#------------------------------------------------------------------------------ #$Date: 2024-10-05 04:57:28 +0300 (Sat, 05 Oct 2024) $ #$Revision: 295069 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/31/26/2312654.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2312654 loop_ _publ_author_name 'Blockhaus, Tobias' 'Sünkel, Karlheinz' _publ_section_title ; Molecular and crystal structures of six poly(arylsulfinyl)- and poly(arylsulfanyl)ferrocenes. ; _journal_coeditor_code UX3008 _journal_issue 11 _journal_name_full 'Acta crystallographica. Section C, Structural chemistry' _journal_paper_doi 10.1107/S2053229624009318 _journal_volume 80 _journal_year 2024 _chemical_formula_iupac '[Fe (C5 H5) (C19 H17 O2 S2)]' _chemical_formula_moiety 'C24 H22 Fe O2 S2' _chemical_formula_sum 'C24 H22 Fe O2 S2' _chemical_formula_weight 462.38 _chemical_name_systematic ; 1,3-Bis[(4-methylbenzene)sulfinyl]ferrocene ; _space_group_crystal_system monoclinic _space_group_IT_number 4 _space_group_name_Hall 'P 2yb' _space_group_name_H-M_alt 'P 1 21 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _audit_creation_method SHELXL-2019/3 _cell_angle_alpha 90 _cell_angle_beta 95.995(2) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 17.1882(10) _cell_length_b 6.0383(4) _cell_length_c 20.4271(12) _cell_measurement_reflns_used 9908 _cell_measurement_temperature 296(2) _cell_measurement_theta_max 28.2658 _cell_measurement_theta_min 2.9501 _cell_volume 2108.5(2) _computing_cell_refinement ; APEX2 (Bruker, 2011) ; _computing_data_collection ; APEX2 (Bruker, 2011) ; _computing_data_reduction ; SAINT (Bruker, 2011) ; _computing_molecular_graphics ; ORTEP-3 for Windows (Farrugia, 2012) and Mercury (Macrae et al., 2020) ; _computing_publication_material ; PLATON (Spek, 2020) ; _computing_structure_refinement ; SHELXL2019 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT2014 (Sheldrick, 2015a) ; _diffrn_ambient_temperature 296(2) _diffrn_detector_area_resol_mean 7.3910 _diffrn_measured_fraction_theta_full 0.996 _diffrn_measured_fraction_theta_max 0.997 _diffrn_measurement_device_type 'Bruker D8 VENTURE' _diffrn_measurement_method 'mix of omega and phi scans' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0315 _diffrn_reflns_av_unetI/netI 0.0406 _diffrn_reflns_limit_h_max 22 _diffrn_reflns_limit_h_min -22 _diffrn_reflns_limit_k_max 8 _diffrn_reflns_limit_k_min -7 _diffrn_reflns_limit_l_max 27 _diffrn_reflns_limit_l_min -27 _diffrn_reflns_number 34842 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 28.311 _diffrn_reflns_theta_min 2.680 _diffrn_source 'rotating anode generator' _exptl_absorpt_coefficient_mu 0.931 _exptl_absorpt_correction_T_max 0.7457 _exptl_absorpt_correction_T_min 0.6483 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (SADABS; Krause et al., 2015) ; _exptl_crystal_colour yellow _exptl_crystal_density_diffrn 1.457 _exptl_crystal_density_method 'not measured' _exptl_crystal_description rod _exptl_crystal_F_000 960 _exptl_crystal_size_max 0.100 _exptl_crystal_size_mid 0.020 _exptl_crystal_size_min 0.020 _refine_diff_density_max 0.504 _refine_diff_density_min -0.227 _refine_ls_abs_structure_details ; Flack x determined using 3063 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013) ; _refine_ls_abs_structure_Flack 0.019(7) _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.020 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 573 _refine_ls_number_reflns 10422 _refine_ls_number_restraints 8 _refine_ls_restrained_S_all 1.020 _refine_ls_R_factor_all 0.0579 _refine_ls_R_factor_gt 0.0418 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0371P)^2^+0.8351P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0884 _refine_ls_wR_factor_ref 0.0948 _reflns_number_gt 8415 _reflns_number_total 10422 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file ux3008.cif _cod_data_source_block compd_2b _cod_original_sg_symbol_H-M 'P 21' _cod_database_code 2312654 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.913 _shelx_estimated_absorpt_t_max 0.982 _shelx_hkl_file ; -2 0 0 0.05 0.11 2 0 0 -0.01 0.19 -2 0 0 -0.10 0.14 -2 0 0 0.07 0.12 3 0 0 0.58 0.31 -3 0 0 0.79 0.36 -3 0 0 0.98 0.37 -3 0 0 0.86 0.31 3 0 0 0.58 0.36 3 0 0 1.07 0.38 4 0 0 271.11 7.10 -4 0 0 274.67 7.10 -4 0 0 270.71 6.95 4 0 0 271.01 7.04 -4 0 0 272.71 7.05 4 0 0 269.92 6.94 5 0 0 3.29 0.59 -5 0 0 3.85 0.59 5 0 0 4.09 0.60 5 0 0 3.22 0.48 -5 0 0 3.74 0.50 -5 0 0 4.14 0.61 -6 0 0 100.82 3.00 -6 0 0 105.26 3.23 6 0 0 102.80 3.22 6 0 0 101.75 3.11 -6 0 0 102.86 3.13 6 0 0 102.20 2.99 -7 0 0 84.03 2.69 -7 0 0 87.92 2.92 7 0 0 84.74 2.91 7 0 0 85.62 2.83 7 0 0 84.57 2.65 -7 0 0 86.78 2.86 -8 0 0 35.15 1.74 8 0 0 33.55 1.48 -8 0 0 34.20 1.52 -8 0 0 35.84 1.72 8 0 0 33.72 1.72 8 0 0 34.39 1.68 -9 0 0 1.62 0.78 9 0 0 1.22 0.58 9 0 0 0.90 0.69 -9 0 0 1.76 0.76 -9 0 0 0.97 0.60 9 0 0 1.69 0.74 -10 0 0 38.40 1.74 -10 0 0 40.53 2.04 -10 0 0 39.87 1.90 10 0 0 39.23 1.86 10 0 0 39.82 1.72 -11 0 0 73.08 2.95 -11 0 0 71.15 2.89 11 0 0 68.04 2.92 11 0 0 67.82 2.80 11 0 0 71.22 2.56 -11 0 0 70.12 2.62 -12 0 0 123.25 4.26 -12 0 0 121.11 4.31 12 0 0 117.63 4.72 -12 0 0 116.47 3.89 12 0 0 120.52 3.85 -13 0 0 52.44 2.58 13 0 0 49.93 2.18 -13 0 0 50.62 2.25 -13 0 0 48.89 2.62 14 0 0 78.85 3.03 -14 0 0 80.39 3.16 -14 0 0 87.72 3.59 -14 0 0 85.01 3.70 -15 0 0 13.72 1.50 -15 0 0 13.03 1.79 -15 0 0 13.73 1.83 15 0 0 13.04 1.57 -16 0 0 60.99 3.26 16 0 0 58.57 2.60 -16 0 0 60.91 3.18 -16 0 0 62.21 2.75 17 0 0 3.38 0.88 -17 0 0 1.62 0.94 -17 0 0 2.07 1.44 -17 0 0 4.70 1.42 -18 0 0 102.46 4.58 -18 0 0 97.59 4.46 -18 0 0 106.48 4.02 -19 0 0 15.64 2.17 -19 0 0 16.29 2.45 -19 0 0 15.97 1.75 -20 0 0 1.35 1.42 -20 0 0 1.29 1.45 -20 0 0 0.49 1.10 -21 0 0 2.93 1.18 -21 0 0 1.94 1.73 -21 0 0 3.39 1.51 -22 0 0 32.79 2.95 -22 0 0 32.38 3.12 -22 0 0 31.61 2.26 0 -1 0 1.28 0.35 0 -1 0 0.60 0.32 0 -1 0 1.54 0.39 0 1 0 0.96 0.34 0 1 0 1.28 0.34 0 1 0 1.09 0.35 -1 -1 0 40.75 1.35 1 -1 0 42.61 1.31 -1 -1 0 44.13 1.45 -1 -1 0 40.83 1.37 -1 1 0 42.43 1.45 -1 1 0 42.33 1.36 1 1 0 40.93 1.37 1 1 0 41.38 1.44 -1 1 0 40.89 1.30 -1 1 0 42.76 1.48 1 1 0 41.25 1.34 -1 1 0 42.16 1.34 -2 -1 0 2046.74 68.77 2 -1 0 2036.08 67.19 2 1 0 2107.98 69.54 -2 1 0 2069.93 67.04 3 -1 0 93.55 2.70 3 -1 0 93.05 2.89 3 -1 0 91.54 2.47 -3 -1 0 92.56 2.70 3 1 0 94.12 2.85 3 1 0 97.76 2.78 -3 1 0 95.92 2.46 -3 1 0 93.30 2.68 4 -1 0 161.79 4.46 4 -1 0 168.05 4.72 -4 -1 0 167.17 4.58 -4 -1 0 158.52 4.62 -4 -1 0 166.12 4.47 4 -1 0 156.38 4.14 -4 1 0 164.51 4.68 4 1 0 165.21 4.54 4 1 0 164.52 4.63 4 1 0 163.77 4.45 -4 1 0 161.69 4.14 -4 1 0 165.36 4.59 -5 -1 0 714.04 17.96 5 -1 0 720.76 18.06 5 1 0 705.68 17.94 -5 1 0 695.49 18.00 5 1 0 701.68 17.87 6 -1 0 693.81 17.58 6 -1 0 692.36 17.86 -6 -1 0 688.09 17.72 6 1 0 695.99 17.67 -6 1 0 696.18 17.16 -6 1 0 702.14 17.83 6 1 0 703.47 17.72 6 1 0 687.25 17.56 7 -1 0 164.83 4.40 -7 -1 0 168.82 4.99 7 -1 0 165.15 5.12 -7 -1 0 166.10 4.87 7 -1 0 169.79 4.87 -7 -1 0 164.45 4.98 -7 1 0 168.64 4.42 7 1 0 168.07 4.96 -7 1 0 172.24 4.86 7 1 0 166.96 4.96 -7 1 0 174.02 5.16 7 1 0 165.52 4.86 -8 -1 0 374.49 10.02 8 -1 0 358.57 10.25 8 -1 0 374.54 9.97 -8 -1 0 364.74 10.08 8 -1 0 378.97 9.48 -8 -1 0 377.45 10.10 -8 1 0 370.62 9.50 8 1 0 366.65 9.99 -8 1 0 375.57 9.96 8 1 0 380.67 10.09 8 1 0 373.97 10.07 -8 1 0 388.88 10.31 9 -1 0 12.73 1.76 9 -1 0 13.34 1.15 -9 -1 0 12.56 1.18 -9 -1 0 13.53 1.30 -9 -1 0 11.25 1.22 9 1 0 12.17 1.11 -9 1 0 12.00 0.79 9 1 0 11.16 1.11 9 1 0 11.84 1.04 -9 1 0 11.77 1.35 -9 1 0 12.03 1.13 10 -1 0 476.32 11.67 -10 -1 0 458.05 12.29 -10 -1 0 463.83 12.40 10 -1 0 450.44 12.59 10 -1 0 451.09 12.22 -10 -1 0 456.91 12.32 -10 1 0 461.33 12.24 10 1 0 447.70 12.27 10 1 0 454.73 12.27 -10 1 0 464.19 12.54 10 1 0 448.47 12.31 11 -1 0 0.99 0.48 11 -1 0 0.46 0.87 11 -1 0 1.14 0.75 -11 -1 0 0.37 0.72 -11 -1 0 1.02 0.82 -11 -1 0 0.54 0.76 11 1 0 0.75 0.65 11 1 0 -0.30 0.63 -11 1 0 0.95 0.50 -11 1 0 1.12 0.74 -11 1 0 -0.19 0.76 -12 -1 0 263.62 7.83 -12 -1 0 261.89 7.85 12 -1 0 272.96 7.15 12 1 0 259.10 7.88 -12 1 0 261.92 7.18 12 1 0 270.97 7.78 -12 1 0 273.71 8.13 -12 1 0 266.37 7.80 13 -1 0 75.79 2.56 -13 -1 0 75.92 3.32 -13 -1 0 73.29 3.30 -13 -1 0 71.79 3.11 -13 1 0 79.79 3.48 -13 1 0 75.29 2.60 13 1 0 75.35 3.06 -14 -1 0 17.39 1.96 14 -1 0 15.11 1.12 -14 -1 0 15.14 1.66 -14 -1 0 12.69 1.69 14 1 0 13.17 1.57 -14 1 0 12.42 1.76 -14 1 0 12.33 1.66 -14 1 0 13.91 1.13 -15 -1 0 11.96 1.72 15 -1 0 12.77 1.13 -15 -1 0 12.78 1.69 -15 -1 0 12.82 1.81 -15 1 0 11.93 1.68 -15 1 0 11.60 1.77 -15 1 0 11.21 1.14 16 -1 0 79.25 2.78 -16 -1 0 76.17 3.85 -16 -1 0 75.45 3.68 -16 -1 0 75.17 3.67 -16 1 0 72.69 3.73 -16 1 0 77.06 2.82 -16 1 0 80.08 3.64 -17 -1 0 33.00 2.68 17 -1 0 34.90 1.75 -17 -1 0 33.21 2.62 -17 -1 0 34.80 2.40 -17 1 0 31.30 2.81 -17 1 0 33.48 1.79 -17 1 0 34.10 2.49 18 -1 0 7.48 1.04 -18 -1 0 6.08 1.76 -18 -1 0 7.34 1.55 -18 -1 0 10.73 1.93 -18 1 0 6.27 1.72 -18 1 0 9.32 1.83 -18 1 0 9.87 1.21 -19 -1 0 21.08 2.14 19 -1 0 23.15 1.58 -19 -1 0 24.95 3.12 -19 -1 0 27.81 2.72 -19 1 0 23.13 1.62 -19 1 0 20.63 2.58 -19 1 0 22.34 2.32 -20 -1 0 19.18 2.52 -20 -1 0 22.17 2.69 -20 -1 0 20.33 2.15 20 -1 0 17.63 2.24 -20 1 0 15.32 1.39 -20 1 0 22.85 2.74 -20 1 0 20.58 2.96 -21 -1 0 2.63 1.31 -21 -1 0 3.19 1.62 -21 -1 0 1.89 1.68 -21 1 0 0.66 