#------------------------------------------------------------------------------ #$Date: 2024-06-28 04:46:00 +0300 (Fri, 28 Jun 2024) $ #$Revision: 292633 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/31/25/2312527.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2312527 loop_ _publ_author_name 'Wysocki, Waldemar' 'Kamecka, Anna' 'Karczmarzyk, Zbigniew' _publ_section_title ; Synthesis and structural characterizations of three carbonyl(α-diimine)hydrido(triphenylphosphine)ruthenium(II) complexes with derivatives of 1,10-phenanthroline. ; _journal_coeditor_code YD3043 _journal_issue 7 _journal_name_full 'Acta crystallographica. Section C, Structural chemistry' _journal_paper_doi 10.1107/S2053229624005898 _journal_volume 80 _journal_year 2024 _chemical_formula_iupac '[Ru H (C12 H8 N2) (C18 H15 P)2 (C O)] P F6' _chemical_formula_moiety 'C49 H39 N2 O P2 Ru +, F6 P -' _chemical_formula_sum 'C49 H39 F6 N2 O P3 Ru' _chemical_formula_weight 979.80 _chemical_name_systematic 'Carbonylhydrido(1,10-phenanthroline-\k^2^N,N)bis(triphenylphosphane-\kP)ruthenium(II) hexafluoridophosphate' _space_group_crystal_system monoclinic _space_group_IT_number 14 _space_group_name_Hall '-P 2yn' _space_group_name_H-M_alt 'P 1 21/n 1' _atom_sites_solution_hydrogens mixed _atom_sites_solution_primary difmap _atom_sites_solution_secondary difmap _audit_creation_method SHELXL-2014/7 _cell_angle_alpha 90 _cell_angle_beta 97.528(5) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 10.5442(6) _cell_length_b 21.1741(13) _cell_length_c 21.9326(13) _cell_measurement_reflns_used 6271 _cell_measurement_temperature 298(2) _cell_measurement_theta_max 28.6730 _cell_measurement_theta_min 2.0870 _cell_volume 4854.6(5) _computing_cell_refinement ; CrysAlis PRO (Rigaku OD, 2022) ; _computing_data_collection ; CrysAlis PRO (Rigaku OD, 2022) ; _computing_data_reduction ; CrysAlis PRO (Rigaku OD, 2022) ; _computing_molecular_graphics ; ORTEP-3 for Windows (Farrugia, 2012) ; _computing_publication_material ; SHELXL2014 (Sheldrick, 2015) and WinGX (Farrugia, 2012) ; _computing_structure_refinement ; SHELXL2014 (Sheldrick, 2015) ; _computing_structure_solution ; SHELXS2013 (Sheldrick, 2008) ; _diffrn_ambient_temperature 298(2) _diffrn_measured_fraction_theta_full 0.999 _diffrn_measured_fraction_theta_max 0.865 _diffrn_measurement_device_type 'KM4 CCD four-circle' _diffrn_measurement_method '\w scans' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0522 _diffrn_reflns_av_unetI/netI 0.1129 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_h_min -13 _diffrn_reflns_limit_k_max 26 _diffrn_reflns_limit_k_min -26 _diffrn_reflns_limit_l_max 21 _diffrn_reflns_limit_l_min -28 _diffrn_reflns_number 23138 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 29.029 _diffrn_reflns_theta_min 1.873 _exptl_absorpt_coefficient_mu 0.481 _exptl_absorpt_correction_T_max 1.00000 _exptl_absorpt_correction_T_min 0.80165 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; CrysAlis PRO (Rigaku OD, 2022) ; _exptl_crystal_colour yellow _exptl_crystal_density_diffrn 1.341 _exptl_crystal_description needle _exptl_crystal_F_000 1992 _exptl_crystal_size_max 0.50 _exptl_crystal_size_mid 0.12 _exptl_crystal_size_min 0.10 _refine_diff_density_max 0.670 _refine_diff_density_min -0.690 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.022 _refine_ls_hydrogen_treatment mixed _refine_ls_matrix_type full _refine_ls_number_parameters 562 _refine_ls_number_reflns 11206 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.022 _refine_ls_R_factor_all 0.1197 _refine_ls_R_factor_gt 0.0596 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0467P)^2^+2.6156P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1175 _refine_ls_wR_factor_ref 0.1460 _reflns_number_gt 6576 _reflns_number_total 11206 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file yd3043sup1.cif _cod_data_source_block 1_Ruphen _cod_original_sg_symbol_H-M 'P 21/n' _cod_database_code 2312527 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; 0 0 -2 14399.8 142.646 1 0 0 2 819.716 38.6614 1 0 0 3 16.7126 11.1949 1 0 0 -3-0.42295 14.2147 1 0 0 -4 5754.86 128.626 1 0 0 4 6080.05 134.921 1 0 0 -5-2.56334 17.4000 1 0 0 -6 2385.75 103.252 1 0 0 -7-10.1385 23.5684 1 0 0 -8 1656.24 99.9089 1 0 0 -9-24.3610 27.8481 1 0 0 -10 222.296 49.6244 1 0 0 -11-42.6188 33.9376 1 0 0 -12 8272.85 274.853 1 0 0 -13-28.4896 33.6361 1 0 0 -14 801.157 95.3165 1 0 0 -15 16.1662 28.5127 1 0 0 -16 3608.14 214.147 1 0 0 -17 6.56633 30.6282 1 0 0 -18 1346.61 138.452 1 0 0 -20 68.1446 32.8440 1 0 0 -21-68.0147 34.0494 1 0 0 -22 512.244 97.0045 1 0 0 -23 21.0054 22.2602 1 0 0 -24 982.587 142.561 1 0 0 -25-64.6001 45.4301 1 0 0 -26 362.912 100.194 1 0 0 -27 106.599 51.8174 1 0 0 -28 90.1663 51.5276 1 0 1 2 2802.60 70.2970 1 0 -1 -2 9444.92 122.627 1 0 1 3 182.791 22.6242 1 0 -1 -3 172.217 23.1043 1 0 1 4 4933.00 121.665 1 0 -1 -4 4837.02 119.128 1 0 1 5 12051.6 209.285 1 0 -1 -5 11398.7 203.761 1 0 1 6 91.0666 24.3011 1 0 1 -6 89.3066 26.7540 1 0 -1 -6 63.7720 27.5043 1 0 -1 -7 413.722 41.6889 1 0 1 -7 408.708 50.9067 1 0 1 7 417.881 45.4740 1 0 1 8 1204.08 84.5232 1 0 1 -8 1097.00 82.1614 1 0 -1 -8 1075.77 80.6123 1 0 1 -9 24.3821 24.0616 1 0 -1 -9 18.5970 19.0486 1 0 1 -10 2808.50 145.699 1 0 -1 -10 2745.76 144.709 1 0 1 -11 241.925 48.9718 1 0 -1 -11 228.088 47.2572 1 0 1 -12 45.0184 30.9193 1 0 -1 -12 40.8178 28.3512 1 0 1 -13 14.6346 26.6201 1 0 -1 -13 9.45402 19.8684 1 0 1 -14 41.3496 32.0362 1 0 -1 -14-5.14019 18.6357 1 0 -1 14 7.34162 16.4821 5 0 1 -15 70.2010 35.8874 1 0 -1 -15 100.156 29.9997 1 0 -1 15 19.5581 16.7737 5 0 -1 16 1623.93 79.0750 5 0 1 -16 1595.89 143.552 1 0 -1 -16 1521.50 141.047 1 0 -1 17 434.229 44.4725 5 0 1 -17 547.457 83.5904 1 0 -1 -17 645.120 92.5553 1 0 -1 -18-9.30024 31.3368 1 0 1 -18-2.86867 25.1281 1 0 -1 18-29.8626 32.1971 5 0 1 -19-93.8118 37.8898 1 0 -1 -19-115.978 45.7390 1 0 1 -20 827.965 117.591 1 0 -1 -20 856.968 118.907 1 0 1 -21-64.6682 43.4340 1 0 -1 -21-77.9301 38.9899 1 0 1 -22 48.4072 32.2814 1 0 -1 -22 146.083 52.9600 1 0 1 -23 14.6783 26.9804 1 0 -1 -23 12.0713 41.5694 1 0 1 -24 169.277 61.9787 1 0 -1 -24 93.0929 69.8416 1 0 -1 -25 6.96516 38.0020 1 0 1 -25-52.8807 46.1716 1 0 -1 -26 250.822 94.6158 1 0 1 -26 332.032 91.8275 1 0 -1 -27 75.6434 35.0429 1 0 1 -27-56.6978 39.9840 1 0 -1 -28 181.471 68.2020 1 0 1 -28 158.488 65.4841 1 0 2 0 45895.7 253.169 4 0 -2 0 46872.7 268.865 2 0 2 -1 5360.08 101.058 2 0 -2 1 5544.85 101.898 2 0 2 1 5195.98 89.5227 4 0 2 2 5968.75 110.312 4 0 -2 -2 6254.11 110.330 4 0 -2 -3 10287.6 160.697 4 0 2 3 9875.12 165.029 1 0 2 4 2030.17 83.3789 1 0 -2 -4 1896.13 80.2443 1 0 2 -4 2018.09 52.7293 5 0 -2 -5 709.229 55.6991 1 0 2 5 739.284 54.6046 1 0 2 6 6260.25 170.648 1 0 -2 -6 6121.56 172.599 1 0 -2 6 5889.41 99.1837 5 0 2 7 1873.82 51.6533 3 0 -2 7 2004.01 60.2409 5 0 -2 -7 2005.76 102.432 1 0 2 7 2124.58 106.761 1 0 2 8 2799.09 130.280 1 0 -2 8 2462.99 71.6847 5 0 2 -8 2441.94 53.6846 3 0 -2 -8 2449.34 122.741 1 0 2 8 2451.05 60.1799 3 0 -2 9 631.058 37.3575 5 0 -2 -9 598.323 64.9683 1 0 2 9 639.506 31.2965 3 0 2 -9 664.254 70.1923 1 0 -2 10 132.072 18.3802 5 0 2 10 102.383 13.6183 3 0 2 -10 135.783 41.4992 1 0 -2 -10 126.649 39.0211 1 0 -2 11 11.1168 7.74578 5 0 2 11 27.0638 9.20221 3 0 -2 -11 34.1903 32.3592 1 0 2 -11 4.16554 25.7252 1 0 2 -12 4239.93 196.950 1 0 2 12 4245.68 75.4297 3 0 -2 12 4363.90 112.422 5 0 -2 -12 4327.23 198.766 1 0 -2 13 693.032 45.5349 5 0 2 -13 753.582 89.2723 1 0 -2 -13 635.447 83.1437 1 0 -2 14 1026.48 56.7434 5 0 2 -14 1115.82 112.318 1 0 -2 -14 1120.05 112.498 1 0 2 -15-0.81458 31.9258 1 0 -2 -15 43.7937 23.0697 1 0 -2 15 9.82508 11.6590 5 0 -2 16 1257.12 65.0572 5 0 2 -16 1168.28 124.115 1 0 -2 -16 1169.18 122.115 1 0 -2 17 889.804 56.0313 5 0 -2 -17 958.769 117.464 1 0 2 -17 927.399 115.282 1 0 -2 -18 666.614 103.832 1 0 2 -18 693.383 102.906 1 0 -2 -19 16.8014 39.2846 1 0 2 -19 2.35227 38.9147 1 0 2 -20-1.92788 5.87743 1 0 -2 -20-13.1374 50.2943 1 0 -2 -21 58.4243 51.6480 1 0 2 -21-28.9426 26.1349 1 0 -2 -22 272.630 86.7520 1 0 2 -22 280.069 72.4868 1 0 2 -23 24.3188 43.5866 1 0 -2 -23 47.3187 50.3483 1 0 2 -24 666.073 122.740 1 0 -2 -24 674.858 125.409 1 0 -2 -25 1.01428 41.3224 1 0 2 -25 93.0044 68.8901 1 0 -2 -26 242.325 86.9904 1 0 2 -26 20.1237 55.0828 1 0 -2 -27-2.79515 51.7033 1 0 2 -27 106.793 81.5174 1 0 -2 -27 29.3828 63.1697 4 0 2 -28-84.7421 82.5332 1 0 -2 -28-67.8196 77.5526 1 0 -3 0 0.79617 10.8759 4 0 3 0 11.6843 13.6236 4 0 3 -1 1532.11 63.5979 2 0 -3 1 1474.12 63.1961 2 0 3 1 1491.51 57.4042 4 0 -3 -1 1528.13 56.3461 4 0 -3 -2 607.620 40.5295 4 0 3 2 620.536 40.5791 4 0 3 3 11.6481 14.4841 4 0 -3 -3 21.7197 19.0349 4 0 -3 -4 21580.3 278.041 4 0 3 4 22282.1 287.844 1 0 -3 -5 957.732 65.6015 4 0 3 5 1061.80 69.7769 1 0 3 -5 1029.25 44.9777 5 0 3 6 521.376 51.5458 1 0 -3 -6 473.799 52.8038 1 0 3 -6 498.211 31.9435 5 0 3 7 3473.65 141.228 1 0 -3 -7 3034.68 132.584 1 0 -3 -8 5134.03 179.173 1 0 3 8 5495.05 186.059 1 0 3 9 3159.86 81.2304 3 0 -3 -9 3007.20 146.187 1 0 3 10 1456.61 55.2938 3 0 -3 -10 1474.82 109.576 1 0 3 -11 20.0313 6.39059 3 0 -3 -11 26.1920 25.6191 1 0 3 -12 271.809 18.9705 3 0 3 12 243.465 24.4213 3 0 -3 -12 349.739 65.6643 1 0 3 -12 333.502 62.2439 1 0 3 13 45.0702 12.1716 3 0 -3 -13 71.0894 42.8730 1 0 3 -13 21.3937 26.4451 1 0 -3 -14 1725.55 141.035 1 0 3 -14 1515.72 129.555 1 0 3 14 1619.41 54.3881 3 0 3 -15 638.921 91.8364 1 0 -3 -15 749.796 100.844 1 0 3 -16 770.382 98.5775 1 0 -3 -16 801.468 103.787 1 0 3 -17 2561.80 188.144 1 0 -3 -17 2746.09 199.746 1 0 -3 -18-21.6781 42.8945 1 0 3 -18-12.7760 32.0104 1 0 3 -19 29.0026 32.4041 1 0 -3 -19 181.660 65.7106 1 0 3 -20 221.547 62.9162 1 0 -3 -20 225.965 72.6673 1 0 -3 -21 31.1523 43.5240 1 0 -3 -22 899.265 134.917 1 0 3 -22 978.304 132.605 1 0 3 -23 3.24926 36.7710 1 0 -3 -23 40.8640 43.0880 1 0 3 -24 12.4244 30.7028 1 0 -3 -24-9.84758 51.9196 1 0 -3 -25-4.25328 62.3145 4 0 3 -25 28.0695 39.4625 1 0 -3 -25-35.7754 53.5429 1 0 -3 -26 251.322 83.3336 4 0 3 -26 351.356 96.9857 1 0 -3 -26 285.924 94.7974 1 0 -3 -27 44.8189 60.0733 4 0 -3 -27 64.4011 63.8296 1 0 3 -27 54.2439 67.0969 1 0 -3 -28 28.4735 55.1109 1 0 4 0 7349.56 141.561 4 0 -4 0 7491.89 141.484 4 0 -4 0 7383.29 153.416 2 0 4 -1 14151.3 215.082 2 0 -4 1 14037.7 219.288 2 0 4 1 13815.2 191.412 4 0 -4 -1 14503.7 197.238 4 0 4 -2 3035.64 106.349 2 0 -4 -2 3061.67 97.7242 4 0 4 2 2911.25 94.8075 4 0 -4 -3 12158.0 205.272 4 0 4 3 11877.0 201.412 4 0 -4 -4 8028.74 176.897 4 0 4 4 8001.24 176.999 4 0 -4 -5 1745.33 92.1680 4 0 4 5 1872.83 95.3225 1 0 -4 -6 6420.51 186.543 4 0 4 -6 6819.26 130.195 5 0 4 6 6922.17 194.795 1 0 -4 -7 609.187 66.1261 4 0 4 -7 659.039 40.9647 5 0 4 7 751.457 68.5889 1 0 4 -8 3129.16 92.6518 5 0 -4 -8 3114.58 144.745 4 0 -4 -9 48.3220 33.0759 1 0 -4 -10 2649.81 148.700 1 0 4 11 1918.31 72.2860 3 0 -4 -11 1936.01 132.494 1 0 4 -12 1486.40 57.1606 3 0 4 12 1650.45 67.9796 3 0 -4 -12 1602.81 127.484 1 0 4 -13 4715.22 96.2234 3 0 4 -13 5200.07 238.920 1 0 -4 -13 4808.44 227.101 1 0 4 13 5101.66 120.444 3 0 4 -14 125.658 44.9233 1 0 4 -14 195.891 17.0194 3 0 4 14 169.597 24.4008 3 0 -4 -14 247.976 63.2077 1 0 4 15 76.8205 15.8427 3 0 4 -15 74.6859 43.8261 1 0 -4 -15 83.6875 45.5668 1 0 4 16 25.8207 10.7215 3 0 -4 -16-13.6801 35.9713 1 0 4 -16 13.1803 35.5475 1 0 -4 -17 543.624 91.8780 1 0 4 -17 521.013 86.0762 1 0 -4 -18 164.595 60.8567 1 0 4 -18 119.744 49.8274 1 0 -4 -19 147.179 52.7506 1 0 4 -19 123.056 42.3793 1 0 -4 -20 548.706 99.1146 1 0 4 -20 460.635 88.2987 1 0 -4 -21 10.7275 45.5252 1 0 4 -21-23.1264 24.7827 1 0 -4 -22 59.4978 54.3416 1 0 4 -22-35.5809 26.3829 1 0 -4 -22 2.15083 46.8735 4 0 -4 -23-3.25425 43.5097 1 0 4 -23-36.2191 29.4040 1 0 -4 -23 47.8760 55.2631 4 0 -4 -24 242.850 83.4321 1 0 4 -24 353.372 90.5483 1 0 -4 -24 343.000 96.0834 4 0 -4 -25-73.1904 74.4451 1 0 4 -25-50.4106 59.1620 1 0 -4 -25 101.576 74.1352 4 0 4 -26-13.1013 46.8647 1 0 -4 -26 40.1848 59.4508 4 0 4 -27-37.0868 59.3893 1 0 -4 -27 64.2783 75.6819 4 0 -5 0-11.3805 25.0059 2 0 5 0-0.30751 11.5993 4 0 -5 1 2985.80 113.074 2 0 5 -1 3072.11 111.815 2 0 -5 -1 3044.30 105.813 4 0 5 1 3016.38 98.5069 4 0 -5 2 20397.8 303.439 2 0 5 -2 20328.9 295.910 2 0 -5 -2 19976.7 266.333 4 0 5 2 19658.4 263.469 4 0 5 -3 24451.9 340.960 2 0 5 3 24281.2 306.943 4 0 -5 -3 24206.3 314.992 4 0 -5 -4 332.627 44.7979 4 0 5 4 336.545 41.6403 4 0 -5 -5 940.372 72.6101 4 0 -5 -6 354.906 50.6796 4 0 5 6 401.284 52.3570 1 0 5 -7 2592.43 88.8365 5 0 -5 -7 2533.30 128.623 4 0 5 -8 4578.58 122.944 5 0 -5 -8 4168.80 172.800 4 0 5 -9 2681.34 93.6747 5 0 -5 -9 2663.95 145.812 4 0 -5 -10 4433.56 193.719 4 0 -5 -11 233.499 58.9802 4 0 -5 -12 2.26839 37.1956 4 0 5 12-6.94110 15.0078 3 0 -5 -13 724.009 95.1169 4 0 5 13 756.814 50.4724 3 0 -5 -14 2613.37 175.660 4 0 5 -14 2330.74 77.7128 3 0 5 14 2635.27 96.5513 3 0 5 -15 1606.07 148.407 1 0 5 15 1805.48 79.2354 3 0 -5 -15 1768.85 152.504 4 0 5 -15 1568.92 58.5020 3 0 -5 -15 1737.91 148.152 1 0 5 -16 53.1398 8.99447 3 0 -5 -16 67.5891 46.9910 4 0 5 -16 73.8238 10.6598 3 0 5 16 52.4983 13.4421 3 0 -5 -16 49.3754 42.5179 1 0 5 -16 6.45392 30.3365 1 0 -5 -17 625.167 101.583 1 0 5 17 513.440 39.1166 3 0 5 -17 