Crystallography Open Database

Information card for entry 7042742

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Coordinates	7042742.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C49 H90 Cl2 Cu2 N6 Si6
Calculated formula	C49 H90 Cl2 Cu2 N6 Si6
SMILES	[Cu]1([Cl][Cu]([Cl]1)[Si]1([N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si]1([N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)N([Si](C)(C)C)[Si](C)(C)C.c1cc(ccc1)C
Title of publication	Strikingly diverse reactivity of structurally identical silylene and stannylene
Authors of publication	Parvin, Nasrina; Dasgupta, Rajarshi; Pal, Shiv; Sen, Sakya Singha; Khan, Shabana
Journal of publication	Dalton Transactions
Year of publication	2017
Journal volume	46
Journal issue	20
Pages of publication	6528 - 6532
a	11.0995 ± 0.0016 Å
b	16.235 ± 0.002 Å
c	17.997 ± 0.003 Å
α	84.77 ± 0.004°
β	72.241 ± 0.004°
γ	74.247 ± 0.004°
Cell volume	2972.4 ± 0.8 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.1263
Residual factor for significantly intense reflections	0.0543
Weighted residual factors for significantly intense reflections	0.0857
Weighted residual factors for all reflections included in the refinement	0.0996
Goodness-of-fit parameter for all reflections included in the refinement	1.171
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
297324 (current)	2025-01-15	Updated bibliographic information in entries 7042742-7042746.	7042742.cif
195647	2017-04-21	cif/ Adding structures of 7042742, 7042743, 7042744, 7042745, 7042746 via cif-deposit CGI script.	7042742.cif