1.75 -21 1 0 2.42 1.46 -22 -1 0 1.42 1.60 -22 -1 0 -0.42 1.42 22 -1 0 0.81 0.82 -22 -1 0 1.15 1.22 -22 1 0 0.91 1.43 -22 1 0 -1.11 1.46 0 2 0 930.65 23.54 0 2 0 950.57 23.54 1 -2 0 200.01 5.47 -1 -2 0 200.34 5.56 -1 -2 0 198.48 5.64 -1 -2 0 199.06 5.52 1 -2 0 201.93 5.70 1 -2 0 200.01 5.61 1 2 0 202.27 5.64 -1 2 0 199.40 5.48 -1 2 0 197.94 5.49 1 2 0 202.49 5.51 1 2 0 206.17 5.52 -1 2 0 202.54 5.61 -1 2 0 205.84 5.50 2 -2 0 285.33 7.37 -2 -2 0 281.10 7.68 -2 -2 0 287.08 7.51 -2 -2 0 281.21 7.53 -2 2 0 276.83 7.44 2 2 0 282.73 7.45 -2 2 0 273.37 7.41 -2 2 0 281.91 7.63 -2 2 0 286.86 7.39 2 2 0 286.32 7.51 -2 2 0 273.51 7.38 -2 2 0 281.56 7.67 2 2 0 277.28 7.65 3 -2 0 70.44 2.41 -3 -2 0 67.67 2.38 -3 -2 0 68.69 2.47 -3 -2 0 67.99 2.61 -3 2 0 74.06 2.39 3 2 0 74.10 2.48 -3 2 0 73.15 2.24 3 2 0 72.48 2.37 -3 2 0 74.56 2.38 3 2 0 77.34 2.66 -3 2 0 77.18 2.66 -3 2 0 74.97 2.62 -4 -2 0 584.35 14.88 4 -2 0 576.53 14.56 -4 -2 0 579.91 14.69 4 -2 0 564.29 14.88 -4 -2 0 564.55 14.53 4 2 0 565.93 14.48 -4 2 0 556.36 14.48 4 2 0 564.23 14.82 -4 2 0 568.09 14.24 -4 2 0 566.18 14.83 4 2 0 563.68 14.64 -4 2 0 577.35 14.26 5 -2 0 16.51 1.17 5 -2 0 14.07 1.29 -5 -2 0 15.17 1.16 -5 -2 0 14.87 1.23 -5 -2 0 13.76 1.29 -5 2 0 18.66 0.81 -5 2 0 17.15 1.35 -5 2 0 16.41 0.80 5 2 0 16.92 1.10 5 2 0 15.32 1.01 5 2 0 18.88 1.35 -5 2 0 18.90 1.09 -6 -2 0 71.02 2.64 -6 -2 0 72.82 2.83 6 -2 0 73.72 2.66 -6 -2 0 74.09 2.96 6 -2 0 72.53 2.99 -6 2 0 81.47 2.22 6 2 0 84.84 2.71 6 2 0 77.25 2.76 -6 2 0 79.15 2.20 6 2 0 79.90 2.99 -6 2 0 79.40 2.66 -6 2 0 84.26 3.08 -7 -2 0 30.17 1.84 -7 -2 0 31.06 1.75 7 -2 0 30.54 1.04 -7 -2 0 30.61 1.57 7 -2 0 33.07 1.90 7 -2 0 31.51 1.55 -7 2 0 28.66 1.80 -7 2 0 26.93 0.98 7 2 0 26.45 1.72 7 2 0 28.65 1.52 7 2 0 26.74 1.61 -7 2 0 26.26 1.45 8 -2 0 302.51 8.81 8 -2 0 303.30 8.34 8 -2 0 297.84 7.61 -8 -2 0 311.46 8.72 -8 -2 0 299.92 8.35 -8 -2 0 294.27 8.52 8 2 0 301.51 8.28 8 2 0 296.25 9.03 -8 2 0 302.39 8.73 -8 2 0 308.60 7.59 -8 2 0 305.43 8.29 8 2 0 297.37 8.45 -9 -2 0 6.38 1.06 9 -2 0 5.11 0.46 9 -2 0 4.10 1.06 9 -2 0 6.47 1.01 -9 -2 0 5.13 1.11 -9 -2 0 4.14 1.09 -9 2 0 5.36 0.93 9 2 0 5.13 1.07 -9 2 0 4.81 0.45 9 2 0 5.44 0.92 9 2 0 6.76 1.09 -9 2 0 6.35 1.16 -10 -2 0 140.37 4.71 10 -2 0 146.01 3.83 -10 -2 0 143.24 4.91 10 -2 0 139.32 4.66 -10 -2 0 144.86 4.98 10 2 0 145.11 4.92 -10 2 0 147.69 5.10 -10 2 0 152.24 4.69 -10 2 0 147.70 3.83 10 2 0 149.15 4.69 -11 -2 0 43.95 2.29 -11 -2 0 46.73 2.49 11 -2 0 40.06 2.15 -11 -2 0 40.53 2.64 11 -2 0 45.12 1.40 11 2 0 45.34 2.24 -11 2 0 43.85 2.17 -11 2 0 47.08 2.97 -11 2 0 42.89 1.38 -12 -2 0 59.40 2.93 12 -2 0 57.97 1.77 -12 -2 0 61.58 2.82 -12 -2 0 61.67 2.97 -12 2 0 56.70 1.75 -12 2 0 60.06 2.72 -12 2 0 58.14 3.01 12 2 0 55.09 2.60 -13 -2 0 11.04 1.70 13 -2 0 10.57 0.66 -13 -2 0 12.31 1.61 -13 -2 0 10.12 1.64 -13 2 0 12.86 1.66 -13 2 0 10.74 0.67 -13 2 0 12.28 1.78 -14 -2 0 58.25 3.41 -14 -2 0 58.54 3.02 -14 -2 0 57.58 3.06 14 -2 0 56.26 1.72 -14 2 0 52.34 1.71 -14 2 0 47.81 3.03 -14 2 0 51.29 2.72 -15 -2 0 16.80 1.98 -15 -2 0 14.48 2.00 -15 -2 0 13.90 1.97 -15 2 0 12.21 1.93 -15 2 0 11.25 0.72 -15 2 0 13.74 1.74 -16 -2 0 7.22 1.65 -16 -2 0 7.22 1.66 -16 -2 0 6.22 1.50 -16 2 0 7.12 1.75 -16 2 0 9.22 1.65 -17 -2 0 5.81 1.61 -17 -2 0 7.42 1.60 -17 -2 0 7.87 1.76 -17 2 0 8.40 1.89 -17 2 0 9.95 1.74 -18 -2 0 72.85 3.92 -18 -2 0 68.69 3.59 -18 2 0 64.08 3.88 -18 2 0 67.53 3.53 -19 -2 0 13.23 2.14 -19 -2 0 13.46 2.26 -19 -2 0 13.23 2.19 -19 2 0 14.42 2.12 -19 2 0 14.32 2.35 -20 -2 0 2.29 1.61 -20 -2 0 0.99 1.35 -20 -2 0 1.50 1.50 -20 2 0 1.40 1.65 -20 2 0 3.29 1.49 -21 -2 0 1.29 1.29 -21 -2 0 2.24 1.60 -21 2 0 2.73 1.77 -21 2 0 3.39 1.56 -22 -2 0 12.41 2.25 -22 -2 0 15.38 2.48 -22 2 0 12.86 2.53 -22 2 0 14.12 2.36 0 -3 0 1.65 0.74 0 -3 0 2.22 0.86 0 -3 0 1.62 0.73 0 3 0 1.70 0.67 0 3 0 1.07 0.64 0 3 0 0.07 0.66 -1 -3 0 101.55 3.54 1 -3 0 99.97 3.32 -1 -3 0 101.71 3.39 1 -3 0 99.03 3.46 1 -3 0 96.32 3.37 -1 -3 0 96.90 3.35 -1 3 0 105.60 3.38 1 3 0 106.95 3.41 -1 3 0 99.99 3.38 -1 3 0 101.57 3.52 -1 3 0 101.04 3.31 -1 3 0 101.47 3.50 1 3 0 101.11 3.33 1 3 0 99.61 3.48 -2 -3 0 276.60 7.80 -2 -3 0 273.86 8.01 2 -3 0 279.97 7.72 -2 -3 0 278.62 7.83 -2 3 0 285.73 8.04 2 3 0 285.77 7.80 -2 3 0 285.46 7.75 2 3 0 282.20 8.02 -2 3 0 281.08 7.72 2 3 0 282.24 7.81 -2 3 0 284.47 7.78 -2 3 0 284.69 7.98 -2 3 0 283.38 7.79 -3 -3 0 38.81 1.84 -3 -3 0 39.57 2.07 -3 -3 0 39.77 1.91 3 3 0 35.81 1.95 3 3 0 36.95 1.78 -3 3 0 35.53 1.70 -3 3 0 35.51 1.67 -3 3 0 35.82 1.97 -3 3 0 36.86 1.74 -3 3 0 35.42 2.04 -3 3 0 36.07 1.64 3 3 0 36.98 1.79 -4 -3 0 39.26 2.14 -4 -3 0 37.36 1.97 -4 -3 0 40.50 1.90 -4 3 0 39.98 1.71 4 3 0 39.78 1.83 -4 3 0 39.52 1.80 4 3 0 40.87 2.37 -4 3 0 41.05 1.69 4 3 0 42.25 1.95 -4 3 0 40.78 2.14 -4 3 0 39.40 2.06 -5 -3 0 2.16 0.84 -5 -3 0 2.96 0.99 5 -3 0 2.26 0.82 -5 -3 0 2.81 0.81 -5 3 0 2.92 0.65 5 3 0 3.84 1.02 5 3 0 3.39 0.97 5 3 0 1.41 0.70 -5 3 0 2.97 0.95 -5 3 0 2.22 0.89 -5 3 0 3.44 0.80 -5 3 0 3.79 0.66 -5 3 0 3.71 0.85 -6 -3 0 254.81 7.65 -6 -3 0 247.01 7.17 6 -3 0 244.11 7.17 -6 -3 0 249.28 7.41 -6 3 0 255.13 6.74 6 3 0 260.83 7.37 -6 3 0 258.97 7.65 6 3 0 261.66 7.64 -6 3 0 250.46 7.58 6 3 0 241.54 7.06 -6 3 0 258.85 7.14 7 -3 0 6.35 1.06 7 -3 0 5.65 1.20 -7 -3 0 6.42 1.28 -7 -3 0 3.88 1.04 -7 -3 0 5.08 0.98 -7 3 0 5.30 0.92 7 3 0 5.70 1.07 -7 3 0 5.96 1.23 -7 3 0 5.68 0.71 -7 3 0 4.77 1.05 -7 3 0 5.13 0.62 7 3 0 4.82 1.10 7 3 0 5.03 0.94 -8 -3 0 122.60 4.09 -8 -3 0 117.49 4.30 -8 -3 0 120.07 4.50 8 3 0 121.51 3.97 -8 3 0 123.62 4.01 -8 3 0 121.55 4.50 -8 3 0 119.76 3.32 -8 3 0 117.17 3.34 9 -3 0 13.33 1.42 -9 -3 0 15.14 1.46 -9 3 0 13.67 0.66 9 3 0 15.62 1.33 -9 3 0 14.08 1.40 -9 3 0 13.35 1.95 -9 3 0 13.14 0.69 10 -3 0 65.05 2.91 -10 -3 0 68.88 3.00 -10 -3 0 71.32 3.27 -10 -3 0 68.83 3.37 -10 3 0 78.16 2.96 -10 3 0 74.41 1.92 -10 3 0 71.78 3.41 -10 3 0 73.59 1.92 10 3 0 75.20 2.95 -11 -3 0 25.96 2.18 -11 -3 0 23.56 1.88 -11 -3 0 22.62 2.02 11 3 0 27.42 1.83 -11 3 0 26.16 2.32 -11 3 0 27.42 1.82 -12 -3 0 97.41 3.87 -12 -3 0 100.30 4.17 -12 -3 0 100.58 4.28 12 3 0 94.01 3.75 -12 3 0 97.42 4.33 -12 3 0 97.44 4.14 -13 -3 0 30.82 2.27 -13 -3 0 35.25 2.56 -13 -3 0 33.58 2.50 -13 3 0 31.85 2.57 -13 3 0 37.69 2.33 -14 -3 0 48.30 2.97 -14 -3 0 45.65 3.12 -14 -3 0 43.06 2.72 -14 3 0 46.90 2.69 -14 3 0 45.29 3.05 -15 -3 0 46.20 2.89 -15 -3 0 45.90 3.16 -15 -3 0 48.20 3.10 -15 3 0 46.28 3.16 -15 3 0 42.97 2.73 -16 -3 0 65.95 3.47 -16 -3 0 64.18 3.74 -16 -3 0 56.65 3.50 -16 3 0 60.11 3.85 -16 3 0 64.53 3.35 -17 -3 0 11.91 1.99 -17 -3 0 14.88 2.30 -17 3 0 10.11 1.73 -18 -3 0 5.10 1.56 -18 -3 0 3.52 1.58 -18 -3 0 5.02 1.74 -18 3 0 3.95 1.79 -18 3 0 2.95 1.40 -19 -3 0 12.65 2.08 -19 -3 0 10.49 1.97 -19 -3 0 8.56 1.93 -19 3 0 12.55 2.39 -19 3 0 10.71 1.86 -20 -3 0 5.16 1.91 -20 -3 0 10.67 2.20 -20 -3 0 9.40 2.01 -20 3 0 12.28 2.16 -20 3 0 12.61 2.53 -21 -3 0 1.85 1.50 -21 -3 0 0.98 1.67 -21 -3 0 2.45 1.72 -21 3 0 2.22 1.41 -21 3 0 -2.01 1.43 0 -4 0 334.98 9.40 0 -4 0 331.18 9.38 0 4 0 322.79 9.20 0 4 0 328.72 9.36 -1 -4 0 10.76 1.42 -1 -4 0 12.23 1.48 1 -4 0 11.18 1.34 1 -4 0 9.10 1.25 -1 -4 0 12.38 1.38 -1 4 0 11.91 1.46 -1 4 0 11.27 1.40 -1 4 0 13.38 1.36 -1 4 0 11.12 1.45 1 4 0 12.15 1.38 1 4 0 11.04 1.28 1 4 0 12.22 1.30 -1 4 0 14.36 1.46 -2 -4 0 25.24 1.73 -2 -4 0 25.72 1.90 -2 -4 0 25.23 1.79 2 4 0 25.79 1.63 -2 4 0 27.29 1.95 -2 4 0 26.05 1.78 2 4 0 27.99 1.94 -2 4 0 27.23 1.72 -2 4 0 26.21 1.70 -2 4 0 27.13 1.79 2 4 0 28.61 1.79 -3 -4 0 11.78 1.28 -3 -4 0 13.74 1.45 -3 -4 0 12.05 1.61 3 4 0 15.13 1.38 3 4 0 11.22 1.32 -3 4 0 11.47 1.37 -3 4 0 11.66 1.52 -3 4 0 11.71 1.22 -3 4 0 12.96 1.64 -3 4 0 11.59 1.36 -4 -4 0 191.48 6.13 -4 -4 0 191.08 6.00 -4 -4 0 196.39 6.42 -4 4 0 202.93 6.00 4 4 0 196.47 5.95 -4 4 0 194.97 5.85 -4 4 0 199.58 6.37 -4 4 0 196.10 5.80 -4 4 0 206.45 6.47 -4 4 0 191.96 6.30 4 4 0 184.66 6.00 -5 -4 0 9.15 1.25 -5 -4 0 9.91 1.43 -5 4 0 8.36 1.45 -5 4 0 7.87 1.00 -5 4 0 6.15 0.95 5 4 0 6.49 1.07 -5 4 0 5.53 1.06 -5 4 0 7.65 1.18 -6 -4 0 33.42 2.05 -6 -4 0 34.51 2.38 -6 -4 0 33.60 2.17 -6 4 0 32.03 1.85 -6 4 0 34.86 1.89 -6 4 0 36.00 1.68 6 4 0 34.06 1.91 -6 4 0 35.19 1.69 -7 -4 0 21.68 1.89 -7 -4 0 18.99 1.83 -7 -4 0 19.16 1.64 -7 4 0 19.23 1.93 -7 4 0 20.28 1.57 -7 4 0 16.36 1.22 -7 4 0 18.08 1.20 -7 4 0 19.76 1.51 -8 -4 0 73.61 3.55 8 -4 0 69.33 2.98 -8 -4 0 71.27 3.18 -8 -4 0 76.12 3.09 -8 4 0 71.04 2.40 -8 4 0 63.67 2.92 -8 4 0 69.21 2.37 -8 4 0 69.89 3.47 -8 4 0 65.60 2.91 8 4 0 66.37 2.86 -9 -4 0 37.70 2.62 -9 -4 0 35.14 2.39 -9 -4 0 35.94 2.16 -9 4 0 27.97 1.31 -9 4 0 31.02 2.03 -9 4 0 33.12 2.52 9 4 0 26.92 1.88 -10 -4 0 30.49 2.36 -10 -4 0 25.79 2.38 -10 -4 0 29.74 2.10 -10 4 0 27.91 2.42 -10 4 0 26.16 2.10 -10 4 0 26.68 1.07 -10 4 0 28.12 1.39 10 4 0 26.09 1.94 -11 -4 0 0.68 1.04 -11 -4 0 1.64 1.31 -11 -4 0 2.80 1.36 -11 4 0 3.46 1.10 -11 4 0 2.64 1.55 -12 -4 0 3.36 1.20 -12 -4 0 1.70 1.29 -12 -4 0 3.46 1.54 -12 4 0 5.88 1.63 -12 4 0 5.46 1.21 -13 -4 0 6.87 1.40 -13 -4 0 8.57 1.83 -13 -4 0 7.58 1.80 -13 4 0 8.62 1.44 -13 4 0 6.26 1.87 -14 -4 0 41.64 3.14 -14 -4 0 42.79 2.74 -14 -4 0 37.77 2.94 -14 4 0 45.29 2.71 -14 4 0 40.45 3.20 -15 -4 0 8.42 1.94 -15 -4 0 7.61 1.57 -15 -4 0 7.36 1.92 -15 4 0 6.96 1.88 -15 4 0 10.06 1.62 -16 -4 0 14.93 2.86 -16 -4 0 12.01 1.86 -16 -4 0 13.74 2.22 -16 4 0 12.68 