606.157 94.2772 1 0 -5 -17 658.719 104.842 4 0 5 -18 28.4045 29.5204 1 0 -5 -18-16.3426 42.5652 1 0 -5 -18 84.8875 66.4812 4 0 5 -19-20.5445 34.9012 1 0 -5 -19-62.2760 56.9218 1 0 -5 -19 41.7517 53.7535 4 0 5 -20-43.2452 47.9632 1 0 -5 -20 31.8391 54.5963 4 0 5 -21 174.356 58.0805 1 0 -5 -21 141.152 71.6794 4 0 5 -22 308.076 79.9940 1 0 -5 -22 338.842 86.6507 4 0 5 -23 73.4702 42.3730 1 0 -5 -23 80.3785 53.4546 4 0 5 -24 8.48601 31.1747 1 0 -5 -24 9.43032 61.9491 4 0 5 -25-52.0269 58.9680 1 0 -5 -25 63.3343 65.9864 4 0 5 -26 201.158 80.3009 1 0 -5 -26 323.368 102.851 4 0 5 -27 74.6265 63.1825 1 0 -6 0 143.581 37.4272 2 0 6 0 199.491 29.2836 4 0 -6 1 1327.06 84.6954 2 0 6 -1 1365.88 82.0180 2 0 -6 -1 1179.09 73.7217 4 0 6 -1 1234.14 69.6691 4 0 6 1 1268.94 71.1412 4 0 -6 -2 5617.55 155.526 4 0 6 2 5736.26 154.786 4 0 6 -2 6001.90 173.850 2 0 -6 2 5692.78 175.156 2 0 -6 -3 3813.58 133.128 4 0 6 3 3853.89 132.289 4 0 6 -3 4031.98 148.856 2 0 -6 -4 2501.46 116.899 4 0 6 -4 2776.93 127.453 2 0 6 4 2800.03 116.412 4 0 6 5 2858.97 124.079 4 0 -6 -5 2724.56 125.203 4 0 -6 -6 11607.0 265.441 4 0 -6 -7 2703.83 137.914 4 0 -6 -8 2279.87 134.698 4 0 6 -8 2308.02 87.8495 5 0 -6 -9 202.002 48.4574 4 0 6 -9 255.760 31.1269 5 0 -6 -10 2076.83 141.172 4 0 6 -10 1954.80 86.7011 5 0 -6 -11 3692.44 191.152 4 0 -6 -12 3339.99 190.535 4 0 -6 -13 2296.56 165.610 4 0 6 13 2280.95 97.2966 3 0 -6 -14 115.064 63.2118 4 0 6 14 21.1797 12.5690 3 0 6 -15 12.6656 11.0859 3 0 6 15-35.5048 19.5356 3 0 -6 -15 42.1302 46.9369 4 0 6 16 23.6039 16.0837 3 0 -6 -16 59.4118 48.1703 4 0 -6 -17 24.9428 52.9624 4 0 6 -17 33.9039 33.1378 1 0 6 17 40.8669 27.2161 3 0 6 -18 289.480 65.0844 1 0 -6 -18 347.506 87.0096 4 0 6 -19-17.7213 31.4023 1 0 -6 -19 24.7832 58.6832 4 0 6 -20 142.736 51.5643 1 0 -6 -20 246.959 77.0429 4 0 6 -21 56.1836 20.6945 1 0 -6 -21 90.7902 71.2244 4 0 6 -22-65.2964 40.3349 1 0 -6 -22-7.51061 54.9476 4 0 6 -23 232.584 69.3022 1 0 -6 -23 252.744 79.4974 4 0 6 -24-22.7103 22.6002 1 0 -6 -24-105.153 88.1958 4 0 6 -25 113.878 52.8339 1 0 -6 -25 139.117 81.0790 4 0 6 -26 48.6722 53.7971 1 0 -6 -26-14.9272 60.2486 4 0 6 -27 62.0472 81.6311 1 0 -7 0 12.0122 31.2204 2 0 7 0 9.05410 17.0992 4 0 -7 1 10495.0 248.827 2 0 -7 -1 10413.8 243.334 2 0 7 -1 11379.4 251.073 2 0 7 1 10852.1 219.415 4 0 7 -1 11032.7 225.606 4 0 -7 -1 10810.9 231.525 4 0 7 -2 3599.22 144.869 2 0 -7 2 3483.26 148.677 2 0 7 2 3584.94 131.706 4 0 -7 -2 3427.32 131.491 4 0 7 -3 12201.3 274.336 2 0 -7 -3 11639.3 244.511 4 0 7 3 11939.7 247.066 4 0 7 4 584.878 59.3760 4 0 -7 -4 594.950 62.5165 4 0 -7 -5 3184.97 140.708 4 0 7 5 3335.70 141.302 4 0 -7 -6-8.48578 32.9033 4 0 -7 -7 2861.61 149.393 4 0 -7 -8 932.081 87.3467 4 0 -7 -9 3147.37 168.075 4 0 7 -9 3178.84 117.053 5 0 7 -10 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4 -13 126.181 50.8774 1 -2 4 12 496.450 54.5575 3 2 4 -12 456.158 49.1907 3 2 -4 -12 515.300 79.2295 1 2 4 -12 506.535 83.0029 1 -2 4 11 2.44165 20.4001 3 2 4 -11 31.9747 13.6578 3 2 -4 -11 46.0243 39.8508 1 2 4 -10 1908.07 96.4201 3 -2 4 10 1843.83 96.9436 3 2 -4 -10 1896.55 131.839 1 2 4 -9 418.548 44.0043 3 -2 4 9 423.485 45.8215 3 2 -4 -9 431.023 62.2504 1 -2 4 8 3800.98 136.689 3 2 4 -8 4132.55 136.130 3 -2 4 7 720.279 58.0140 3 2 4 -7 795.976 59.5929 3 2 -4 -6 88.7456 18.8758 3 -2 4 6 96.8009 23.4015 3 -2 4 6 75.6355 26.7621 1 2 -4 -5 22.1133 14.9691 3 -2 4 5 30.1475 15.9464 3 -2 4 5 36.3865 21.2808 1 -2 4 4 1674.17 83.8490 3 2 -4 -4 1955.28 84.5301 3 -2 4 3 674.780 53.5959 3 2 -4 -3 644.643 50.0894 3 -2 4 2 627.307 51.9806 3 2 -4 -2 628.484 49.3499 3 2 -4 -2 649.184 33.0468 4 -2 4 1 4231.87 129.070 5 -2 4 1 4027.99 125.325 3 2 4 -1 4070.27 114.498 2 2 -4 -1 4234.88 121.032 3 -2 4 0 2273.26 96.5767 5 2 4 0 2582.31 111.177 4 -2 4 0 2440.13 96.0976 3 2 4 0 2513.03 84.5635 2 -2 -4 0 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69.9681 1 -2 -4 -16 395.828 77.1305 1 -2 -4 -17-2.27037 52.7960 4 2 -4 17 16.0559 27.4746 5 -2 4 -17 34.8946 21.1739 1 -2 -4 -17 28.3731 43.9062 1 -2 -4 -18 428.103 99.2189 4 2 -4 18 479.931 64.7523 5 -2 -4 -18 425.024 82.2239 1 -2 4 -18 496.944 88.5926 1 -2 -4 -19 553.153 105.980 4 -2 -4 -19 482.878 87.9788 1 -2 4 -19 480.964 87.8564 1 -2 -4 -20 453.069 101.785 4 -2 -4 -20 282.562 68.3458 1 -2 4 -20 338.411 78.8999 1 -2 -4 -21 300.385 93.8902 4 -2 -4 -21 225.407 74.0611 1 -2 4 -21 201.525 62.2461 1 -2 -4 -22 284.643 93.1703 4 -2 4 -22 174.248 56.0953 1 -2 -4 -23 2.71698 49.9657 4 -2 4 -23-1.35856 51.9456 1 -2 -4 -24 39.3395 68.6703 4 -2 4 -24 13.6073 32.2670 1 -2 -4 -25 78.7474 64.9242 4 -2 4 -25 86.4113 55.7530 1 -2 -4 -26 191.911 78.5028 4 -2 4 -26 281.967 86.7079 1 -2 4 -27 52.2138 54.8074 1 2 -5 -27-26.9841 55.6416 4 2 5 -27 90.7677 80.1560 1 2 5 -26 172.537 96.8619 1 2 5 -25 71.9140 63.3127 1 2 5 -24 282.991 80.0063 1 2 5 -23 19.8619 25.2397 1 2 5 -22 22.0352 39.9928 1 2 5 -21 79.0718 57.5576 1 2 -5 -21 117.993 67.4624 1 2 5 -20 24.1616 34.4328 1 2 -5 -20 57.3240 57.0329 1 2 5 -19 206.915 69.5838 1 2 -5 -19 199.049 69.6232 1 -2 5 18 462.900 51.9937 3 2 5 -18 461.419 89.7689 1 2 -5 -18 354.987 88.4438 1 -2 5 17 313.146 45.1515 3 2 5 -17 300.519 74.6560 1 2 -5 -17 347.593 81.2318 1 2 5 -16 2929.22 121.388 3 -2 5 16 3207.05 140.447 3 2 5 -16 3074.84 212.264 1 2 -5 -16 3037.50 209.709 1 2 5 -15 239.981 34.8032 3 -2 5 15 322.123 46.4332 3 2 5 -15 351.688 77.2486 1 2 -5 -15 351.827 77.6391 1 2 5 -14 491.805 80.1882 1 -2 5 14 508.190 57.7381 3 2 -5 -14 491.959 87.5740 1 2 5 -14 489.859 53.3791 3 2 5 -13 611.679 56.3695 3 -2 5 13 666.070 65.8795 3 2 5 -12 4469.64 153.321 3 -2 5 12 4325.14 160.152 3 2 5 -11 3317.44 129.991 3 -2 5 11 3159.02 134.388 3 2 5 -11 3245.99 63.4058 5 -2 5 10 6019.76 182.018 3 2 5 -10 6014.73 175.149 3 -2 5 9 1698.44 94.3814 3 2 5 -9 1835.76 97.1379 3 -2 5 8 19.3990 11.7424 3 -2 5 7 643.724 57.1680 3 -2 5 6 1465.21 85.0304 3 -2 5 5 1389.67 81.0795 3 -2 5 4 271.661 35.1854 3 2 -5 -4 311.741 36.5370 4 -2 5 3 145.215 28.9142 3 2 -5 -3 173.641 25.7045 4 2 -5 -2 35.2820 14.7452 4 2 5 -2 17.6034 10.4402 2 -2 5 2 17.3205 16.3245 3 2 -5 -1 1589.70 47.5716 4 2 5 -1 1708.05 95.9573 4 -2 5 1 1598.32 82.8925 3 2 5 -1 1659.24 80.9633 2 2 5 0 612.864 59.4794 4 2 5 0 581.887 48.3661 2 2 -5 0 548.375 52.5219 2 -2 5 0 560.585 50.2075 3 -2 -5 0 546.701 47.4588 2 2 5 1 265.002 39.0431 4 -2 -5 -1 271.388 46.6118 4 -2 -5 -1 288.551 37.5942 2 2 -5 1 324.819 43.8916 2 -2 5 -1 280.854 35.4789 5 -2 5 -1 278.748 35.5953 3 -2 5 -2 5800.01 160.885 2 2 -5 2 5535.88 161.010 2 -2 5 -2 5848.98 151.598 3 2 5 2 6013.51 178.662 4 -2 -5 -2 5971.17 187.872 4 -2 5 -2 6229.62 172.383 5 -2 -5 -3 54.6628 31.7266 4 -2 5 -3 59.3927 18.2516 3 2 5 3 73.1571 28.8277 4 -2 5 -3 56.6224 24.2395 2 -2 5 -3 179.135 29.4260 5 -2 5 -4 3135.53 128.244 5 -2 5 -4 3007.74 107.688 3 -2 5 -4 3094.39 125.924 2 -2 -5 -4 2991.50 137.794 4 2 5 4 3184.73 137.493 4 -2 5 -5 6159.35 184.510 2 -2 5 -5 5035.74 164.362 5 -2 5 -5 5811.76 149.056 3 -2 -5 -5 6076.35 203.917 4 -2 5 -6 8434.97 217.236 5 2 5 6 10164.9 231.481 1 -2 5 -6 9812.81 191.902 3 -2 -5 -6 10187.0 271.542 4 2 -5 7 1058.36 76.4156 5 -2 -5 -7 1123.65 97.8665 4 2 5 7 1149.87 81.7858 1 -2 5 -7 1124.59 66.8763 3 2 -5 8 500.276 54.0245 5 -2 5 -8 495.924 43.8170 3 -2 -5 -8 520.481 74.3259 4 -2 -5 -9 42.5015 37.3797 4 2 -5 9 28.7321 14.8038 5 -2 5 -9 43.0933 14.8362 3 2 -5 10 1567.50 98.0846 5 -2 -5 -10 1565.38 126.146 4 -2 5 -10 1482.73 72.0090 3 -2 -5 -11 352.335 65.6618 4 -2 5 -11 388.905 36.6097 3 2 -5 11 335.603 45.3754 5 2 -5 12 2365.26 124.484 5 -2 5 -12 2274.87 86.8162 3 -2 -5 -12 2345.70 166.227 4 -2 5 -13 1827.48 72.7432 3 -2 -5 -13 1914.69 156.037 4 2 -5 13 1923.45 113.455 5 -2 5 -14 445.907 33.3115 3 -2 -5 -14 449.576 82.9358 4 2 5 14 507.868 43.0166 3 2 -5 14 533.270 60.6794 5 -2 -5 -15 953.945 119.908 4 2 -5 15 952.734 81.9018 5 -2 5 -15 798.300 35.2581 3 -2 5 -15 845.493 106.693 1 -2 -5 -16 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95.6289 25.9189 3 -2 6 16 383.867 54.3320 3 2 6 -16 406.833 85.5964 1 2 6 -16 330.568 43.1048 3 2 6 -15 518.748 54.5151 3 -2 6 15 573.645 63.0164 3 -2 6 14 1025.77 80.4591 3 2 6 -14 1080.13 79.1147 3 -2 6 13 587.555 62.4534 3 2 6 -13 607.768 58.9508 3 2 6 -12 2121.01 61.9742 5 2 6 -12 2234.64 113.368 3 -2 6 12 2168.23 116.852 3 2 6 -11 710.365 62.4930 3 -2 6 11 636.033 62.0786 3 -2 6 10 1051.53 77.8700 3 -2 6 9 520.519 54.5539 3 -2 6 8 2768.66 123.821 3 -2 6 7 259.104 35.5219 3 2 -6 -6 39.4676 24.7579 4 -2 6 6 96.3899 23.5396 3 2 -6 -5 238.152 36.6387 4 -2 6 5 271.535 38.3150 3 2 -6 -4 12.7065 18.5561 4 -2 6 4 42.1860 20.2410 3 -2 6 3 6348.07 175.830 3 2 6 -3 6724.01 192.321 2 2 -6 -3 6219.38 137.318 4 2 6 -2 2509.13 111.636 2 -2 6 2 2503.07 109.637 3 2 -6 -2 2416.42 78.3762 4 -2 6 1 1631.36 56.5762 4 -2 -6 1 1720.45 94.6282 2 2 6 -1 1776.47 91.6636 2 -2 6 1 1793.16 91.9700 3 2 6 -1 1730.41 103.136 4 2 -6 -1 1671.71 59.2944 4 -2 -6 0 1205.66 78.0572 2 -2 6 0 1225.72 75.6297 3 2 6 0 1316.53 76.1390 2 2 -6 0 1159.17 78.7246 2 -2 6 0 1150.00 44.4547 4 2 6 0 1251.65 86.9301 4 -2 6 -1 2329.11 104.442 3 2 -6 1 2499.39 115.368 2 -2 -6 -1 2441.20 108.026 2 2 6 1 2537.34 121.608 4 -2 6 -1 2348.70 66.1197 4 -2 -6 -1 2505.11 129.419 4 -2 6 -2 4744.13 156.989 2 2 -6 2 4500.66 155.637 2 -2 6 -2 4265.86 138.739 3 -2 -6 -2 4372.25 142.589 2 2 6 2 4762.45 165.583 4 -2 -6 -2 4611.21 176.126 4 -2 6 -2 4174.27 145.120 5 2 -6 3 3789.82 148.235 2 -2 6 -3 3920.93 130.858 3 -2 6 -3 4090.20 149.316 2 -2 -6 -3 3965.65 163.854 4 -2 6 -3 3724.14 142.233 5 -2 6 -4 1968.60 93.1218 3 -2 6 -4 2273.86 115.219 2 -2 -6 -4 2063.00 119.924 4 -2 6 -4 2085.71 109.644 5 -2 -6 -5 720.071 76.2419 4 -2 6 -5 809.185 71.3053 2 -2 6 -5 791.537 59.0201 3 -2 6 -6 74.0800 31.1060 3 -2 -6 -6 50.2093 36.1522 4 -2 6 -7 1072.50 66.3343 3 -2 -6 -7 1186.37 100.783 4 -2 6 -8 3930.92 127.828 3 -2 -6 -8 3892.20 190.325 4 -2 6 -9 7710.07 178.613 3 -2 -6 -9 7922.55 278.903 4 -2 6 -10 609.872 50.1985 3 -2 -6 -10 606.053 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544.105 76.6627 3 4 7 -15 2593.51 202.188 1 -4 7 15 2312.47 156.615 3 -4 7 14 742.672 86.3404 3 -4 7 13 1122.77 108.220 3 -4 7 12 51.9730 39.3502 3 -4 7 11 338.583 63.2268 3 -4 7 9 3233.38 169.977 3 -4 7 8 411.809 61.9299 3 -4 7 7 1024.41 94.2386 3 -4 7 6 191.344 41.6814 3 -4 7 5-14.2409 12.9507 3 -4 7 4-71.2132 24.4103 3 4 -7 -4 26.1010 20.7166 4 4 7 -3 2999.79 138.681 2 4 -7 -3 2846.83 80.5737 4 -4 7 3 3097.44 159.046 3 4 7 -2 1725.04 103.027 2 4 -7 -2 1668.82 46.4022 4 -4 7 2 1690.52 117.800 3 -4 7 1 2792.69 149.941 3 4 7 -1 2849.03 123.470 2 4 -7 0 108.053 39.8997 2 -4 7 0 86.9857 17.8492 3 4 -7 1 159.061 48.0431 2 -4 7 -1 109.807 35.9352 3 -4 -7 -1 86.0800 25.4434 2 4 -7 2 1465.87 100.705 2 -4 -7 -2 1459.28 89.5025 2 -4 7 -2 1525.82 109.019 3 -4 -7 -2 1442.46 122.744 4 -4 -7 -3 627.016 59.3699 2 4 -7 3 617.963 66.2780 2 -4 -7 -3 663.728 86.5895 4 -4 7 -3 684.481 76.1201 3 -4 -7 -4 3386.61 136.715 2 -4 7 -4 3237.37 81.7840 4 -4 7 -4 3399.98 161.130 3 -4 -7 -4 3310.64 189.181 4 -4 7 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21.5383 19.5468 1 -4 -7 -20 44.7134 60.9350 4 -4 7 -21 632.772 105.707 1 -4 -7 -21 771.290 139.030 4 -4 7 -22 134.595 57.3642 1 -4 -7 -22 22.4516 57.7478 4 -4 7 -23 16.5314 21.4511 1 -4 -7 -23 236.457 96.6992 4 -4 7 -24-28.0841 51.7252 1 -4 7 -24 43.7075 48.3472 4 -4 7 -25 126.157 73.9549 1 -4 7 -25 126.728 78.5234 4 4 -8 -26 72.4667 73.5204 4 4 8 -25 38.5327 38.5103 1 4 -8 -25 62.3364 56.6949 4 4 8 -24 320.009 85.8702 1 4 8 -23 267.369 78.5117 1 4 8 -22 138.139 56.2831 1 4 8 -21 86.3646 43.8229 1 4 8 -20 6.72527 31.8072 1 -4 8 19-26.7732 24.2139 3 4 8 -19-43.7938 57.6535 1 -4 8 18 193.742 46.3738 3 4 8 -18 202.895 78.2630 1 -4 8 17 265.711 53.2325 3 4 8 -17 299.963 79.9951 1 -4 8 16 152.621 43.6479 3 -4 8 15 36.1854 36.9704 3 -4 8 14 440.022 71.5592 3 -4 8 13 1766.44 138.312 3 -4 8 12-73.0473 28.5235 3 -4 8 11 2843.87 173.403 3 -4 8 10 910.495 95.1204 3 -4 8 9 350.163 59.4172 3 -4 8 8 125.513 35.5868 3 4 -8 -7 5301.22 170.538 4 -4 8 7 5723.92 230.490 3 -4 8 6-88.1708 30.6023 3 4 -8 -6 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216.278 80.2547 4 5 9 -25 87.6964 70.4681 1 5 -9 -25 12.2715 48.0631 4 5 9 -24 98.3412 50.8780 1 5 -9 -24 61.3322 61.3670 4 5 9 -23 129.968 55.3857 1 5 9 -22 314.865 81.5213 1 5 9 -21 153.143 71.5771 1 5 9 -20 181.307 66.5746 1 -5 9 19 37.0098 22.0897 3 5 9 -19 116.495 54.4469 1 -5 9 18 4.31830 24.9151 3 5 9 -18 15.4001 48.8346 1 -5 9 17 80.8896 37.5262 3 5 9 -17 87.7171 58.8627 1 -5 9 16 411.619 76.0541 3 -5 9 15 35.4528 32.4223 3 -5 9 14 481.371 82.8658 3 -5 9 13 508.699 85.9503 3 -5 9 12 641.609 96.2252 3 -5 9 11 31.9628 43.3798 3 -5 9 10 6727.96 288.063 3 -5 9 9 737.692 94.7780 3 5 -9 -9 835.131 82.2077 4 -5 9 8 825.088 99.2093 3 5 -9 -8 810.302 73.4415 4 -5 9 7 182.638 49.6435 3 5 -9 -7 231.877 40.5334 4 -5 9 6 714.142 89.4479 3 5 -9 -6 588.924 54.6797 4 5 -9 -5 531.333 45.6921 4 -5 9 5 513.408 75.7632 3 5 -9 -4 2867.23 89.5368 4 -5 9 4 2993.93 180.693 3 5 -9 -3 4.76941 8.72086 4 -5 9 3-68.7311 30.3959 3 -5 9 2 630.949 81.3856 3 -5 9 1 209.407 47.4106 3 5 -9 -1 238.717 54.8784 2 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1 -5 -10 -20 154.105 80.3006 4 -5 10 -21 12.7189 53.1023 1 -5 -10 -21-45.9410 58.3155 4 -5 -10 -22-49.8934 37.0855 4 5 -11 -25-41.7684 68.2679 4 5 11 -24 60.2631 45.8829 1 5 -11 -24 13.7185 72.8954 4 5 11 -23-3.12487 41.2290 1 5 -11 -23-0.24082 58.9258 4 5 11 -22 251.116 76.5372 1 5 -11 -22 442.140 106.232 4 5 11 -21 138.132 59.5578 1 5 -11 -21 39.5799 61.3503 4 5 11 -20-15.2953 40.0483 1 5 -11 -20-32.8138 56.4373 4 5 11 -19 79.6682 45.7953 1 5 -11 -19 6.09804 49.9244 4 -5 11 19 134.510 44.3688 3 5 -11 -18 78.8932 45.5200 4 -5 11 18 64.8590 33.8711 3 5 -11 -17 76.3977 51.6772 4 -5 11 17 87.2702 44.4494 3 5 -11 -16 76.2845 49.8413 4 -5 11 16 109.592 54.4326 3 5 -11 -15 23.7726 45.7087 4 -5 11 15-3.99004 41.2562 3 5 -11 -14 331.364 71.3990 4 -5 11 14 266.361 69.4088 3 5 -11 -13 163.168 55.4338 4 -5 11 13 91.1047 36.9935 3 5 -11 -12 73.4072 45.6472 4 -5 11 12 73.2243 33.5249 3 5 -11 -11-7.65742 37.3619 4 5 -11 -10 4906.67 200.363 4 -5 11 10 5188.88 261.876 3 5 -11 -9 7.78753 25.2734 4 -5 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66.0335 32.3360 3 -5 -11 -7 172.800 48.3865 2 -5 -11 -7 210.970 63.3587 4 -5 -11 -8 2612.33 213.742 4 -5 11 -8 2962.49 181.131 3 -5 -11 -9 396.284 92.9193 4 -5 11 -9 467.952 73.4554 3 -5 -11 -10 225.932 72.4404 4 -5 11 -10 135.776 44.5424 3 -5 -11 -11 21.7867 41.9710 4 -5 11 -11-16.7419 15.3592 3 -5 -11 -12 1186.09 153.214 4 -5 11 -12 1123.68 116.083 3 -5 -11 -13 219.507 82.7329 4 -5 11 -13 273.178 60.6498 3 -5 -11 -14 1630.67 187.812 4 -5 11 -14 1516.35 125.641 3 -5 -11 -15 189.111 87.6209 4 -5 -11 -16 85.4782 63.7611 4 -5 -11 -17-32.9580 51.8037 4 -5 -11 -18 220.549 84.1659 4 -5 -11 -19 24.2228 60.7062 4 -5 11 -20 339.665 77.5293 1 -5 -11 -20 316.421 100.110 4 -5 11 -21 51.6479 56.6102 1 -5 -11 -21 36.4962 62.3213 4 5 -12 -25 6.25184 56.2037 4 5 -12 -24 395.698 101.735 4 5 12 -23 206.900 81.5345 1 5 -12 -23-44.7738 60.5802 4 5 12 -22-37.7259 30.5003 1 5 -12 -22 26.3969 55.0582 4 5 12 -21-3.89827 60.0062 1 5 -12 -21-20.5656 50.3118 4 5 12 -20 166.499 54.7628 1 5 -12 -20 283.330 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58.8537 38.0393 3 6 2 -13 12.1482 32.4669 1 -6 -2 12 1066.44 107.648 3 -6 2 12 979.544 109.609 3 6 2 -12 1043.56 110.493 1 6 -2 -12 1158.67 118.766 1 6 2 -12 975.043 66.8011 5 6 2 -11 107.063 51.3914 1 6 2 -11 54.9538 19.0366 5 -6 2 11 37.7263 23.9684 3 -6 -2 11 21.5871 28.9042 3 6 -2 -11 101.397 55.1707 1 6 2 -10 462.059 70.4198 1 -6 -2 10 547.178 79.7531 3 -6 2 10 517.873 83.7275 3 6 -2 -10 503.481 79.1734 1 6 2 -10 499.322 54.1346 5 6 2 -9 28.0267 29.4952 1 6 2 -9 23.2000 13.9192 5 -6 2 9 14.9927 26.5341 3 -6 -2 9 22.2318 30.7303 3 6 -2 -9 38.3214 37.8834 1 -6 -2 8 4454.72 213.952 3 -6 2 8 4532.72 224.296 3 6 2 -8 4423.57 186.438 1 6 -2 -8 4301.86 171.201 5 6 -2 -7 299.208 46.6500 5 -6 -2 7 395.201 66.6437 3 -6 2 7 328.922 64.1716 3 6 2 -7 325.779 49.6496 1 -6 -2 6 501.905 75.3256 3 -6 2 6 458.171 77.7497 3 6 2 -6 482.101 56.2812 1 6 -2 -6 463.805 62.9451 5 6 -2 -5 81.3741 13.4231 5 -6 2 5 74.9537 35.6082 3 -6 -2 5 42.4558 25.1984 3 6 2 -5 68.5603 22.7550 1 -6 2 5 99.2990 28.3220 1 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84.6896 51.8294 4 -6 -2 -20 44.1877 58.0134 4 -6 2 -21 194.054 77.6065 4 -6 -2 -21 86.9427 57.3113 4 -6 2 -22 247.867 82.4380 4 -6 -2 -22 315.427 108.748 4 -6 2 -23 186.536 74.4533 4 -6 -2 -23 292.659 102.531 4 -6 2 -24 89.0554 71.1306 4 -6 -2 -24 7.77408 65.7231 4 6 3 -26-25.0429 76.0749 1 6 3 -25 117.356 68.7907 1 6 -3 -25 39.4494 63.2611 1 6 3 -24 82.9313 56.4077 1 6 -3 -24 108.832 63.0612 1 6 3 -23 349.390 90.4612 1 6 -3 -23 278.852 85.8804 1 6 3 -22 252.938 74.2172 1 6 -3 -22 73.5596 51.9065 1 6 3 -21 13.4323 22.7718 1 6 -3 -21-82.0583 67.2743 1 -6 3 20 42.1629 33.8212 3 6 3 -20-6.67402 13.4931 1 6 -3 -20 78.8512 67.2355 1 -6 3 19 170.245 47.8258 3 6 3 -19 170.178 59.1434 1 6 -3 -19 142.661 71.7936 1 -6 3 18 738.610 97.6584 3 6 -3 -18 674.045 116.901 1 6 3 -18 647.716 104.809 1 -6 3 17-2.45386 27.3597 3 6 -3 -17 12.0390 44.7020 1 -6 3 16 130.511 50.7855 3 6 3 -16 145.298 60.2046 1 6 -3 -16 188.766 67.3050 1 -6 3 15 1018.40 113.734 3 6 3 -15 1074.89 136.085 1 6 -3 -15 1017.99 130.311 1 -6 3 14 15.2412 31.2945 3 6 3 -14-11.6547 31.3928 1 6 -3 -14 18.2857 46.7655 1 6 3 -13 2116.91 162.204 1 -6 3 13 2091.63 159.370 3 6 -3 -13 2138.91 166.718 1 6 3 -13 2113.76 94.1964 5 6 3 -12 1532.44 132.810 1 -6 3 12 1442.23 134.165 3 6 -3 -12 1458.36 131.889 1 6 3 -12 1404.07 83.9953 5 6 3 -11 261.852 39.8379 5 6 3 -11 257.087 69.3379 1 -6 3 11 201.661 49.7623 3 -6 -3 10 1908.14 143.327 3 6 3 -10 1959.35 138.810 1 -6 3 10 1935.46 149.957 3 6 3 -9 3.27654 27.2694 1 -6 3 9-38.9134 39.0135 3 -6 -3 9-13.8957 33.9109 3 -6 3 8 2.37063 27.5894 3 -6 -3 8 31.1503 34.4327 3 6 3 -8 14.9000 31.9558 1 -6 -3 7 2025.43 145.075 3 6 -3 -7 1968.90 119.703 5 -6 3 7 1943.91 149.215 3 6 3 -7 1912.30 118.891 1 -6 -3 6 2040.82 145.610 3 -6 3 6 2060.68 154.719 3 6 3 -6 1996.13 113.399 1 6 -3 -6 2030.06 125.368 5 6 3 -5 24.5528 25.7761 1 6 -3 -5-15.7539 20.8254 5 -6 -3 5 7.61521 31.0807 3 -6 3 5-5.43777 29.2075 3 6 -3 -4 2184.98 135.014 5 -6 -3 4 2228.66 149.513 3 -6 3 4 2437.41 165.183 3 -6 3 4 2300.23 117.457 1 6 3 -4 2194.88 102.184 1 6 -3 -3 372.720 52.0764 5 6 3 -3 532.198 48.7149 1 -6 -3 3 476.615 72.9273 3 -6 3 3 543.507 81.6470 3 -6 3 3 416.057 47.5242 1 6 -3 -2 43.0628 13.4466 4 6 -3 -2 172.961 39.0174 5 6 3 -2 67.7145 18.9035 1 -6 3 2 70.8582 20.9168 1 -6 -3 2 66.8701 35.0163 3 -6 3 2 67.2540 43.8677 3 6 3 -1 14.5993 14.3672 2 6 3 -1 8.86789 8.19299 1 -6 3 1 44.1295 15.0804 1 6 -3 -1 17.8539 16.8399 5 6 -3 -1 22.0586 16.8614 4 -6 -3 1 7.69652 31.1561 3 -6 3 1-14.0095 33.1954 3 6 -3 0 1848.44 133.020 5 6 -3 0 1912.51 84.1210 4 6 -3 0 1934.87 79.5543 2 -6 -3 0 1998.73 139.604 3 -6 3 0 2219.95 154.271 3 -6 3 0 1905.26 81.3232 1 6 -3 1 661.526 51.0601 4 -6 -3 -1 675.389 81.1415 3 6 -3 1 684.752 44.9470 2 -6 3 -1 663.658 87.6778 3 6 -3 1 667.944 83.7861 5 6 -3 2 243.795 52.2674 5 -6 -3 -2 287.485 58.3800 3 -6 3 -2 252.354 56.1370 3 6 -3 2 277.743 34.0909 4 -6 3 -3 1300.53 110.514 3 -6 -3 -3 1220.06 107.509 4 6 -3 3 1369.51 118.605 5 6 -3 3 1185.92 69.8713 4 6 -3 4 179.229 49.4233 5 -6 3 -4 201.984 31.4436 4 -6 -3 -4 258.249 55.6215 4 -6 3 -4 230.905 48.7217 3 6 -3 5 5.69861 22.7668 5 -6 -3 -5 24.5154 22.9253 4 -6 3 -5 41.7829 19.2421 4 -6 3 -5 28.4193 32.5793 3 -6 -3 -6 3696.87 198.912 4 6 -3 6 3342.58 198.702 5 -6 3 -6 3619.75 185.206 3 -6 3 -6 3538.88 150.074 4 -6 3 -7 933.787 64.3121 2 -6 -3 -7 960.010 106.088 4 -6 3 -7 1057.01 88.5740 4 -6 3 -7 1022.75 99.4708 3 6 -3 7 1065.33 112.592 5 -6 -3 -8-0.91847 30.0041 4 -6 3 -8-5.00926 25.7105 4 -6 3 -8-13.5063 9.92813 1 -6 3 -8 6.98211 36.2107 3 -6 3 -8 5.62681 18.0319 2 6 -3 9 120.847 47.2756 5 -6 -3 -9 78.1761 43.9631 4 -6 3 -9 84.4070 20.9773 1 -6 3 -9 117.202 37.6677 4 -6 3 -9 96.6058 38.7643 3 -6 3 -9 122.941 35.4418 2 -6 -3 -10 363.352 77.1057 4 -6 3 -10 325.282 44.5810 1 -6 3 -10 344.450 62.1741 4 -6 3 -10 387.052 59.5011 3 6 -3 10 214.055 61.2568 5 -6 -3 -11 227.717 64.7053 4 -6 3 -11 141.576 26.8748 1 -6 3 -11 201.349 47.4110 4 -6 3 -11 218.912 50.0851 3 6 -3 11 195.048 61.4186 5 -6 3 -12 1547.78 113.927 3 -6 3 -12 1441.77 108.027 1 -6 -3 -12 1497.19 149.819 4 -6 3 -12 1487.29 129.307 4 6 -3 12 1493.19 144.823 5 -6 3 -13-5.48400 20.3000 1 -6 3 -13-29.4947 25.0529 3 6 -3 13 5.84695 53.2977 5 -6 3 -13 4.90510 39.3420 4 -6 -3 -13 16.5616 42.7806 4 -6 3 -14 190.241 41.9274 1 -6 3 -14 158.706 35.1140 3 -6 3 -14 185.797 58.4836 4 -6 -3 -14 232.600 62.6487 4 6 -3 14 230.410 72.3204 5 -6 3 -15 133.859 55.4709 4 -6 -3 -15 45.0753 36.9984 4 -6 3 -15 71.3733 33.5746 1 6 -3 15 73.3373 58.6713 5 -6 3 -16 52.5148 43.4474 4 -6 -3 -16 48.3031 49.4560 4 -6 3 -16 47.2848 41.1930 1 6 -3 16-20.8991 69.6552 5 -6 3 -17 186.954 61.8391 4 -6 -3 -17 197.310 73.9048 4 6 -3 17 102.401 74.3868 5 -6 3 -18 1227.35 144.469 4 -6 -3 -18 1178.02 154.946 4 6 -3 18 1016.68 137.648 5 6 -3 19-41.1621 84.3276 5 -6 3 -19 33.6959 34.7950 4 -6 -3 -19 70.7822 68.9781 4 -6 3 -20 49.8345 35.9266 4 -6 -3 -20 122.971 60.2215 4 -6 3 -21 128.023 63.4887 4 -6 -3 -21-28.2536 54.0616 4 -6 3 -22 150.667 78.7482 4 -6 -3 -22 88.1470 72.7446 4 -6 3 -23 109.105 60.5100 4 -6 -3 -23 127.911 87.5731 4 -6 3 -24 193.908 74.9016 4 -6 -3 -24 104.294 74.8090 4 6 4 -25-53.4707 80.1588 1 6 4 -24 52.9881 56.0391 1 6 4 -23 48.1438 45.6780 1 6 4 -22 83.6750 45.9439 1 6 4 -21 583.322 106.452 1 -6 4 20 960.729 110.646 3 6 4 -20 1011.88 140.024 1 -6 4 19 1018.17 114.456 3 6 4 -19 962.751 135.865 1 -6 4 18-18.3171 39.4920 3 6 4 -18 6.42290 29.0794 1 -6 4 17 101.348 46.7640 3 6 4 -17 97.5369 43.1089 1 -6 4 16 396.781 74.7516 3 6 4 -16 447.814 92.9706 1 -6 4 15 237.045 55.6877 3 6 4 -15 341.953 85.8494 1 -6 4 14 2377.56 173.734 3 6 4 -14 2455.33 92.7379 5 6 4 -14 2589.34 187.883 1 -6 4 13 179.177 48.1328 3 6 4 -13 121.516 27.5083 5 6 4 -13 123.391 35.4423 1 6 4 -12 149.734 31.6847 5 -6 4 12 197.286 53.6485 3 6 4 -12 207.409 53.7285 1 -6 4 11 11.8833 24.5325 3 6 4 -11 74.5648 46.9611 1 -6 4 10 574.888 88.1710 3 6 4 -10 540.272 75.4865 1 -6 4 9 676.319 95.4503 3 6 4 -9 725.751 84.1824 1 -6 4 8 2254.79 165.730 3 6 4 -8 1967.48 128.061 1 -6 4 7 1198.79 122.892 3 6 4 -7 1110.39 91.5846 1 -6 4 6 102.414 43.4513 3 6 4 -6 157.003 33.5199 1 6 -4 -5 119.779 30.1921 5 -6 4 5 84.5066 37.6710 3 6 4 -5 130.538 33.7192 1 6 -4 -4-14.4627 14.7795 5 -6 4 4 11.3662 33.2547 3 6 4 -4-21.0847 22.4421 1 -6 4 4-15.0167 27.2797 1 6 -4 -3 1579.61 116.620 5 6 4 -3 1558.61 85.2833 1 -6 4 3 1681.15 141.307 3 -6 4 3 1670.07 97.9726 1 6 -4 -2 5354.20 140.790 4 6 -4 -2 5773.01 227.477 5 6 4 -2 5889.39 148.942 1 6 4 -2 5508.11 143.057 2 -6 4 2 5724.90 253.410 3 -6 4 2 5640.92 172.757 1 6 -4 -1 161.931 36.9906 5 6 -4 -1 165.057 24.6432 4 6 4 -1 175.368 26.5064 1 -6 4 1 173.687 48.4592 3 6 4 -1 173.350 26.5723 2 -6 4 1 181.717 29.5753 1 6 -4 0 4938.66 116.933 4 6 4 0 5204.49 104.851 1 6 -4 0 5184.52 144.834 2 -6 4 0 5630.99 246.297 3 6 -4 0 5250.73 225.097 5 6 -4 1 580.656 47.6679 2 -6 4 -1 622.940 86.8572 3 6 -4 1 645.279 78.4269 5 6 -4 1 540.870 39.9284 4 6 -4 2 2083.36 146.031 5 -6 4 -2 2123.62 151.076 3 -6 4 -3 490.306 77.0315 3 6 -4 3 421.390 67.8091 5 -6 -4 -3 486.259 69.8215 4 -6 4 -4 4024.76 204.390 3 -6 4 -4 3762.57 132.394 4 -6 -4 -4 3815.45 205.873 4 6 -4 4 3794.78 203.166 5 -6 4 -5 1183.13 112.106 3 -6 4 -5 1223.05 80.6887 4 6 -4 5 1182.80 114.314 5 -6 -4 -5 1151.20 116.951 4 6 -4 6 188.859 52.4945 5 -6 4 -6 120.943 35.7909 3 -6 -4 -6 132.926 19.5197 2 -6 4 -6 103.383 28.4310 4 -6 -4 -6 93.1603 41.9835 4 6 -4 7 12.3485 50.6474 5 -6 4 -7 7.10309 17.3545 4 -6 -4 -7 6.50163 32.7496 4 -6 4 -7-11.5142 26.2613 3 -6 4 -7 21.4628 23.5102 2 -6 4 -8 635.319 70.5134 4 -6 -4 -8 562.698 85.4662 4 -6 4 -8 599.833 61.9419 2 -6 4 -8 664.267 81.6260 3 -6 4 -9 273.991 47.6339 4 -6 4 -9 297.246 52.4354 3 -6 -4 -9 271.879 67.7235 4 6 -4 9 190.820 60.8024 5 -6 -4 -10 1506.76 144.018 4 -6 4 -10 1582.75 118.700 4 6 -4 10 1415.45 136.831 5 -6 4 -10 1532.77 118.544 3 -6 4 -10 1474.63 101.483 1 -6 -4 -11 333.257 76.3283 4 6 -4 11 324.813 74.5743 5 -6 4 -11 299.491 58.2509 4 -6 4 -11 353.953 65.1322 3 -6 4 -11 217.149 38.1991 1 -6 -4 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33.5401 2 -6 8 0-5.06444 47.2865 3 6 -8 1 68.5989 32.8396 2 -6 8 -1 118.391 51.1326 3 6 -8 2 23.5312 21.4128 2 -6 8 -2 52.1510 38.0173 3 -6 8 -3 6350.81 275.348 3 -6 -8 -4 1325.64 86.7241 2 -6 8 -4 1349.64 130.493 3 -6 -8 -4 1276.83 135.228 4 -6 -8 -5 54.1378 37.9692 4 -6 -8 -5 82.2725 26.8248 2 -6 8 -5 148.242 56.2152 3 -6 8 -5 57.2560 10.8302 4 -6 8 -6 212.706 26.6995 4 -6 -8 -6 187.335 59.3970 4 6 -8 6 249.332 56.0735 5 6 8 6 212.579 36.3902 1 -6 -8 -6 220.364 44.9269 2 -6 8 -6 180.008 49.7360 3 6 -8 7 289.970 61.0174 5 -6 -8 -7 422.245 86.1910 4 -6 8 -7 352.097 38.2460 4 -6 -8 -7 372.585 53.8193 2 6 8 7 289.292 46.6352 1 -6 8 -7 389.879 69.7522 3 -6 8 -8 168.533 31.7432 4 -6 -8 -8 198.921 61.2161 4 -6 8 -8 217.082 50.9091 3 6 -8 8 211.605 53.4294 5 -6 -8 -9 1389.57 153.471 4 6 -8 9 1301.36 128.271 5 -6 8 -9 1560.49 135.520 3 -6 8 -9 1371.00 93.8172 4 -6 8 -10 20.5898 14.9732 4 6 -8 10 38.3513 34.7451 5 -6 8 -10 31.8313 38.2469 3 -6 -8 -10 69.3272 46.7085 4 6 -8 11 544.838 88.6250 5 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38.5604 4 7 -4 16-25.9451 70.4958 5 -7 -4 -16-19.5962 47.5593 4 -7 4 -17 57.7847 53.0970 4 7 -4 17 7.23660 67.0685 5 -7 -4 -17-9.72430 40.0789 4 7 -4 18 147.930 78.3977 5 -7 -4 -18 133.866 66.7148 4 7 -4 19 373.658 105.151 5 -7 -4 -19 548.001 115.018 4 7 -4 20 406.147 115.207 5 -7 -4 -20 545.459 120.548 4 -7 -4 -21 20.0380 56.2160 4 -7 -4 -22 206.153 87.0072 4 7 5 -25 117.122 98.6785 1 7 5 -24 571.268 126.797 1 7 5 -23 188.774 75.2766 1 7 5 -22 437.826 100.267 1 7 5 -21-89.7049 87.9296 1 -7 5 20 249.506 61.1360 3 7 5 -20 337.579 80.4404 1 -7 5 19 487.779 90.4580 3 7 5 -19 610.205 111.710 1 -7 5 18 448.255 86.3287 3 7 5 -18 460.084 85.5229 1 -7 5 17 211.835 60.4291 3 7 5 -17 237.863 77.7113 1 -7 5 16 110.461 48.3961 3 7 5 -16 116.450 50.8416 1 -7 5 15-31.0582 33.8194 3 7 5 -15 46.2038 42.7297 1 -7 5 14 608.039 94.1589 3 7 5 -14 450.967 58.5182 5 7 5 -14 698.448 107.275 1 -7 5 13 428.259 84.3012 3 7 5 -13 359.552 53.4096 5 7 5 -13 474.655 81.1878 1 -7 5 12-11.0654 28.6852 3 7 5 -12 34.8977 45.4343 1 -7 5 