79 7 -6 11 0.43 0.40 8 -6 11 4.47 0.51 9 -6 11 1.88 0.39 0 -7 11 0.10 0.46 1 -7 11 1.14 0.47 2 -7 11 0.92 0.46 -3 -7 -11 2.45 1.06 3 -7 -11 4.65 1.07 3 -7 11 2.14 0.51 -4 -7 -11 8.44 1.16 4 -7 -11 6.94 1.13 4 -7 11 7.14 0.65 -5 -7 -11 5.36 1.02 5 -7 -11 5.87 0.98 5 -7 11 4.82 0.55 -6 -7 -11 17.73 1.29 6 -7 -11 15.98 1.24 6 -7 11 14.40 0.96 7 -7 -11 13.31 1.08 7 -7 11 13.97 0.87 0 -8 -11 -0.64 1.00 1 -8 -11 8.18 1.15 2 -8 -11 1.92 0.95 -3 -8 -11 4.83 0.99 3 -8 -11 4.21 1.02 -4 -8 -11 1.01 0.96 4 -8 -11 2.53 0.90 -5 -8 -11 6.73 0.99 5 -8 -11 6.20 0.92 6 -8 -11 0.91 0.66 -6 -8 -11 0.56 0.68 0 -9 -11 -0.86 0.97 1 -9 -11 5.46 0.96 2 -9 -11 -0.14 0.81 -3 -9 -11 8.74 1.02 3 -9 -11 8.39 1.02 -4 -9 -11 0.75 0.77 4 -9 -11 3.08 0.74 0 -10 -11 0.12 0.72 1 -10 -11 1.89 0.73 -2 -10 -11 -0.53 0.72 2 -10 -11 0.85 0.64 0 0 0 0.00 0.00 TITL CC2_10B in Pccn REM Pccn (#56, found as Pnaa in -cba setting) CELL 1.54184 27.770063 21.227788 9.388822 90.0000 90.0000 90.0000 ZERR 24.00 0.000771 0.000355 0.000136 0.0000 0.0000 0.0000 LATT 1 SYMM -x+1/2,-y+1/2, z SYMM -x, y+1/2,-z+1/2 SYMM x+1/2,-y,-z+1/2 SFAC C H N O Cu UNIT 168.00 144.00 48.00 72.00 24.00 TREF HKLF 4 END _computing_structure_solution 'SHELXT 2014/5 (Sheldrick, 2014)' ; _shelx_hkl_checksum 55199 _shelx_res_file ; TITL cc2_10b_a.res in Pccn compound_1.res created by SHELXL-2018/3 at 19:55:09 on 07-May-2024 REM Old TITL CC2_10B in Pccn REM SHELXT solution in Pccn REM R1 0.234, Rweak 0.010, Alpha 0.024, Orientation as input REM Formula found by SHELXT: C27 N O11 Cu CELL 1.54184 27.7701 21.2278 9.3888 90 90 90 ZERR 4 0.0008 0.0004 0.0001 0 0 0 LATT 1 SYMM 0.5-X,0.5-Y,+Z SYMM -X,0.5+Y,0.5-Z SYMM 0.5+X,-Y,0.5-Z SFAC C H Cu O UNIT 208 272 8 96 DFIX 0.85 O6 H6 DFIX 0.85 O3 H3 L.S. 4 0 0 PLAN 2 SIZE 0.05 0.126 0.14 TEMP -173.14(10) CONF BOND $H list 4 MORE -1 HTAB fmap 2 53 acta REM REM REM WGHT 0.097500 4.360500 FVAR 0.18658 CU1 3 0.504012 0.455259 0.592367 11.00000 0.07700 0.03160 = 0.02884 0.00427 0.01713 0.00377 O7 4 0.505985 0.379300 0.753238 11.00000 0.08808 0.03117 = 0.02767 0.00216 0.01783 0.00182 O4 4 0.549387 0.415578 0.460661 11.00000 0.08033 0.03852 = 0.03272 0.00542 0.01524 0.01053 O5 4 0.542287 0.493303 0.299745 11.00000 0.08635 0.03476 = 0.03432 0.00659 0.01929 0.01133 O6 4 0.663185 0.292955 -0.047762 11.00000 0.08625 0.04872 = 0.04466 -0.00312 0.02269 0.00972 AFIX 147 H6 2 0.668464 0.312064 -0.124535 11.00000 -1.50000 AFIX 0 O2 4 0.547817 0.582598 0.519422 11.00000 0.08208 0.03973 = 0.03675 0.00588 0.01693 -0.00285 O8 4 0.479136 0.278134 0.931527 11.00000 0.09830 0.03578 = 0.03728 0.00328 0.01504 -0.00197 O3 4 0.672613 0.715533 0.994971 11.00000 0.09095 0.04845 = 0.04299 -0.00390 0.01296 -0.00617 AFIX 147 H3 2 0.673537 0.752619 0.963883 11.00000 -1.50000 AFIX 0 O9 4 0.686112 0.834199 0.897983 11.00000 0.07944 0.04789 = 0.05642 0.00733 -0.00541 -0.00139 O1 4 0.555474 0.504076 0.679512 11.00000 0.08809 0.03650 = 0.03822 0.00665 0.01103 -0.00328 O11 4 0.691343 0.348462 -0.282603 11.00000 0.06575 0.07466 = 0.04432 0.00944 0.01043 -0.00464 O12 4 0.726126 0.437183 -0.474844 11.00000 0.13287 0.07472 = 0.07232 0.01632 0.00966 -0.03651 C9 1 0.586648 0.403131 0.237654 11.00000 0.06603 0.03409 = 0.03227 -0.00059 0.01005 0.00001 C10 1 0.601836 0.342596 0.270935 11.00000 0.06485 0.03809 = 0.03096 -0.00038 0.00726 0.00162 AFIX 43 H10 2 0.594393 0.325537 0.361853 11.00000 -1.20000 AFIX 0 C2 1 0.595345 0.599550 0.721927 11.00000 0.08132 0.03793 = 0.03297 -0.00052 0.01701 -0.00108 C1 1 0.564479 0.559197 0.633798 11.00000 0.07662 0.03588 = 0.03628 -0.00096 0.02210 0.00165 C16 1 0.488127 0.339511 0.987992 11.00000 0.08490 0.04014 = 0.02957 0.00249 0.00981 0.00439 AFIX 23 H16A 2 0.522070 0.342274 1.019622 11.00000 -1.20000 H16B 2 0.467273 0.346584 1.072004 11.00000 -1.20000 AFIX 0 C14 1 0.597343 0.427001 0.102623 11.00000 0.07248 0.03879 = 0.03853 0.00244 0.01568 0.00448 AFIX 43 H14 2 0.587022 0.468190 0.077453 11.00000 -1.20000 AFIX 0 C3 1 0.618625 0.575640 0.841447 11.00000 0.07552 0.04109 = 0.04400 0.00011 0.01871 0.00188 AFIX 43 H3A 2 0.616246 0.531981 0.862540 11.00000 -1.20000 AFIX 0 C8 1 0.557657 0.440176 0.339408 11.00000 0.06903 0.03792 = 0.03218 0.00216 0.00981 0.00281 C13 1 0.622916 0.391079 0.004878 11.00000 0.07848 0.04782 = 0.03793 0.00212 0.02051 0.00170 AFIX 43 H13 2 0.630185 0.407712 -0.086565 11.00000 -1.20000 AFIX 0 C12 1 0.637816 0.330800 0.041255 11.00000 0.06386 0.03855 = 0.03993 -0.00425 0.01180 0.00291 C4 1 0.645259 0.614502 0.930344 11.00000 0.07488 0.04915 = 0.04050 -0.00015 0.01588 0.00260 AFIX 43 H4 2 0.661817 0.597262 1.009843 11.00000 -1.20000 AFIX 0 C11 1 0.627417 0.306780 0.175193 11.00000 0.06607 0.03924 = 0.03782 -0.00170 0.00646 0.00350 AFIX 43 H11 2 0.637937 0.265716 0.200681 11.00000 -1.20000 AFIX 0 C7 1 0.598874 0.663937 0.693465 11.00000 0.09557 0.04464 = 0.03409 0.00271 0.01297 -0.00165 AFIX 43 H7 2 0.583379 0.680893 0.611805 11.00000 -1.20000 AFIX 0 O10 4 0.701024 0.943465 0.737944 11.00000 0.14975 0.08774 = 0.19557 0.08178 -0.11022 -0.06021 C18 1 0.499033 0.317384 0.697715 11.00000 0.09330 0.03054 = 0.03372 -0.00093 0.01232 0.00306 AFIX 23 H18A 2 0.521433 0.310258 0.617282 11.00000 -1.20000 H18B 2 0.465720 0.313232 0.661358 11.00000 -1.20000 AFIX 0 C15 1 0.478528 0.389645 0.879052 11.00000 0.08551 0.04061 = 0.02895 -0.00091 0.01510 0.00566 AFIX 23 H15A 2 0.443826 0.389838 0.854902 11.00000 -1.20000 H15B 2 0.486774 0.431350 0.919453 11.00000 -1.20000 AFIX 0 C5 1 0.647636 0.678731 0.902714 11.00000 0.07860 0.04685 = 0.03909 -0.00609 0.01957 -0.00379 C17 1 0.507791 0.268716 0.811355 11.00000 0.09850 0.03535 = 0.03647 0.00108 0.01117 0.00282 AFIX 23 H17A 2 0.501140 0.226371 0.771792 11.00000 -1.20000 