1.79 -16 4 0 12.85 2.30 -17 -4 0 2.97 1.86 -17 -4 0 2.43 1.64 -17 -4 0 1.70 1.26 -17 4 0 1.15 1.17 -17 4 0 0.60 1.72 -18 -4 0 3.79 1.80 -18 -4 0 10.28 2.36 -18 -4 0 9.36 1.79 -18 4 0 9.76 1.90 -18 4 0 10.75 2.27 -19 -4 0 7.11 1.72 -19 -4 0 6.02 1.98 -19 -4 0 7.58 1.99 -19 4 0 7.78 1.84 -19 4 0 7.36 2.19 0 -5 0 1.61 1.00 0 -5 0 2.04 1.10 0 5 0 1.76 1.14 0 5 0 1.68 1.08 0 5 0 2.87 1.10 -1 -5 0 2.72 1.25 -1 -5 0 3.38 1.14 -1 -5 0 2.75 1.29 -1 5 0 0.96 1.00 -1 5 0 2.92 1.18 -1 5 0 2.12 1.18 -2 -5 0 43.66 2.69 -2 -5 0 44.97 2.51 -2 -5 0 41.36 2.84 2 5 0 52.04 2.93 -2 5 0 47.06 2.57 -2 5 0 48.32 2.83 -2 5 0 49.28 2.57 -3 -5 0 32.85 2.28 -3 -5 0 30.81 2.40 -3 -5 0 33.28 2.25 -3 5 0 30.97 2.22 -3 5 0 33.63 2.24 3 5 0 34.54 2.20 -3 5 0 35.83 2.14 -3 5 0 30.81 2.46 -4 -5 0 24.66 2.05 -4 -5 0 25.16 2.25 -4 -5 0 23.07 2.04 4 5 0 22.90 1.88 -4 5 0 24.06 2.32 -4 5 0 23.60 1.82 -4 5 0 23.86 1.75 -4 5 0 22.57 1.85 -5 -5 0 15.79 1.85 -5 -5 0 14.28 2.00 -5 -5 0 16.23 1.78 -5 5 0 11.79 1.44 -5 5 0 13.11 1.49 -5 5 0 11.49 1.62 5 5 0 9.68 1.41 -5 5 0 12.32 1.84 -6 -5 0 88.88 3.95 -6 -5 0 93.82 3.79 -6 -5 0 96.32 4.32 -6 5 0 90.59 3.39 -6 5 0 93.81 3.67 -6 5 0 90.14 4.20 -6 5 0 92.11 3.41 6 5 0 85.27 3.60 -7 -5 0 3.39 1.25 -7 -5 0 2.13 1.41 -7 -5 0 5.18 1.40 -7 5 0 4.44 1.01 -7 5 0 3.86 1.28 -7 5 0 3.33 1.43 -7 5 0 3.05 0.92 -8 -5 0 24.01 2.03 -8 -5 0 23.99 2.26 -8 -5 0 25.41 2.52 -8 5 0 22.70 1.83 -8 5 0 26.23 2.61 -8 5 0 19.21 1.44 -8 5 0 19.46 1.49 -9 -5 0 16.96 2.36 -9 -5 0 14.81 2.12 -9 -5 0 16.54 1.84 -9 5 0 14.98 1.20 -9 5 0 15.73 2.19 -9 5 0 17.50 1.69 -9 5 0 13.11 1.27 -10 -5 0 9.09 1.79 -10 -5 0 12.59 2.19 -10 5 0 12.26 1.65 -10 5 0 11.35 0.95 -10 5 0 13.77 2.16 -10 5 0 8.87 0.92 -11 -5 0 0.90 1.42 -11 -5 0 2.51 1.22 -11 -5 0 1.97 1.36 -11 5 0 2.43 1.51 -11 5 0 3.31 0.43 -11 5 0 3.19 1.24 -12 -5 0 4.80 1.69 -12 -5 0 6.12 1.85 -12 -5 0 5.60 1.43 -12 5 0 6.50 1.46 -12 5 0 7.56 2.04 -13 -5 0 7.06 1.54 -13 -5 0 2.69 1.56 -13 5 0 4.90 1.36 -14 -5 0 12.45 2.19 -14 -5 0 16.25 2.00 -14 -5 0 12.14 2.36 -14 5 0 15.08 2.45 -14 5 0 11.91 1.71 -15 -5 0 5.64 1.63 -15 -5 0 6.40 1.59 -15 -5 0 5.18 2.00 -15 5 0 4.53 1.38 -15 5 0 5.51 1.94 -16 -5 0 21.45 2.28 -16 -5 0 18.33 2.75 -16 -5 0 18.69 2.67 -16 5 0 21.70 2.27 -16 5 0 14.14 2.65 -17 -5 0 1.04 1.23 -17 -5 0 1.77 1.65 -17 -5 0 -0.27 1.55 -17 5 0 -2.07 1.40 -17 5 0 1.87 1.53 0 6 0 10.19 1.84 0 6 0 8.13 1.57 0 6 0 10.89 1.79 -1 -6 0 11.60 1.92 -1 6 0 10.63 1.76 -1 6 0 10.79 1.84 1 6 0 9.28 1.88 1 6 0 9.56 1.66 -1 6 0 8.55 1.72 1 6 0 11.06 1.85 -2 -6 0 10.47 1.85 -2 -6 0 12.02 1.83 -2 -6 0 11.15 1.88 2 6 0 12.01 2.05 -2 6 0 12.49 1.76 -2 6 0 12.02 1.90 2 6 0 15.90 2.09 -2 6 0 11.02 1.92 -3 -6 0 2.51 1.31 -3 -6 0 0.94 1.19 -3 -6 0 1.36 1.35 -3 6 0 0.44 1.24 3 6 0 2.50 1.53 -3 6 0 2.03 1.23 -3 6 0 2.04 1.18 -4 -6 0 23.75 2.22 -4 -6 0 21.95 2.20 -4 -6 0 23.78 2.62 -4 6 0 23.33 2.23 -4 6 0 24.47 2.35 -4 6 0 25.02 2.15 -5 -6 0 10.33 1.72 -5 -6 0 7.95 1.81 -5 -6 0 9.31 1.76 -5 6 0 4.74 1.38 -5 6 0 7.82 1.83 -5 6 0 8.05 1.52 -6 -6 0 7.23 1.68 -6 -6 0 6.33 1.77 -6 -6 0 5.95 1.50 -6 6 0 6.18 1.41 -6 6 0 6.40 1.32 -6 6 0 5.82 1.70 -7 -6 0 8.94 2.04 -7 -6 0 6.34 1.74 -7 -6 0 9.40 1.65 -7 6 0 7.62 1.92 -7 6 0 6.76 1.31 -7 6 0 7.34 1.59 -8 -6 0 22.69 2.19 -8 -6 0 23.90 2.69 -8 -6 0 19.50 2.40 -8 6 0 26.33 1.70 -8 6 0 22.31 2.59 -8 6 0 21.40 1.99 -8 6 0 21.50 1.80 -9 -6 0 7.81 1.85 -9 -6 0 6.95 1.56 -9 6 0 7.52 2.03 -9 6 0 5.79 1.48 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7 0 2.33 1.48 -4 7 0 1.26 1.48 -5 -7 0 7.47 2.00 -5 -7 0 5.42 1.84 -5 -7 0 3.63 1.51 -5 7 0 6.02 1.84 -5 7 0 2.62 1.29 5 7 0 4.24 1.93 -5 7 0 0.96 1.28 -6 -7 0 9.46 1.77 -6 -7 0 10.62 2.26 -6 -7 0 8.34 2.13 -6 7 0 8.56 1.80 -6 7 0 7.58 1.64 6 7 0 10.19 2.40 -7 -7 0 7.08 1.66 -7 -7 0 9.31 2.22 -7 -7 0 7.32 1.87 -7 7 0 4.78 1.42 -7 7 0 8.42 1.79 -7 7 0 7.12 2.11 7 7 0 9.65 2.44 -8 -7 0 3.88 1.91 -8 -7 0 3.34 1.67 -8 -7 0 3.64 1.51 -8 7 0 3.47 1.92 -8 7 0 -0.30 1.22 8 7 0 5.34 2.20 -9 -7 0 3.06 1.42 -9 -7 0 4.33 1.89 -9 -7 0 -0.22 1.59 -9 7 0 -1.24 1.07 -9 7 0 -1.26 1.22 9 7 0 2.91 2.00 -9 7 0 -0.54 1.52 -10 -7 0 3.66 1.88 -10 -7 0 3.71 2.09 -10 -7 0 5.08 1.50 -10 7 0 0.45 1.30 -10 7 0 4.55 1.91 -11 -7 0 5.37 1.45 -11 -7 0 1.89 1.78 -11 -7 0 1.15 1.69 -11 7 0 2.92 1.86 -11 7 0 4.44 1.55 0 8 0 7.08 2.09 0 8 0 4.09 2.00 0 8 0 4.49 1.98 1 8 0 8.17 2.21 -1 8 0 7.17 1.94 1 8 0 7.05 2.08 -1 8 0 6.12 1.88 -1 8 0 9.81 2.28 -2 8 0 0.30 1.56 2 8 0 1.46 1.74 2 8 0 -0.42 1.40 -2 8 0 0.24 1.47 2 8 0 1.75 1.66 -22 0 1 31.31 2.86 -22 0 1 30.32 2.13 -22 0 1 31.66 3.15 -21 0 1 8.43 1.57 -21 0 1 6.74 1.84 -21 0 1 9.01 2.22 -20 0 1 -1.42 1.32 -20 0 1 1.09 1.14 -20 0 1 -0.72 1.49 -19 0 1 0.29 0.96 -19 0 1 -0.69 1.29 -19 0 1 0.84 1.30 -18 0 1 40.18 2.85 -18 0 1 44.32 2.48 -18 0 1 44.95 3.25 18 0 -1 50.80 2.38 -17 0 1 157.18 5.88 17 0 -1 159.77 5.09 -17 0 1 157.08 5.74 -17 0 1 152.41 5.17 -16 0 1 -0.27 0.81 -16 0 1 0.47 1.15 16 0 -1 1.77 0.79 -16 0 1 0.61 0.86 -15 0 1 45.97 2.32 -15 0 1 46.40 2.78 15 0 -1 52.71 2.31 -15 0 1 47.34 2.70 14 0 -1 1.33 0.73 -14 0 1 1.53 1.00 -14 0 1 0.94 0.79 -14 0 1 2.37 1.25 -13 0 1 67.76 2.70 13 0 -1 67.89 2.60 -12 0 1 7.28 1.27 -12 0 1 6.33 1.18 12 0 -1 6.13 0.91 -12 0 1 6.81 0.99 11 0 -1 364.98 9.65 -11 0 1 363.77 10.03 -11 0 1 362.89 10.16 11 0 -1 354.41 10.19 -11 0 1 359.84 9.71 11 0 -1 362.29 9.99 10 0 -1 109.62 3.94 -10 0 1 107.55 3.50 -10 0 1 112.56 3.90 10 0 -1 115.30 3.78 -10 0 1 111.97 3.78 10 0 -1 110.05 3.46 9 0 -1 78.94 2.83 -9 0 1 76.94 2.95 -9 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-4 1 -25 3.16 1.76 -4 1 -25 1.04 1.45 -5 -1 -25 3.41 1.81 -5 -1 -25 2.46 0.95 -5 -1 -25 5.60 1.42 -5 1 -25 1.93 1.39 -5 1 -25 4.00 1.54 -5 1 -25 3.28 1.77 -6 -1 -25 4.40 1.81 -6 -1 -25 0.89 1.24 -6 1 -25 3.43 1.51 -6 1 -25 0.82 1.64 -6 1 -25 3.73 1.65 -9 -2 25 5.97 2.00 9 2 -25 6.45 1.72 9 2 -25 4.29 2.03 -9 2 25 10.61 1.97 8 -2 -25 3.13 1.61 -8 -2 25 3.04 1.78 -8 2 25 3.86 1.51 8 2 -25 0.84 1.50 8 2 -25 1.10 1.78 -7 -2 25 2.00 1.69 7 -2 -25 5.38 1.73 7 2 -25 1.22 1.80 -7 2 25 4.58 1.53 7 2 -25 1.40 1.40 6 -2 -25 3.45 1.72 -6 -2 25 1.18 1.75 6 2 -25 -0.68 1.34 6 2 -25 2.23 1.83 -6 2 25 3.93 1.40 -5 -2 25 8.04 2.06 5 -2 -25 8.08 1.94 5 2 -25 6.81 2.15 5 2 -25 7.64 1.88 -5 2 25 10.17 1.76 -4 -2 25 0.45 1.49 4 -2 -25 1.55 1.52 -4 2 25 2.09 1.17 4 2 -25 2.65 1.74 4 2 -25 -0.77 1.29 3 -2 -25 6.68 1.84 -3 -2 25 5.13 1.83 3 2 -25 6.77 2.10 -3 2 25 8.28 1.43 3 2 -25 4.86 1.61 -2 -2 25 0.69 1.44 2 -2 -25 3.91 1.69 2 2 -25 3.05 1.90 2 2 -25 -0.66 1.39 -2 2 25 4.39 1.18 1 -2 -25 17.73 2.66 -1 -2 25 17.27 2.54 1 -2 -25 19.23 1.22 -1 2 25 19.47 1.81 1 2 -25 19.63 2.83 0 -2 25 5.50 1.83 0 -2 -25 3.06 0.80 0 -2 -25 3.57 1.79 0 2 -25 3.42 1.84 0 2 25 6.70 1.02 0 2 -25 4.57 2.00 -1 -2 -25 0.19 0.75 -1 -2 -25 1.21 1.52 1 -2 25 0.42 1.41 -1 2 -25 0.22 1.53 -1 2 -25 0.46 1.35 2 -2 25 1.15 1.61 -2 -2 -25 -0.05 1.49 -2 2 -25 -0.85 1.47 -2 2 -25 1.62 1.62 -3 -2 -25 11.96 2.31 -3 -2 -25 10.31 1.41 3 -2 25 9.65 2.13 -3 2 -25 11.15 2.33 -3 2 -25 7.99 1.85 4 -2 25 1.25 1.39 -4 -2 -25 1.38 1.02 -4 -2 -25 2.46 1.81 -4 2 -25 0.61 1.59 -4 2 -25 1.83 1.72 -5 -3 25 -0.71 1.54 5 -3 -25 0.95 1.53 5 3 -25 -0.15 1.51 5 3 -25 -1.78 1.66 4 -3 -25 2.57 1.66 -4 -3 25 -1.21 1.69 4 3 -25 0.98 1.66 -4 3 25 2.84 1.04 4 3 -25 -0.52 1.78 -3 -3 25 4.94 1.98 3 -3 -25 5.08 1.70 3 3 -25 6.28 1.90 3 3 -25 6.91 2.23 -2 -3 25 2.06 1.70 2 -3 -25 2.14 1.68 2 3 -25 1.36 1.83 2 3 -25 -0.96 1.53 1 -3 -25 1.48 1.69 -1 -3 25 1.30 1.60 1 3 -25 0.32 1.44 1 3 -25 -2.08 1.57 0 -3 -25 0.84 1.49 0 -3 25 2.49 1.91 0 3 -25 -0.99 1.58 0 3 -25 -1.12 1.71 -1 -3 -25 1.62 1.60 -1 3 -25 1.67 1.64 -1 3 -25 3.24 1.93 9 0 -26 -0.40 0.93 9 0 -26 1.39 1.46 -9 0 26 6.50 1.90 8 0 -26 30.94 2.88 -8 0 26 35.31 3.22 8 0 -26 25.81 1.92 7 0 -26 0.29 0.93 -7 0 26 0.64 1.60 7 0 -26 0.71 1.57 -6 0 26 2.98 1.61 6 0 -26 3.28 1.69 6 0 -26 3.06 1.07 5 0 -26 -0.32 0.88 5 0 -26 0.67 1.44 -5 0 26 2.30 1.29 4 0 -26 0.67 0.99 4 0 -26 -0.66 1.60 -4 0 26 1.25 1.38 -3 0 26 1.59 1.30 3 0 -26 1.23 1.07 3 0 -26 2.84 1.78 -2 0 26 5.99 1.66 2 0 -26 5.69 1.87 2 0 -26 4.14 1.24 1 0 -26 2.85 1.70 -1 0 26 1.59 1.37 1 0 -26 -1.10 0.98 0 0 -26 2.55 1.84 0 0 -26 0.70 1.08 0 0 26 1.83 1.21 -1 0 -26 0.28 1.13 1 0 26 2.61 1.35 -1 0 -26 0.96 1.58 -2 0 -26 0.36 1.16 2 0 26 2.20 1.36 -2 0 -26 -0.49 1.57 3 0 26 0.76 1.29 -3 0 -26 0.80 1.55 -3 0 -26 -0.25 1.09 -4 0 -26 4.35 1.46 -4 0 -26 4.97 1.88 -4 0 -26 4.73 1.29 -8 -1 26 -0.45 1.50 8 -1 -26 1.21 1.50 8 1 -26 1.18 1.74 8 1 -26 -0.11 1.11 7 -1 -26 7.27 1.81 -7 -1 26 3.32 1.69 -7 1 26 5.85 1.64 7 1 -26 6.92 2.17 7 1 -26 1.85 1.23 6 -1 -26 4.24 1.86 -6 -1 26 4.38 1.96 -6 1 26 4.91 1.61 6 1 -26 4.26 1.45 6 1 -26 6.13 2.05 5 -1 -26 1.97 0.85 -5 -1 26 2.30 1.64 5 -1 -26 3.48 1.63 5 1 -26 1.17 1.27 -5 1 26 2.50 1.45 5 1 -26 3.44 1.87 4 -1 -26 0.09 0.77 -4 -1 26 2.62 1.72 4 -1 -26 1.56 1.47 4 1 -26 1.38 1.59 4 1 -26 -0.63 1.13 -4 1 26 2.32 1.40 3 -1 -26 -0.41 0.77 3 -1 -26 -0.37 1.35 3 1 -26 0.71 1.26 3 1 -26 1.51 1.60 -3 1 26 2.66 1.27 2 -1 -26 16.99 2.56 -2 -1 26 14.31 2.38 2 -1 -26 15.63 1.55 2 1 -26 16.23 2.06 -2 1 26 23.54 2.31 2 1 -26 22.23 2.83 1 -1 -26 -0.43 1.27 1 -1 -26 0.97 1.45 -1 -1 26 3.46 1.53 1 1 -26 1.11 1.55 -1 1 26 2.38 1.25 1 1 -26 -0.61 1.25 0 -1 26 5.25 1.62 0 -1 -26 4.97 1.18 0 -1 -26 2.45 1.82 0 1 26 4.95 1.32 0 1 -26 3.01 1.29 0 