11 53.9959 34.9066 3 7 5 -11 25.3876 33.8184 1 -7 5 10 235.534 62.2351 3 7 5 -10 233.374 49.6722 1 -7 5 9 156.523 52.5737 3 7 5 -9 152.436 38.9289 1 -7 5 8 422.321 87.6679 3 7 5 -8 329.079 53.3246 1 -7 5 7 1018.97 124.128 3 7 5 -7 1083.21 93.0267 1 -7 5 6 1647.36 156.173 3 7 5 -6 1569.70 108.092 1 7 5 -5 278.461 54.6166 1 -7 5 5 236.066 74.6217 3 7 5 -4 411.444 58.9257 1 7 -5 -4 340.986 58.1329 5 -7 5 4 291.584 73.2370 3 7 -5 -3-18.1727 19.8269 5 7 -5 -3 23.9584 15.8179 4 7 5 -3 47.5710 30.0229 1 -7 5 3 49.0426 52.4913 3 7 5 -3 44.8132 17.7831 2 7 -5 -2 1751.54 138.481 5 7 -5 -2 1672.05 75.1971 4 7 5 -2 1738.54 84.7828 1 7 5 -2 1620.94 83.3990 2 -7 5 2 1764.76 157.477 3 -7 5 2 1667.93 102.534 1 7 -5 -1 5042.57 235.980 5 7 -5 -1 4731.90 115.231 4 7 5 -1 4839.00 123.659 1 7 -5 -1 5073.87 165.429 2 -7 5 1 5285.84 265.512 3 -7 5 1 4702.23 161.096 1 7 -5 0 805.543 94.3421 5 7 -5 0 850.613 46.9540 4 7 -5 0 902.790 71.5308 2 -7 5 0 852.965 67.3722 1 -7 5 0 944.753 115.186 3 7 5 0 866.981 45.6033 1 -7 5 -1 3660.71 222.304 3 7 -5 1 3397.89 200.159 5 7 -5 1 3534.06 133.174 2 -7 5 -2 85.1331 60.1839 3 -7 5 -3 281.058 74.6277 3 7 -5 3 252.620 55.7455 5 -7 5 -4 745.004 105.012 3 7 -5 4 880.985 104.681 5 -7 -5 -4 769.260 99.2438 4 -7 5 -5 755.651 98.7134 3 7 -5 5 733.743 97.3095 5 -7 5 -5 849.412 65.5978 4 -7 -5 -5 722.984 101.093 4 -7 5 -6 948.062 108.327 3 -7 -5 -6 807.285 109.717 4 -7 5 -6 879.580 72.9311 4 7 -5 6 769.531 102.261 5 -7 5 -7 47.7736 29.5959 3 -7 5 -7 115.640 30.0496 4 -7 -5 -7 37.3374 33.1888 4 -7 5 -8 140.411 54.5968 3 -7 -5 -8 95.3630 39.7414 4 -7 5 -8 91.5184 27.9749 4 7 -5 8 165.343 53.3250 5 -7 5 -9 13.5093 32.2110 3 -7 -5 -9 42.4739 36.4728 4 -7 5 -9 55.6161 30.3979 4 7 -5 9 23.7837 49.4162 5 -7 5 -10 756.679 81.6734 4 -7 -5 -10 911.443 121.130 4 7 -5 10 819.202 114.858 5 -7 5 -10 902.090 105.037 3 -7 5 -10 727.836 71.1565 1 -7 5 -11 14.1731 18.2488 4 7 -5 11-13.4398 61.6007 5 -7 5 -11 24.2751 32.3483 3 -7 -5 -11 23.2051 36.4340 4 -7 5 -12 105.190 40.0866 4 7 -5 12 61.5431 45.6267 5 -7 -5 -12 67.1773 38.0482 4 -7 5 -12 34.0597 28.8879 3 7 -5 13 438.382 93.2183 5 -7 5 -13 658.479 79.9321 3 -7 -5 -13 483.710 96.1705 4 -7 5 -13 558.796 84.7791 4 -7 -5 -14 9.71990 47.3741 4 7 -5 14-16.7023 54.1068 5 -7 5 -14 33.2800 37.0385 4 -7 -5 -15 66.7892 47.9219 4 7 -5 15 87.7962 59.0032 5 -7 5 -15 175.666 58.1087 4 -7 -5 -16 331.394 93.9014 4 7 -5 16 239.541 78.5251 5 -7 -5 -17 974.359 146.993 4 7 -5 17 996.250 137.024 5 -7 -5 -18 9.77400 68.1909 4 7 -5 18 41.0930 80.9282 5 -7 -5 -19-53.3635 58.3867 4 7 -5 19-68.1980 86.6934 5 -7 -5 -20-24.6778 70.5146 4 7 -5 20 163.728 112.299 5 -7 -5 -21 225.086 93.0559 4 -7 -5 -22-53.7453 86.7868 4 7 6 -24 46.6653 75.2759 1 7 6 -23 4.97848 43.8795 1 7 6 -22 155.522 64.5088 1 7 6 -21 351.070 84.9412 1 7 6 -20 624.149 109.480 1 -7 6 20 522.187 91.2585 3 7 6 -19 538.958 102.029 1 -7 6 19 407.426 81.4006 3 7 6 -18 9.53178 50.2385 1 -7 6 18-1.48768 39.5743 3 7 6 -17 339.537 82.6130 1 -7 6 17 369.599 77.4391 3 7 6 -16 434.301 88.1441 1 -7 6 16 408.397 82.7500 3 7 6 -15 1048.58 128.539 1 -7 6 15 786.412 109.139 3 -7 6 14 56.4721 38.5944 3 7 6 -14 85.2291 54.3105 1 -7 6 13 31.2606 36.2235 3 7 6 -13-17.3490 39.2836 1 -7 6 12 183.540 54.4207 3 7 6 -12 300.710 74.1899 1 -7 6 11 101.947 52.4564 3 7 6 -11 170.428 56.2511 1 -7 6 10-13.1870 32.3647 3 7 6 -10-27.2297 43.7646 1 -7 6 9 24.4901 36.9167 3 7 6 -9 7.72391 23.2085 1 -7 6 8 48.9507 45.4830 3 7 6 -8 91.3280 32.1776 1 -7 6 7 93.3249 48.3801 3 7 6 -7 51.2943 33.7432 1 -7 6 6-17.1086 40.4563 3 7 6 -6 4.72681 35.3356 1 -7 6 5 871.687 115.443 3 7 6 -4 2014.21 112.186 2 -7 6 4 1880.85 166.240 3 7 6 -3 3773.20 142.911 2 -7 6 3 4101.39 240.151 3 7 -6 -3 3741.16 108.125 4 7 6 -2 933.998 65.9167 2 7 -6 -2 993.225 105.750 5 -7 6 2 1013.10 123.673 3 7 -6 -2 954.154 44.9683 4 7 -6 -1 347.414 60.8246 2 7 -6 -1 216.241 52.0472 5 -7 6 1 261.219 70.9680 3 -7 6 0 1541.80 147.230 3 7 -6 0 1449.61 131.747 5 7 -6 0 1683.64 105.893 2 -7 6 -1 2868.52 198.629 3 7 -6 1 2738.31 180.992 5 7 -6 1 2527.08 122.156 2 7 -6 2 4526.68 234.289 5 -7 6 -2 4352.94 241.212 3 7 -6 3 1160.25 120.690 5 -7 6 -3 1261.43 133.847 3 7 6 3 1246.53 45.1843 1 7 -6 4 1651.38 143.053 5 -7 -6 -4 1563.28 147.123 4 7 6 4 1624.25 48.7915 1 -7 6 -4 1776.43 154.352 3 7 -6 5 834.030 102.175 5 -7 -6 -5 829.381 108.063 4 -7 6 -5 1003.85 115.715 3 7 6 5 930.768 39.4434 1 -7 6 -6-12.3937 17.8882 4 -7 -6 -6 41.3860 43.0059 4 -7 6 -6 33.2123 35.3756 3 7 -6 6-37.4315 43.1478 5 -7 6 -7-35.3713 16.1466 4 -7 -6 -7 30.5491 33.6098 4 -7 6 -7-10.4676 36.3790 3 7 -6 7-32.4684 37.5985 5 7 -6 8 665.627 98.7894 5 -7 -6 -8 698.204 111.649 4 -7 6 -8 644.357 63.8822 4 -7 6 -8 782.620 99.2992 3 -7 -6 -9 769.638 115.203 4 7 -6 9 727.678 102.070 5 -7 6 -9 685.292 71.2396 4 -7 6 -9 811.776 95.4213 3 7 -6 10-4.25268 45.0960 5 -7 6 -10 50.0088 35.0058 3 -7 6 -10 30.1139 20.5751 4 -7 -6 -10 35.3139 42.1853 4 -7 6 -11 77.2352 27.5662 4 7 -6 11 13.0658 45.2257 5 -7 6 -11 44.3516 26.2938 3 -7 -6 -11 95.7992 41.7337 4 -7 6 -12 51.3844 23.8022 4 -7 6 -12 109.460 44.9385 3 7 -6 12 87.2373 56.9248 5 -7 -6 -12 125.344 61.0136 4 -7 6 -13 232.277 53.4238 3 7 -6 13 191.076 64.7797 5 -7 -6 -13 283.372 89.6538 4 7 -6 14 481.073 94.7161 5 -7 -6 -14 740.677 128.251 4 7 -6 15 5.92016 62.3628 5 -7 -6 -15 51.9906 60.4340 4 7 -6 16 241.221 79.4463 5 -7 -6 -16 307.660 89.6135 4 7 -6 17 121.618 71.1835 5 -7 -6 -17 102.617 65.6217 4 7 -6 18 238.386 90.6563 5 -7 -6 -18 527.413 115.154 4 7 -6 19 350.145 114.878 5 -7 -6 -19 389.635 110.768 4 -7 -6 -20 409.264 110.043 4 -7 -6 -21 9.72923 73.7763 4 -7 -6 -22 5.71824 45.3291 4 7 7 -24 102.960 80.7742 1 7 7 -23 210.342 79.4773 1 7 7 -22 169.598 66.1865 1 7 7 -21 43.3479 32.1512 1 7 7 -20 296.759 82.6971 1 -7 7 20 360.965 76.4318 3 7 7 -19 53.4598 39.5756 1 -7 7 19 58.0301 36.2081 3 7 7 -18 616.085 114.067 1 -7 7 18 635.848 101.642 3 7 7 -17 145.501 63.6587 1 -7 7 17 127.110 47.1376 3 7 7 -16 40.7755 42.3171 1 -7 7 16 20.1759 34.5787 3 7 7 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48.5264 27.3904 4 7 -7 6 537.142 85.5367 5 -7 7 -6 449.505 42.7203 4 -7 7 -6 624.470 94.2044 3 -7 -7 -6 512.156 89.1678 4 7 -7 7 92.4984 42.1715 5 -7 7 -7 226.100 69.1698 3 -7 7 -7 134.990 25.0556 4 -7 -7 -7 87.9761 35.9011 4 7 -7 8-45.1783 45.8089 5 -7 7 -8-22.1002 36.9915 3 -7 -7 -8 27.0822 43.6733 4 -7 7 -8 1.73595 14.6293 4 7 -7 9 143.396 53.3751 5 -7 7 -9 125.685 45.4501 3 -7 -7 -9 153.401 60.7749 4 7 -7 10 447.761 86.7809 5 -7 7 -10 473.249 75.0235 3 -7 -7 -10 465.348 91.6890 4 -7 7 -11-26.1961 29.8136 3 7 -7 11-63.7582 55.9140 5 -7 -7 -11 37.2850 35.7132 4 -7 7 -12 1126.10 114.794 3 7 -7 12 988.499 127.788 5 -7 -7 -12 1049.77 137.449 4 -7 7 -13 52.0073 34.8317 3 7 -7 13 22.4421 47.1843 5 -7 -7 -13-37.0293 62.3093 4 7 -7 14 307.669 84.2231 5 -7 -7 -14 435.395 107.515 4 7 -7 15 15.4992 62.4893 5 -7 -7 -15 92.4317 63.6580 4 7 -7 16 815.374 126.843 5 -7 -7 -16 721.170 135.002 4 7 -7 17 134.022 71.5759 5 -7 -7 -17 126.219 55.8777 4 7 -7 18 356.452 112.603 5 -7 -7 -18 246.207 89.9379 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510.908 58.9331 2 7 -8 -2 525.265 73.5127 2 -7 8 2 518.242 89.7657 3 -7 8 1 108.390 53.7540 3 7 -8 -1 74.3725 36.7986 2 -7 8 0 1132.72 127.791 3 7 -8 0 981.609 90.7934 2 -7 8 -1 187.246 64.2400 3 7 -8 1 155.077 40.2052 2 -7 8 -2 2219.73 175.970 3 7 -8 2 2259.70 132.326 2 -7 8 -3 488.649 90.8640 3 7 -8 4-89.1944 41.1446 5 -7 8 -4-40.8896 54.0211 3 7 -8 5 441.048 77.1246 5 -7 -8 -5 558.815 94.0264 4 -7 8 -5 583.710 89.9379 3 -7 -8 -6 96.3553 26.1284 2 7 -8 6 204.617 56.2762 5 -7 8 -6 191.727 62.0971 3 -7 -8 -6 150.720 54.3751 4 7 -8 7 326.765 69.4562 5 -7 8 -7 350.213 81.7462 3 -7 -8 -7 287.221 75.7265 4 -7 8 -8 1914.55 162.705 3 -7 -8 -8 1889.14 186.334 4 7 -8 8 2046.29 168.712 5 7 -8 9-17.6812 44.6062 5 -7 8 -9 118.594 53.7075 3 -7 -8 -9 116.069 45.6262 4 7 -8 10 401.629 84.4568 5 -7 8 -10 314.494 71.2533 3 -7 -8 -10 313.276 79.3239 4 7 -8 11 28.0693 42.3853 5 -7 8 -11 57.5796 31.0250 3 -7 -8 -11 78.0822 54.4093 4 -7 -8 -12 316.756 81.6906 4 7 -8 12 78.2664 52.6276 5 -7 8 -12 404.128 72.7376 3 -7 -8 -13 366.438 96.8013 4 7 -8 13 265.214 76.4155 5 -7 8 -13 317.364 59.1497 3 -7 -8 -14 1628.56 185.628 4 7 -8 14 1396.13 153.649 5 -7 -8 -15 133.041 67.2515 4 7 -8 15 84.7155 59.7667 5 -7 -8 -16 450.692 119.326 4 7 -8 16 229.935 81.1698 5 -7 -8 -17 56.0313 64.3096 4 -7 -8 -18 103.660 78.9265 4 -7 -8 -19 66.7067 62.8089 4 -7 -8 -20 175.971 97.5005 4 -7 -8 -21 186.999 87.7044 4 7 9 -24 75.3803 91.0595 1 7 9 -23 55.3851 46.5244 1 7 9 -21-33.1680 41.9192 1 7 9 -20 263.752 75.0305 1 -7 9 20 353.499 82.4793 3 -7 9 19-143.416 49.8271 3 7 9 -19-39.0808 39.3977 1 -7 9 18 530.606 98.4203 3 7 9 -18 441.118 94.6099 1 -7 9 17 43.8230 35.4529 3 7 9 -17 117.714 53.3890 1 -7 9 16 50.7050 50.6742 3 7 9 -16 44.7430 48.1315 1 -7 9 15 45.4280 47.0765 3 7 9 -15 35.1332 42.0045 1 -7 9 14 579.401 101.767 3 7 9 -14 733.519 109.931 1 -7 9 13-15.9549 40.4215 3 7 9 -13 17.9761 38.2106 1 -7 9 12 750.034 112.845 3 -7 9 11 289.890 73.7238 3 -7 9 10 457.474 88.2753 3 -7 9 9 181.977 58.5906 3 -7 9 8 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34.9460 56.7874 1 9 1 -23 19.8748 58.3112 1 9 1 -22-5.42689 55.4005 1 9 -1 -22-85.5217 70.3402 1 -9 1 21 150.156 56.1186 3 9 -1 -21 279.810 94.1320 1 9 1 -21 211.397 82.9213 1 -9 1 20 3.37475 28.3358 3 9 1 -20-15.5631 53.9598 1 9 -1 -20-32.4462 59.9365 1 -9 1 19 195.842 58.9164 3 9 1 -19 262.738 83.2232 1 9 -1 -19 334.453 95.5763 1 -9 1 18-34.2905 40.7497 3 9 1 -18-3.57425 50.5971 1 9 -1 -18-6.39452 55.4554 1 -9 -1 17 338.021 80.7184 3 -9 1 17 354.906 83.7610 3 9 -1 -17 426.001 100.396 1 9 1 -17 315.801 84.5148 1 -9 -1 16-13.6413 43.1412 3 -9 1 16-68.2948 39.2805 3 9 1 -16-4.83761 50.9413 1 9 1 -15 1460.84 153.989 1 -9 1 15 1271.95 148.480 3 -9 -1 15 1236.39 147.114 3 -9 1 14 14.0776 38.9565 3 -9 -1 14 3.76267 39.1455 3 9 1 -14-23.8079 52.5028 1 9 1 -13 480.303 71.9846 5 -9 -1 13 586.976 102.744 3 9 1 -13 534.853 88.2758 1 -9 1 13 586.033 107.349 3 9 1 -12-12.0865 34.6982 5 9 1 -12 9.15155 37.5776 1 -9 1 12 13.5802 30.6159 3 -9 -1 12-18.1508 48.3370 3 9 -1 -11 276.719 56.1654 5 9 1 -11 216.542 50.6612 5 9 1 -11 107.431 43.4608 1 -9 1 11 192.872 57.6906 3 -9 -1 11 95.1095 38.0762 3 9 -1 -10 36.0910 28.7388 5 -9 1 10 108.616 49.3415 3 -9 -1 10 106.560 44.5130 3 9 1 -10 131.557 48.3364 1 -9 -1 9 1991.27 180.550 3 9 1 -9 2352.35 163.545 5 9 -1 -9 2224.17 154.775 5 -9 1 9 2162.21 193.432 3 9 1 -8 5.87031 44.2897 5 9 -1 -8-22.5096 17.9348 5 -9 1 8-24.8927 57.1974 3 -9 -1 8-2.27574 47.8126 3 9 1 -7 307.039 66.5020 5 9 -1 -7 311.067 63.1292 5 -9 1 7 401.244 84.1715 3 -9 -1 7 369.440 81.6299 3 9 -1 -6 55.1326 34.1667 5 -9 1 6 29.4433 29.1701 3 -9 -1 6 115.887 46.4886 3 9 -1 -5 5.60821 31.2835 5 9 1 -5 1.70385 31.4392 5 -9 1 5 87.3233 52.5535 3 -9 -1 5 9.39590 39.5612 3 9 -1 -4 72.0201 46.7431 5 9 1 -4 247.469 63.2627 5 -9 1 4 107.068 53.9451 3 -9 -1 4 154.194 49.7794 3 -9 1 3 71.9827 45.2020 3 -9 -1 3 8.49516 37.3671 3 9 -1 -2-68.6527 57.2733 5 -9 1 2-16.3708 31.6093 3 -9 -1 2 55.1457 51.1585 3 9 -1 -1 129.851 54.7389 5 -9 -1 1 66.2232 43.2096 3 -9 1 1 148.401 54.3333 3 9 -1 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33.4392 26.3036 4 9 -1 13 319.443 84.8283 5 -9 -1 -13 326.931 77.8559 4 9 -1 14-52.0471 89.3612 5 -9 -1 -14-98.8175 41.7692 4 9 -1 15 192.271 93.0621 5 -9 -1 -15 406.820 87.2784 4 9 -1 16-103.567 120.359 5 9 -1 17 79.5683 111.334 5 9 1 17-194.606 134.635 5 9 -1 18-125.275 127.510 5 9 1 18 89.9946 120.848 5 9 1 19-56.7750 169.192 5 9 -1 20-9.09245 160.171 5 9 1 20-18.4801 155.516 5 9 2 -24 189.805 72.9469 1 9 2 -23 228.839 68.7348 1 9 2 -22-44.4515 55.4188 1 -9 2 21-108.509 46.7988 3 9 2 -21-17.0865 41.5115 1 -9 2 20 28.0224 31.5150 3 9 2 -20 98.7152 42.0784 1 -9 2 19 649.537 112.750 3 9 2 -19 757.800 130.335 1 -9 2 18 24.0038 38.4671 3 9 2 -18 15.2416 45.3650 1 -9 2 17 530.546 97.9701 3 9 2 -17 655.788 121.140 1 -9 2 16-0.21485 41.8101 3 9 2 -16 26.5772 41.7832 1 -9 2 15-42.2832 28.4905 3 9 2 -15 25.9898 41.4471 1 -9 -2 14 197.799 71.3172 3 -9 2 14 86.7391 47.2624 3 9 2 -14 97.8214 44.3573 1 -9 -2 13 1226.50 146.275 3 -9 2 13 1264.04 151.533 3 9 2 -13 1312.19 134.607 1 9 2 -13 1319.60 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17.8312 37.9349 3 -9 2 3 33.7388 43.4528 3 9 -2 -2 508.387 91.3042 5 -9 -2 2 462.840 98.2177 3 -9 2 2 436.485 90.4749 3 -9 -2 1 1498.75 155.468 3 9 -2 -1 1635.75 155.574 5 -9 2 1 1478.28 159.323 3 9 -2 0 233.479 70.9665 5 -9 -2 0 72.4035 54.5271 3 -9 2 0 74.5451 67.6127 3 -9 -2 -1 629.240 103.962 3 9 -2 1 457.714 91.2265 5 -9 2 -1 560.359 103.325 3 9 -2 2 341.035 75.8832 5 -9 -2 -2 419.535 82.4996 3 -9 2 -2 364.536 74.5311 3 9 -2 3 244.858 72.9900 5 -9 2 -3 92.2273 35.9040 3 -9 -2 -3 134.186 56.4909 3 9 -2 4-5.35805 53.9295 5 -9 2 -4-12.0306 29.3980 3 -9 -2 -4-52.9913 47.0078 3 9 -2 5 1176.01 144.456 5 -9 2 -5 1340.80 142.705 3 9 -2 6 159.262 58.9776 5 -9 2 -6 244.251 69.8924 3 9 -2 7 3.28060 55.6035 5 -9 -2 -7 109.952 51.6103 4 -9 2 -7 72.2125 51.0636 3 -9 2 -8 1072.82 124.692 3 9 -2 8 1012.37 140.677 5 -9 -2 -8 862.496 114.117 4 9 -2 9 103.381 63.4055 5 -9 -2 -9 108.253 41.7586 4 -9 2 -9 154.531 54.7465 3 9 -2 10 88.2655 64.1830 5 -9 2 -10 55.3306 44.5922 