H17B 2 0.542108 0.270035 0.839761 11.00000 -1.20000 AFIX 0 C6 1 0.624633 0.703346 0.782609 11.00000 0.10325 0.03961 = 0.03721 -0.00060 0.01666 -0.00544 AFIX 43 H6A 2 0.626689 0.747099 0.762227 11.00000 -1.20000 AFIX 0 C19 1 0.647329 0.869607 0.839183 11.00000 0.07370 0.07156 = 0.05085 -0.00671 0.00111 0.01419 AFIX 23 H19A 2 0.619030 0.866925 0.903022 11.00000 -1.20000 H19B 2 0.638175 0.851694 0.745667 11.00000 -1.20000 AFIX 0 C22 1 0.728027 0.840917 0.811536 11.00000 0.05762 0.09381 = 0.09854 0.04285 -0.00237 -0.00261 AFIX 23 H22A 2 0.721990 0.822756 0.716070 11.00000 -1.20000 H22B 2 0.755268 0.817883 0.855291 11.00000 -1.20000 AFIX 0 C23 1 0.741744 0.354410 -0.306585 11.00000 0.07021 0.07483 = 0.07752 0.00599 0.00763 -0.00210 AFIX 23 H23A 2 0.751884 0.325377 -0.383462 11.00000 -1.20000 H23B 2 0.759605 0.343188 -0.218927 11.00000 -1.20000 AFIX 0 C26 1 0.664365 0.365756 -0.405758 11.00000 0.09309 0.07252 = 0.07159 0.01938 -0.02296 -0.01669 AFIX 23 H26A 2 0.629503 0.361967 -0.385441 11.00000 -1.20000 H26B 2 0.672262 0.336957 -0.485339 11.00000 -1.20000 AFIX 0 C24 1 0.752826 0.420989 -0.347976 11.00000 0.08126 0.07605 = 0.09179 0.00602 -0.00128 -0.01791 AFIX 23 H24A 2 0.743885 0.449817 -0.269421 11.00000 -1.20000 H24B 2 0.787774 0.425563 -0.366055 11.00000 -1.20000 AFIX 0 C25 1 0.675723 0.430907 -0.446610 11.00000 0.12261 0.07296 = 0.10078 0.02984 -0.03913 -0.01874 AFIX 23 H25A 2 0.657138 0.442523 -0.532673 11.00000 -1.20000 H25B 2 0.666371 0.459876 -0.368743 11.00000 -1.20000 AFIX 0 C20 1 0.661431 0.935956 0.821363 11.00000 0.21660 0.04013 = 0.13079 -0.01965 -0.10213 0.01940 AFIX 23 H20A 2 0.634225 0.959429 0.778626 11.00000 -1.20000 H20B 2 0.667934 0.954400 0.916282 11.00000 -1.20000 AFIX 0 C21 1 0.740591 0.909887 0.797602 11.00000 0.10571 0.12856 = 0.17960 0.09852 -0.07825 -0.05161 AFIX 23 H21A 2 0.748471 0.927386 0.892523 11.00000 -1.20000 H21B 2 0.769217 0.914722 0.735716 11.00000 -1.20000 AFIX 0 HKLF 4 REM cc2_10b_a.res in Pccn REM wR2 = 0.1865, GooF = S = 1.038, Restrained GooF = 1.037 for all data REM R1 = 0.0626 for 4112 Fo > 4sig(Fo) and 0.0833 for all 5586 data REM 354 parameters refined using 2 restraints END WGHT 0.0975 4.3605 REM Instructions for potential hydrogen bonds HTAB O6 O11 HTAB O3 O9 EQIV $2 x, -y+3/2, z+1/2 HTAB C4 O10_$2 HTAB C19 O2_$2 EQIV $3 x, -y+3/2, z-1/2 HTAB C22 O3_$3 EQIV $4 -x+3/2, -y+3/2, z HTAB C22 O3_$4 REM Highest difference peak 0.470, deepest hole -0.481, 1-sigma level 0.074 Q1 1 0.7003 0.9560 0.7797 11.00000 0.05 0.47 Q2 1 0.6807 0.3986 -0.2851 11.00000 0.05 0.42 ; _shelx_res_checksum 409 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, -y+1/2, z' '-x, y+1/2, -z+1/2' 'x+1/2, -y, -z+1/2' '-x, -y, -z' 'x-1/2, y-1/2, -z' 'x, -y-1/2, z-1/2' '-x-1/2, y, z-1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Cu Cu1 0.50401(2) 0.45526(2) 0.59237(5) 