1 -26 1.90 1.68 -1 -1 -26 0.27 0.96 -1 -1 -26 0.77 1.43 1 -1 26 -0.88 1.28 -1 1 -26 -1.95 1.16 1 1 26 2.52 1.11 -1 1 -26 -1.12 1.47 2 -1 26 8.23 1.86 -2 -1 -26 7.44 1.44 -2 -1 -26 9.86 2.26 -2 1 -26 7.76 2.21 -3 -1 -26 -1.01 0.97 -3 -1 -26 1.04 0.96 -3 -1 -26 2.07 1.71 3 -1 26 2.46 1.52 -3 1 -26 -0.47 1.20 -3 1 -26 1.08 1.62 6 -2 -26 2.59 1.67 -6 -2 26 2.18 1.60 -6 2 26 0.87 1.21 6 2 -26 -1.04 1.60 -5 -2 26 0.16 1.61 5 -2 -26 0.64 1.41 -5 2 26 2.30 1.14 5 2 -26 3.50 1.93 -4 -2 26 5.44 2.00 4 -2 -26 3.08 1.68 4 2 -26 2.54 1.81 -4 2 26 6.76 1.48 3 -2 -26 2.05 1.74 -3 -2 26 2.30 1.76 3 2 -26 0.01 1.80 3 2 -26 1.25 1.35 -3 2 26 5.06 1.29 -2 -2 26 3.39 1.79 2 -2 -26 3.10 1.80 2 2 -26 0.55 1.44 2 2 -26 1.58 1.69 -1 -2 26 9.45 2.24 1 -2 -26 11.00 2.22 -1 2 26 15.35 1.64 1 2 -26 9.18 1.83 1 2 -26 10.44 2.32 0 -2 26 5.12 1.84 0 -2 -26 4.80 1.08 0 -2 -26 2.13 1.62 0 2 -26 4.31 1.95 0 2 -26 0.78 1.58 -1 -2 -26 5.09 1.84 1 -2 26 4.17 1.85 -1 -2 -26 3.91 1.03 -1 2 -26 4.84 1.79 -1 2 -26 2.84 1.74 5 0 -27 -2.07 0.86 5 0 -27 -0.38 1.30 4 0 -27 -0.83 0.90 4 0 -27 3.43 1.58 -4 0 27 1.49 1.44 3 0 -27 4.13 1.72 3 0 -27 3.90 1.16 -3 0 27 4.81 1.64 2 0 -27 -0.03 0.91 2 0 -27 -0.52 1.39 -2 0 27 1.25 1.30 1 0 -27 0.95 1.06 -1 0 27 3.57 1.37 1 0 -27 1.60 1.54 0 0 27 3.23 1.41 0 0 -27 0.23 1.06 0 0 -27 4.47 1.76 3 -1 -27 3.88 1.71 3 -1 -27 -0.72 0.85 -3 -1 27 1.23 1.45 3 1 -27 -0.10 1.27 -3 1 27 3.46 1.26 3 1 -27 -0.87 1.53 -2 -1 27 0.69 1.39 2 -1 -27 1.38 1.51 2 1 -27 0.86 1.29 2 1 -27 1.39 1.56 -2 1 27 2.44 1.28 1 -1 -27 2.10 1.57 1 1 -27 2.80 1.75 0 0 0 0.00 0.00 _exptl_absorpt_process_details ) SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., J. Appl. Cryst. 48 (2015) 3-10 ) _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_max 0.7457 _exptl_absorpt_correction_T_min 0.6483 _exptl_special_details ) The following wavelength and cell were deduced by SADABS from the direction cosines etc. They are given here for emergency use only: CELL 0.71077 17.190 6.042 20.435 90.003 95.984 89.995 ) _computing_structure_solution 'SHELXT2014 (Sheldrick, 2015a)' ; _shelx_hkl_checksum 60624 _shelx_res_file ; TITL shelxt_b.res in P2(1) shelx.res created by SHELXL-2019/3 at 11:15:08 on 04-Feb-2024 CELL 0.71073 17.1882 6.0383 20.4271 90.000 95.995 90.000 ZERR 4.00 0.0010 0.0004 0.0012 0.000 0.002 0.000 LATT -1 SYMM - X, 1/2 + Y, - Z SFAC C H FE O S UNIT 96 88 4 8 8 MERG 2 OMIT 1 -1 -4 OMIT -1 -1 4 OMIT -2 0 0 OMIT 2 0 0 OMIT -1 0 2 OMIT -1 0 -2 OMIT 1 0 2 OMIT 1 0 -2 OMIT -1 0 3 OMIT 1 0 -3 OMIT 2 0 -1 OMIT -2 0 1 OMIT 5 0 0 FMAP 2 PLAN 5 SIZE 0.020 0.020 0.100 ACTA BOND $H DELU 0.001 S21 O21 C15B C16B C18B C19B C26B C27B CONF LIST 4 L.S. 64 TEMP 23.00 WGHT 0.037100 0.835100 FVAR 0.26972 0.45148 0.50194 C10 1 0.509333 0.679160 0.137002 11.00000 0.02892 0.04823 = 0.03800 0.00445 0.00569 0.00513 C11 1 0.487630 0.806771 0.189921 11.00000 0.03653 0.04185 = 0.04783 0.00520 0.00182 0.00574 AFIX 43 H11 2 0.500529 0.954121 0.198740 11.00000 -1.20000 AFIX 0 C12 1 0.442010 0.666716 0.227488 11.00000 0.03508 0.05085 = 0.03985 0.00507 0.00903 0.01161 C13 1 0.436357 0.456691 0.197352 11.00000 0.03861 0.04751 = 0.06673 0.01619 0.01004 0.00551 AFIX 43 H13 2 0.409920 0.335061 0.212077 11.00000 -1.20000 AFIX 0 C14 1 0.477791 0.461657 0.140693 11.00000 0.03693 0.04502 = 0.06216 -0.00598 0.00121 0.00490 AFIX 43 H14 2 0.483272 0.345486 0.111637 11.00000 -1.20000 PART 1 21 AFIX 9 C15A 1 0.342988 0.953165 0.075792 21.00000 0.04043 0.05410 = 0.04995 -0.00320 0.00267 0.01171 AFIX 43 H15A 2 0.368006 1.082245 0.064628 21.00000 -1.20000 AFIX 5 C16A 1 0.341438 0.755021 0.041843 21.00000 0.05171 0.05363 = 0.04180 -0.01322 -0.00591 0.01408 AFIX 43 H16A 2 0.365230 0.727323 0.003818 21.00000 -1.20000 AFIX 5 C17A 1 0.298332 0.605252 0.074312 21.00000 0.04373 0.05694 = 0.11888 0.02315 -0.01861 -0.02044 AFIX 43 H17A 2 0.288017 0.459056 0.061976 21.00000 -1.20000 AFIX 5 C18A 1 0.273243 0.710834 0.128326 21.00000 0.03242 0.12330 = 0.07848 0.01031 0.01053 0.01449 AFIX 43 H18A 2 0.243076 0.648176 0.158727 21.00000 -1.20000 AFIX 5 C19A 1 0.300841 0.925857 0.129243 21.00000 0.04817 0.09317 = 0.06228 -0.00055 0.00334 0.02333 AFIX 43 H19A 2 0.292511 1.033328 0.160369 21.00000 -1.20000 AFIX 5 PART 2 -21 C15B 1 0.327746 0.962756 0.099681 -21.00000 0.05243 0.05401 = 0.08577 0.00743 -0.01464 0.01843 AFIX 43 H15B 2 0.340516 1.110524 0.107916 -21.00000 -1.20000 AFIX 5 C16B 1 0.350512 0.832309 0.046426 -21.00000 0.04511 0.06474 = 0.05843 0.02895 0.00047 0.00624 AFIX 43 H16B 2 0.380682 0.880364 0.013956 -21.00000 -1.20000 AFIX 5 C17B 1 0.318725 0.614972 0.051880 -21.00000 0.03187 0.06593 = 0.05492 -0.00220 -0.00583 -0.00288 AFIX 43 H17B 2 0.324601 0.496903 0.023578 -21.00000 -1.20000 AFIX 5 C18B 1 0.276315 0.611099 0.108503 -21.00000 0.02005 0.07505 = 0.07661 0.00847 0.00742 0.00422 AFIX 43 H18B 2 0.249774 0.490077 0.123481 -21.00000 -1.20000 AFIX 5 C19B 1 0.281894 0.826044 0.138046 -21.00000 0.04451 0.08030 = 0.06231 0.00436 0.00444 0.03969 AFIX 43 H19B 2 0.259618 0.869314 0.175606 -21.00000 -1.20000 AFIX 0 PART 0 C111 1 0.659396 0.720027 0.115681 11.00000 0.02841 0.04578 = 0.03972 0.00347 0.00994 0.00313 C112 1 0.679935 0.506240 0.135175 11.00000 0.03729 0.04133 = 0.06723 0.00332 0.00561 -0.00156 AFIX 43 H112 2 0.645068 0.389850 0.125968 11.00000 -1.20000 AFIX 0 C113 1 0.752809 0.468255 0.168437 11.00000 0.04445 0.04235 = 0.06632 0.00659 0.00349 0.01180 AFIX 43 H113 2 0.766215 0.325137 0.182149 11.00000 -1.20000 AFIX 0 C114 1 0.806761 0.638179 0.182014 11.00000 0.03111 0.04824 = 0.04343 -0.00323 0.00975 0.00322 C115 1 0.785794 0.845194 0.158611 11.00000 0.03722 0.04975 = 0.08119 0.00043 0.00073 -0.00900 AFIX 43 H115 2 0.821670 0.960386 0.165217 11.00000 -1.20000 AFIX 0 C116 1 0.712318 0.888131 0.125216 11.00000 0.04315 0.04285 = 0.07449 0.00896 0.00339 0.00332 AFIX 43 H116 2 0.699609 1.029691 0.109656 11.00000 -1.20000 AFIX 0 C117 1 0.884388 0.594464 0.219893 11.00000 0.04017 0.07772 = 0.05722 -0.00356 0.00033 0.00880 AFIX 137 H11A 2 0.910161 0.732565 0.230930 11.00000 -1.50000 H11B 2 0.915975 0.507366 0.193565 11.00000 -1.50000 H11C 2 0.876897 0.515376 0.259519 11.00000 -1.50000 AFIX 0 C131 1 0.467930 0.631833 0.357513 11.00000 0.06012 0.05843 = 0.04561 0.00213 0.02223 0.00781 C132 1 0.454322 0.429612 0.384234 11.00000 0.04537 0.07793 = 0.04842 -0.00030 0.01006 -0.00655 AFIX 43 H132 2 0.408518 0.352457 0.371080 11.00000 -1.20000 AFIX 0 C133 1 0.509959 0.340875 0.431379 11.00000 0.05335 0.07156 = 0.05495 0.00926 0.01563 -0.00241 AFIX 43 H133 2 0.500957 0.202260 0.448948 11.00000 -1.20000 AFIX 0 C134 1 0.578141 0.451960 0.452947 11.00000 0.06489 0.08248 = 0.03713 0.00227 0.01139 -0.00746 C135 1 0.588168 0.658675 0.425767 11.00000 0.06892 0.09128 = 0.05556 -0.01025 0.00451 -0.02135 AFIX 43 H135 2 0.632843 0.739617 0.439823 11.00000 -1.20000 AFIX 0 C136 1 0.534609 0.747731 0.378975 11.00000 0.08394 0.06218 = 0.06125 -0.00111 0.02429 -0.01809 AFIX 43 H136 2 0.543259 0.886893 0.361621 11.00000 -1.20000 AFIX 0 C137 1 0.637812 0.352202 0.503037 11.00000 0.06887 0.16312 = 0.05578 0.02324 -0.00970 -0.01485 AFIX 137 H13A 2 0.680807 0.296307 0.481495 11.00000 -1.50000 H13B 2 0.614441 0.233163 0.525230 11.00000 -1.50000 H13C 2 0.656441 0.463186 0.534495 11.00000 -1.50000 AFIX 0 C20 1 0.068487 0.282600 0.272046 11.00000 0.02948 0.04691 = 0.04135 0.00376 0.00228 0.00461 C21 1 0.024975 0.124605 0.305164 11.00000 0.03253 0.04235 = 0.04372 -0.00732 0.00045 0.00279 AFIX 43 H21 2 0.015118 -0.021861 0.292886 11.00000 -1.20000 AFIX 0 C22 1 -0.000517 0.235494 0.360926 11.00000 0.03059 0.04528 = 0.04149 -0.00107 0.00365 0.00162 C23 1 0.027261 0.459465 0.362110 11.00000 0.04347 0.03898 = 0.04562 -0.00457 0.00415 0.00786 AFIX 43 H23 2 0.018840 0.566381 0.393374 11.00000 -1.20000 AFIX 0 C24 1 0.070006 0.488376 0.306813 11.00000 0.03785 0.03807 = 0.05229 0.00450 -0.00382 0.00144 AFIX 43 H24 2 0.094551 0.617822 0.295306 11.00000 -1.20000 PART 1 31 AFIX 9 C25A 1 0.174695 -0.022862 0.409291 31.00000 0.07382 0.03680 = 0.12833 0.00582 -0.05515 0.00559 AFIX 43 H25A 2 0.158313 -0.169619 0.406157 31.00000 -1.20000 AFIX 5 C26A 1 0.156701 0.129324 0.456885 31.00000 0.04983 0.09472 = 0.06373 0.03995 -0.01879 -0.02245 AFIX 43 H26A 2 0.126227 0.101776 0.491032 31.00000 -1.20000 AFIX 5 C27A 1 0.192476 0.330111 0.444232 31.00000 0.04486 0.07520 = 0.06482 0.00647 -0.02294 -0.01224 AFIX 43 H27A 2 0.190021 0.459845 0.468467 31.00000 -1.20000 AFIX 5 C28A 1 0.232581 0.302020 0.388820 31.00000 0.02456 0.12143 = 0.04330 0.01877 0.00124 -0.00405 AFIX 43 H28A 2 0.261542 0.409744 0.369653 31.00000 -1.20000 AFIX 5 C29A 1 0.221590 0.083868 0.367226 31.00000 0.05027 0.10087 = 0.07720 -0.02918 -0.02211 0.03556 AFIX 43 H29A 2 0.241941 0.020712 0.331143 31.00000 -1.20000 AFIX 5 PART 2 -31 C25B 1 0.200814 -0.014098 0.375852 -31.00000 0.03429 0.05995 = 0.06316 0.00333 -0.00004 0.00696 AFIX 43 H25B 2 0.200453 -0.144022 0.351374 -31.00000 -1.20000 AFIX 5 C26B 1 0.164537 0.017423 0.434242 -31.00000 0.03447 0.05208 = 0.06617 0.01726 -0.00367 0.00534 AFIX 43 H26B 2 0.136154 -0.088154 0.454870 -31.00000 -1.20000 AFIX 5 C27B 1 0.179036 0.237814 0.455730 -31.00000 0.05702 0.06597 = 0.04045 -0.00550 -0.00157 0.01293 AFIX 43 H27B 2 0.161852 0.302490 0.492955 -31.00000 -1.20000 AFIX 5 C28B 1 0.224277 0.342504 0.410624 -31.00000 