3 -9 -2 -10-50.8919 30.7891 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49.5412 3 9 6 -8 77.1288 27.5007 1 -9 6 7 2134.10 198.939 3 9 6 -7 2074.66 131.395 1 -9 6 6 990.820 132.690 3 9 6 -6 816.187 77.1101 1 -9 6 5 1824.40 184.417 3 -9 6 4 289.169 81.1283 3 9 -6 -4 249.323 59.0069 5 9 -6 -3 55.0441 33.9487 5 -9 6 3 151.131 61.0725 3 9 -6 -3 64.9178 30.9847 2 -9 6 2 747.920 118.662 3 9 -6 -2 601.232 92.5152 5 9 -6 -2 582.570 66.5963 2 9 -6 -1 65.2620 35.8452 5 -9 6 1 438.376 95.1332 3 9 -6 0 411.467 81.0284 5 -9 6 0 447.803 92.3011 3 9 -6 1-151.486 99.2469 5 -9 6 -1 144.602 51.6074 3 9 -6 2 450.596 88.2785 5 -9 6 -2 476.858 92.2866 3 9 -6 3 154.747 57.1614 5 -9 6 -3 161.968 58.4664 3 9 -6 4 434.836 89.1054 5 -9 6 -4 693.414 112.571 3 9 -6 5 236.280 67.9334 5 -9 6 -5 356.262 83.7642 3 9 -6 6 3.95158 36.7904 5 -9 6 -6 87.3799 43.7943 3 9 -6 7 274.389 78.2044 5 -9 6 -7 342.315 87.5379 3 -9 -6 -8 106.414 54.4136 4 9 -6 8 136.843 60.1307 5 -9 6 -8 243.385 64.4957 3 -9 -6 -9 12.2237 24.9670 4 9 -6 9 0.63438 50.6933 5 -9 6 -9 23.8830 38.3515 3 -9 -6 -10 34.4339 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371.466 93.4096 3 9 7 -13 102.456 47.8791 1 -9 7 13 64.2521 49.2156 3 9 7 -12-7.14129 23.6616 1 9 7 -11 314.869 64.9380 1 -9 7 11 361.353 89.4918 3 9 7 -10 1065.14 110.162 1 -9 7 10 985.746 137.650 3 9 7 -9 352.781 59.0783 1 -9 7 9 356.285 91.0277 3 9 7 -8 1602.16 123.216 1 -9 7 8 1498.21 173.267 3 9 7 -7 64.4872 27.7552 1 -9 7 7-38.1987 57.6492 3 9 7 -6 43.0631 18.6666 1 -9 7 6 6.23058 40.9415 3 -9 7 5 405.002 95.8470 3 -9 7 4 1306.93 158.406 3 -9 7 3 931.070 137.891 3 9 -7 -3 817.832 85.4004 2 -9 7 2 874.066 130.555 3 9 -7 -2 554.580 65.9906 2 -9 7 1 564.802 99.6893 3 9 -7 -1 430.957 80.8719 5 -9 7 0 241.558 75.7213 3 9 -7 0 69.3477 42.2789 5 -9 7 -1-8.03459 50.0612 3 9 -7 2 988.373 128.276 5 -9 7 -2 880.601 128.398 3 9 -7 3 768.112 113.824 5 -9 7 -3 762.988 118.349 3 9 -7 4 231.013 72.4301 5 -9 7 -4 305.713 79.0819 3 9 -7 5-21.9473 55.0320 5 -9 7 -5 20.2006 35.7724 3 9 -7 6 209.817 71.9983 5 -9 7 -6 247.646 65.1465 3 9 -7 7 77.5601 54.7608 5 -9 7 -7 44.1556 49.1598 3 9 -7 8 181.566 72.9981 5 -9 -7 -8 36.1971 48.3264 4 -9 7 -8 135.819 52.5313 3 9 -7 9 151.560 66.0793 5 -9 7 -9 102.250 48.8149 3 9 -7 10 453.908 104.657 5 -9 -7 -10 486.399 101.674 4 -9 7 -10 573.706 95.6873 3 9 -7 11 13.6363 62.9749 5 -9 -7 -11-101.392 51.3064 4 -9 7 -11 73.9718 51.2144 3 9 -7 12-24.4199 78.6430 5 -9 -7 -12 60.1692 35.5087 4 -9 7 -12-0.86970 14.1952 3 9 -7 13 164.020 84.6905 5 -9 -7 -13 172.568 70.7328 4 9 -7 14 1006.63 158.671 5 -9 -7 -14 966.469 153.949 4 9 -7 15 35.6374 79.2399 5 -9 -7 -15 5.87741 31.9449 4 9 -7 16-79.6306 97.0371 5 -9 -7 -16 92.4301 64.2654 4 9 -7 17 62.1406 111.672 5 -9 -7 -17 36.8063 51.8614 4 9 -7 18-81.3618 125.495 5 -9 -7 -18 70.7885 39.6248 4 9 -7 19-42.4088 130.443 5 -9 -7 -19 58.6328 49.7465 4 9 8 -22-16.5763 62.9445 1 9 8 -21-13.9482 72.9192 1 -9 8 20 380.232 92.6277 3 9 8 -20 236.810 79.1042 1 -9 8 19 81.0079 49.7316 3 9 8 -19-141.404 79.3491 1 -9 8 18 795.521 133.305 3 9 8 -18 726.848 120.562 1 -9 8 17 248.096 86.4552 3 9 8 -17 73.9529 47.9226 1 -9 8 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538.910 160.893 5 -12 2 -6 401.513 97.0883 3 12 -2 7 49.2524 136.478 5 12 2 7 84.6155 124.643 5 -12 2 -7 46.2948 34.6880 3 12 -2 8 486.406 176.812 5 12 2 8 631.553 187.143 5 -12 2 -8 570.133 109.141 3 -12 3 17 60.9249 48.8897 3 -12 3 16 169.182 70.3279 3 -12 3 15 453.653 108.653 3 -12 3 14-83.9975 47.4840 3 -12 3 13 174.628 66.6269 3 -12 3 12 267.419 83.6921 3 -12 3 11-1.77704 44.3164 3 12 3 -10 103.925 101.458 5 -12 3 10 110.429 55.2863 3 12 3 -9-72.5633 87.0279 5 -12 3 9-43.0813 32.2139 3 12 3 -8 896.878 145.036 5 12 -3 -8 899.672 137.690 5 -12 3 8 797.835 140.025 3 12 3 -7-56.9904 84.1465 5 -12 3 7 126.725 56.0553 3 12 3 -6 12.7995 108.003 5 12 -3 -6 93.6336 74.5689 5 -12 3 6 240.655 76.7246 3 12 -3 -5 220.930 88.9100 5 12 3 -5 178.552 90.8776 5 -12 3 5 120.529 53.3306 3 12 -3 -4 211.381 84.2445 5 12 3 -4 40.6175 82.9712 5 -12 3 4 287.677 81.5753 3 12 -3 -3-26.3072 69.0934 5 12 3 -3 34.0007 99.0958 5 -12 3 3-45.5649 35.0369 3 12 -3 -2 743.823 132.744 5 12 3 -2 692.660 140.079 5 -12 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39.5245 3 -12 8 -1 543.271 111.220 3 -12 8 -2 53.3521 61.9137 3 12 -8 4 148.291 96.9495 5 -12 8 -4 89.5759 51.0009 3 -12 8 -5 3.07662 49.2382 3 -12 8 -6 213.339 70.7835 3 -12 8 -7 544.791 113.105 3 -12 8 -8-4.58180 46.2270 3 -12 8 -9 565.985 127.825 3 -12 9 11 100.858 61.2694 3 -12 9 10 267.234 88.9846 3 -12 9 9 169.790 71.6808 3 -12 9 8 200.971 74.2603 3 -12 9 7 609.539 127.131 3 -12 9 6 235.453 79.6148 3 -12 9 5-115.481 56.6647 3 -12 9 4-136.081 59.2376 3 -12 9 3 742.684 142.782 3 -12 9 1 337.691 93.8018 3 -12 9 0 18.1934 33.7683 3 -12 9 -1 69.5835 62.8670 3 -12 9 -2 83.1636 47.5530 3 -12 9 -3 331.317 92.6679 3 -12 9 -4 110.604 52.9977 3 -12 9 -5 644.831 129.262 3 -12 9 -6 51.6620 45.7110 3 -12 9 -7 2.51564 8.52905 3 -12 9 -8 234.738 80.7792 3 -12 9 -9 305.082 99.7936 3 -12 10 8 50.8475 55.1883 3 -12 10 7 288.276 95.1302 3 -12 10 6-24.0475 50.3408 3 -12 10 5 189.682 78.2885 3 -12 10 4-57.8289 59.1937 3 -12 10 3 343.846 97.4007 3 -12 10 2-59.3712 59.5690 3 -12 10 1 67.2392 46.1946 3 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5 -13 0 3 57.9621 41.6180 3 13 0 -2-20.3489 106.460 5 -13 0 2 2.58154 26.8164 3 13 0 -1 620.305 174.000 5 -13 0 1 732.174 138.872 3 13 0 0 31.7289 110.303 5 -13 0 0-33.6596 50.7433 3 13 0 1 964.946 194.064 5 -13 0 -1 894.775 152.119 3 -13 0 -2 14.3278 33.8486 3 13 0 2 80.9215 132.873 5 13 -1 -10 69.7047 91.8400 5 13 1 -10-154.195 116.584 5 -13 -1 9 9.94712 27.5715 3 13 -1 -9-1.12035 85.6364 5 13 1 -9 160.234 93.2642 5 -13 -1 8 105.222 41.2611 3 -13 1 8 72.7820 42.7738 3 13 -1 -8-37.2713 100.864 5 13 1 -8 34.0867 85.0767 5 -13 -1 7 54.8448 48.9167 3 -13 1 7 138.884 61.3304 3 13 1 -7 77.9667 89.1479 5 13 -1 -7 2.10925 88.2847 5 -13 -1 6 47.0437 37.7078 3 -13 1 6 69.7595 44.3771 3 13 1 -6-0.48756 110.418 5 13 -1 -6-4.54104 92.3677 5 -13 -1 5 161.559 63.7341 3 -13 1 5 146.687 61.1927 3 13 -1 -5 157.239 103.242 5 -13 -1 4 32.6863 40.9607 3 -13 1 4-107.900 53.4487 3 13 1 -4-123.587 123.796 5 13 -1 -4-129.778 108.767 5 -13 -1 3 527.195 118.895 3 -13 1 3 532.847 116.903 3 13 1 -3 723.953 165.625 5 13 -1 -3 354.680 121.827 5 -13 1 2-179.871 72.0802 3 13 1 -2-120.727 138.573 5 13 -1 -2-27.6771 106.605 5 -13 1 1 41.9496 39.2091 3 13 1 -1-15.3580 115.904 5 13 -1 -1 208.958 131.047 5 -13 1 0 1.42411 28.2206 3 13 1 0 65.4092 139.139 5 13 -1 0 79.4513 111.848 5 -13 1 -1 480.818 113.557 3 13 1 1 524.699 158.352 5 13 -1 1 342.068 135.057 5 -13 1 -2 167.899 80.5230 3 13 1 2 79.7178 139.082 5 13 -1 2 3.41308 126.623 5 -13 1 -3 580.022 122.983 3 -13 1 -4 31.2453 32.3363 3 13 -2 -9-11.0994 90.7588 5 13 2 -9 84.4807 103.238 5 -13 2 8 170.154 71.9385 3 13 -2 -8 20.3970 83.1455 5 13 2 -8-22.3528 100.219 5 -13 2 7 394.609 102.883 3 13 -2 -7 538.359 132.336 5 13 2 -7 525.555 147.088 5 -13 2 6 41.4424 40.6813 3 13 -2 -6 14.9222 92.6025 5 13 2 -6 26.3190 114.847 5 -13 2 5 426.895 106.250 3 13 2 -5 276.288 125.409 5 -13 2 4 158.444 65.6713 3 13 2 -4 187.295 125.774 5 13 -2 -4 234.834 101.517 5 -13 2 3 16.0333 46.7816 3 13 2 -3 137.672 129.601 5 13 -2 -3 1.27824 105.473 5 -13 2 2-188.060 69.4413 3 13 2 -2 3.51719 114.066 5 13 -2 -2-148.393 113.913 5 -13 2 1 501.740 113.503 3 13 2 -1 519.502 149.534 5 13 -2 -1 632.663 145.843 5 -13 2 0 150.172 65.7511 3 13 2 0 313.156 159.249 5 13 -2 0 77.9311 106.170 5 -13 2 -1 475.306 114.531 3 13 2 1 685.667 161.986 5 13 -2 1 492.291 156.151 5 -13 2 -2 59.8794 57.0885 3 13 -2 2 107.846 124.304 5 13 2 2 147.016 158.116 5 -13 2 -3 22.0415 31.5747 3 -13 2 -4 53.9672 34.4291 3 -13 2 -5 187.687 67.4491 3 -13 2 -6 18.1967 39.0092 3 13 3 -9 518.277 161.193 5 13 3 -8 201.403 120.773 5 13 -3 -8 83.6585 93.5113 5 -13 3 7 64.3623 77.5690 3 13 3 -7-49.7680 111.276 5 13 -3 -7 5.85095 102.746 5 -13 3 6 341.600 103.152 3 13 3 -6 252.187 130.137 5 13 -3 -6 67.1870 90.4862 5 -13 3 5 107.616 67.0780 3 13 3 -5 124.295 105.082 5 13 -3 -5 277.493 126.890 5 -13 3 4 20.5980 51.0846 3 13 -3 -4 169.580 108.790 5 13 3 -4 126.884 109.311 5 -13 3 3 489.079 112.032 3 13 3 -3 445.588 135.111 5 13 -3 -3 422.092 105.486 5 -13 3 2-21.4416 58.4886 3 13 -3 -2 190.327 110.727 5 13 3 -2 45.3160 127.916 5 -13 3 1-41.5758 32.2084 3 13 -3 -1 82.8679 90.0133 5 13 3 -1-46.7921 128.855 5 -13 3 0 32.0692 37.2301 3 13 -3 0 15.4365 97.2988 5 13 3 0 121.098 134.439 5 -13 3 -1 324.686 90.7787 3 13 -3 1 156.585 115.328 5 13 3 1 34.3631 122.978 5 -13 3 -2 226.383 73.2324 3 13 3 2-57.3107 136.508 5 -13 3 -3 131.540 56.8313 3 -13 3 -4-77.1378 45.2284 3 -13 3 -5 75.8289 43.1211 3 -13 3 -6 141.479 58.0008 3 -13 3 -7 275.763 78.1714 3 -13 3 -8 111.301 51.2053 3 13 4 -9-44.5342 120.376 5 13 4 -8-149.666 124.577 5 13 4 -7 279.161 124.504 5 -13 4 6 60.1061 69.8457 3 13 4 -6 70.5957 106.524 5 13 -4 -6 2.87689 90.8440 5 -13 4 5 96.3560 70.4857 3 13 4 -5 80.8533 97.8051 5 13 -4 -5 72.6617 85.5071 5 -13 4 4 194.169 84.6815 3 13 -4 -4 103.326 98.3062 5 13 4 -4 140.936 122.186 5 -13 4 3 30.5167 47.7330 3 13 -4 -3-122.961 118.007 5 13 4 -3-62.8447 136.780 5 -13 4 2 0.30857 58.9194 3 13 -4 -2 61.6113 96.7023 5 13 4 -2-189.436 138.208 5 -13 4 1 156.657 76.2563 3 13 -4 -1 229.719 127.240 5 13 4 -1 163.832 125.888 5 -13 4 0 17.7770 64.6004 3 13 4 0-34.9283 133.824 5 13 -4 0 151.418 125.369 5 -13 4 -1 128.896 67.3010 3 13 -4 1 177.242 124.284 5 -13 4 -2 36.5272 43.9098 3 -13 4 -3-63.0656 68.8247 3 -13 4 -4 14.4921 32.1347 3 -13 4 -5 332.917 90.1017 3 -13 4 -6 165.260 63.6037 3 -13 4 -7 230.812 72.0554 3 -13 4 -8-76.4075 60.2030 3 13 5 -9 158.902 124.328 5 13 5 -8 104.368 118.073 5 13 5 -7 87.5618 101.894 5 13 5 -6-154.832 128.424 5 -13 5 5-71.9009 77.3444 3 13 5 -5-49.9941 100.823 5 -13 5 4 252.839 96.7639 3 13 -5 -4 221.505 106.145 5 13 5 -4 316.909 135.074 5 -13 5 3 93.0096 81.0530 3 13 -5 -3 117.047 116.033 5 13 5 -3-63.5603 125.725 5 -13 5 2 186.539 87.2257 3 13 -5 -2 31.0478 109.226 5 -13 5 1-20.9520 79.9522 3 13 -5 -1 55.2207 137.364 5 -13 5 0-136.891 100.722 3 13 -5 0-18.0854 110.667 5 -13 5 -1-19.0114 66.2529 3 -13 5 -2-2.41234 58.7773 3 -13 5 -3-30.5732 65.6417 3 -13 5 -4-73.1792 65.2314 3 -13 5 -5-24.0103 52.9563 3 -13 5 -6-98.9495 74.7019 3 -13 5 -7 95.2980 50.0093 3 13 6 -8 53.1504 121.543 5 13 6 -7 17.1622 111.057 5 13 6 -6 6.72826 100.053 5 -13 6 2 21.7258 57.9947 3 13 -6 -2-117.674 127.706 5 -13 6 1 0.63532 57.0404 3 13 -6 -1-119.047 115.945 5 -13 6 0-5.97700 83.3630 3 -13 6 -1-57.0280 76.2266 3 -13 6 -2 8.37183 69.2956 3 -13 6 -3-25.0658 70.5932 3 -13 6 -4-124.302 94.1348 3 13 7 -8-11.9635 120.659 5 14 0 -9 3.23886 125.624 5 14 0 -8-6.11595 126.626 5 14 0 -7-14.3189 110.034 5 14 0 -6-40.3375 122.803 5 14 -1 -9-13.5469 121.100 5 14 -1 -8 53.4565 124.491 5 14 1 -8-25.8825 110.566 5 14 -1 -7 198.817 133.828 5 14 1 -7-52.7353 114.524 5 14 1 -6 42.3713 124.659 5 14 -1 -6-25.8760 155.156 5 14 -2 -8 429.181 155.031 5 14 2 -8 456.121 156.050 5 14 -2 -7 289.719 147.033 5 14 2 -7 231.933 138.232 5 14 2 -6 654.065 181.961 5 14 3 -8 218.678 149.080 5 14 3 -7 267.453 155.616 5 14 3 -6 504.952 181.923 5 14 4 -8 426.534 173.671 5 14 4 -7 67.8685 150.987 5 14 4 -6-108.584 160.769 5 14 5 -7-4.65530 156.463 5 14 6 -7 230.363 174.571 5 0 0 0 0.00 0.00 0 TITL AK_Ru_phen_20220608_autored in P2(1)/n REM P2(1)/n (#14 in standard setting) CELL 0.71073 10.544175 21.174115 21.932563 90.0000 97.5279 90.0000 ZERR 4.00 0.000554 0.001327 0.001261 0.0000 0.0048 0.0000 LATT 1 SYMM -x+1/2, y+1/2,-z+1/2 SFAC C H N O F P Ru UNIT 196.00 156.00 8.00 4.00 24.00 12.00 4.00 TREF HKLF 4 END ; _shelx_hkl_checksum 30215 _shelx_res_file ; shelx.res created by SHELXL-2014/7 TITL SIR92 run in space group P 1 21/n 1 CELL 0.71073 10.5442 21.1741 21.9326 90.000 97.528 90.000 ZERR 4.00 0.0006 0.0013 0.0013 0.000 0.005 0.000 LATT 1 SYMM 1/2 - X, 1/2 + Y, 1/2 - Z SFAC C H N O F P RU UNIT 196 156 8 4 24 12 4 MERG 2 FMAP 2 PLAN -10 ACTA BOND $H CONF L.S. 50 TEMP 25.00 ABIN WGHT 0.046700 2.615600 FVAR 0.61822 C2 1 0.361282 0.234204 0.088220 11.00000 0.04058 0.04869 = 0.04488 0.00124 0.00961 -0.00245 AFIX 43 H2 2 0.304333 0.255106 0.059059 11.00000 -1.50000 AFIX 0 C3 1 0.485762 0.224387 0.075891 11.00000 0.04542 0.06599 = 0.06295 -0.00468 0.02520 -0.00436 AFIX 43 H3 2 0.511285 0.238717 0.039306 11.00000 -1.50000 AFIX 0 C4 1 0.570232 0.193381 0.118257 11.00000 0.03627 0.06400 = 0.07530 -0.01414 0.01855 -0.00175 AFIX 43 H4 2 0.653731 0.186336 0.110556 11.00000 -1.50000 AFIX 0 C5 1 0.613617 0.141747 0.219701 11.00000 0.03082 0.04007 = 0.08500 -0.00625 0.00081 0.01153 AFIX 43 H5 2 0.697992 0.133756 0.214002 11.00000 -1.50000 AFIX 0 C6 1 0.572520 0.123941 0.272226 11.00000 0.03802 0.04517 = 0.08071 -0.00312 -0.01820 0.01767 AFIX 43 H6 2 0.629748 0.104935 0.302614 11.00000 -1.50000 AFIX 0 C7 1 0.394120 0.115849 0.336707 11.00000 0.06224 0.05129 = 0.05974 0.01847 -0.00880 0.00303 AFIX 43 H7 2 0.446139 0.095405 0.368157 11.00000 -1.50000 AFIX 0 C8 1 0.270722 0.128656 0.343116 11.00000 0.07091 0.05630 = 0.05158 0.01968 0.00567 -0.00730 AFIX 43 H8 2 0.238424 0.117861 0.379192 11.00000 -1.50000 AFIX 0 C9 1 0.192237 0.158180 0.295213 11.00000 0.04659 0.04465 = 0.04658 