0.0458(2) Uani d 1 . . O O7 0.50598(10) 0.37930(11) 0.7532(2) 0.0490(6) Uani d 1 . . O O4 0.54939(10) 0.41558(10) 0.4607(2) 0.0505(6) Uani d 1 . . O O5 0.54229(10) 0.49330(10) 0.2997(2) 0.0518(6) Uani d 1 . . O O6 0.66319(11) 0.29296(12) -0.0478(3) 0.0599(7) Uani d 1 . . H H6 0.668464 0.312064 -0.124535 0.090 Uiso calc 1 . . O O2 0.54782(10) 0.58260(11) 0.5194(2) 0.0529(6) Uani d 1 . . O O8 0.47914(12) 0.27813(11) 0.9315(3) 0.0571(7) Uani d 1 . . O O3 0.67261(11) 0.71553(12) 0.9950(3) 0.0608(7) Uani d 1 . . H H3 0.673537 0.752619 0.963883 0.091 Uiso calc 1 . . O O9 0.68611(11) 0.83420(12) 0.8980(3) 0.0612(7) Uani d 1 . . O O1 0.55547(11) 0.50408(11) 0.6795(2) 0.0543(7) Uani d 1 . . O O11 0.69134(11) 0.34846(14) -0.2826(3) 0.0616(7) Uani d 1 . . O O12 0.72613(16) 0.43718(16) -0.4748(4) 0.0933(12) Uani d 1 . . C C9 0.58665(14) 0.40313(15) 0.2377(3) 0.0441(8) Uani d 1 . . C C10 0.60184(14) 0.34260(15) 0.2709(3) 0.0446(8) Uani d 1 . . H H10 0.594393 0.325537 0.361853 0.054 Uiso calc 1 . . C C2 0.59535(15) 0.59955(16) 0.7219(3) 0.0507(9) Uani d 1 . . C C1 0.56448(15) 0.55920(16) 0.6338(4) 0.0496(9) Uani d 1 . . C C16 0.48813(16) 0.33951(16) 0.9880(3) 0.0515(9) Uani d 1 . . H H16A 0.522070 0.342274 1.019622 0.062 Uiso calc 1 . . H H16B 0.467273 0.346584 1.072004 0.062 Uiso calc 1 . . C C14 0.59734(15) 0.42700(16) 0.1026(3) 0.0499(9) Uani d 1 . . H H14 0.587022 0.468190 0.077453 0.060 Uiso calc 1 . . C C3 0.61863(15) 0.57564(17) 0.8414(4) 0.0535(9) Uani d 1 . . H H3A 0.616246 0.531981 0.862540 0.064 Uiso calc 1 . . C C8 0.55766(14) 0.44018(16) 0.3394(3) 0.0464(8) Uani d 1 . . C C13 0.62292(15) 0.39108(17) 0.0049(4) 0.0547(9) Uani d 1 . . H H13 0.630185 0.407712 -0.086565 0.066 Uiso calc 1 . . C C12 0.63782(14) 0.33080(16) 0.0413(4) 0.0474(8) Uani d 1 . . C C4 0.64526(16) 0.61450(17) 0.9303(4) 0.0548(9) Uani d 1 . . H H4 0.661817 0.597262 1.009843 0.066 Uiso calc 1 . . C C11 0.62742(14) 0.30678(16) 0.1752(3) 0.0477(8) Uani d 1 . . H H11 0.637937 0.265716 0.200681 0.057 Uiso calc 1 . . C C7 0.59887(17) 0.66394(17) 0.6935(4) 0.0581(10) Uani d 1 . . H H7 0.583379 0.680893 0.611805 0.070 Uiso calc 1 . . O O10 0.7010(2) 0.9435(2) 0.7379(7) 0.144(3) Uani d 1 . . C C18 0.49903(16) 0.31738(16) 0.6977(4) 0.0525(9) Uani d 1 . . H H18A 0.521433 0.310258 0.617282 0.063 Uiso calc 1 . . H H18B 0.465720 0.313232 0.661358 0.063 Uiso calc 1 . . C C15 0.47853(16) 0.38964(16) 0.8791(3) 0.0517(9) Uani d 1 . . H H15A 0.443826 0.389838 0.854902 0.062 Uiso calc 1 . . H H15B 0.486774 0.431350 0.919453 0.062 Uiso calc 1 . . C C5 0.64764(16) 0.67873(17) 0.9027(4) 0.0548(9) Uani d 1 . . C C17 0.50779(16) 0.26872(17) 0.8114(4) 0.0568(10) Uani d 1 . . H H17A 0.501140 0.226371 0.771792 0.068 Uiso calc 1 . . H H17B 0.542108 0.270035 0.839761 0.068 Uiso calc 1 . . C C6 0.62463(17) 0.70335(17) 0.7826(4) 0.0600(11) Uani d 