0.04096 0.04256 = 0.04921 0.00241 0.00321 -0.00683 AFIX 43 H28B 2 0.242043 0.488051 0.413006 -31.00000 -1.20000 AFIX 5 C29B 1 0.237737 0.186817 0.361255 -31.00000 0.03160 0.04616 = 0.04562 -0.00288 0.00195 0.00159 AFIX 43 H29B 2 0.265900 0.212097 0.325500 -31.00000 -1.20000 AFIX 0 PART 0 C211 1 0.041512 0.310811 0.140555 11.00000 0.03942 0.05417 = 0.03208 -0.00233 0.01184 0.00076 C212 1 0.045527 0.519904 0.114418 11.00000 0.04599 0.05473 = 0.04790 -0.00384 0.01109 -0.00859 AFIX 43 H212 2 0.087483 0.612358 0.127757 11.00000 -1.20000 AFIX 0 C213 1 -0.013691 0.591105 0.067976 11.00000 0.06016 0.04926 = 0.04177 0.00236 0.01022 -0.00794 AFIX 43 H213 2 -0.010608 0.731449 0.049673 11.00000 -1.20000 AFIX 0 C214 1 -0.076946 0.458611 0.048368 11.00000 0.04782 0.06870 = 0.03277 -0.00170 0.00403 -0.00570 C215 1 -0.079332 0.249808 0.074508 11.00000 0.05801 0.06146 = 0.04550 -0.01033 0.00301 -0.02031 AFIX 43 H215 2 -0.121233 0.157627 0.060789 11.00000 -1.20000 AFIX 0 C216 1 -0.021398 0.173065 0.120482 11.00000 0.06112 0.04433 = 0.04801 0.00013 0.00974 -0.00530 AFIX 43 H216 2 -0.024236 0.031311 0.137876 11.00000 -1.20000 AFIX 0 C217 1 -0.142337 0.537608 -0.001213 11.00000 0.07290 0.09464 = 0.05735 0.01343 -0.00419 -0.00384 AFIX 137 H21A 2 -0.138392 0.465928 -0.042685 11.00000 -1.50000 H21B 2 -0.138420 0.695024 -0.006582 11.00000 -1.50000 H21C 2 -0.191783 0.502110 0.014097 11.00000 -1.50000 AFIX 0 C231 1 -0.148746 0.156589 0.380650 11.00000 0.04424 0.04672 = 0.04076 0.00028 0.01389 -0.00002 C232 1 -0.188649 -0.013238 0.346943 11.00000 0.05522 0.05346 = 0.08791 -0.01574 0.00982 -0.00262 AFIX 43 H232 2 -0.166369 -0.153217 0.345295 11.00000 -1.20000 AFIX 0 C233 1 -0.263321 0.028765 0.315228 11.00000 0.06014 0.07713 = 0.07781 -0.01659 0.00057 -0.02124 AFIX 43 H233 2 -0.290210 -0.084932 0.291964 11.00000 -1.20000 AFIX 0 C234 1 -0.297882 0.232119 0.317458 11.00000 0.04112 0.07328 = 0.04595 0.00756 0.01234 -0.00202 C235 1 -0.256853 0.397105 0.351646 11.00000 0.05024 0.06047 = 0.07600 0.00005 0.00546 0.00918 AFIX 43 H235 2 -0.279026 0.537158 0.353510 11.00000 -1.20000 AFIX 0 C236 1 -0.182807 0.359080 0.383549 11.00000 0.05792 0.04824 = 0.06024 -0.00672 -0.00036 -0.00383 AFIX 43 H236 2 -0.156285 0.472843 0.407076 11.00000 -1.20000 AFIX 0 C237 1 -0.378258 0.276029 0.282423 11.00000 0.04665 0.11960 = 0.06856 -0.00049 0.00247 -0.01252 AFIX 137 H23A 2 -0.417253 0.240325 0.311127 11.00000 -1.50000 H23B 2 -0.385990 0.186115 0.243529 11.00000 -1.50000 H23C 2 -0.382582 0.429537 0.270360 11.00000 -1.50000 AFIX 0 FE1 3 0.391579 0.698256 0.134102 11.00000 0.02664 0.04975 = 0.04502 0.00443 0.00544 0.00388 FE2 3 0.117831 0.238012 0.365294 11.00000 0.03195 0.04338 = 0.04243 0.00320 -0.00194 0.00171 O11 4 0.557032 1.022985 0.072418 11.00000 0.04875 0.06243 = 0.08619 0.03788 0.01441 0.01382 O13 4 0.324406 0.618608 0.298018 11.00000 0.04474 0.14954 = 0.08383 0.03884 0.02191 0.01286 O21 4 0.118672 -0.026719 0.198128 11.00000 0.08755 0.07559 = 0.06742 -0.00536 0.01657 0.04227 O23 4 -0.043280 0.244622 0.480897 11.00000 0.06773 0.08350 = 0.04194 -0.01052 0.00656 0.00157 S11 5 0.564132 0.777366 0.073471 11.00000 0.03291 0.06675 = 0.04089 0.00865 0.00754 0.00690 S13 5 0.396631 0.750589 0.296972 11.00000 0.06474 0.08459 = 0.05810 0.01532 0.02845 0.02774 S21 5 0.116736 0.217475 0.201800 11.00000 0.03753 0.07546 = 0.04899 0.00223 0.01232 0.01370 S23 5 -0.052344 0.103608 0.420730 11.00000 0.04536 0.05207 = 0.04120 0.00212 0.00877 0.00395 HKLF 4 REM shelxt_b.res in P2(1) REM wR2 = 0.0948, GooF = S = 1.020, Restrained GooF = 1.020 for all data REM R1 = 0.0418 for 8415 Fo > 4sig(Fo) and 0.0579 for all 10422 data REM 573 parameters refined using 8 restraints END WGHT 0.0370 0.8398 REM Highest difference peak 0.504, deepest hole -0.227, 1-sigma level 0.048 Q1 1 0.3779 0.5532 0.2822 11.00000 0.05 0.50 Q2 1 0.1261 0.3629 0.2172 11.00000 0.05 0.32 Q3 1 0.3977 0.8459 0.1429 11.00000 0.05 0.32 Q4 1 0.3783 0.7007 0.1696 11.00000 0.05 0.30 Q5 1 0.0924 0.1014 0.3840 11.00000 0.05 0.28 ; _shelx_res_checksum 65143 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y+1/2, -z' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group C C10 0.5093(2) 0.6792(8) 0.1370(2) 0.0382(10) Uani d 1 . . C C11 0.4876(2) 0.8068(8) 0.1899(2) 0.0423(11) Uani d 1 . . H H11 0.500529 0.954121 0.198740 0.051 Uiso calc 1 . . C C12 0.4420(2) 0.6667(8) 0.2275(2) 0.0416(11) Uani d 1 . . C C13 0.4364(3) 0.4567(9) 0.1974(2) 0.0506(12) Uani d 1 . . H H13 0.409920 0.335061 0.212077 0.061 Uiso calc 1 . . C C14 0.4778(2) 0.4617(8) 0.1407(3) 0.0483(12) Uani d 1 . . H H14 0.483272 0.345486 0.111637 0.058 Uiso calc 1 . . C C15A 0.3430(4) 0.9532(14) 0.0758(6) 0.048(4) Uani d 0.45(3) A 1 H H15A 0.368006 1.082245 0.064628 0.058 Uiso calc 0.45(3) A 1 C C16A 0.3414(4) 0.755(2) 0.0418(3) 0.050(5) Uani d 0.45(3) A 1 H H16A 0.365230 0.727323 0.003818 0.060 Uiso calc 0.45(3) A 1 C C17A 0.2983(5) 0.6053(12) 0.0743(5) 0.075(9) Uani d 0.45(3) A 1 H H17A 0.288017 0.459056 0.061976 0.090 Uiso calc 0.45(3) A 1 C C18A 0.2732(3) 0.711(2) 0.1283(4) 0.078(10) Uani d 0.45(3) A 1 H H18A 0.243076 0.648176 0.158727 0.093 Uiso calc 0.45(3) A 1 C C19A 0.3008(6) 0.9259(18) 0.1292(4) 0.068(7) Uani d 0.45(3) A 1 H H19A 0.292511 1.033328 0.160369 0.082 Uiso calc 0.45(3) A 1 C C15B 0.3277(5) 0.9628(11) 0.0997(6) 0.066(4) Uani d 0.55(3) A 2 H H15B 0.340516 1.110524 0.107916 0.079 Uiso calc 0.55(3) A 2 C C16B 0.3505(4) 0.832(2) 0.0464(4) 0.056(4) Uani d 0.55(3) A 2 H H16B 0.380682 0.880364 0.013956 0.068 Uiso calc 0.55(3) A 2 C C17B 0.3187(6) 0.6150(15) 0.0519(5) 0.052(4) Uani d 0.55(3) A 2 H H17B 0.324601 0.496903 0.023578 0.062 Uiso calc 0.55(3) A 2 C C18B 0.2763(4) 0.6111(18) 0.1085(6) 0.057(5) Uani d 0.55(3) A 2 H H18B 0.249774 0.490077 0.123481 0.068 Uiso calc 0.55(3) A 2 C C19B 0.2819(5) 0.826(2) 0.1380(3) 0.062(5) Uani d 0.55(3) A 2 H H19B 0.259618 0.869314 0.175606 0.075 Uiso calc 0.55(3) A 2 C C111 0.6594(2) 0.7200(9) 0.11568(19) 0.0375(9) Uani d 1 . . C C112 0.6799(3) 0.5062(8) 0.1352(2) 0.0486(12) Uani d 1 . . H H112 0.645068 0.389850 0.125968 0.058 Uiso calc 1 . . C C113 0.7528(3) 0.4683(9) 0.1684(2) 0.0512(12) Uani d 1 . . H H113 0.766215 0.325137 0.182149 0.061 Uiso calc 1 . . C C114 0.8068(2) 0.6382(8) 0.1820(2) 0.0405(10) Uani d 1 . . C C115 0.7858(3) 0.8452(9) 0.1586(3) 0.0564(13) Uani d 1 . . H H115 0.821670 0.960386 0.165217 0.068 Uiso calc 1 . . C C116 0.7123(3) 0.8881(8) 0.1252(3) 0.0537(12) Uani d 1 . . H H116 0.699609 1.029691 0.109656 0.064 Uiso calc 1 . . C C117 0.8844(3) 0.5945(10) 0.2199(2) 0.0587(14) Uani d 1 . . H H11A 0.910161 0.732565 0.230930 0.088 Uiso calc 1 . . H H11B 0.915975 0.507366 0.193565 0.088 Uiso calc 1 . . H H11C 0.876897 0.515376 0.259519 0.088 Uiso calc 1 . . C C131 0.4679(3) 0.6318(9) 0.3575(2) 0.0535(13) Uani d 1 . . C C132 0.4543(3) 0.4296(11) 0.3842(2) 0.0569(14) Uani d 1 . . H H132 0.408518 0.352457 0.371080 0.068 Uiso calc 1 . . C C133 0.5100(3) 0.3409(10) 0.4314(2) 0.0593(14) Uani d 1 . . H H133 0.500957 0.202260 0.448948 0.071 Uiso calc 1 . . C C134 0.5781(3) 0.4520(11) 0.4529(2) 0.0611(15) Uani d 1 . . C C135 0.5882(3) 0.6587(12) 0.4258(3) 0.0721(18) Uani d 1 . . H H135 0.632843 0.739617 0.439823 0.086 Uiso calc 1 . . C C136 0.5346(3) 0.7477(11) 0.3790(3) 0.0679(14) Uani d 1 . . H H136 0.543259 0.886893 0.361621 0.082 Uiso calc 1 . . C C137 0.6378(4) 0.3522(16) 0.5030(3) 0.097(3) Uani d 1 . . H H13A 0.680807 0.296307 0.481495 0.146 Uiso calc 1 . . H H13B 0.614441 0.233163 0.525230 0.146 Uiso calc 1 . . H H13C 0.656441 0.463186 0.534495 0.146 Uiso calc 1 . . C C20 0.0685(2) 0.2826(8) 0.2720(2) 0.0393(10) Uani d 1 . . C C21 0.0250(2) 0.1246(8) 0.3052(2) 0.0398(10) Uani d 1 . . H H21 0.015118 -0.021861 0.292886 0.048 Uiso calc 1 . . C C22 -0.0005(2) 0.2355(9) 0.36093(19) 0.0391(9) Uani d 1 . . C C23 0.0273(2) 0.4595(8) 0.3621(2) 0.0427(10) Uani d 1 . . H H23 0.018840 0.566381 0.393374 0.051 Uiso calc 1 . . C C24 0.0700(2) 0.4884(8) 0.3068(2) 0.0433(11) Uani d 1 . . H H24 0.094551 0.617822 0.295306 0.052 Uiso calc 1 . . C C25A 0.1747(5) -0.0229(10) 0.4093(5) 0.084(10) Uani d 0.50(3) B 1 H H25A 0.158313 -0.169619 0.406157 0.101 Uiso calc 0.50(3) B 1 C C26A 0.1567(5) 0.129(2) 0.4569(4) 0.071(7) Uani d 0.50(3) B 1 H H26A 0.126227 0.101776 0.491032 0.085 Uiso calc 0.50(3) B 1 C C27A 0.1925(6) 0.3301(16) 0.4442(5) 0.064(5) Uani d 0.50(3) B 1 H H27A 0.190021 0.459845 0.468467 0.076 Uiso calc 0.50(3) B 1 C C28A 0.2326(4) 0.3020(13) 0.3888(5) 0.063(7) Uani d 0.50(3) B 1 H H28A 0.261542 0.409744 0.369653 0.076 Uiso calc 0.50(3) B 1 C C29A 0.2216(4) 0.0839(16) 0.3672(3) 0.078(9) Uani d 0.50(3) B 1 H H29A 0.241941 0.020712 0.331143 0.094 Uiso calc 0.50(3) B 1 C C25B 0.2008(5) -0.0141(13) 0.3759(5) 0.053(4) Uani d 0.50(3) B 2 H H25B 0.200453 -0.144022 0.351374 0.063 Uiso calc 0.50(3) B 2 C C26B 0.1645(4) 0.0174(15) 0.4342(5) 0.052(5) Uani d 0.50(3) B 2 H H26B 0.136154 -0.088154 0.454870 0.062 Uiso calc 0.50(3) B 2 C C27B 0.1790(5) 0.2378(19) 0.4557(3) 0.055(5) Uani d 0.50(3) B 2 H H27B 0.161852 0.302490 0.492955 0.066 Uiso calc 0.50(3) B 2 C C28B 0.2243(5) 0.3425(11) 0.4106(5) 0.044(4) Uani d 0.50(3) B 2 H H28B 0.242043 0.488051 0.413006 0.053 Uiso calc 0.50(3) B 2 C C29B 0.2377(3) 0.1868(19) 0.3613(4) 0.041(3) Uani d 0.50(3) B 2 H H29B 0.265900 0.212097 0.325500 