0.00312 0.00971 -0.00337 AFIX 43 H9 2 0.107517 0.166325 0.300159 11.00000 -1.50000 AFIX 0 C11 1 0.404232 0.183341 0.181785 11.00000 0.02995 0.02616 = 0.04589 -0.00498 0.00009 -0.00343 C12 1 0.531317 0.172627 0.172332 11.00000 0.02734 0.04080 = 0.05939 -0.01089 0.00778 0.00066 C13 1 0.358823 0.163552 0.236775 11.00000 0.02956 0.02226 = 0.04693 -0.00599 0.00034 0.00285 C14 1 0.443851 0.133263 0.282876 11.00000 0.04224 0.03311 = 0.05597 0.00278 -0.00552 0.00051 C21 1 -0.028955 0.241376 0.183221 11.00000 0.03382 0.03961 = 0.03766 -0.00638 0.00195 -0.00302 C31 1 0.101066 0.367218 0.253712 11.00000 0.03552 0.03384 = 0.03513 -0.00082 0.00365 0.00482 C32 1 0.032423 0.332912 0.292830 11.00000 0.04149 0.03971 = 0.04150 -0.00419 0.00402 0.00145 AFIX 43 H32 2 0.042485 0.289315 0.295332 11.00000 -1.50000 AFIX 0 C33 1 -0.049456 0.361995 0.327632 11.00000 0.04726 0.06664 = 0.04226 -0.00260 0.00878 0.00511 AFIX 43 H33 2 -0.092963 0.338245 0.353915 11.00000 -1.50000 AFIX 0 C34 1 -0.067198 0.426071 0.323693 11.00000 0.07129 0.05912 = 0.05446 0.00023 0.01855 0.02754 AFIX 43 H34 2 -0.123380 0.446100 0.346745 11.00000 -1.50000 AFIX 0 C35 1 -0.001069 0.459949 0.285398 11.00000 0.10752 0.04355 = 0.08331 0.00709 0.03600 0.02655 AFIX 43 H35 2 -0.012850 0.503427 0.282512 11.00000 -1.50000 AFIX 0 C36 1 0.082406 0.431423 0.251037 11.00000 0.06918 0.04023 = 0.06629 0.00902 0.03419 0.01614 AFIX 43 H36 2 0.126863 0.455813 0.225649 11.00000 -1.50000 AFIX 0 C41 1 0.253035 0.385508 0.155904 11.00000 0.04784 0.03370 = 0.03781 0.00386 0.01055 0.00188 C42 1 0.204806 0.384606 0.094764 11.00000 0.09873 0.04047 = 0.04522 0.00608 0.00460 -0.00731 AFIX 43 H42 2 0.147328 0.353220 0.079770 11.00000 -1.50000 AFIX 0 C43 1 0.241227 0.430249 0.055099 11.00000 0.15436 0.06424 = 0.05005 0.00292 0.00792 -0.01822 AFIX 43 H43 2 0.210216 0.428571 0.013435 11.00000 -1.50000 AFIX 0 C44 1 0.322504 0.477626 0.077101 11.00000 0.13301 0.06217 = 0.06760 0.02440 0.03001 -0.01548 AFIX 43 H44 2 0.345589 0.508566 0.050543 11.00000 -1.50000 AFIX 0 C45 1 0.369219 0.479563 0.137210 11.00000 0.07642 0.04355 = 0.09985 0.01582 0.01646 -0.02516 AFIX 43 H45 2 0.424531 0.511941 0.151915 11.00000 -1.50000 AFIX 0 C46 1 0.336298 0.434527 0.176817 11.00000 0.06359 0.03779 = 0.06844 0.00775 0.00345 -0.01166 AFIX 43 H46 2 0.369655 0.436488 0.218182 11.00000 -1.50000 AFIX 0 C51 1 0.355662 0.315466 0.262639 11.00000 0.03285 0.02553 = 0.04065 -0.00640 0.00131 -0.00237 C52 1 0.473128 0.312195 0.240506 11.00000 0.03897 0.03996 = 0.05298 -0.00951 0.00388 -0.00068 AFIX 43 H52 2 0.478451 0.320888 0.199355 11.00000 -1.50000 AFIX 0 C53 1 0.582362 0.296002 0.279636 11.00000 0.03550 0.04243 = 0.08240 -0.01597 0.00046 0.00153 AFIX 43 H53 2 0.660887 0.293957 0.264749 11.00000 -1.50000 AFIX 0 C54 1 0.574665 0.283012 0.340230 11.00000 0.04537 0.04316 = 0.07913 -0.01187 -0.02226 0.00502 AFIX 43 H54 2 0.648188 0.272263 0.366363 11.00000 -1.50000 AFIX 0 C55 1 0.459524 0.285744 0.362580 11.00000 0.05406 0.05437 = 0.04600 -0.00331 -0.00994 -0.00316 AFIX 43 H55 2 0.454742 0.276434 0.403655 11.00000 -1.50000 AFIX 0 C56 1 0.350786 0.302307 0.324106 11.00000 0.03912 0.03841 = 0.04764 -0.00268 0.00100 0.00370 AFIX 43 H56 2 0.272979 0.304686 0.339638 11.00000 -1.50000 AFIX 0 C61 1 -0.086564 0.152936 0.050854 11.00000 0.02978 0.03853 = 0.03674 -0.00764 0.00108 -0.00048 C62 1 -0.152059 0.101897 0.022689 11.00000 0.05296 0.04534 = 0.08125 -0.00693 -0.01885 -0.00474 AFIX 43 H62 2 -0.125377 0.060981 0.033082 11.00000 -1.50000 AFIX 0 C63 1 -0.258206 0.111927 -0.021333 11.00000 0.05134 0.07486 = 0.07827 -0.02430 -0.01979 -0.01072 AFIX 43 H63 2 -0.300384 0.077617 -0.041215 11.00000 -1.50000 AFIX 0 C64 1 -0.300401 0.171505 -0.035363 11.00000 0.03633 0.08383 = 0.04942 -0.00351 -0.00832 0.00612 AFIX 43 H64 2 -0.372911 0.177902 -0.063711 11.00000 -1.50000 AFIX 0 C65 1 -0.236093 0.221672 -0.007756 11.00000 0.04451 0.05702 = 0.04847 0.00247 -0.00674 0.01438 AFIX 43 H65 2 -0.264034 0.262473 -0.017828 11.00000 -1.50000 AFIX 0 C66 1 -0.129623 0.212529 0.035118 11.00000 0.03743 0.05152 = 0.04412 0.00013 -0.00307 -0.00365 AFIX 43 H66 2 -0.086519 0.247317 0.053580 11.00000 -1.50000 AFIX 0 C71 1 0.007302 0.071476 0.149265 11.00000 0.03259 0.03576 = 0.04335 0.00200 -0.00090 0.00104 C72 1 0.019593 0.009812 0.129890 11.00000 0.05386 0.03604 = 0.05917 -0.00366 0.00311 -0.00592 AFIX 43 H72 2 0.061923 0.001655 0.096101 11.00000 -1.50000 AFIX 0 C73 1 -0.030099 -0.039618 0.160039 11.00000 0.06499 0.03074 = 0.09843 0.00795 -0.01610 -0.00435 AFIX 43 H73 2 -0.021273 -0.080851 0.146604 11.00000 -1.50000 AFIX 0 C74 1 -0.092949 -0.027837 0.210174 11.00000 0.04264 0.06058 = 0.09197 0.03630 0.00323 -0.00709 AFIX 43 H74 2 -0.127994 -0.061284 0.229793 11.00000 -1.50000 AFIX 0 C75 1 -0.104635 0.033078 0.231732 11.00000 0.04903 0.05639 = 0.07509 0.02191 0.01096 0.00447 AFIX 43 H75 2 -0.145774 0.040876 0.265976 11.00000 -1.50000 AFIX 0 C76 1 -0.053338 0.082222 0.200897 11.00000 0.03641 0.04399 = 0.06135 0.01410 0.00658 0.00329 AFIX 43 H76 2 -0.059707 0.123323 0.215134 11.00000 -1.50000 AFIX 0 C81 1 0.172279 0.108477 0.061155 11.00000 0.03291 0.02870 = 0.04658 -0.00532 0.00324 -0.00052 C82 1 0.169064 0.123456 -0.000091 11.00000 0.05322 0.06453 = 0.04868 -0.00028 0.01110 0.00746 AFIX 43 H82 2 0.099929 0.146065 -0.019800 11.00000 -1.50000 AFIX 0 C83 1 0.265748 0.105716 -0.032643 11.00000 0.06397 0.09258 = 0.05893 -0.00039 0.02431 0.00724 AFIX 43 H83 2 0.261181 0.116083 -0.074077 11.00000 -1.50000 AFIX 0 C84 1 0.368068 0.073111 -0.004725 11.00000 0.05859 0.08192 = 0.07404 -0.02548 0.02321 0.00873 AFIX 43 H84 2 0.433364 0.061056 -0.026956 11.00000 -1.50000 AFIX 0 C85 1 0.374669 0.058108 0.056108 11.00000 0.04127 0.05564 = 0.08261 -0.02732 -0.00077 0.01818 AFIX 43 H85 2 0.445733 0.036661 0.075486 11.00000 -1.50000 AFIX 0 C86 1 0.276681 0.074498 0.089209 11.00000 0.04268 0.03623 = 0.05648 -0.01088 0.00269 0.00648 AFIX 43 H86 2 0.280650 0.062771 0.130279 11.00000 -1.50000 AFIX 0 N1 3 0.320124 0.214999 0.139906 11.00000 0.02805 0.02831 = 0.03465 -0.00450 0.00442 -0.00091 N10 3 0.233388 0.175089 0.242985 11.00000 0.02850 0.02737 = 0.04076 0.00305 0.00296 -0.00167 O22 4 -0.133542 0.248772 0.191644 11.00000 0.03368 0.06456 = 0.07782 -0.01526 0.01208 0.00400 P1 6 0.208769 0.325695 0.208672 11.00000 0.02995 0.02785 = 0.03502 -0.00238 0.00282 -0.00070 P2 6 0.055837 0.140005 0.107455 11.00000 0.02806 0.02819 = 0.03665 -0.00316 0.00106 0.00061 RU1 7 0.133623 0.227916 0.165113 11.00000 0.02368 0.02833 = 0.03491 -0.00235 0.00221 0.00046 H1 2 0.091457 0.268056 0.104792 11.00000 -1.50000 MOLE 2 F1 5 0.267437 0.359778 -0.093754 11.00000 0.09615 0.24896 = 0.11657 -0.01375 0.00927 0.07558 F2 5 0.363563 0.309977 -0.160187 11.00000 0.13941 0.21424 = 0.07421 -0.03515 -0.01681 0.02546 F3 5 0.453677 0.392333 -0.117256 11.00000 0.21774 0.09497 = 0.29498 0.07215 0.04540 -0.04862 F4 5 0.354213 0.267741 -0.070254 11.00000 0.18388 0.15789 = 0.16815 0.05252 -0.00683 -0.06373 F5 5 0.437806 0.350100 -0.025162 11.00000 0.15423 0.20693 = 0.08276 -0.05063 -0.01891 0.00917 F6 5 0.535390 0.301057 -0.092883 11.00000 0.09131 0.22244 = 0.13482 0.03511 0.00957 0.05708 P3 6 0.402074 0.332898 -0.092891 11.00000 0.05554 0.07832 = 0.05541 0.01001 0.00254 -0.00407 HKLF 4 REM SIR92 run in space group P 1 21/n 1 REM R1 = 0.0596 for 6576 Fo > 4sig(Fo) and 0.1197 for all 11206 data REM 562 parameters refined using 0 restraints END WGHT 0.0447 2.7723 REM Highest difference peak 0.670, deepest hole -0.690, 1-sigma level 0.093 Q1 1 0.0542 0.3187 0.1169 11.00000 0.05 0.67 Q2 1 0.1368 0.3155 0.1641 11.00000 0.05 0.66 Q3 1 0.4057 0.3599 -0.1512 11.00000 0.05 0.61 Q4 1 0.0375 0.2213 0.1876 11.00000 0.05 0.53 Q5 1 0.3791 0.4161 -0.0867 11.00000 0.05 0.50 Q6 1 0.4380 0.2658 -0.1016 11.00000 0.05 0.50 Q7 1 0.5159 0.3557 -0.1065 11.00000 0.05 0.50 Q8 1 0.5443 0.3609 -0.0921 11.00000 0.05 0.49 Q9 1 0.4354 0.3436 -0.0115 11.00000 0.05 0.47 Q10 1 0.5377 0.2837 -0.0968 11.00000 0.05 0.45 ; _shelx_res_checksum 19428 _shelx_fab_file ; 0 0 2 74.91 0.00 0 0 4 -37.43 0.00 0 0 6 -14.94 0.00 0 0 8 5.66 0.00 0 0 10 2.12 0.00 0 0 12 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26 6 1.09 0.00 -3 26 6 0.73 0.00 -2 26 6 -1.03 0.00 -1 27 6 2.62 0.00 0 27 6 -1.24 0.00 -13 7 7 0.18 0.00 -13 8 7 0.71 0.00 -12 11 7 2.03 0.00 -12 12 7 1.43 0.00 -12 13 7 -1.50 0.00 -11 15 7 1.92 0.00 -11 16 7 2.45 0.00 -10 17 7 -0.21 0.00 -10 18 7 -0.81 0.00 6 23 7 0.30 0.00 -6 24 7 -0.61 0.00 -5 25 7 1.81 0.00 -4 25 7 -0.45 0.00 -3 26 7 0.61 0.00 -2 26 7 3.08 0.00 -1 26 7 -2.73 0.00 -13 8 8 -0.11 0.00 -12 11 8 -0.82 0.00 -12 12 8 -0.54 0.00 -11 15 8 -1.11 0.00 -10 17 8 -0.25 0.00 -10 18 8 -0.15 0.00 -7 23 8 1.47 0.00 -6 24 8 1.33 0.00 -4 25 8 0.27 0.00 -3 26 8 0.39 0.00 -2 26 8 -0.55 0.00 -1 26 8 2.07 0.00 0 26 8 -3.96 0.00 1 26 8 -0.37 0.00 2 26 8 0.53 0.00 12 1 9 3.86 0.00 12 2 9 0.03 0.00 -13 6 9 1.51 0.00 -13 7 9 0.54 0.00 -12 10 9 1.50 0.00 -12 11 9 3.08 0.00 -12 12 9 -0.84 0.00 -11 14 9 2.06 0.00 -11 15 9 1.48 0.00 -10 18 9 1.90 0.00 -5 24 9 1.15 0.00 -4 25 9 2.34 0.00 -2 26 9 1.89 0.00 -1 26 9 0.01 0.00 0 26 9 -1.53 0.00 1 26 9 -0.93 0.00 12 0 10 -4.53 0.00 12 1 10 0.53 0.00 -13 2 10 -3.17 0.00 12 2 10 -2.71 0.00 -13 3 10 -1.06 0.00 12 3 10 1.44 0.00 -13 4 10 0.14 0.00 12 4 10 -0.24 0.00 -13 5 10 -0.71 0.00 -13 6 10 -0.05 0.00 -4 7 10 0.12 0.00 -12 10 10 -2.32 0.00 11 10 10 0.15 0.00 -12 11 10 1.40 0.00 -11 14 10 -0.68 0.00 -11 15 10 0.26 0.00 -10 17 10 -1.20 0.00 -6 23 10 1.22 0.00 -5 24 10 -0.68 0.00 -4 25 10 0.61 0.00 -1 25 10 -0.61 0.00 -13 0 11 1.37 0.00 -13 1 11 1.65 0.00 10 1 11 -2.26 0.00 -13 2 11 0.05 0.00 -13 3 11 3.63 0.00 -13 4 11 1.14 0.00 -13 5 11 -0.13 0.00 11 7 11 0.37 0.00 11 8 11 1.08 0.00 11 9 11 -1.56 0.00 -12 10 11 -0.26 0.00 -12 11 11 -0.38 0.00 10 11 11 1.72 0.00 10 12 11 -1.16 0.00 10 13 11 2.57 0.00 -11 14 11 1.60 0.00 9 15 11 -2.89 0.00 -10 16 11 -1.94 0.00 9 16 11 3.96 0.00 -10 17 11 -1.01 0.00 -9 19 11 0.72 0.00 -8 20 11 -0.58 0.00 -7 22 11 3.13 0.00 -6 23 11 -2.28 0.00 -5 24 11 2.40 0.00 -3 25 11 0.61 0.00 -13 1 12 -0.26 0.00 -13 2 12 -2.49 0.00 -13 3 12 -0.11 0.00 -13 4 12 -2.14 0.00 11 6 12 -2.15 0.00 11 7 12 0.32 0.00 11 8 12 0.24 0.00 -12 9 12 0.81 0.00 -12 10 12 2.02 0.00 -11 13 12 -2.41 0.00 -11 14 12 -1.90 0.00 8 14 12 -0.38 0.00 9 15 12 -1.68 0.00 -10 16 12 1.49 0.00 -6 16 12 0.92 0.00 8 17 12 -0.59 0.00 -9 18 12 -1.95 0.00 7 19 12 -0.33 0.00 -8 20 12 2.01 0.00 6 21 12 -0.67 0.00 -4 23 12 -0.97 0.00 11 0 13 6.06 0.00 11 1 13 -1.89 0.00 11 2 13 1.80 0.00 11 3 13 -3.17 0.00 11 4 13 -1.53 0.00 11 5 13 0.01 0.00 -12 8 13 -3.13 0.00 -12 9 13 -0.85 0.00 -11 13 13 3.25 0.00 -10 16 13 -3.72 0.00 8 16 13 -0.93 0.00 -6 17 13 0.98 0.00 8 17 13 -1.32 0.00 -9 18 13 0.45 0.00 -6 18 13 0.64 0.00 7 18 13 0.81 0.00 2 20 13 0.97 0.00 6 20 13 -0.43 0.00 -7 21 13 0.35 0.00 5 21 13 -0.81 0.00 11 1 14 -2.20 0.00 11 2 14 3.17 0.00 -12 8 14 -0.36 0.00 -11 12 14 -2.29 0.00 -10 15 14 4.87 0.00 8 16 14 2.46 0.00 -9 17 14 -1.84 0.00 -6 17 14 2.38 0.00 7 17 14 -1.17 0.00 7 18 14 0.03 0.00 -7 19 14 0.27 0.00 6 19 14 0.77 0.00 5 20 14 0.83 0.00 5 21 14 -0.25 0.00 -12 2 15 -2.02 0.00 10 3 15 0.72 0.00 -12 7 15 -0.29 0.00 8 15 15 0.46 0.00 7 16 15 -0.52 0.00 -9 17 15 1.60 0.00 7 17 15 0.75 0.00 6 18 15 -0.69 0.00 5 19 15 -1.14 0.00 5 20 15 -0.98 0.00 7 15 16 2.09 0.00 7 16 16 -1.97 0.00 6 17 16 0.59 0.00 -5 18 16 -1.95 0.00 6 18 16 -3.34 0.00 3 19 16 1.60 0.00 5 19 16 2.34 0.00 4 20 16 -1.76 0.00 3 21 16 2.20 0.00 2 22 16 -1.59 0.00 -7 14 17 1.39 0.00 7 14 17 -2.39 0.00 7 15 17 0.79 0.00 6 16 17 1.04 0.00 6 17 17 0.22 0.00 5 18 17 0.04 0.00 4 19 17 1.51 0.00 -4 20 17 0.24 0.00 3 20 17 -1.09 0.00 2 21 17 0.69 0.00 8 11 18 -0.61 0.00 7 13 18 -0.12 0.00 6 15 18 -2.02 0.00 5 17 18 -1.96 0.00 4 18 18 0.40 0.00 3 19 18 0.03 0.00 2 20 18 -0.87 0.00 1 21 18 -0.53 0.00 -11 0 19 -1.44 0.00 7 12 19 0.45 0.00 6 14 19 0.08 0.00 5 15 19 1.23 0.00 5 16 19 1.20 0.00 4 17 19 -1.82 0.00 3 18 19 0.13 0.00 2 19 19 1.10 0.00 1 20 19 -0.47 0.00 -10 0 20 -0.74 0.00 7 10 20 0.80 0.00 6 12 20 0.02 0.00 6 13 20 2.12 0.00 5 14 20 0.02 0.00 -6 15 20 -2.09 0.00 5 15 20 -0.29 0.00 -7 16 20 0.31 0.00 -6 16 20 0.48 0.00 4 16 20 1.00 0.00 -6 17 20 1.39 0.00 3 17 20 0.03 0.00 -5 18 20 -0.19 0.00 2 18 20 -0.09 0.00 1 19 20 0.66 0.00 6 11 21 0.02 0.00 4 14 21 -1.24 0.00 1 15 21 -0.75 0.00 4 15 21 -0.01 0.00 -6 16 21 0.54 0.00 3 16 21 0.08 0.00 -5 17 21 2.29 0.00 2 17 21 -0.36 0.00 1 18 21 0.06 0.00 -10 0 22 -1.10 0.00 -3 5 22 1.95 0.00 -7 9 22 2.54 0.00 6 9 22 1.14 0.00 5 11 22 0.44 0.00 5 12 22 -1.61 0.00 2 14 22 1.13 0.00 3 14 22 -1.27 0.00 -6 15 22 -2.88 0.00 2 15 22 -0.83 0.00 3 15 22 0.20 0.00 1 16 22 0.19 0.00 2 16 22 -0.73 0.00 0 17 22 -2.52 0.00 1 17 22 -1.08 0.00 5 9 23 -2.83 0.00 5 10 23 2.34 0.00 2 14 23 0.65 0.00 1 15 23 -0.69 0.00 -1 16 23 -0.98 0.00 0 16 23 0.67 0.00 5 7 24 -2.39 0.00 0 14 24 -2.48 0.00 1 14 24 0.99 0.00 -2 15 24 0.20 0.00 -1 15 24 -0.02 0.00 -8 1 25 1.75 0.00 -8 2 25 4.99 0.00 -8 3 25 -2.82 0.00 -7 6 25 -2.27 0.00 -7 7 25 -0.26 0.00 -6 8 25 0.80 0.00 -6 9 25 0.25 0.00 -1 12 25 1.36 0.00 -3 13 25 -0.32 0.00 -2 13 25 -1.08 0.00 -1 13 25 -0.02 0.00 0 13 25 1.25 0.00 -7 1 26 -0.57 0.00 -7 2 26 4.04 0.00 -7 3 26 0.58 0.00 -7 4 26 0.20 0.00 -6 4 26 -2.07 0.00 -6 5 26 -1.65 0.00 -6 6 