1 . . H H6A 0.626689 0.747099 0.762227 0.072 Uiso calc 1 . . C C19 0.64733(17) 0.8696(2) 0.8392(4) 0.0654(11) Uani d 1 . . H H19A 0.619030 0.866925 0.903022 0.078 Uiso calc 1 . . H H19B 0.638175 0.851694 0.745667 0.078 Uiso calc 1 . . C C22 0.72803(17) 0.8409(3) 0.8115(6) 0.0833(15) Uani d 1 . . H H22A 0.721990 0.822756 0.716070 0.100 Uiso calc 1 . . H H22B 0.755268 0.817883 0.855291 0.100 Uiso calc 1 . . C C23 0.74174(18) 0.3544(2) -0.3066(6) 0.0742(12) Uani d 1 . . H H23A 0.751884 0.325377 -0.383462 0.089 Uiso calc 1 . . H H23B 0.759605 0.343188 -0.218927 0.089 Uiso calc 1 . . C C26 0.6644(2) 0.3658(2) -0.4058(5) 0.0791(14) Uani d 1 . . H H26A 0.629503 0.361967 -0.385441 0.095 Uiso calc 1 . . H H26B 0.672262 0.336957 -0.485339 0.095 Uiso calc 1 . . C C24 0.7528(2) 0.4210(2) -0.3480(6) 0.0830(14) Uani d 1 . . H H24A 0.743885 0.449817 -0.269421 0.100 Uiso calc 1 . . H H24B 0.787774 0.425563 -0.366055 0.100 Uiso calc 1 . . C C25 0.6757(2) 0.4309(3) -0.4466(7) 0.0988(19) Uani d 1 . . H H25A 0.657138 0.442523 -0.532673 0.119 Uiso calc 1 . . H H25B 0.666371 0.459876 -0.368743 0.119 Uiso calc 1 . . C C20 0.6614(3) 0.9360(2) 0.8214(8) 0.129(3) Uani d 1 . . H H20A 0.634225 0.959429 0.778626 0.155 Uiso calc 1 . . H H20B 0.667934 0.954400 0.916282 0.155 Uiso calc 1 . . C C21 0.7406(2) 0.9099(3) 0.7976(9) 0.138(3) Uani d 1 . . H H21A 0.748471 0.927386 0.892523 0.166 Uiso calc 1 . . H H21B 0.769217 0.914722 0.735716 0.166 Uiso calc 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Cu1 0.0770(4) 0.0316(3) 0.0288(3) 0.0038(2) 0.0171(2) 0.00427(18) O7 0.0881(19) 0.0312(11) 0.0277(11) 0.0018(11) 0.0178(11) 0.0022(9) O4 0.0803(18) 0.0385(12) 0.0327(11) 0.0105(11) 0.0152(11) 0.0054(9) O5 0.0864(18) 0.0348(12) 0.0343(11) 0.0113(11) 0.0193(12) 0.0066(9) O6 0.086(2) 0.0487(14) 0.0447(13) 0.0097(13) 0.0227(14) -0.0031(11) O2 0.0821(18) 0.0397(12) 0.0368(12) -0.0028(11) 0.0169(12) 0.0059(10) O8 0.098(2) 0.0358(12) 0.0373(12) -0.0020(12) 0.0150(13) 0.0033(10) O3 0.091(2) 0.0485(15) 0.0430(13) -0.0062(14) 0.0130(13) -0.0039(11) O9 0.0794(19) 0.0479(14) 0.0564(15) -0.0014(13) -0.0054(14) 0.0073(12) O1 0.0881(19) 0.0365(12) 0.0382(11) -0.0033(12) 0.0110(12) 0.0067(9) O11 0.0657(17) 0.0747(18) 0.0443(13) -0.0046(14) 0.0104(13) 0.0094(12) O12 0.133(3) 0.075(2) 0.072(2) -0.037(2) 0.010(2) 0.0163(17) C9 0.066(2) 0.0341(16) 0.0323(15) 0.0000(14) 0.0100(15) -0.0006(12) C10 0.065(2) 0.0381(17) 0.0310(14) 0.0016(15) 0.0073(15) -0.0004(12) C2 0.081(3) 0.0379(17) 0.0330(15) -0.0011(16) 0.0170(17) -0.0005(13) C1 0.077(2) 0.0359(16) 0.0363(16) 0.0016(15) 0.0221(17) -0.0010(13) C16 0.085(3) 0.0401(18) 0.0296(15) 0.0044(16) 0.0098(16) 0.0025(13) C14 0.072(2) 0.0388(17) 0.0385(16) 0.0045(16) 0.0157(17) 0.0024(14) C3 0.076(3) 0.0411(18) 0.0440(18) 0.0019(17) 0.0187(18) 0.0001(15) C8 0.069(2) 0.0379(17) 0.0322(15) 0.0028(15) 