0.050 Uiso calc 0.50(3) B 2 C C211 0.0415(2) 0.3108(8) 0.1406(2) 0.0413(11) Uani d 1 . . C C212 0.0455(3) 0.5199(9) 0.1144(2) 0.0491(12) Uani d 1 . . H H212 0.087483 0.612358 0.127757 0.059 Uiso calc 1 . . C C213 -0.0137(3) 0.5911(9) 0.0680(2) 0.0501(12) Uani d 1 . . H H213 -0.010608 0.731449 0.049673 0.060 Uiso calc 1 . . C C214 -0.0769(3) 0.4586(10) 0.0484(2) 0.0498(12) Uani d 1 . . C C215 -0.0793(3) 0.2498(11) 0.0745(2) 0.0552(12) Uani d 1 . . H H215 -0.121233 0.157627 0.060789 0.066 Uiso calc 1 . . C C216 -0.0214(3) 0.1731(9) 0.1205(2) 0.0509(11) Uani d 1 . . H H216 -0.024236 0.031311 0.137876 0.061 Uiso calc 1 . . C C217 -0.1423(3) 0.5376(13) -0.0012(3) 0.0757(18) Uani d 1 . . H H21A -0.138392 0.465928 -0.042685 0.114 Uiso calc 1 . . H H21B -0.138420 0.695024 -0.006582 0.114 Uiso calc 1 . . H H21C -0.191783 0.502110 0.014097 0.114 Uiso calc 1 . . C C231 -0.1487(2) 0.1566(8) 0.3807(2) 0.0432(11) Uani d 1 . . C C232 -0.1886(3) -0.0132(10) 0.3469(3) 0.0654(14) Uani d 1 . . H H232 -0.166369 -0.153217 0.345295 0.078 Uiso calc 1 . . C C233 -0.2633(3) 0.0288(11) 0.3152(3) 0.0722(17) Uani d 1 . . H H233 -0.290210 -0.084932 0.291964 0.087 Uiso calc 1 . . C C234 -0.2979(2) 0.2321(11) 0.3175(2) 0.0529(12) Uani d 1 . . C C235 -0.2569(3) 0.3971(10) 0.3516(3) 0.0623(14) Uani d 1 . . H H235 -0.279026 0.537158 0.353510 0.075 Uiso calc 1 . . C C236 -0.1828(3) 0.3591(9) 0.3835(3) 0.0559(13) Uani d 1 . . H H236 -0.156285 0.472843 0.407076 0.067 Uiso calc 1 . . C C237 -0.3783(3) 0.2760(13) 0.2824(3) 0.0785(19) Uani d 1 . . H H23A -0.417253 0.240325 0.311127 0.118 Uiso calc 1 . . H H23B -0.385990 0.186115 0.243529 0.118 Uiso calc 1 . . H H23C -0.382582 0.429537 0.270360 0.118 Uiso calc 1 . . Fe Fe1 0.39158(3) 0.69826(9) 0.13410(3) 0.04035(17) Uani d 1 . . Fe Fe2 0.11783(3) 0.23801(10) 0.36529(3) 0.03966(16) Uani d 1 . . O O11 0.55703(18) 1.0230(6) 0.07242(18) 0.0653(10) Uani d 1 . . O O13 0.3244(2) 0.6186(9) 0.2980(2) 0.0916(15) Uani d 1 . . O O21 0.1187(2) -0.0267(7) 0.19813(18) 0.0763(11) Uani d 1 . . O O23 -0.04328(18) 0.2446(7) 0.48090(14) 0.0643(9) Uani d 1 . . S S11 0.56413(6) 0.7774(2) 0.07347(5) 0.0466(3) Uani d 1 . . S S13 0.39663(8) 0.7506(3) 0.29697(6) 0.0676(4) Uani d 1 . . S S21 0.11674(6) 0.2175(3) 0.20180(6) 0.0534(3) Uani d 1 . . S S23 -0.05234(7) 0.1036(2) 0.42073(6) 0.0459(3) Uani d 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 C10 0.0289(17) 0.048(3) 0.038(2) 0.0051(19) 0.0057(15) 0.004(2) C11 0.037(2) 0.042(3) 0.048(3) 0.0057(18) 0.0018(18) 0.005(2) C12 0.0351(19) 0.051(3) 0.040(2) 0.0116(19) 0.0090(16) 0.005(2) C13 0.039(2) 0.048(3) 0.067(3) 0.006(2) 0.010(2) 0.016(3) C14 0.037(2) 0.045(3) 0.062(3) 0.005(2) 0.001(2) -0.006(2) C15A 0.040(6) 0.054(8) 0.050(9) 0.012(6) 0.003(6) -0.003(7) C16A 0.052(9) 0.054(11) 0.042(7) 0.014(8) -0.006(5) -0.013(7) C17A 0.044(12) 0.057(10) 0.12(2) -0.020(8) -0.019(12) 0.023(11) C18A 0.032(7) 0.12(3) 0.078(14) 0.014(16) 0.011(8) 0.010(18) C19A 0.048(12) 0.093(15) 0.062(12) 0.023(10) 0.003(8) -0.001(12) C15B 0.052(9) 0.054(6) 0.086(13) 0.018(5) -0.015(7) 0.007(6) C16B 0.045(6) 0.065(9) 0.058(8) 0.006(6) 0.000(5) 0.029(6) C17B 0.032(6) 0.066(10) 0.055(7) -0.003(6) -0.006(5) -0.002(7) C18B 0.020(6) 0.075(7) 0.077(13) 0.004(5) 0.007(6) 0.008(8) C19B 0.045(9) 0.080(12) 0.062(7) 0.040(9) 0.004(6) 0.004(8) C111 0.0284(16) 0.046(2) 0.040(2) 0.003(2) 0.0099(14) 0.003(2) C112 0.037(2) 0.041(3) 0.067(3) -0.0016(19) 0.006(2) 0.003(2) C113 0.044(2) 0.042(3) 0.066(3) 0.012(2) 0.003(2) 0.007(2) C114 0.031(2) 0.048(3) 0.043(2) 0.0032(18) 0.0097(17) -0.0032(19) C115 0.037(2) 0.050(3) 0.081(4) -0.009(2) 0.001(2) 0.000(3) C116 0.043(3) 0.043(3) 0.074(3) 0.003(2) 0.003(2) 0.009(2) C117 0.040(2) 0.078(4) 0.057(3) 0.009(2) 0.000(2) -0.004(3) C131 0.060(3) 0.058(3) 0.046(3) 0.008(2) 0.022(2) 0.002(2) C132 0.045(3) 0.078(4) 0.048(3) -0.007(3) 0.010(2) 0.000(3) C133 0.053(3) 0.072(4) 0.055(3) -0.002(3) 0.016(2) 0.009(3) C134 0.065(3) 0.082(4) 0.037(3) -0.007(3) 0.011(2) 0.002(3) C135 0.069(3) 0.091(5) 0.056(3) -0.021(3) 0.005(3) -0.010(3) C136 0.084(4) 0.062(3) 0.061(3) -0.018(4) 0.024(3) -0.001(3) C137 0.069(4) 0.163(8) 0.056(4) -0.015(4) -0.010(3) 0.023(4) C20 0.0295(18) 0.047(3) 0.041(2) 0.0046(18) 0.0023(15) 0.004(2) C21 0.033(2) 0.042(3) 0.044(2) 0.0028(18) 0.0005(17) -0.007(2) C22 0.0306(17) 0.045(2) 0.041(2) 0.002(2) 0.0037(15) -0.001(2) C23 0.043(2) 0.039(2) 0.046(3) 0.008(2) 0.0041(19) -0.005(2) C24 0.038(2) 0.038(2) 0.052(3) 0.0014(19) -0.0038(19) 0.004(2) C25A 0.074(16) 0.037(7) 0.13(2) 0.006(8) -0.055(15) 0.006(10) C26A 0.050(7) 0.095(18) 0.064(10) -0.022(9) -0.019(6) 0.040(11) C27A 0.045(8) 0.075(11) 0.065(11) -0.012(7) -0.023(7) 0.006(9) C28A 0.025(5) 0.121(18) 0.043(9) -0.004(7) 0.001(5) 0.019(10) C29A 0.050(12) 0.10(2) 0.077(12) 0.036(14) -0.022(8) -0.029(13) C25B 0.034(8) 0.060(10) 0.063(9) 0.007(6) 0.000(6) 0.003(7) C26B 0.034(6) 0.052(9) 0.066(11) 0.005(6) -0.004(6) 0.017(8) C27B 0.057(9) 0.066(10) 0.040(6) 0.013(8) -0.002(5) -0.006(8) C28B 0.041(7) 0.043(6) 0.049(9) -0.007(5) 0.003(6) 0.002(6) C29B 0.032(5) 0.046(8) 0.046(7) 0.002(5) 0.002(5) -0.003(5) C211 0.039(2) 0.054(3) 0.032(2) 0.0008(19) 0.0118(17) -0.002(2) C212 0.046(2) 0.055(3) 0.048(3) -0.009(2) 0.011(2) -0.004(2) C213 0.060(3) 0.049(3) 0.042(3) -0.008(2) 0.010(2) 0.002(2) C214 0.048(3) 0.069(3) 0.033(2) -0.006(2) 0.004(2) -0.002(2) C215 0.058(3) 0.061(3) 0.045(3) -0.020(3) 0.003(2) -0.010(3) C216 0.061(3) 0.044(3) 0.048(3) -0.005(2) 0.010(2) 0.000(2) C217 0.073(4) 0.095(5) 0.057(3) -0.004(4) -0.004(3) 0.013(3) C231 0.044(2) 0.047(3) 0.041(2) 0.000(2) 0.0139(18) 0.0003(19) C232 0.055(3) 0.053(3) 0.088(4) -0.003(2) 0.010(3) -0.016(3) C233 0.060(3) 0.077(4) 0.078(4) -0.021(3) 0.001(3) -0.017(3) C234 0.041(2) 0.073(3) 0.046(2) -0.002(3) 0.0123(18) 0.008(3) C235 0.050(3) 0.060(3) 0.076(4) 0.009(3) 0.005(3) 0.000(3) C236 0.058(3) 0.048(3) 0.060(3) -0.004(2) 0.000(2) -0.007(3) C237 0.047(3) 0.120(6) 0.069(3) -0.013(3) 0.002(2) 0.000(4) Fe1 0.0266(2) 0.0497(4) 0.0450(3) 0.0039(3) 0.0054(2) 0.0044(3) Fe2 0.0320(3) 0.0434(4) 0.0424(3) 0.0017(3) -0.0019(2) 0.0032(3) O11 0.0487(18) 0.062(2) 0.086(3) 0.0138(16) 0.0144(17) 0.038(2) O13 0.0447(19) 0.150(4) 0.084(3) 0.013(2) 0.0219(18) 0.039(3) O21 0.088(3) 0.0756(14) 0.067(2) 0.042(2) 0.017(2) -0.005(2) O23 0.068(2) 0.084(2) 0.0419(16) 0.002(2) 0.0066(14) -0.0105(19) S11 0.0329(5) 0.0667(8) 0.0409(6) 0.0069(5) 0.0075(4) 0.0087(6) S13 0.0647(7) 0.0846(11) 0.0581(7) 0.0277(8) 0.0285(6) 0.0153(8) S21 0.0375(5) 0.0755(8) 0.0490(6) 0.0137(7) 0.0123(4) 0.0022(7) S23 0.0454(6) 0.0521(7) 0.0412(6) 0.0039(5) 0.0088(5) 0.0021(5) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag C11 C10 C14 . . 109.3(4) ? C11 C10 S11 . . 125.4(4) ? C14 C10 S11 . . 125.3(4) ? C11 C10 Fe1 . . 69.3(2) ? C14 C10 Fe1 . . 70.7(2) ? S11 C10 Fe1 . . 124.3(2) ? C10 C11 C12 . . 107.0(4) ? C10 C11 Fe1 . . 69.8(2) ? C12 C11 Fe1 . . 69.4(3) ? C10 C11 H11 . . 126.5 ? C12 C11 H11 . . 126.5 ? Fe1 C11 H11 . . 125.8 ? C13 C12 C11 . . 108.3(4) ? C13 C12 S13 . . 126.4(4) ? C11 C12 S13 . . 125.1(4) ? C13 C12 Fe1 . . 70.7(3) ? C11 C12 Fe1 . . 69.1(2) ? S13 C12 Fe1 . . 123.4(2) ? C12 C13 C14 . . 108.6(4) ? C12 C13 Fe1 . . 68.8(3) ? C14 C13 Fe1 . . 70.0(3) ? C12 C13 H13 . . 125.7 ? C14 C13 H13 . . 125.7 ? Fe1 C13 H13 . . 127.1 ? C13 C14 C10 . . 106.7(4) ? C13 C14 Fe1 . . 69.4(3) ? C10 C14 Fe1 . . 68.4(2) ? C13 C14 H14 . . 126.6 ? C10 C14 H14 . . 126.6 ? Fe1 C14 H14 . . 127.1 ? C16A C15A C19A . . 108.0 ? C16A C15A Fe1 . . 68.3(3) ? C19A C15A Fe1 . . 70.7(2) ? C16A C15A H15A . . 126.0 ? C19A C15A H15A . . 126.0 ? Fe1 C15A H15A . . 126.6 ? C15A C16A C17A . . 108.0 ? C15A C16A Fe1 . . 72.2(3) ? C17A C16A Fe1 . . 68.8(3) ? C15A C16A H16A . . 126.0 ? C17A C16A H16A . . 126.0 ? Fe1 C16A H16A . . 124.6 ? C18A C17A C16A . . 108.0 ? C18A C17A Fe1 . . 71.2(2) ? C16A C17A Fe1 . . 70.9(2) ? C18A C17A H17A . . 126.0 ? C16A C17A H17A . . 126.0 ? Fe1 C17A H17A . . 123.5 ? C17A C18A C19A . . 108.0 ? C17A C18A Fe1 . . 68.5(3) ? C19A C18A Fe1 . . 72.1(3) ? C17A C18A H18A . . 126.0 ? C19A C18A H18A . . 126.0 ? Fe1 C18A H18A . . 124.9 ? C18A C19A C15A . . 108.0 ? C18A C19A Fe1 . . 68.5(3) ? C15A C19A Fe1 . . 70.3(2) ? C18A C19A H19A . . 126.0 ? C15A C19A H19A . . 126.0 ? Fe1 C19A H19A . . 126.8 ? C19B C15B C16B . . 108.0 ? C19B C15B Fe1 . . 70.3(2) ? C16B C15B Fe1 . . 69.4(2) ? C19B C15B H15B . . 126.0 ? C16B C15B H15B . . 126.0 ? Fe1 C15B H15B . . 125.9 ? C15B C16B C17B . . 108.0 ? C15B C16B Fe1 . . 69.2(3) ? C17B C16B Fe1 . . 70.4(3) ? C15B C16B H16B . . 126.0 ? C17B C16B H16B . . 126.0 ? Fe1 C16B H16B . . 125.9 ? C18B C17B C16B . . 108.0 ? C18B C17B Fe1 . . 70.2(2) ? C16B C17B Fe1 . . 68.5(3) ? C18B C17B H17B . . 126.0 ? C16B C17B H17B . . 126.0 ? Fe1 C17B H17B . . 126.9 ? C19B C18B C17B . . 108.0 ? C19B C18B Fe1 . . 69.0(3) ? C17B C18B Fe1 . . 69.1(2) ? C19B C18B H18B . . 126.0 ? C17B C18B H18B . . 126.0 ? Fe1 C18B H18B . . 127.4 ? C15B C19B C18B . . 108.0 ? C15B C19B Fe1 . . 68.5(3) ? C18B C19B Fe1 . . 70.3(3) ? C15B C19B H19B . . 126.0 ? C18B C19B H19B . . 126.0 ? Fe1 C19B H19B . . 126.8 ? C116 C111 C112 . . 120.4(4) ? C116 C111 S11 . . 119.0(4) ? C112 C111 S11 . . 120.5(3) ? C113 C112 C111 . . 119.1(4) ? C113 C112 H112 . . 120.4 ? C111 C112 H112 . . 120.4 ? C112 C113 C114 . . 121.8(5) ? C112 C113 H113 . . 