26 -0.86 0.00 -6 7 26 -0.97 0.00 -5 7 26 1.98 0.00 -5 8 26 0.41 0.00 -2 10 26 -1.44 0.00 -1 10 26 -0.17 0.00 -3 11 26 0.39 0.00 -2 11 26 -0.03 0.00 -1 11 26 -1.13 0.00 0 11 26 0.25 0.00 -5 0 27 0.10 0.00 -6 1 27 0.39 0.00 -5 1 27 -0.63 0.00 -6 2 27 1.00 0.00 -5 2 27 -0.27 0.00 -6 3 27 1.70 0.00 -5 3 27 0.03 0.00 -5 4 27 0.25 0.00 -4 4 27 -2.21 0.00 -5 5 27 -1.68 0.00 -4 5 27 -0.41 0.00 -5 6 27 -1.10 0.00 -4 6 27 -2.42 0.00 -3 6 27 1.00 0.00 -4 7 27 1.18 0.00 -3 7 27 1.35 0.00 -2 7 27 -1.74 0.00 -1 7 27 -0.96 0.00 -4 8 27 0.03 0.00 -3 8 27 2.92 0.00 -2 8 27 -0.51 0.00 -1 8 27 -0.47 0.00 0 8 27 0.47 0.00 -2 9 27 -0.01 0.00 -1 9 27 0.06 0.00 -4 0 28 0.48 0.00 -2 0 28 -1.10 0.00 -4 1 28 -0.62 0.00 -3 1 28 1.03 0.00 -2 1 28 -2.22 0.00 -4 2 28 1.42 0.00 -3 2 28 0.77 0.00 -2 2 28 -0.01 0.00 -4 3 28 0.98 0.00 -3 3 28 -1.42 0.00 -2 3 28 -1.77 0.00 -1 3 28 1.12 0.00 -3 4 28 -1.59 0.00 -2 4 28 -0.10 0.00 -1 4 28 0.89 0.00 0 4 28 1.68 0.00 -3 5 28 0.00 0.00 -2 5 28 0.59 0.00 -1 5 28 1.26 0.00 0 0 0 0.00 0.00 # SQUEEZE RESULTS (Version = 270319) # Note: Data are Listed for all Voids in the P1 Unit Cell # i.e. Centre of Gravity, Solvent Accessible Volume, # Recovered number of Electrons in the Void and # Details about the Squeezed Material loop_ _platon_squeeze_void_nr _platon_squeeze_void_average_x _platon_squeeze_void_average_y _platon_squeeze_void_average_z _platon_squeeze_void_volume _platon_squeeze_void_count_electrons _platon_squeeze_void_content 1 0.000 0.500 1.000 388 81 ' ' 2 0.500 0.000 0.500 388 81 ' ' 3 0.186 0.445 0.617 11 0 ' ' 4 0.314 0.945 0.883 11 0 ' ' 5 0.686 0.055 0.117 11 0 ' ' 6 0.814 0.555 0.383 11 0 ' ' # Missing Reflections Below sin(th)/lambda = 0.25 loop_ _platon_missing_refln_index_h _platon_missing_refln_index_k _platon_missing_refln_index_l _platon_missing_refln_theta 0 1 1 1.342 -3 5 5 8.517 _platon_squeeze_void_probe_radius 1.20 _platon_squeeze_details ) TITL SIR92 run in space group P 1 21/n 1 CELL 10.5442 21.1741 21.9326 90.00 97.53 90.00 SPGR P21/n # Solvent Accessible Volume = 820 # Electrons Found in S.A.V. = 162 # Note: Atoms in Void are Labelled as Cxxx and Qxxx for all Others C101 0.782 0.889 0.484 ! 2.72 eA-3 C102 0.723 0.423 0.086 ! 2.35 eA-3 C103 0.799 0.892 0.368 ! 1.97 eA-3 C104 0.299 0.611 0.867 ! 1.97 eA-3 C105 0.851 0.455 0.088 ! 1.96 eA-3 C106 0.660 0.922 0.438 ! 1.84 eA-3 C107 0.694 0.888 0.467 ! 1.73 eA-3 C108 0.757 0.455 0.067 ! 1.64 eA-3 C109 0.699 0.923 0.400 ! 1.63 eA-3 C110 0.747 0.921 0.356 ! 1.56 eA-3 C111 0.263 0.043 0.611 ! 1.55 eA-3 C112 0.719 0.986 0.381 ! 1.50 eA-3 C113 0.775 0.376 0.106 ! 1.19 eA-3 C114 0.640 0.987 0.382 ! 1.19 eA-3 C115 0.924 0.449 0.114 ! 1.17 eA-3 C116 0.585 0.948 0.435 ! 1.17 eA-3 C117 0.814 0.970 0.412 ! 1.10 eA-3 Q118 0.056 0.312 0.117 ! 1.08 eA-3 C119 0.718 0.343 0.075 ! 1.08 eA-3 Q120 0.335 0.623 0.005 ! 1.05 eA-3 C121 0.928 0.487 0.101 ! 1.02 eA-3 Q122 0.687 0.595 0.827 ! 0.98 eA-3 Q123 0.069 0.578 0.842 ! 0.96 eA-3 Q124 0.653 0.265 0.631 ! 0.95 eA-3 C125 0.749 0.465 0.158 ! 0.94 eA-3 C126 0.641 0.903 0.477 ! 0.89 eA-3 Q127 0.935 0.235 0.396 ! 0.89 eA-3 Q128 0.210 0.328 0.219 ! 0.87 eA-3 Q129 0.478 0.720 0.091 ! 0.86 eA-3 Q130 0.357 0.405 0.923 ! 0.85 eA-3 Q131 0.624 0.640 0.145 ! 0.85 eA-3 Q132 0.365 0.814 0.335 ! 0.84 eA-3 Q133 0.469 0.703 0.650 ! 0.83 eA-3 C134 0.336 0.971 0.628 ! 0.82 eA-3 Q135 0.548 0.608 0.134 ! 0.82 eA-3 Q136 0.565 0.409 0.094 ! 0.78 eA-3 Q137 0.408 0.751 0.280 ! 0.78 eA-3 Q138 0.595 0.374 0.213 ! 0.78 eA-3 Q139 0.566 0.846 0.384 ! 0.75 eA-3 C140 0.091 0.499 0.938 ! 0.75 eA-3 C141 0.336 0.155 0.567 ! 0.75 eA-3 Q142 0.252 0.186 0.376 ! 0.75 eA-3 Q143 0.273 0.717 0.288 ! 0.74 eA-3 Q144 0.810 0.688 0.002 ! 0.74 eA-3 C145 0.491 0.155 0.471 ! 0.74 eA-3 Q146 0.459 0.717 0.323 ! 0.74 eA-3 Q147 0.875 0.186 0.807 ! 0.74 eA-3 Q148 0.067 0.642 0.093 ! 0.74 eA-3 Q149 0.431 0.893 0.393 ! 0.73 eA-3 C150 0.667 0.890 0.344 ! 0.73 eA-3 Q151 0.940 0.984 0.526 ! 0.73 eA-3 Q152 0.097 0.265 0.030 ! 0.73 eA-3 Q153 0.547 0.361 0.914 ! 0.73 eA-3 Q154 0.440 0.596 0.587 ! 0.72 eA-3 Q155 0.124 0.919 0.594 ! 0.72 eA-3 Q156 0.779 0.327 0.102 ! 0.71 eA-3 Q157 0.342 0.250 0.937 ! 0.71 eA-3 Q158 0.503 0.034 0.561 ! 0.71 eA-3 Q159 0.275 0.612 0.118 ! 0.70 eA-3 Q160 0.187 0.614 0.083 ! 0.70 eA-3 Q161 0.669 0.345 0.025 ! 0.69 eA-3 Q162 0.278 0.095 0.227 ! 0.69 eA-3 Q163 0.339 0.233 0.078 ! 0.69 eA-3 Q164 0.960 0.187 0.877 ! 0.69 eA-3 Q165 0.842 0.378 0.946 ! 0.69 eA-3 Q166 0.901 0.079 0.437 ! 0.68 eA-3 Q167 0.920 0.157 0.486 ! 0.68 eA-3 Q168 0.539 0.449 0.351 ! 0.68 eA-3 Q169 0.592 0.596 0.045 ! 0.68 eA-3 Q170 0.651 0.622 0.100 ! 0.68 eA-3 Q171 0.779 0.158 0.377 ! 0.68 eA-3 Q172 0.939 0.828 0.549 ! 0.68 eA-3 Q173 0.815 0.968 0.468 ! 0.67 eA-3 Q174 0.940 0.861 0.890 ! 0.67 eA-3 Q175 0.218 0.233 0.163 ! 0.67 eA-3 Q176 0.293 0.486 0.117 ! 0.66 eA-3 Q177 0.558 0.095 0.039 ! 0.66 eA-3 Q178 0.847 0.719-0.002 ! 0.66 eA-3 C179 0.464 0.065 0.524 ! 0.66 eA-3 Q180 1.000 0.514 0.163 ! 0.66 eA-3 C181 0.683 0.392 0.195 ! 0.65 eA-3 Q182 0.246 0.232 0.501 ! 0.65 eA-3 Q183 0.378 0.813 0.891 ! 0.65 eA-3 Q184 0.290 0.143 0.438 ! 0.65 eA-3 Q185 0.807 0.156 0.743 ! 0.65 eA-3 Q186 0.995 0.531 0.391 ! 0.65 eA-3 Q187 0.845 0.344 0.140 ! 0.65 eA-3 Q188 0.954 0.360 0.421 ! 0.65 eA-3 Q189 0.411 0.441 0.693 ! 0.64 eA-3 Q190 0.033 0.468 0.288 ! 0.64 eA-3 C191 0.998 0.515 0.876 ! 0.64 eA-3 Q192 0.278 0.559 0.055 ! 0.64 eA-3 Q193 0.040 0.404 0.023 ! 0.64 eA-3 Q194 0.097 0.751 0.344 ! 0.63 eA-3 Q195 0.844 0.703 0.882 ! 0.63 eA-3 Q196 1.007 0.376 0.454 ! 0.63 eA-3 Q197 0.933 0.766 0.985 ! 0.63 eA-3 Q198 0.035 0.409 0.492 ! 0.63 eA-3 Q199 0.104 0.531 0.048 ! 0.63 eA-3 ) ; _shelx_fab_checksum 78504 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group C C2 0.3613(4) 0.2342(2) 0.0882(2) 0.0444(12) Uani d 1 . . H H2 0.3043 0.2551 0.0591 0.067 Uiso calc 1 . . C C3 0.4858(5) 0.2244(3) 0.0759(2) 0.0565(15) Uani d 1 . . H H3 0.5113 0.2387 0.0393 0.085 Uiso calc 1 . . C C4 0.5702(5) 0.1934(3) 0.1183(3) 0.0575(15) Uani d 1 . . H H4 0.6537 0.1863 0.1106 0.086 Uiso calc 1 . . C C5 0.6136(4) 0.1417(3) 0.2197(3) 0.0526(14) Uani d 1 . . H H5 0.6980 0.1338 0.2140 0.079 Uiso calc 1 . . C C6 0.5725(5) 0.1239(3) 0.2722(3) 0.0569(16) Uani d 1 . . H H6 0.6297 0.1049 0.3026 0.085 Uiso calc 1 . . C C7 0.3941(5) 0.1158(3) 0.3367(2) 0.0592(15) Uani d 1 . . H H7 0.4461 0.0954 0.3682 0.089 Uiso calc 1 . . C C8 0.2707(5) 0.1287(3) 0.3431(2) 0.0598(16) Uani d 1 . . H H8 0.2384 0.1179 0.3792 0.090 Uiso calc 1 . . C C9 0.1922(4) 0.1582(2) 0.2952(2) 0.0456(12) Uani d 1 . . H H9 0.1075 0.1663 0.3002 0.068 Uiso calc 1 . . C C11 0.4042(4) 0.1833(2) 0.1818(2) 0.0344(10) Uani d 1 . . C C12 0.5313(4) 0.1726(2) 0.1723(2) 0.0423(12) Uani d 1 . . C C13 0.3588(4) 0.1636(2) 0.2368(2) 0.0333(10) Uani d 1 . . C C14 0.4439(4) 0.1333(2) 0.2829(2) 0.0448(12) Uani d 1 . . C C21 -0.0290(4) 0.2414(2) 0.18322(19) 0.0373(11) Uani d 1 . . C C31 0.1011(4) 0.3672(2) 0.25371(19) 0.0349(11) Uani d 1 . . C C32 0.0324(4) 0.3329(2) 0.2928(2) 0.0410(12) Uani d 1 . . H H32 0.0425 0.2893 0.2953 0.062 Uiso calc 1 . . C C33 -0.0495(5) 0.3620(3) 0.3276(2) 0.0518(14) Uani d 1 . . H H33 -0.0930 0.3382 0.3539 0.078 Uiso calc 1 . . C C34 -0.0672(5) 0.4261(3) 0.3237(2) 0.0607(16) Uani d 1 . . H H34 -0.1234 0.4461 0.3467 0.091 Uiso calc 1 . . C C35 -0.0011(6) 0.4599(3) 0.2854(3) 0.0760(19) Uani d 1 . . H H35 -0.0129 0.5034 0.2825 0.114 Uiso calc 1 . . C C36 0.0824(5) 0.4314(3) 0.2510(2) 0.0563(15) Uani d 1 . . H H36 0.1269 0.4558 0.2256 0.084 Uiso calc 1 . . C C41 0.2530(4) 0.3855(2) 0.1559(2) 0.0393(11) Uani d 1 . . C C42 0.2048(6) 0.3846(3) 0.0948(2) 0.0619(16) Uani d 1 . . H H42 0.1473 0.3532 0.0798 0.093 Uiso calc 1 . . C C43 0.2412(7) 0.4302(3) 0.0551(3) 0.090(2) Uani d 1 . . H H43 0.2102 0.4286 0.0134 0.135 Uiso calc 1 . . C C44 0.3225(7) 0.4776(3) 0.0771(3) 0.086(2) Uani d 1 . . H H44 0.3456 0.5086 0.0505 0.129 Uiso calc 1 . . C C45 0.3692(6) 0.4796(3) 0.1372(3) 0.0728(18) Uani d 1 . . H H45 0.4245 0.5119 0.1519 0.109 Uiso calc 1 . . C C46 0.3363(5) 0.4345(3) 0.1768(3) 0.0571(15) Uani d 1 . . H H46 0.3697 0.4365 0.2182 0.086 Uiso calc 1 . . C C51 0.3557(4) 0.3155(2) 0.26264(19) 0.0333(10) Uani d 1 . . C C52 0.4731(4) 0.3122(2) 0.2405(2) 0.0442(12) Uani d 1 . . H H52 0.4785 0.3209 0.1994 0.066 Uiso calc 1 . . C C53 0.5824(4) 0.2960(3) 0.2796(3) 0.0541(14) Uani d 1 . . H H53 0.6609 0.2940 0.2647 0.081 Uiso calc 1 . . C C54 0.5747(5) 0.2830(3) 0.3402(3) 0.0586(16) Uani d 1 . . H H54 0.6482 0.2723 0.3664 0.088 Uiso calc 1 . . C C55 0.4595(5) 0.2857(3) 0.3626(2) 0.0529(14) Uani d 1 . . H H55 0.4547 0.2764 0.4037 0.079 Uiso calc 1 . . C C56 0.3508(4) 0.3023(2) 0.3241(2) 0.0421(12) Uani d 1 . . H H56 0.2730 0.3047 0.3396 0.063 Uiso calc 1 . . C C61 -0.0866(4) 0.1529(2) 0.05085(19) 0.0353(11) Uani d 1 . . C C62 -0.1521(5) 0.1019(3) 0.0227(3) 0.0623(16) Uani d 1 . . H H62 -0.1254 0.0610 0.0331 0.093 Uiso calc 1 . . C C63 -0.2582(5) 0.1119(3) -0.0213(3) 0.0707(18) Uani d 1 . . H H63 -0.3004 0.0776 -0.0412 0.106 Uiso calc 1 . . C C64 -0.3004(5) 0.1715(3) -0.0354(2) 0.0578(16) Uani d 1 . . H H64 -0.3729 0.1779 -0.0637 0.087 Uiso calc 1 . . C C65 -0.2361(4) 0.2217(3) -0.0078(2) 0.0511(14) Uani d 1 . . H H65 -0.2640 0.2625 -0.0178 0.077 Uiso calc 1 . . C C66 -0.1296(4) 0.2125(3) 0.0351(2) 0.0451(13) Uani d 1 . . H H66 -0.0865 0.2473 0.0536 0.068 Uiso calc 1 . . C C71 0.0073(4) 0.0715(2) 0.1493(2) 0.0378(11) Uani d 1 . . C C72 0.0196(5) 0.0098(2) 0.1299(2) 0.0501(13) Uani d 1 . . H H72 0.0619 0.0017 0.0961 0.075 Uiso calc 1 . . C C73 -0.0301(5) -0.0396(3) 0.1600(3) 0.0671(17) Uani d 1 . . H H73 -0.0213 -0.0809 0.1466 0.101 Uiso calc 1 . . C C74 -0.0929(5) -0.0278(3) 0.2102(3) 0.0656(18) Uani d 1 . . H H74 -0.1280 -0.0613 0.2298 0.098 Uiso calc 1 . . C C75 -0.1046(5) 0.0331(3) 0.2317(3) 0.0599(16) Uani d 1 . . H H75 -0.1458 0.0409 0.2660 0.090 Uiso calc 1 . . C C76 -0.0533(4) 0.0822(3) 0.2009(2) 0.0472(13) Uani d 1 . . H H76 -0.0597 0.1233 0.2151 0.071 Uiso calc 1 . . C C81 0.1723(4) 0.1085(2) 0.0612(2) 0.0362(11) Uani d 1 . . C C82 0.1691(5) 0.1235(3) -0.0001(2) 0.0551(15) Uani d 1 . . H H82 0.0999 0.1461 -0.0198 0.083 Uiso calc 1 . . C C83 0.2657(5) 0.1057(3) -0.0326(3) 0.0704(18) Uani d 1 . . H H83 0.2612 0.1161 -0.0741 0.106 Uiso calc 1 . . C C84 0.3681(5) 0.0731(3) -0.0047(3) 0.0702(18) Uani d 1 . . H H84 0.4334 0.0611 -0.0270 0.105 Uiso calc 1 . . C C85 0.3747(5) 0.0581(3) 0.0561(3) 0.0606(16) Uani d 1 . . H H85 0.4457 0.0367 0.0755 0.091 Uiso calc 1 . . C C86 0.2767(4) 0.0745(2) 0.0892(2) 0.0455(13) Uani d 1 . . H H86 0.2807 0.0628 0.1303 0.068 Uiso calc 1 . . N N1 0.3201(3) 0.21500(17) 0.13991(15) 0.0303(8) Uani d 1 . . N N10 0.2334(3) 0.17509(17) 0.24298(16) 0.0324(8) Uani d 1 . . O O22 -0.1335(3) 0.24877(18) 0.19164(17) 0.0583(10) Uani d 1 . . P P1 0.20877(10) 0.32570(6) 0.20867(5) 0.0311(3) Uani d 1 . . P P2 0.05584(10) 0.14000(6) 0.10746(5) 0.0312(3) Uani d 1 . . Ru Ru1 0.13362(3) 0.22792(2) 0.16511(2) 0.02912(11) Uani d 1 . . H H1 0.091(4) 0.268(2) 0.1048(18) 0.044 Uiso d 1 . . F F1 0.2674(4) 0.3598(3) -0.0938(2) 0.154(2) Uani d 1 . . F F2 0.3636(4) 0.3100(3) -0.16019(17) 0.145(2) Uani d 1 . . F F3 0.4537(6) 0.3923(3) -0.1173(4) 0.202(3) Uani d 1 . . F F4 0.3542(6) 0.2677(3) -0.0703(3) 0.173(2) Uani d 1 . . F F5 0.4378(4) 0.3501(3) -0.02516(19) 0.151(2) Uani d 1 . . F F6 0.5354(4) 0.3011(3) -0.0929(2) 0.150(2) Uani d 1 . . P P3 0.40207(14) 0.33290(9) -0.09289(7) 0.0635(5) Uani d 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 C2 0.041(3) 0.049(3) 0.045(3) -0.002(2) 0.010(2) 0.001(3) C3 0.045(3) 0.066(4) 0.063(3) -0.004(3) 0.025(2) -0.005(3) C4 0.036(3) 0.064(4) 0.075(4) -0.002(3) 0.019(3) -0.014(3) C5 0.031(3) 0.040(3) 0.085(4) 0.012(2) 0.001(3) -0.006(3) C6 0.038(3) 0.045(4) 0.081(4) 0.018(3) -0.018(3) -0.003(3) C7 0.062(4) 0.051(4) 0.060(3) 0.003(3) -0.009(3) 0.018(3) C8 0.071(4) 0.056(4) 0.052(3) -0.007(3) 0.006(3) 0.020(3) C9 0.047(3) 0.045(3) 0.047(3) -0.003(2) 0.010(2) 0.003(3) C11 0.030(2) 0.026(3) 0.046(3) -0.003(2) 0.0001(19) -0.005(2) C12 0.027(2) 0.041(3) 0.059(3) 0.001(2) 0.008(2) -0.011(3) C13 0.030(2) 0.022(2) 0.047(3) 0.0028(19) 0.0003(19) -0.006(2) C14 0.042(3) 0.033(3) 0.056(3) 0.001(2) -0.006(2) 0.003(3) C21 0.034(3) 0.040(3) 0.038(2) -0.003(2) 0.0020(19) -0.006(2) C31 0.036(2) 0.034(3) 0.035(2) 0.005(2) 0.0036(18) -0.001(2) C32 0.041(3) 0.040(3) 0.041(3) 0.001(2) 0.004(2) -0.004(2) C33 0.047(3) 0.067(4) 0.042(3) 0.005(3) 0.009(2) -0.003(3) C34 0.071(4) 0.059(4) 0.054(3) 0.028(3) 0.019(3) 0.000(3) C35 0.108(5) 0.044(4) 0.083(4) 0.027(4) 0.036(4) 0.007(4) C36 0.069(4) 0.040(3) 0.066(4) 0.016(3) 0.034(3) 0.009(3) C41 0.048(3) 0.034(3) 0.038(3) 0.002(2) 0.011(2) 0.004(2) C42 0.099(4) 0.040(3) 0.045(3) -0.007(3) 0.005(3) 0.006(3) C43 0.154(7) 0.064(5) 0.050(4) -0.018(5) 0.008(4) 0.003(4) C44 0.133(6) 0.062(5) 0.068(4) -0.015(4) 0.030(4) 0.024(4) C45 0.076(4) 0.044(4) 0.100(5) -0.025(3) 0.016(4) 0.016(4) C46 0.064(4) 0.038(3) 0.068(4) -0.012(3) 0.003(3) 0.008(3) C51 0.033(2) 0.026(2) 0.041(3) -0.002(2) 0.0013(19) -0.006(2) C52 0.039(3) 0.040(3) 0.053(3) -0.001(2) 0.004(2) -0.010(3) C53 0.036(3) 0.042(3) 0.082(4) 0.002(2) 0.000(3) -0.016(3) C54 0.045(3) 0.043(4) 0.079(4) 0.005(3) -0.022(3) -0.012(3) C55 0.054(3) 0.054(4) 0.046(3) -0.003(3) -0.010(2) -0.003(3) C56 