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Information card for entry 4308315
Preview
| Coordinates | 4308315.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C18 H48 Al6 N6 |
|---|---|
| Calculated formula | C18 H48 Al6 N6 |
| Title of publication | Preparation and Characterization of Lithium Imidoalanate Complexes Li2[(RN)4(AlH2)6] (R = Me or tBu): First Examples of Aluminum-Rich Imidoalanes with an Adamantoid Structure |
| Authors of publication | Christina Y. Tang; Andrew R. Cowley; Anthony J. Downs; Simon Parsons |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2007 |
| Journal volume | 46 |
| Pages of publication | 5439 - 5446 |
| a | 10.5708 ± 0.0002 Å |
| b | 16.547 ± 0.0004 Å |
| c | 17.0406 ± 0.0004 Å |
| α | 92.1463 ± 0.0009° |
| β | 93.8153 ± 0.0009° |
| γ | 91.387 ± 0.0011° |
| Cell volume | 2970.9 ± 0.11 Å3 |
| Cell temperature | 150 K |
| Ambient diffraction temperature | 150 K |
| Sample thermal history | The material was crystallised at ambient temperature. A suitable crystal was cooled rapidly to 150K for single-crystal X-ray diffraction analysis. |
| Number of distinct elements | 4 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.1078 |
| Residual factor for significantly intense reflections | 0.0405 |
| Weighted residual factors for all reflections | 0.097 |
| Weighted residual factors for significantly intense reflections | 0.0449 |
| Weighted residual factors for all reflections included in the refinement | 0.0449 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.0872 |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179121 (current) | 2016-03-23 | cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/83. |
4308315.cif |
| 120081 | 2014-07-12 | Adding DOIs to range 4/30 structures. | 4308315.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4308315.cif |
| 5312 | 2011-01-03 | cif/ Adding files, updated with the 'cif_fix_enum' program and the cif_core.dic dictionary. The enumerator values were fixed, mostly incorrect case, but also some values that had extra underscores, dashes or spaces. Unfortunately, 22 had non-ASCII characters with the 8-th bit set, and these got incorrectly interpreted as latin1 characters and converted to their UTF8 equivalents by Perl. To fix the structures, however, they need to be redeposited from the original files with the new CIFParser/cif_filter version. |
4308315.cif |
| 1194 | 2010-06-06 | cif/4/ Adding data from Inorg-Chem-2007_01-13/ processing directory. |
4308315.cif |
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