0.0098(15) 0.0022(13) C13 0.078(3) 0.0478(19) 0.0379(17) 0.0017(18) 0.0205(17) 0.0021(15) C12 0.064(2) 0.0386(17) 0.0399(16) 0.0029(15) 0.0118(16) -0.0042(13) C4 0.075(3) 0.049(2) 0.0405(18) 0.0026(18) 0.0159(17) -0.0002(15) C11 0.066(2) 0.0392(17) 0.0378(16) 0.0035(15) 0.0065(16) -0.0017(13) C7 0.096(3) 0.045(2) 0.0341(16) -0.0017(19) 0.0130(18) 0.0027(14) O10 0.150(4) 0.088(3) 0.196(6) -0.060(3) -0.110(4) 0.082(3) C18 0.093(3) 0.0305(16) 0.0337(16) 0.0031(16) 0.0123(17) -0.0009(13) C15 0.086(3) 0.0406(18) 0.0290(15) 0.0057(17) 0.0151(17) -0.0009(13) C5 0.079(3) 0.0469(19) 0.0391(17) -0.0038(18) 0.0196(17) -0.0061(15) C17 0.099(3) 0.0354(17) 0.0365(17) 0.0028(17) 0.0112(18) 0.0011(14) C6 0.103(3) 0.0396(18) 0.0372(17) -0.0054(19) 0.0167(19) -0.0006(14) C19 0.074(3) 0.072(3) 0.051(2) 0.014(2) 0.001(2) -0.0067(19) C22 0.058(3) 0.094(4) 0.099(4) -0.003(2) -0.002(3) 0.043(3) C23 0.070(3) 0.075(3) 0.078(3) -0.002(2) 0.008(2) 0.006(2) C26 0.093(4) 0.073(3) 0.072(3) -0.017(3) -0.023(3) 0.019(2) C24 0.081(3) 0.076(3) 0.092(4) -0.018(3) -0.001(3) 0.006(3) C25 0.123(5) 0.073(3) 0.101(4) -0.019(3) -0.039(4) 0.030(3) C20 0.217(9) 0.040(3) 0.131(6) 0.019(4) -0.102(6) -0.020(3) C21 0.106(5) 0.129(5) 0.180(7) -0.052(4) -0.078(5) 0.099(5) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cu Cu -1.9646 0.5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag O7 Cu1 Cu1 . 5_666 176.39(8) ? O4 Cu1 Cu1 . 5_666 87.01(7) ? O4 Cu1 O7 . . 95.85(9) ? O4 Cu1 O5 . 5_666 170.18(9) ? O5 Cu1 Cu1 5_666 5_666 83.17(7) ? O5 Cu1 O7 5_666 . 93.97(9) ? O2 Cu1 Cu1 5_666 5_666 83.00(7) ? O2 Cu1 O7 5_666 . 94.89(10) ? O2 Cu1 O4 5_666 . 87.58(11) ? O2 Cu1 O5 5_666 5_666 91.34(12) ? O1 Cu1 Cu1 . 5_666 87.37(7) ? O1 Cu1 O7 . . 94.76(10) ? O1 Cu1 O4 . . 91.26(12) ? O1 Cu1 O5 . 5_666 88.16(12) ? O1 Cu1 O2 . 5_666 170.35(10) ? C18 O7 Cu1 . . 114.77(19) ? C15 O7 Cu1 . . 116.20(19) ? C15 O7 C18 . . 111.9(3) ? C8 O4 Cu1 . . 120.3(2) ? C8 O5 Cu1 . 5_666 124.4(2) ? C12 O6 H6 . . 109.5 ? C1 O2 Cu1 . 5_666 124.2(2) ? C17 O8 C16 . . 109.3(3) ? C5 O3 H3 . . 109.5 ? C19 O9 C22 . . 110.1(3) ? C1 O1 Cu1 . . 119.5(3) ? C23 O11 C26 . . 111.4(3) ? C25 O12 C24 . . 109.1(4) ? C10 C9 C14 . . 118.4(3) ? C10 C9 C8 . . 120.9(3) ? C14 C9 C8 . . 120.7(3) ? C9 C10 H10 . . 119.3 ? C11 C10 C9 . . 121.4(3) ? C11 C10 H10 . . 119.3 ? C3 C2 C1 . . 120.9(3) ? C3 C2 C7 . . 118.6(4) ? C7 C2 C1 . . 120.3(3) ? O2 C1 O1 . . 125.0(4) ? O2 C1 C2 . . 117.5(3) ? O1 C1 C2 . . 117.5(3) ? O8 C16 H16A . . 109.4 ? O8 C16 H16B . . 109.4 ? O8 C16 C15 . . 111.3(3) ? H16A C16 H16B . . 108.0 ? C15 C16 H16A . . 109.4 ? C15 C16 H16B . . 109.4 ? C9 C14 H14 . . 119.7 ? C13 C14 C9 . . 120.6(3) ? C13 C14 H14 . . 119.7 ? C2 C3 H3A . . 119.5 ? C4 C3 C2 . . 121.1(3) ? C4 C3 H3A . . 119.5 ? O4 C8 C9 . . 117.3(3) ? O5 C8 O4 . . 124.7(3) ? O5 C8 C9 . . 118.0(3) ? C14 C13 H13 . . 