0.039(3) 0.038(3) 0.048(3) 0.004(2) 0.001(2) -0.003(2) C61 0.030(2) 0.039(3) 0.037(2) 0.000(2) 0.0011(18) -0.008(2) C62 0.053(3) 0.045(4) 0.081(4) -0.005(3) -0.019(3) -0.007(3) C63 0.051(3) 0.075(5) 0.078(4) -0.011(3) -0.020(3) -0.024(4) C64 0.036(3) 0.084(5) 0.049(3) 0.006(3) -0.008(2) -0.004(3) C65 0.045(3) 0.057(4) 0.048(3) 0.014(3) -0.007(2) 0.002(3) C66 0.037(3) 0.052(4) 0.044(3) -0.004(2) -0.003(2) 0.000(3) C71 0.033(2) 0.036(3) 0.043(3) 0.001(2) -0.001(2) 0.002(2) C72 0.054(3) 0.036(3) 0.059(3) -0.006(3) 0.003(2) -0.004(3) C73 0.065(4) 0.031(3) 0.098(5) -0.004(3) -0.016(3) 0.008(3) C74 0.043(3) 0.061(4) 0.092(5) -0.007(3) 0.003(3) 0.036(4) C75 0.049(3) 0.056(4) 0.075(4) 0.004(3) 0.011(3) 0.022(3) C76 0.036(3) 0.044(3) 0.061(3) 0.003(2) 0.007(2) 0.014(3) C81 0.033(2) 0.029(3) 0.047(3) -0.001(2) 0.0032(19) -0.005(2) C82 0.053(3) 0.065(4) 0.049(3) 0.007(3) 0.011(2) 0.000(3) C83 0.064(4) 0.093(5) 0.059(4) 0.007(4) 0.024(3) 0.000(4) C84 0.059(4) 0.082(5) 0.074(4) 0.009(3) 0.023(3) -0.025(4) C85 0.041(3) 0.056(4) 0.083(4) 0.018(3) -0.001(3) -0.027(3) C86 0.043(3) 0.036(3) 0.056(3) 0.006(2) 0.003(2) -0.011(3) N1 0.0281(18) 0.028(2) 0.0347(19) -0.0009(16) 0.0044(14) -0.0045(17) N10 0.0285(19) 0.027(2) 0.041(2) -0.0017(16) 0.0030(15) 0.0030(18) O22 0.0337(19) 0.065(3) 0.078(2) 0.0040(18) 0.0121(17) -0.015(2) P1 0.0300(6) 0.0278(7) 0.0350(6) -0.0007(5) 0.0028(5) -0.0024(5) P2 0.0281(6) 0.0282(7) 0.0367(6) 0.0006(5) 0.0011(4) -0.0032(5) Ru1 0.02368(18) 0.0283(2) 0.03491(19) 0.00046(16) 0.00221(13) -0.00235(18) F1 0.096(3) 0.249(7) 0.117(3) 0.076(4) 0.009(3) -0.014(4) F2 0.139(4) 0.214(6) 0.074(3) 0.025(4) -0.017(3) -0.035(3) F3 0.218(6) 0.095(4) 0.295(8) -0.049(4) 0.045(6) 0.072(5) F4 0.184(5) 0.158(6) 0.168(5) -0.064(4) -0.007(4) 0.053(5) F5 0.154(4) 0.207(6) 0.083(3) 0.009(4) -0.019(3) -0.051(4) F6 0.091(3) 0.222(6) 0.135(4) 0.057(4) 0.010(3) 0.035(4) P3 0.0555(10) 0.0783(13) 0.0554(9) -0.0041(9) 0.0025(7) 0.0100(9) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag N1 C2 C3 . . 122.8(4) ? N1 C2 H2 . . 118.6 ? C3 C2 H2 . . 118.6 ? C4 C3 C2 . . 119.1(5) ? C4 C3 H3 . . 120.4 ? C2 C3 H3 . . 120.4 ? C3 C4 C12 . . 119.8(5) ? C3 C4 H4 . . 120.1 ? C12 C4 H4 . . 120.1 ? C6 C5 C12 . . 121.6(5) ? C6 C5 H5 . . 119.2 ? C12 C5 H5 . . 119.2 ? C5 C6 C14 . . 121.8(5) ? C5 C6 H6 . . 119.1 ? C14 C6 H6 . . 119.1 ? C8 C7 C14 . . 120.3(5) ? C8 C7 H7 . . 119.8 ? C14 C7 H7 . . 119.8 ? C7 C8 C9 . . 119.6(5) ? C7 C8 H8 . . 120.2 ? C9 C8 H8 . . 120.2 ? N10 C9 C8 . . 122.8(5) ? N10 C9 H9 . . 118.6 ? C8 C9 H9 . . 118.6 ? N1 C11 C12 . . 122.0(4) ? N1 C11 C13 . . 117.1(4) ? C12 C11 C13 . . 120.9(4) ? C4 C12 C11 . . 118.3(4) ? C4 C12 C5 . . 123.6(5) ? C11 C12 C5 . . 118.0(5) ? N10 C13 C14 . . 122.7(4) ? N10 C13 C11 . . 118.0(4) ? C14 C13 C11 . . 119.3(4) ? C7 C14 C13 . . 116.7(4) ? C7 C14 C6 . . 124.9(5) ? C13 C14 C6 . . 118.4(5) ? O22 C21 Ru1 . . 176.5(4) ? C36 C31 C32 . . 117.3(5) ? C36 C31 P1 . . 123.3(4) ? C32 C31 P1 . . 119.4(4) ? C33 C32 C31 . . 121.5(5) ? C33 C32 H32 . . 119.2 ? C31 C32 H32 . . 119.2 ? C34 C33 C32 . . 120.0(5) ? C34 C33 H33 . . 120.0 ? C32 C33 H33 . . 120.0 ? C35 C34 C33 . . 118.9(5) ? C35 C34 H34 . . 120.6 ? C33 C34 H34 . . 120.6 ? C34 C35 C36 . . 121.6(6) ? C34 C35 H35 . . 119.2 ? C36 C35 H35 . . 119.2 ? C35 C36 C31 . . 120.7(5) ? C35 C36 H36 . . 119.6 ? C31 C36 H36 . . 119.6 ? C42 C41 C46 . . 117.9(5) ? C42 C41 P1 . . 121.3(4) ? C46 C41 P1 . . 120.7(4) ? C41 C42 C43 . . 120.4(6) ? C41 C42 H42 . . 119.8 ? C43 C42 H42 . . 119.8 ? C44 C43 C42 . . 120.2(6) ? C44 C43 H43 . . 119.9 ? C42 C43 H43 . . 119.9 ? C45 C44 C43 . . 120.0(6) ? C45 C44 H44 . . 120.0 ? C43 C44 H44 . . 120.0 ? C44 C45 C46 . . 120.7(6) ? C44 C45 H45 . . 119.6 ? C46 C45 H45 . . 119.6 ? C45 C46 C41 . . 120.7(5) ? C45 C46 H46 . . 119.6 ? C41 C46 H46 . . 119.6 ? C56 C51 C52 . . 118.6(4) ? C56 C51 P1 . . 121.1(3) ? C52 C51 P1 . . 119.7(3) ? C53 C52 C51 . . 120.1(5) ? C53 C52 H52 . . 119.9 ? C51 C52 H52 . . 119.9 ? C54 C53 C52 . . 120.0(5) ? C54 C53 H53 . . 120.0 ? C52 C53 H53 . . 120.0 ? C55 C54 C53 . . 120.5(5) ? C55 C54 H54 . . 119.8 ? C53 C54 H54 . . 119.8 ? C54 C55 C56 . . 119.8(5) ? C54 C55 H55 . . 120.1 ? C56 C55 H55 . . 120.1 ? C55 C56 C51 . . 120.9(5) ? C55 C56 H56 . . 119.5 ? C51 C56 H56 . . 119.5 ? C66 C61 C62 . . 118.5(4) ? C66 C61 P2 . . 121.4(3) ? C62 C61 P2 . . 120.0(4) ? C61 C62 C63 . . 119.9(5) ? C61 C62 H62 . . 120.1 ? C63 C62 H62 . . 120.1 ? C64 C63 C62 . . 120.5(5) ? C64 C63 H63 . . 119.8 ? C62 C63 H63 . . 119.8 ? C65 C64 C63 . . 119.7(5) ? C65 C64 H64 . . 120.2 ? C63 C64 H64 . . 120.2 ? C64 C65 C66 . . 120.5(5) ? C64 C65 H65 . . 119.7 ? C66 C65 H65 . . 119.7 ? C61 C66 C65 . . 120.9(5) ? C61 C66 H66 . . 119.5 ? C65 C66 H66 . . 119.5 ? C72 C71 C76 . . 118.4(5) ? C72 C71 P2 . . 123.5(4) ? C76 C71 P2 . . 117.9(4) ? C73 C72 C71 . . 120.8(5) ? C73 C72 H72 . . 119.6 ? C71 C72 H72 . . 119.6 ? C72 C73 C74 . . 119.9(6) ? C72 C73 H73 . . 120.1 ? C74 C73 H73 . . 120.1 ? C73 C74 C75 . . 121.0(6) ? C73 C74 H74 . . 119.5 ? C75 C74 H74 . . 119.5 ? C74 C75 C76 . . 118.3(6) ? C74 C75 H75 . . 120.9 ? C76 C75 H75 . . 120.9 ? C75 C76 C71 . . 121.6(5) ? C75 C76 H76 . . 119.2 ? C71 C76 H76 . . 119.2 ? C82 C81 C86 . . 117.9(4) ? C82 C81 P2 . . 121.9(4) ? C86 C81 P2 . . 119.7(4) ? C83 C82 C81 . . 121.3(5) ? C83 C82 H82 . . 119.3 ? C81 C82 H82 . . 119.3 ? C84 C83 C82 . . 120.4(6) ? C84 C83 H83 . . 119.8 ? C82 C83 H83 . . 119.8 ? C83 C84 C85 . . 119.7(5) ? C83 C84 H84 . . 120.2 ? C85 C84 H84 . . 120.2 ? C84 C85 C86 . . 120.6(5) ? C84 C85 H85 . . 119.7 ? C86 C85 H85 . . 119.7 ? C85 C86 C81 . . 120.0(5) ? C85 C86 H86 . . 120.0 ? C81 C86 H86 . . 120.0 ? C2 N1 C11 . . 117.9(4) ? C2 N1 Ru1 . . 126.7(3) ? C11 N1 Ru1 . . 115.4(3) ? C9 N10 C13 . . 117.9(4) ? C9 N10 Ru1 . . 129.3(3) ? C13 N10 Ru1 . . 112.6(3) ? C41 P1 C31 . . 103.8(2) ? C41 P1 C51 . . 103.2(2) ? C31 P1 C51 . . 103.90(19) ? C41 P1 Ru1 . . 116.86(16) ? C31 P1 Ru1 . . 116.08(15) ? C51 P1 Ru1 . . 111.46(15) ? C81 P2 C71 . . 104.1(2) ? C81 P2 C61 . . 103.2(2) ? C71 P2 C61 . . 101.5(2) ? C81 P2 Ru1 . . 112.30(15) ? C71 P2 Ru1 . . 117.57(15) ? C61 P2 Ru1 . . 116.37(16) ? C21 Ru1 N1 . . 177.09(17) ? C21 Ru1 N10 . . 106.12(16) ? N1 Ru1 N10 . . 76.79(13) ? C21 Ru1 P2 . . 88.23(14) ? N1 Ru1 P2 . . 91.59(9) ? N10 Ru1 P2 . . 96.53(10) ? C21 Ru1 P1 . . 92.84(15) ? N1 Ru1 P1 . . 86.88(10) ? N10 Ru1 P1 . . 91.76(10) ? P2 Ru1 P1 . . 171.00(4) ? C21 Ru1 H1 . . 86.0(14) ? N1 Ru1 H1 . . 91.1(14) ? N10 Ru1 H1 . . 167.6(14) ? P2 Ru1 H1 . . 86.3(15) ? P1 Ru1 H1 . . 84.9(15) ? F3 P3 F5 . . 95.3(4) ? F3 P3 F1 . . 93.6(4) ? F5 P3 F1 . . 91.9(3) ? F3 P3 F2 . . 89.2(4) ? F5 P3 F2 . . 175.5(4) ? F1 P3 F2 . . 88.7(2) ? F3 P3 F6 . . 89.6(3) ? F5 P3 F6 . . 89.7(3) ? F1 P3 F6 . . 176.2(4) ? F2 P3 F6 . . 89.3(3) ? F3 P3 F4 . . 175.8(4) ? F5 P3 F4 . . 87.2(3) ? F1 P3 F4 . . 89.7(3) ? F2 P3 F4 . . 88.3(3) ? F6 P3 F4 . . 87.0(3) ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag C2 N1 . 1.330(5) ? C2 C3 . 1.390(6) ? C2 H2 . 0.9300 ? C3 C4 . 1.368(7) ? C3 H3 . 0.9300 ? C4 C12 . 1.377(7) ? C4 H4 . 0.9300 ? C5 C6 . 1.337(7) ? C5 C12 . 1.423(7) ? C5 H5 . 0.9300 ? C6 C14 . 1.420(7) ? C6 H6 . 0.9300 ? C7 C8 . 1.354(7) ? C7 C14 . 1.403(7) ? C7 H7 . 0.9300 ? C8 C9 . 1.397(6) ? C8 H8 . 0.9300 ? C9 N10 . 1.326(5) ? C9 H9 . 0.9300 ? C11 N1 . 1.366(5) ? C11 C12 . 1.401(6) ? C11 C13 . 1.418(6) ? C13 N10 . 1.369(5) ? C13 C14 . 1.414(6) ? C21 O22 . 1.152(5) ? C21 Ru1 . 1.832(5) ? C31 C36 . 1.374(7) ? C31 C32 . 1.397(6) ? C31 P1 . 1.826(4) ? C32 C33 . 1.371(6) ? C32 H32 . 0.9300 ? C33 C34 . 1.371(8) ? C33 H33 . 0.9300 ? C34 C35 . 1.364(8) ? C34 H34 . 0.9300 ? C35 C36 . 1.372(7) ? C35 H35 . 0.9300 ? C36 H36 . 0.9300 ? C41 C42 . 1.371(6) ? C41 C46 . 1.397(7) ? C41 P1 . 1.817(5) ? C42 C43 . 1.388(8) ? C42 H42 . 0.9300 ? C43 C44 . 1.366(9) ? C43 H43 . 0.9300 ? C44 C45 . 1.346(8) ? C44 H44 . 0.9300 ? C45 C46 . 1.365(7) ? C45 H45 . 0.9300 ? C46 H46 . 0.9300 ? C51 C56 . 1.384(6) ? C51 C52 . 1.390(6) ? C51 P1 . 1.835(4) ? C52 C53 . 1.386(6) ? C52 H52 . 0.9300 ? C53 C54 . 1.370(7) ? C53 H53 . 0.9300 ? C54 C55 . 1.369(7) ? C54 H54 . 0.9300 ? C55 C56 . 1.377(6) ? C55 H55 . 0.9300 ? C56 H56 . 0.9300 ? C61 C66 . 1.370(7) ? C61 C62 . 1.384(6) ? C61 P2 . 1.839(4) ? C62 C63 . 1.395(7) ? C62 H62 . 0.9300 ? C63 C64 . 1.359(8) ? C63 H63 . 0.9300 ? C64 C65 . 1.359(7) ? C64 H64 . 0.9300 ? C65 C66 . 1.380(6) ? C65 H65 . 0.9300 ? C66 H66 . 0.9300 ? C71 C72 . 1.384(7) ? C71 C76 . 1.390(6) ? C71 P2 . 1.825(5) ? C72 C73 . 1.378(7) ? C72 H72 . 0.9300 ? C73 C74 . 1.379(8) ? C73 H73 . 0.9300 ? C74 C75 . 1.385(8) ? C74 H74 . 0.9300 ? C75 C76 . 1.389(7) ? C75 H75 . 0.9300 ? C76 H76 . 0.9300 ? C81 C82 . 1.376(6) ? C81 C86 . 1.389(6) ? C81 P2 . 1.820(5) ? C82 C83 . 1.371(7) ? C82 H82 . 0.9300 ? C83 C84 . 1.357(8) ? C83 H83 . 0.9300 ? C84 C85 . 1.364(8) ? C84 H84 . 0.9300 ? C85 C86 . 1.383(6) ? C85 H85 . 0.9300 ? C86 H86 . 0.9300 ? N1 Ru1 . 2.129(3) ? N10 Ru1 . 2.192(3) ? P1 Ru1 . 2.3725(12) ? P2 Ru1 . 2.3378(12) ? Ru1 H1 . 1.59(4) ? F1 P3 . 1.527(4) ? F2 P3 . 1.556(4) ? F3 P3 . 1.497(5) ? F4 P3 . 1.572(5) ? F5 P3 . 1.528(4) ? F6 P3 . 1.559(4) ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag N1 C2 C3 C4 . . . . 0.4(8) ? C2 C3 C4 C12 . . . . -0.2(8) ? C12 C5 C6 C14 . . . . 1.8(9) ? C14 C7 C8 C9 . . . . 1.3(8) ? C7 C8 C9 N10 . . . . -0.6(8) ? C3 C4 C12 C11 . . . . 0.9(8) ? C3 C4 C12 C5 . . . . -178.0(5) ? N1 C11 C12 C4 . . . . -1.8(7) ? C13 C11 C12 C4 . . . . -179.5(5) ? N1 C11 C12 C5 . . . . 177.2(4) ? C13 C11 C12 C5 . . . . -0.5(7) ? C6 C5 C12 C4 . . . . 178.1(5) ? C6 C5 C12 C11 . . . . -0.8(8) ? N1 C11 C13 N10 . . . . 2.6(6) ? C12 C11 C13 N10 . . . . -179.6(4) ? N1 C11 C13 C14 . . . . -177.0(4) ? C12 C11 C13 C14 . . . . 0.8(7) ? C8 C7 C14 C13 . . . . -0.7(8) ? C8 C7 C14 C6 . . . . 177.9(5) ? N10 C13 C14 C7 . . . . -0.8(7) ? C11 C13 C14 C7 . . . . 178.8(5) ? N10 C13 C14 C6 . . . . -179.5(4) ? C11 C13 C14 C6 . . . . 0.2(7) ? C5 C6 C14 C7 . . . . -180.0(6) ? C5 C6 C14 C13 . . . . -1.4(8) ? C36 C31 C32 C33 . . . . -0.6(7) ? P1 C31 C32 C33 . . . . 179.9(3) ? C31 C32 C33 C34 . . . . 1.2(7) ? C32 C33 C34 C35 . . . . -0.8(8) ? C33 C34 C35 C36 . . . . -0.1(9) ? C34 C35 C36 C31 . . . . 0.7(10) ? C32 C31 C36 C35 . . . . -0.3(8) ? P1 C31 C36 C35 . . . . 179.2(4) ? C46 C41 C42 C43 . . . . 1.8(9) ? P1 C41 C42 C43 . . . . -179.1(5) ? C41 C42 C43 C44 . . . . -2.0(11) ? C42 C43 C44 C45 . . . . 1.1(12) ? C43 C44 C45 C46 . . . . 0.0(11) ? C44 C45 C46 C41 . . . . -0.2(9) ? C42 C41 C46 C45 . . . . -0.7(8) ? P1 C41 C46 C45 . . . . -179.8(4) ? C56 C51 C52 C53 . . . . 0.0(7) ? P1 C51 C52 C53 . . . . -171.3(4) ? C51 C52 C53 C54 . . . . 0.2(8) ? C52 C53 C54 C55 . . . . 0.2(8) ? C53 C54 C55 C56 . . . . -0.7(8) ? C54 C55 C56 C51 . . . . 0.9(8) ? C52 C51 C56 C55 . . . . -0.6(7) ? P1 C51 C56 C55 . . . . 170.6(4) ? C66 C61 C62 C63 . . . . 1.0(8) ? P2 C61 C62 C63 . . . . -178.4(4) ? C61 C62 C63 C64 . . . . -2.1(9) ? C62 C63 C64 C65 . . . . 2.2(10) ? C63 C64 C65 C66 . . . . -1.1(9) ? C62 C61 C66 C65 . . . . 0.1(8) ? P2 C61 C66 C65 . . . . 179.5(4) ? C64 C65 C66 C61 . . . . -0.1(8) ? C76 C71 C72 C73 . . . . 1.7(7) ? P2 C71 C72 C73 . . . . -173.6(4) ? C71 C72 C73 C74 . . . . 0.0(8) ? C72 C73 C74 C75 . . . . -1.4(8) ? C73 C74 C75 C76 . . . . 1.1(8) ? C74 C75 C76 C71 . . . . 0.7(7) ? C72 C71 C76 C75 . . . . -2.1(7) ? P2 C71 C76 C75 . . . . 173.5(4) ? C86 C81 C82 C83 . . . . -0.2(8) ? P2 C81 C82 C83 . . . . 172.0(5) ? C81 C82 C83 C84 . . . . -0.5(10) ? C82 C83 C84 C85 . . . . -0.2(10) ? C83 C84 C85 C86 . . . . 1.5(10) ? C84 C85 C86 C81 . . . . -2.3(9) ? C82 C81 C86 C85 . . . . 1.6(7) ? P2 C81 C86 C85 . . . . -170.9(4) ? C3 C2 N1 C11 . . . . -1.2(7) ? C3 C2 N1 Ru1 . . . . 179.1(4) ? C12 C11 N1 C2 . . . . 1.9(6) ? C13 C11 N1 C2 . . . . 179.6(4) ? C12 C11 N1 Ru1 . . . . -178.4(3) ? C13 C11 N1 Ru1 . . . . -0.6(5) ? C8 C9 N10 C13 . . . . -0.9(7) ? C8 C9 N10 Ru1 . . . . -174.8(4) ? C14 C13 N10 C9 . . . . 1.6(6) ? C11 C13 N10 C9 . . . . -178.1(4) ? C14 C13 N10 Ru1 . . . . 176.4(3) ? C11 C13 N10 Ru1 . . . . -3.2(5) ? C42 C41 P1 C31 . . . . -106.4(5) ? C46 C41 P1 C31 . . . . 72.7(4) ? C42 C41 P1 C51 . . . . 145.4(4) ? C46 C41 P1 C51 . . . . -35.5(5) ? C42 C41 P1 Ru1 . . . . 22.8(5) ? C46 C41 P1 Ru1 . . . . -158.2(4) ? C36 C31 P1 C41 . . . . -9.3(5) ? C32 C31 P1 C41 . . . . 170.2(3) ? C36 C31 P1 C51 . . . . 98.3(4) ? C32 C31 P1 C51 . . . . -82.2(4) ? C36 C31 P1 Ru1 . . . . -139.0(4) ? C32 C31 P1 Ru1 . . . . 40.5(4) ? C56 C51 P1 C41 . . . . 145.6(4) ? C52 C51 P1 C41 . . . . -43.3(4) ? C56 C51 P1 C31 . . . . 37.5(5) ? C52 C51 P1 C31 . . . . -151.4(4) ? C56 C51 P1 Ru1 . . . . -88.2(4) ? C52 C51 P1 Ru1 . . . . 82.9(4) ? C82 C81 P2 C71 . . . . 134.0(4) ? C86 C81 P2 C71 . . . . -53.9(4) ? C82 C81 P2 C61 . . . . 28.4(5) ? C86 C81 P2 C61 . . . . -159.5(4) ? C82 C81 P2 Ru1 . . . . -97.8(4) ? C86 C81 P2 Ru1 . . . . 74.3(4) ? C72 C71 P2 C81 . . . . -22.3(4) ? C76 C71 P2 C81 . . . . 162.4(3) ? C72 C71 P2 C61 . . . . 84.7(4) ? C76 C71 P2 C61 . . . . -90.7(4) ? C72 C71 P2 Ru1 . . . . -147.2(3) ? C76 C71 P2 Ru1 . . . . 37.5(4) ? C66 C61 P2 C81 . . . . -111.4(4) ? C62 C61 P2 C81 . . . . 67.9(5) ? C66 C61 P2 C71 . . . . 141.0(4) ? C62 C61 P2 C71 . . . . -39.7(5) ? C66 C61 P2 Ru1 . . . . 12.0(5) ? C62 C61 P2 Ru1 . . . . -168.6(4) ? _cod_database_fobs_code 2312527