119.1 ? C114 C113 H113 . . 119.1 ? C115 C114 C113 . . 117.2(4) ? C115 C114 C117 . . 121.9(4) ? C113 C114 C117 . . 120.9(4) ? C114 C115 C116 . . 122.0(4) ? C114 C115 H115 . . 119.0 ? C116 C115 H115 . . 119.0 ? C111 C116 C115 . . 119.2(4) ? C111 C116 H116 . . 120.4 ? C115 C116 H116 . . 120.4 ? C114 C117 H11A . . 109.5 ? C114 C117 H11B . . 109.5 ? H11A C117 H11B . . 109.5 ? C114 C117 H11C . . 109.5 ? H11A C117 H11C . . 109.5 ? H11B C117 H11C . . 109.5 ? C132 C131 C136 . . 119.9(5) ? C132 C131 S13 . . 119.9(4) ? C136 C131 S13 . . 120.1(5) ? C131 C132 C133 . . 119.1(5) ? C131 C132 H132 . . 120.5 ? C133 C132 H132 . . 120.5 ? C134 C133 C132 . . 122.2(6) ? C134 C133 H133 . . 118.9 ? C132 C133 H133 . . 118.9 ? C133 C134 C135 . . 116.5(5) ? C133 C134 C137 . . 121.3(6) ? C135 C134 C137 . . 122.1(6) ? C136 C135 C134 . . 122.2(6) ? C136 C135 H135 . . 118.9 ? C134 C135 H135 . . 118.9 ? C135 C136 C131 . . 120.1(6) ? C135 C136 H136 . . 120.0 ? C131 C136 H136 . . 120.0 ? C134 C137 H13A . . 109.5 ? C134 C137 H13B . . 109.5 ? H13A C137 H13B . . 109.5 ? C134 C137 H13C . . 109.5 ? H13A C137 H13C . . 109.5 ? H13B C137 H13C . . 109.5 ? C21 C20 C24 . . 109.2(4) ? C21 C20 S21 . . 123.2(4) ? C24 C20 S21 . . 127.5(3) ? C21 C20 Fe2 . . 69.7(2) ? C24 C20 Fe2 . . 70.3(2) ? S21 C20 Fe2 . . 123.2(2) ? C20 C21 C22 . . 106.5(4) ? C20 C21 Fe2 . . 69.1(2) ? C22 C21 Fe2 . . 69.3(2) ? C20 C21 H21 . . 126.7 ? C22 C21 H21 . . 126.7 ? Fe2 C21 H21 . . 126.4 ? C21 C22 C23 . . 109.0(4) ? C21 C22 S23 . . 123.8(4) ? C23 C22 S23 . . 127.0(4) ? C21 C22 Fe2 . . 69.4(2) ? C23 C22 Fe2 . . 70.2(2) ? S23 C22 Fe2 . . 123.2(2) ? C24 C23 C22 . . 107.5(4) ? C24 C23 Fe2 . . 69.6(2) ? C22 C23 Fe2 . . 68.6(2) ? C24 C23 H23 . . 126.2 ? C22 C23 H23 . . 126.2 ? Fe2 C23 H23 . . 127.1 ? C23 C24 C20 . . 107.7(4) ? C23 C24 Fe2 . . 69.8(3) ? C20 C24 Fe2 . . 68.5(2) ? C23 C24 H24 . . 126.2 ? C20 C24 H24 . . 126.2 ? Fe2 C24 H24 . . 127.1 ? C29A C25A C26A . . 108.0 ? C29A C25A Fe2 . . 69.4(3) ? C26A C25A Fe2 . . 70.3(2) ? C29A C25A H25A . . 126.0 ? C26A C25A H25A . . 126.0 ? Fe2 C25A H25A . . 125.8 ? C27A C26A C25A . . 108.0 ? C27A C26A Fe2 . . 70.0(2) ? C25A C26A Fe2 . . 69.3(2) ? C27A C26A H26A . . 126.0 ? C25A C26A H26A . . 126.0 ? Fe2 C26A H26A . . 126.3 ? C26A C27A C28A . . 108.0 ? C26A C27A Fe2 . . 69.8(2) ? C28A C27A Fe2 . . 69.4(3) ? C26A C27A H27A . . 126.0 ? C28A C27A H27A . . 126.0 ? Fe2 C27A H27A . . 126.4 ? C29A C28A C27A . . 108.0 ? C29A C28A Fe2 . . 69.3(2) ? C27A C28A Fe2 . . 70.3(2) ? C29A C28A H28A . . 126.0 ? C27A C28A H28A . . 126.0 ? Fe2 C28A H28A . . 125.9 ? C28A C29A C25A . . 108.0 ? C28A C29A Fe2 . . 70.1(2) ? C25A C29A Fe2 . . 70.0(3) ? C28A C29A H29A . . 126.0 ? C25A C29A H29A . . 126.0 ? Fe2 C29A H29A . . 125.5 ? C26B C25B C29B . . 108.0 ? C26B C25B Fe2 . . 68.4(2) ? C29B C25B Fe2 . . 70.7(3) ? C26B C25B H25B . . 126.0 ? C29B C25B H25B . . 126.0 ? Fe2 C25B H25B . . 126.5 ? C27B C26B C25B . . 108.0 ? C27B C26B Fe2 . . 69.2(2) ? C25B C26B Fe2 . . 71.5(2) ? C27B C26B H26B . . 126.0 ? C25B C26B H26B . . 126.0 ? Fe2 C26B H26B . . 124.9 ? C28B C27B C26B . . 108.0 ? C28B C27B Fe2 . . 71.0(3) ? C26B C27B Fe2 . . 70.1(2) ? C28B C27B H27B . . 126.0 ? C26B C27B H27B . . 126.0 ? Fe2 C27B H27B . . 124.4 ? C27B C28B C29B . . 108.0 ? C27B C28B Fe2 . . 68.5(2) ? C29B C28B Fe2 . . 71.3(2) ? C27B C28B H28B . . 126.0 ? C29B C28B H28B . . 126.0 ? Fe2 C28B H28B . . 125.7 ? C28B C29B C25B . . 108.0 ? C28B C29B Fe2 . . 68.8(2) ? C25B C29B Fe2 . . 69.7(2) ? C28B C29B H29B . . 126.0 ? C25B C29B H29B . . 126.0 ? Fe2 C29B H29B . . 127.0 ? C212 C211 C216 . . 120.2(4) ? C212 C211 S21 . . 119.8(4) ? C216 C211 S21 . . 119.9(4) ? C211 C212 C213 . . 119.2(5) ? C211 C212 H212 . . 120.4 ? C213 C212 H212 . . 120.4 ? C214 C213 C212 . . 121.4(5) ? C214 C213 H213 . . 119.3 ? C212 C213 H213 . . 119.3 ? C215 C214 C213 . . 118.4(5) ? C215 C214 C217 . . 120.1(5) ? C213 C214 C217 . . 121.5(5) ? C214 C215 C216 . . 121.8(5) ? C214 C215 H215 . . 119.1 ? C216 C215 H215 . . 119.1 ? C215 C216 C211 . . 119.0(5) ? C215 C216 H216 . . 120.5 ? C211 C216 H216 . . 120.5 ? C214 C217 H21A . . 109.5 ? C214 C217 H21B . . 109.5 ? H21A C217 H21B . . 109.5 ? C214 C217 H21C . . 109.5 ? H21A C217 H21C . . 109.5 ? H21B C217 H21C . . 109.5 ? C236 C231 C232 . . 119.8(5) ? C236 C231 S23 . . 121.4(4) ? C232 C231 S23 . . 118.8(4) ? C231 C232 C233 . . 118.8(5) ? C231 C232 H232 . . 120.6 ? C233 C232 H232 . . 120.6 ? C234 C233 C232 . . 121.9(5) ? C234 C233 H233 . . 119.1 ? C232 C233 H233 . . 119.1 ? C233 C234 C235 . . 117.9(5) ? C233 C234 C237 . . 121.4(6) ? C235 C234 C237 . . 120.7(6) ? C234 C235 C236 . . 121.2(5) ? C234 C235 H235 . . 119.4 ? C236 C235 H235 . . 119.4 ? C231 C236 C235 . . 120.4(5) ? C231 C236 H236 . . 119.8 ? C235 C236 H236 . . 119.8 ? C234 C237 H23A . . 109.5 ? C234 C237 H23B . . 109.5 ? H23A C237 H23B . . 109.5 ? C234 C237 H23C . . 109.5 ? H23A C237 H23C . . 109.5 ? H23B C237 H23C . . 109.5 ? C17A Fe1 C11 . . 176.2(3) ? C11 Fe1 C15B . . 108.8(2) ? C17A Fe1 C16A . . 40.31(13) ? C11 Fe1 C16A . . 135.9(3) ? C17A Fe1 C12 . . 142.3(3) ? C11 Fe1 C12 . . 41.50(17) ? C15B Fe1 C12 . . 124.5(3) ? C16A Fe1 C12 . . 175.6(4) ? C17A Fe1 C18A . . 40.21(13) ? C11 Fe1 C18A . . 141.1(4) ? C16A Fe1 C18A . . 67.12(19) ? C12 Fe1 C18A . . 112.8(2) ? C17A Fe1 C10 . . 137.8(4) ? C11 Fe1 C10 . . 40.86(17) ? C15B Fe1 C10 . . 124.1(3) ? C16A Fe1 C10 . . 111.4(2) ? C12 Fe1 C10 . . 68.74(16) ? C18A Fe1 C10 . . 178.0(4) ? C11 Fe1 C16B . . 124.1(3) ? C15B Fe1 C16B . . 41.41(14) ? C12 Fe1 C16B . . 161.6(4) ? C10 Fe1 C16B . . 107.7(2) ? C11 Fe1 C19B . . 124.0(3) ? C15B Fe1 C19B . . 41.16(15) ? C12 Fe1 C19B . . 107.7(2) ? C10 Fe1 C19B . . 160.7(4) ? C16B Fe1 C19B . . 69.3(2) ? C17A Fe1 C13 . . 114.3(3) ? C11 Fe1 C13 . . 69.05(19) ? C15B Fe1 C13 . . 159.7(4) ? C16A Fe1 C13 . . 143.8(4) ? C12 Fe1 C13 . . 40.5(2) ? C18A Fe1 C13 . . 111.9(3) ? C10 Fe1 C13 . . 68.36(17) ? C16B Fe1 C13 . . 156.6(4) ? C19B Fe1 C13 . . 122.1(3) ? C11 Fe1 C17B . . 159.6(4) ? C15B Fe1 C17B . . 69.27(19) ? C12 Fe1 C17B . . 156.3(4) ? C10 Fe1 C17B . . 122.3(3) ? C16B Fe1 C17B . . 41.10(13) ? C19B Fe1 C17B . . 68.80(19) ? C13 Fe1 C17B . . 120.0(3) ? C17A Fe1 C14 . . 111.9(3) ? C11 Fe1 C14 . . 69.27(19) ? C15B Fe1 C14 . . 159.1(4) ? C16A Fe1 C14 . . 114.5(3) ? C12 Fe1 C14 . . 68.70(18) ? C18A Fe1 C14 . . 138.0(4) ? C10 Fe1 C14 . . 40.96(19) ? C16B Fe1 C14 . . 121.3(3) ? C19B Fe1 C14 . . 157.2(4) ? C13 Fe1 C14 . . 40.59(19) ? C17B Fe1 C14 . . 105.0(2) ? C29A Fe2 C28A . . 40.56(15) ? C29A Fe2 C25A . . 40.59(14) ? C28A Fe2 C25A . . 68.1(2) ? C29A Fe2 C20 . . 111.4(2) ? C28A Fe2 C20 . . 120.2(3) ? C25A Fe2 C20 . . 131.4(3) ? C29A Fe2 C22 . . 151.9(3) ? C28A Fe2 C22 . . 164.4(4) ? C25A Fe2 C22 . . 116.8(3) ? C20 Fe2 C22 . . 68.84(16) ? C20 Fe2 C27B . . 170.2(4) ? C22 Fe2 C27B . . 117.6(3) ? C29A Fe2 C27A . . 68.0(2) ? C28A Fe2 C27A . . 40.33(13) ? C25A Fe2 C27A . . 67.86(18) ? C20 Fe2 C27A . . 151.7(4) ? C22 Fe2 C27A . . 125.8(3) ? C29A Fe2 C21 . . 119.8(3) ? C28A Fe2 C21 . . 153.7(4) ? C25A Fe2 C21 . . 108.7(2) ? C20 Fe2 C21 . . 41.23(17) ? C22 Fe2 C21 . . 41.26(16) ? C27B Fe2 C21 . . 148.4(4) ? C27A Fe2 C21 . . 164.8(4) ? C29A Fe2 C26A . . 68.02(19) ? C28A Fe2 C26A . . 67.84(19) ? C25A Fe2 C26A . . 40.38(13) ? C20 Fe2 C26A . . 167.9(4) ? C22 Fe2 C26A . . 105.7(3) ? C27A Fe2 C26A . . 40.22(12) ? C21 Fe2 C26A . . 127.7(3) ? C20 Fe2 C26B . . 146.5(4) ? C22 Fe2 C26B . . 110.2(3) ? C27B Fe2 C26B . . 40.70(12) ? C21 Fe2 C26B . . 115.2(3) ? C29A Fe2 C24 . . 131.0(3) ? C28A Fe2 C24 . . 108.7(2) ? C25A Fe2 C24 . . 170.0(4) ? C20 Fe2 C24 . . 41.18(18) ? C22 Fe2 C24 . . 68.87(18) ? C27B Fe2 C24 . . 132.1(4) ? C27A Fe2 C24 . . 116.3(3) ? C21 Fe2 C24 . . 69.70(18) ? C26A Fe2 C24 . . 148.3(4) ? C26B Fe2 C24 . . 172.1(4) ? C29A Fe2 C23 . . 166.8(3) ? C28A Fe2 C23 . . 127.1(3) ? C25A Fe2 C23 . . 148.9(4) ? C20 Fe2 C23 . . 68.91(17) ? C22 Fe2 C23 . . 41.19(19) ? C27B Fe2 C23 . . 110.5(3) ? C27A Fe2 C23 . . 105.2(3) ? C21 Fe2 C23 . . 69.75(18) ? C26A Fe2 C23 . . 114.6(4) ? C26B Fe2 C23 . . 133.7(4) ? C24 Fe2 C23 . . 40.63(17) ? O11 S11 C10 . . 107.1(2) ? O11 S11 C111 . . 105.5(2) ? C10 S11 C111 . . 96.34(18) ? O13 S13 C12 . . 107.4(3) ? O13 S13 C131 . . 106.8(3) ? C12 S13 C131 . . 96.4(2) ? O21 S21 C20 . . 106.1(2) ? O21 S21 C211 . . 107.3(2) ? C20 S21 C211 . . 97.51(18) ? O23 S23 C22 . . 107.1(2) ? O23 S23 C231 . . 106.6(2) ? C22 S23 C231 . . 96.41(19) ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag C10 C11 . 1.409(6) ? C10 C14 . 1.426(7) ? C10 S11 . 1.783(4) ? C10 Fe1 . 2.022(4) ? C11 C12 . 1.430(6) ? C11 Fe1 . 2.015(4) ? C11 H11 . 0.9300 ? C12 C13 . 1.409(7) ? C12 S13 . 1.764(4) ? C12 Fe1 . 2.020(4) ? C13 C14 . 1.421(7) ? C13 Fe1 . 2.045(5) ? C13 H13 . 0.9300 ? C14 Fe1 . 2.053(5) ? C14 H14 . 0.9300 ? C15A C16A . 1.382(4) ? C15A C19A . 1.382(4) ? C15A Fe1 . 2.068(7) ? C15A H15A . 0.9300 ? C16A C17A . 1.382(4) ? C16A Fe1 . 2.018(5) ? C16A H16A . 0.9300 ? C17A C18A . 1.382(4) ? C17A Fe1 . 1.992(6) ? C17A H17A . 0.9300 ? C18A C19A . 1.382(4) ? C18A Fe1 . 2.026(5) ? C18A H18A . 0.9300 ? C19A Fe1 . 2.073(7) ? C19A H19A . 0.9300 ? C15B C19B . 1.430(4) ? C15B C16B . 1.430(4) ? C15B Fe1 . 2.022(7) ? C15B H15B . 0.9300 ? C16B C17B . 1.430(4) ? C16B Fe1 . 2.024(6) ? C16B H16B . 0.9300 ? C17B C18B . 1.430(4) ? C17B Fe1 . 2.050(7) ? C17B H17B . 0.9300 ? C18B C19B . 