120.1 ? C12 C13 C14 . . 119.8(3) ? C12 C13 H13 . . 120.1 ? O6 C12 C13 . . 123.3(3) ? O6 C12 C11 . . 116.7(3) ? C11 C12 C13 . . 120.0(3) ? C3 C4 H4 . . 120.1 ? C3 C4 C5 . . 119.8(4) ? C5 C4 H4 . . 120.1 ? C10 C11 C12 . . 119.8(3) ? C10 C11 H11 . . 120.1 ? C12 C11 H11 . . 120.1 ? C2 C7 H7 . . 119.6 ? C6 C7 C2 . . 120.8(4) ? C6 C7 H7 . . 119.6 ? C20 O10 C21 . . 109.8(5) ? O7 C18 H18A . . 109.5 ? O7 C18 H18B . . 109.5 ? O7 C18 C17 . . 110.6(3) ? H18A C18 H18B . . 108.1 ? C17 C18 H18A . . 109.5 ? C17 C18 H18B . . 109.5 ? O7 C15 C16 . . 111.2(3) ? O7 C15 H15A . . 109.4 ? O7 C15 H15B . . 109.4 ? C16 C15 H15A . . 109.4 ? C16 C15 H15B . . 109.4 ? H15A C15 H15B . . 108.0 ? O3 C5 C4 . . 118.0(4) ? O3 C5 C6 . . 122.2(3) ? C4 C5 C6 . . 119.7(4) ? O8 C17 C18 . . 112.5(3) ? O8 C17 H17A . . 109.1 ? O8 C17 H17B . . 109.1 ? C18 C17 H17A . . 109.1 ? C18 C17 H17B . . 109.1 ? H17A C17 H17B . . 107.8 ? C7 C6 C5 . . 119.9(3) ? C7 C6 H6A . . 120.0 ? C5 C6 H6A . . 120.0 ? O9 C19 H19A . . 109.6 ? O9 C19 H19B . . 109.6 ? O9 C19 C20 . . 110.4(5) ? H19A C19 H19B . . 108.1 ? C20 C19 H19A . . 109.6 ? C20 C19 H19B . . 109.6 ? O9 C22 H22A . . 109.8 ? O9 C22 H22B . . 109.8 ? O9 C22 C21 . . 109.6(5) ? H22A C22 H22B . . 108.2 ? C21 C22 H22A . . 109.8 ? C21 C22 H22B . . 109.8 ? O11 C23 H23A . . 109.9 ? O11 C23 H23B . . 109.9 ? O11 C23 C24 . . 109.1(4) ? H23A C23 H23B . . 108.3 ? C24 C23 H23A . . 109.9 ? C24 C23 H23B . . 109.9 ? O11 C26 H26A . . 109.7 ? O11 C26 H26B . . 109.7 ? O11 C26 C25 . . 110.0(4) ? H26A C26 H26B . . 108.2 ? C25 C26 H26A . . 109.7 ? C25 C26 H26B . . 109.7 ? O12 C24 C23 . . 109.5(4) ? O12 C24 H24A . . 109.8 ? O12 C24 H24B . . 109.8 ? C23 C24 H24A . . 109.8 ? C23 C24 H24B . . 109.8 ? H24A C24 H24B . . 108.2 ? O12 C25 C26 . . 110.2(5) ? O12 C25 H25A . . 109.6 ? O12 C25 H25B . . 109.6 ? C26 C25 H25A . . 109.6 ? C26 C25 H25B . . 109.6 ? H25A C25 H25B . . 108.1 ? O10 C20 C19 . . 113.1(6) ? O10 C20 H20A . . 109.0 ? O10 C20 H20B . . 109.0 ? C19 C20 H20A . . 109.0 ? C19 C20 H20B . . 109.0 ? H20A C20 H20B . . 107.8 ? O10 C21 C22 . . 109.9(4) ? O10 C21 H21A . . 109.7 ? O10 C21 H21B . . 109.7 ? C22 C21 H21A . . 109.7 ? C22 C21 H21B . . 109.7 ? H21A C21 H21B . . 108.2 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Cu1 Cu1 5_666 2.5818(9) ? Cu1 O7 . 2.210(2) ? Cu1 O4 . 1.956(2) ? Cu1 O5 5_666 1.968(2) ? Cu1 O2 5_666 1.954(3) ? Cu1 O1 . 1.946(3) ? O7 C18 . 1.427(4) ? O7 C15 . 1.423(4) ? O4 C8 . 1.273(4) ? O5 C8 . 1.262(4) ? O6 H6 . 0.8400 ? O6 C12 . 1.357(4) ? O2 C1 . 1.270(4) ? O8 C16 . 1.429(4) ? O8 C17 . 1.395(4) ? O3 H3 . 0.8400 ? O3 C5 . 1.357(5) ? O9 C19 . 1.425(5) ? O9 C22 . 1.426(5) ? O1 C1 . 1.271(4) ? O11 C23 . 1.423(5) ? O11 C26 . 1.426(5) ? O12 C24 . 1.445(6) ? O12 C25 . 1.431(7) ? C9 C10 . 1.388(5) ? C9 C14 . 1.397(4) ? C9 C8 . 1.476(5) ? C10 H10 . 0.9500 ? C10 C11 . 1.375(5) ? C2 C1 . 1.467(5) ? C2 C3 . 1.391(5) ? C2 C7 . 1.396(5) ? C16 H16A . 0.9900 ? C16 H16B . 0.9900 ? C16 C15 . 1.500(5) ? C14 H14 . 0.9500 ? C14 C13 . 1.389(5) ? C3 H3A . 0.9500 ? C3 C4 . 1.387(6) ? C13 H13 . 0.9500 ? C13 C12 . 1.388(5) ? C12 C11 . 1.387(5) ? C4 H4 . 0.9500 ? C4 C5 . 1.389(5) ? C11 H11 . 0.9500 ? C7 H7 . 0.9500 ? C7 C6 . 1.383(6) ? O10 C20 . 1.359(10) ? O10 C21 . 1.424(7) ? C18 H18A . 0.9900 ? C18 H18B . 0.9900 ? C18 C17 . 1.505(5) ? C15 H15A . 0.9900 ? C15 H15B . 0.9900 ? C5 C6 . 1.397(6) ? C17 H17A . 0.9900 ? C17 H17B . 0.9900 ? C6 H6A . 0.9500 ? C19 H19A . 0.9900 ? C19 H19B . 0.9900 ? C19 C20 . 1.471(8) ? C22 H22A . 0.9900 ? C22 H22B . 0.9900 ? C22 C21 . 1.511(8) ? C23 H23A . 0.9900 ? C23 H23B . 0.9900 ? C23 C24 . 1.498(7) ? C26 H26A . 0.9900 ? C26 H26B . 0.9900 ? C26 C25 . 1.469(7) ? C24 H24A . 0.9900 ? C24 H24B . 0.9900 ? C25 H25A . 0.9900 ? C25 H25B . 0.9900 ? C20 H20A . 0.9900 ? C20 H20B . 0.9900 ? C21 H21A . 0.9900 ? C21 H21B . 0.9900 ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag Cu1 O7 C18 C17 . . . . 172.2(3) ? Cu1 O7 C15 C16 . . . . -172.0(3) ? Cu1 O4 C8 O5 . . . . 7.6(5) ? Cu1 O4 C8 C9 . . . . -171.3(3) ? Cu1 O5 C8 O4 5_666 . . . -7.7(6) ? Cu1 O5 C8 C9 5_666 . . . 171.2(2) ? Cu1 O2 C1 O1 5_666 . . . 11.5(5) ? Cu1 O2 C1 C2 5_666 . . . -166.6(2) ? Cu1 O1 C1 O2 . . . . -11.9(5) ? Cu1 O1 C1 C2 . . . . 166.2(2) ? O7 C18 C17 O8 . . . . 55.9(5) ? O6 C12 C11 C10 . . . . 180.0(4) ? O8 C16 C15 O7 . . . . -56.0(5) ? O3 C5 C6 C7 . . . . -178.8(4) ? O9 C19 C20 O10 . . . . 57.5(6) ? O9 C22 C21 O10 . . . . -58.0(8) ? O11 C23 C24 O12 . . . . -58.8(6) ? O11 C26 C25 O12 . . . . 58.7(6) ? C9 C10 C11 C12 . . . . -1.1(6) ? C9 C14 C13 C12 . . . . 0.3(6) ? C10 C9 C14 C13 . . . . -0.6(6) ? C10 C9 C8 O4 . . . . 3.5(6) ? C10 C9 C8 O5 . . . . -175.5(4) ? C2 C3 C4 C5 . . . . 2.0(6) ? C2 C7 C6 C5 . . . . 0.2(6) ? C1 C2 C3 C4 . . . . -175.7(3) ? C1 C2 C7 C6 . . . . 174.6(4) ? C16 O8 C17 C18 . . . . -58.0(4) ? C14 C9 C10 C11 . . . . 0.9(6) ? C14 C9 C8 O4 . . . . -179.8(4) ? C14 C9 C8 O5 . . . . 1.2(6) ? C14 C13 C12 O6 . . . . -179.5(4) ? C14 C13 C12 C11 . . . . -0.4(6) ? C3 C2 C1 O2 . . . . -173.9(3) ? C3 C2 C1 O1 . . . . 7.9(5) ? C3 C2 C7 C6 . . . . -0.5(6) ? C3 C4 C5 O3 . . . . 177.7(3) ? C3 C4 C5 C6 . . . . -2.3(6) ? C8 C9 C10 C11 . . . . 177.7(4) ? C8 C9 C14 C13 . . . . -177.3(4) ? C13 C12 C11 C10 . . . . 0.8(6) ? C4 C5 C6 C7 . . . . 1.3(6) ? C7 C2 C1 O2 . . . . 11.1(5) ? C7 C2 C1 O1 . . . . -167.1(3) ? C7 C2 C3 C4 . . . . -0.6(6) ? C18 O7 C15 C16 . . . . 53.5(4) ? C15 O7 C18 C17 . . . . -52.7(4) ? C17 O8 C16 C15 . . . . 57.8(4) ? C19 O9 C22 C21 . . . . 56.7(5) ? C22 O9 C19 C20 . . . . -55.6(6) ? C23 O11 C26 C25 . . . . -58.2(6) ? C26 O11 C23 C24 . . . . 58.1(5) ? C24 O12 C25 C26 . . . . -60.1(6) ? C25 O12 C24 C23 . . . . 60.0(6) ? C20 O10 C21 C22 . . . . 58.2(8) ? C21 O10 C20 C19 . . . . -58.5(7) ?