1.430(4) ? C18B Fe1 . 2.064(6) ? C18B H18B . 0.9300 ? C19B Fe1 . 2.046(6) ? C19B H19B . 0.9300 ? C111 C116 . 1.363(6) ? C111 C112 . 1.386(7) ? C111 S11 . 1.803(4) ? C112 C113 . 1.380(6) ? C112 H112 . 0.9300 ? C113 C114 . 1.391(7) ? C113 H113 . 0.9300 ? C114 C115 . 1.373(7) ? C114 C117 . 1.494(6) ? C115 C116 . 1.396(6) ? C115 H115 . 0.9300 ? C116 H116 . 0.9300 ? C117 H11A . 0.9600 ? C117 H11B . 0.9600 ? C117 H11C . 0.9600 ? C131 C132 . 1.368(8) ? C131 C136 . 1.375(7) ? C131 S13 . 1.797(6) ? C132 C133 . 1.392(7) ? C132 H132 . 0.9300 ? C133 C134 . 1.382(7) ? C133 H133 . 0.9300 ? C134 C135 . 1.384(9) ? C134 C137 . 1.498(8) ? C135 C136 . 1.366(8) ? C135 H135 . 0.9300 ? C136 H136 . 0.9300 ? C137 H13A . 0.9600 ? C137 H13B . 0.9600 ? C137 H13C . 0.9600 ? C20 C21 . 1.426(6) ? C20 C24 . 1.430(6) ? C20 S21 . 1.775(4) ? C20 Fe2 . 2.021(4) ? C21 C22 . 1.429(6) ? C21 Fe2 . 2.029(4) ? C21 H21 . 0.9300 ? C22 C23 . 1.434(7) ? C22 S23 . 1.774(4) ? C22 Fe2 . 2.027(4) ? C23 C24 . 1.421(6) ? C23 Fe2 . 2.048(4) ? C23 H23 . 0.9300 ? C24 Fe2 . 2.045(5) ? C24 H24 . 0.9300 ? C25A C29A . 1.396(4) ? C25A C26A . 1.396(4) ? C25A Fe2 . 2.015(6) ? C25A H25A . 0.9300 ? C26A C27A . 1.396(4) ? C26A Fe2 . 2.029(6) ? C26A H26A . 0.9300 ? C27A C28A . 1.396(4) ? C27A Fe2 . 2.031(6) ? C27A H27A . 0.9300 ? C28A C29A . 1.396(4) ? C28A Fe2 . 2.018(5) ? C28A H28A . 0.9300 ? C29A Fe2 . 2.008(5) ? C29A H29A . 0.9300 ? C25B C26B . 1.415(4) ? C25B C29B . 1.415(4) ? C25B Fe2 . 2.082(6) ? C25B H25B . 0.9300 ? C26B C27B . 1.415(4) ? C26B Fe2 . 2.041(6) ? C26B H26B . 0.9300 ? C27B C28B . 1.415(4) ? C27B Fe2 . 2.028(5) ? C27B H27B . 0.9300 ? C28B C29B . 1.415(4) ? C28B Fe2 . 2.061(5) ? C28B H28B . 0.9300 ? C29B Fe2 . 2.094(6) ? C29B H29B . 0.9300 ? C211 C212 . 1.375(7) ? C211 C216 . 1.392(6) ? C211 S21 . 1.794(5) ? C212 C213 . 1.385(7) ? C212 H212 . 0.9300 ? C213 C214 . 1.375(7) ? C213 H213 . 0.9300 ? C214 C215 . 1.372(8) ? C214 C217 . 1.510(7) ? C215 C216 . 1.376(7) ? C215 H215 . 0.9300 ? C216 H216 . 0.9300 ? C217 H21A . 0.9600 ? C217 H21B . 0.9600 ? C217 H21C . 0.9600 ? C231 C236 . 1.360(7) ? C231 C232 . 1.377(7) ? C231 S23 . 1.799(5) ? C232 C233 . 1.399(8) ? C232 H232 . 0.9300 ? C233 C234 . 1.367(9) ? C233 H233 . 0.9300 ? C234 C235 . 1.369(8) ? C234 C237 . 1.511(6) ? C235 C236 . 1.387(7) ? C235 H235 . 0.9300 ? C236 H236 . 0.9300 ? C237 H23A . 0.9600 ? C237 H23B . 0.9600 ? C237 H23C . 0.9600 ? O11 S11 . 1.488(4) ? O13 S13 . 1.477(4) ? O21 S21 . 1.477(4) ? O23 S23 . 1.490(3) ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag C14 C10 C11 C12 . . . . 0.2(5) ? S11 C10 C11 C12 . . . . 177.8(3) ? Fe1 C10 C11 C12 . . . . 59.8(3) ? C14 C10 C11 Fe1 . . . . -59.5(3) ? S11 C10 C11 Fe1 . . . . 118.0(3) ? C10 C11 C12 C13 . . . . 0.0(5) ? Fe1 C11 C12 C13 . . . . 60.0(3) ? C10 C11 C12 S13 . . . . -176.9(3) ? Fe1 C11 C12 S13 . . . . -116.9(3) ? C10 C11 C12 Fe1 . . . . -60.0(3) ? C11 C12 C13 C14 . . . . -0.2(5) ? S13 C12 C13 C14 . . . . 176.6(3) ? Fe1 C12 C13 C14 . . . . 58.8(3) ? C11 C12 C13 Fe1 . . . . -59.0(3) ? S13 C12 C13 Fe1 . . . . 117.8(3) ? C12 C13 C14 C10 . . . . 0.3(5) ? Fe1 C13 C14 C10 . . . . 58.4(3) ? C12 C13 C14 Fe1 . . . . -58.1(3) ? C11 C10 C14 C13 . . . . -0.3(5) ? S11 C10 C14 C13 . . . . -177.9(3) ? Fe1 C10 C14 C13 . . . . -59.0(3) ? C11 C10 C14 Fe1 . . . . 58.7(3) ? S11 C10 C14 Fe1 . . . . -118.9(3) ? C19A C15A C16A C17A . . . . 0.0 ? Fe1 C15A C16A C17A . . . . 59.8(2) ? C19A C15A C16A Fe1 . . . . -59.8(2) ? C15A C16A C17A C18A . . . . 0.0 ? Fe1 C16A C17A C18A . . . . 61.9(3) ? C15A C16A C17A Fe1 . . . . -61.9(3) ? C16A C17A C18A C19A . . . . 0.0 ? Fe1 C17A C18A C19A . . . . 61.7(3) ? C16A C17A C18A Fe1 . . . . -61.7(3) ? C17A C18A C19A C15A . . . . 0.0 ? Fe1 C18A C19A C15A . . . . 59.4(2) ? C17A C18A C19A Fe1 . . . . -59.4(2) ? C16A C15A C19A C18A . . . . 0.0 ? Fe1 C15A C19A C18A . . . . -58.3(3) ? C16A C15A C19A Fe1 . . . . 58.3(3) ? C19B C15B C16B C17B . . . . 0.0 ? Fe1 C15B C16B C17B . . . . 60.0(3) ? C19B C15B C16B Fe1 . . . . -60.0(3) ? C15B C16B C17B C18B . . . . 0.0 ? Fe1 C16B C17B C18B . . . . 59.2(2) ? C15B C16B C17B Fe1 . . . . -59.2(2) ? C16B C17B C18B C19B . . . . 0.0 ? Fe1 C17B C18B C19B . . . . 58.2(3) ? C16B C17B C18B Fe1 . . . . -58.2(3) ? C16B C15B C19B C18B . . . . 0.0 ? Fe1 C15B C19B C18B . . . . -59.4(3) ? C16B C15B C19B Fe1 . . . . 59.4(3) ? C17B C18B C19B C15B . . . . 0.0 ? Fe1 C18B C19B C15B . . . . 58.3(2) ? C17B C18B C19B Fe1 . . . . -58.3(2) ? C116 C111 C112 C113 . . . . 4.4(7) ? S11 C111 C112 C113 . . . . -178.9(4) ? C111 C112 C113 C114 . . . . -1.1(8) ? C112 C113 C114 C115 . . . . -2.5(7) ? C112 C113 C114 C117 . . . . 178.1(5) ? C113 C114 C115 C116 . . . . 2.9(8) ? C117 C114 C115 C116 . . . . -177.7(5) ? C112 C111 C116 C115 . . . . -4.1(7) ? S11 C111 C116 C115 . . . . 179.2(4) ? C114 C115 C116 C111 . . . . 0.3(8) ? C136 C131 C132 C133 . . . . -2.2(7) ? S13 C131 C132 C133 . . . . -179.6(4) ? C131 C132 C133 C134 . . . . 1.0(8) ? C132 C133 C134 C135 . . . . 0.7(8) ? C132 C133 C134 C137 . . . . -179.1(5) ? C133 C134 C135 C136 . . . . -1.4(8) ? C137 C134 C135 C136 . . . . 178.5(6) ? C134 C135 C136 C131 . . . . 0.2(9) ? C132 C131 C136 C135 . . . . 1.6(8) ? S13 C131 C136 C135 . . . . 179.0(4) ? C24 C20 C21 C22 . . . . 0.1(5) ? S21 C20 C21 C22 . . . . 176.5(3) ? Fe2 C20 C21 C22 . . . . 59.5(3) ? C24 C20 C21 Fe2 . . . . -59.4(3) ? S21 C20 C21 Fe2 . . . . 117.1(3) ? C20 C21 C22 C23 . . . . -0.1(5) ? Fe2 C21 C22 C23 . . . . 59.2(3) ? C20 C21 C22 S23 . . . . -176.2(3) ? Fe2 C21 C22 S23 . . . . -116.9(3) ? C20 C21 C22 Fe2 . . . . -59.3(3) ? C21 C22 C23 C24 . . . . 0.2(5) ? S23 C22 C23 C24 . . . . 176.0(3) ? Fe2 C22 C23 C24 . . . . 58.9(3) ? C21 C22 C23 Fe2 . . . . -58.7(3) ? S23 C22 C23 Fe2 . . . . 117.2(3) ? C22 C23 C24 C20 . . . . -0.1(5) ? Fe2 C23 C24 C20 . . . . 58.2(3) ? C22 C23 C24 Fe2 . . . . -58.3(3) ? C21 C20 C24 C23 . . . . 0.0(5) ? S21 C20 C24 C23 . . . . -176.2(3) ? Fe2 C20 C24 C23 . . . . -59.0(3) ? C21 C20 C24 Fe2 . . . . 59.0(3) ? S21 C20 C24 Fe2 . . . . -117.3(3) ? C29A C25A C26A C27A . . . . 0.0 ? Fe2 C25A C26A C27A . . . . -59.5(3) ? C29A C25A C26A Fe2 . . . . 59.5(3) ? C25A C26A C27A C28A . . . . 0.0 ? Fe2 C26A C27A C28A . . . . -59.0(3) ? C25A C26A C27A Fe2 . . . . 59.0(3) ? C26A C27A C28A C29A . . . . 0.0 ? Fe2 C27A C28A C29A . . . . -59.3(2) ? C26A C27A C28A Fe2 . . . . 59.3(2) ? C27A C28A C29A C25A . . . . 0.0 ? Fe2 C28A C29A C25A . . . . -59.9(2) ? C27A C28A C29A Fe2 . . . . 59.9(2) ? C26A C25A C29A C28A . . . . 0.0 ? Fe2 C25A C29A C28A . . . . 60.0(2) ? C26A C25A C29A Fe2 . . . . -60.0(2) ? C29B C25B C26B C27B . . . . 0.0 ? Fe2 C25B C26B C27B . . . . -59.8(2) ? C29B C25B C26B Fe2 . . . . 59.8(2) ? C25B C26B C27B C28B . . . . 0.0 ? Fe2 C26B C27B C28B . . . . -61.2(3) ? C25B C26B C27B Fe2 . . . . 61.2(3) ? C26B C27B C28B C29B . . . . 0.0 ? Fe2 C27B C28B C29B . . . . -60.7(2) ? C26B C27B C28B Fe2 . . . . 60.7(2) ? C27B C28B C29B C25B . . . . 0.0 ? Fe2 C28B C29B C25B . . . . -58.9(2) ? C27B C28B C29B Fe2 . . . . 58.9(2) ? C26B C25B C29B C28B . . . . 0.0 ? Fe2 C25B C29B C28B . . . . 58.4(2) ? C26B C25B C29B Fe2 . . . . -58.4(2) ? C216 C211 C212 C213 . . . . 0.0(7) ? S21 C211 C212 C213 . . . . -178.9(3) ? C211 C212 C213 C214 . . . . 1.1(7) ? C212 C213 C214 C215 . . . . -1.9(7) ? C212 C213 C214 C217 . . . . 178.8(5) ? C213 C214 C215 C216 . . . . 1.5(7) ? C217 C214 C215 C216 . . . . -179.1(5) ? C214 C215 C216 C211 . . . . -0.5(7) ? C212 C211 C216 C215 . . . . -0.3(7) ? S21 C211 C216 C215 . . . . 178.6(3) ? C236 C231 C232 C233 . . . . 1.2(8) ? S23 C231 C232 C233 . . . . -179.4(4) ? C231 C232 C233 C234 . . . . -0.8(9) ? C232 C233 C234 C235 . . . . 0.4(8) ? C232 C233 C234 C237 . . . . 179.4(5) ? C233 C234 C235 C236 . . . . -0.6(8) ? C237 C234 C235 C236 . . . . -179.5(5) ? C232 C231 C236 C235 . . . . -1.3(8) ? S23 C231 C236 C235 . . . . 179.3(4) ? C234 C235 C236 C231 . . . . 1.0(8) ? C11 C10 S11 O11 . . . . -20.2(4) ? C14 C10 S11 O11 . . . . 157.0(4) ? Fe1 C10 S11 O11 . . . . 67.5(3) ? C11 C10 S11 C111 . . . . 88.2(4) ? C14 C10 S11 C111 . . . . -94.6(4) ? Fe1 C10 S11 C111 . . . . 175.9(3) ? C116 C111 S11 O11 . . . . -14.2(4) ? C112 C111 S11 O11 . . . . 169.0(4) ? C116 C111 S11 C10 . . . . -123.9(4) ? C112 C111 S11 C10 . . . . 59.3(4) ? C13 C12 S13 O13 . . . . -28.1(5) ? C11 C12 S13 O13 . . . . 148.2(4) ? Fe1 C12 S13 O13 . . . . 61.6(4) ? C13 C12 S13 C131 . . . . 81.8(4) ? C11 C12 S13 C131 . . . . -101.9(4) ? Fe1 C12 S13 C131 . . . . 171.5(3) ? C132 C131 S13 O13 . . . . 12.6(5) ? C136 C131 S13 O13 . . . . -164.8(4) ? C132 C131 S13 C12 . . . . -97.8(4) ? C136 C131 S13 C12 . . . . 84.8(4) ? C21 C20 S21 O21 . . . . -13.9(4) ? C24 C20 S21 O21 . . . . 161.8(4) ? Fe2 C20 S21 O21 . . . . 72.2(3) ? C21 C20 S21 C211 . . . . 96.5(4) ? C24 C20 S21 C211 . . . . -87.7(4) ? Fe2 C20 S21 C211 . . . . -177.4(3) ? C212 C211 S21 O21 . . . . -154.4(4) ? C216 C211 S21 O21 . . . . 26.8(4) ? C212 C211 S21 C20 . . . . 96.1(4) ? C216 C211 S21 C20 . . . . -82.7(4) ? C21 C22 S23 O23 . . . . 160.2(3) ? C23 C22 S23 O23 . . . . -15.1(4) ? Fe2 C22 S23 O23 . . . . 74.1(3) ? C21 C22 S23 C231 . . . . -90.2(4) ? C23 C22 S23 C231 . . . . 94.5(4) ? Fe2 C22 S23 C231 . . . . -176.3(3) ? C236 C231 S23 O23 . . . . 32.5(5) ? C232 C231 S23 O23 . . . . -146.9(4) ? C236 C231 S23 C22 . . . . -77.6(4) ? C232 C231 S23 C22 . . . . 103.0(4) ?