#------------------------------------------------------------------------------ #$Date: 2025-01-15 11:55:26 +0200 (Wed, 15 Jan 2025) $ #$Revision: 297324 $ #$URL: file:///home/coder/svn-repositories/cod/cif/7/04/27/7042744.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_7042744 loop_ _publ_author_name 'Parvin, Nasrina' 'Dasgupta, Rajarshi' 'Pal, Shiv' 'Sen, Sakya Singha' 'Khan, Shabana' _publ_section_title ; Strikingly diverse reactivity of structurally identical silylene and stannylene ; _journal_coden_ASTM DTARAF _journal_issue 20 _journal_name_full 'Dalton Transactions' _journal_page_first 6528 _journal_page_last 6532 _journal_paper_doi 10.1039/C7DT01055A _journal_volume 46 _journal_year 2017 _chemical_formula_moiety 'C15 H23 Br N2 Sn' _chemical_formula_sum 'C15 H23 Br N2 Sn' _chemical_formula_weight 429.95 _chemical_properties_physical ', Air-sensitive,Moisture-sensitive,Oxygen-sensitive' _space_group_crystal_system triclinic _space_group_IT_number 2 _space_group_name_Hall '-P 1' _space_group_name_H-M_alt 'P -1' _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _atom_sites_solution_hydrogens geom _audit_creation_method SHELXL-2014/7 _audit_update_record ; 2017-03-03 deposited with the CCDC. 2017-04-20 downloaded from the CCDC. ; _cell_angle_alpha 86.414(9) _cell_angle_beta 84.020(8) _cell_angle_gamma 85.949(8) _cell_formula_units_Z 2 _cell_length_a 6.2709(19) _cell_length_b 10.323(3) _cell_length_c 13.767(5) _cell_measurement_reflns_used 5722 _cell_measurement_temperature 150(2) _cell_measurement_theta_max 27.66 _cell_measurement_theta_min 2.41 _cell_volume 882.8(5) _computing_cell_refinement 'Bruker SAINT' _computing_data_collection 'Bruker APEX2' _computing_data_reduction 'Bruker SAINT' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _computing_structure_refinement 'SHELXL-2014 (Sheldrick 2014)' _computing_structure_solution 'SHELXS-97 (Sheldrick 2008)' _diffrn_ambient_temperature 150(2) _diffrn_measured_fraction_theta_full 0.999 _diffrn_measured_fraction_theta_max 0.999 _diffrn_measurement_device_type 'Bruker APEX-II CCD' _diffrn_measurement_method '\f and \w scans' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.1081 _diffrn_reflns_av_unetI/netI 0.0839 _diffrn_reflns_Laue_measured_fraction_full 0.999 _diffrn_reflns_Laue_measured_fraction_max 0.999 _diffrn_reflns_limit_h_max 7 _diffrn_reflns_limit_h_min -7 _diffrn_reflns_limit_k_max 12 _diffrn_reflns_limit_k_min -12 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_number 15506 _diffrn_reflns_point_group_measured_fraction_full 0.999 _diffrn_reflns_point_group_measured_fraction_max 0.999 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 25.246 _diffrn_reflns_theta_min 2.412 _exptl_absorpt_coefficient_mu 3.701 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details 'Sheldrick, G. M. (2012) SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.' _exptl_crystal_colour colorless _exptl_crystal_density_diffrn 1.618 _exptl_crystal_description block _exptl_crystal_F_000 424 _exptl_crystal_size_max 0.1 _exptl_crystal_size_mid 0.1 _exptl_crystal_size_min 0.1 _exptl_transmission_factor_max 0.7457 _exptl_transmission_factor_min 0.5480 _refine_diff_density_max 0.866 _refine_diff_density_min -0.724 _refine_diff_density_rms 0.136 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.011 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 178 _refine_ls_number_reflns 3205 _refine_ls_number_restraints 6 _refine_ls_restrained_S_all 1.012 _refine_ls_R_factor_all 0.0971 _refine_ls_R_factor_gt 0.0571 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0681P)^2^+1.7767P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1313 _refine_ls_wR_factor_ref 0.1514 _reflns_Friedel_coverage 0.000 _reflns_number_gt 2141 _reflns_number_total 3205 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file c7dt01055a2.cif _cod_data_source_block mo_NP_168_0m_a _cod_database_code 7042744 _shelx_shelxl_version_number 2014/7 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_res_file ; mo_NP_168_0m_a.res created by SHELXL-2014/7 TITL mo_NP_168_0m_a.res in P-1 CELL 0.71073 6.2709 10.3231 13.7669 86.414 84.020 85.949 ZERR 2.000 0.0019 0.0034 0.0045 0.009 0.008 0.008 LATT 1 SFAC C H Br N Sn UNIT 30 46 2 4 2 OMIT -3 50.5 L.S. 10 ACTA BOND $H FMAP 2 PLAN 20 ISOR 0.001 C9 TEMP -123.00 WGHT 0.068100 1.776700 FVAR 0.48128 PART 1 SN1 5 0.715950 0.960459 0.740938 11.00000 0.05260 0.02440 = 0.07640 -0.00315 -0.00871 0.00126 BR1 3 0.300666 0.938395 0.749737 11.00000 0.04642 0.07618 = 0.07861 0.00684 -0.00428 0.00979 N2 4 0.775929 0.781547 0.828111 11.00000 0.05476 0.02342 = 0.04380 -0.01081 -0.01243 0.00908 N1 4 0.791532 0.779201 0.669576 11.00000 0.05196 0.03434 = 0.03820 0.00576 -0.00402 0.00850 C1 1 0.823813 0.710119 0.750810 11.00000 0.02424 0.02927 = 0.04879 -0.00519 -0.00853 -0.00284 C10 1 0.899912 0.569184 0.756824 11.00000 0.03899 0.03629 = 0.04069 -0.00869 -0.00901 0.00446 C2 1 0.814453 0.744922 0.566285 11.00000 0.05556 0.04856 = 0.03679 0.00795 -0.00364 0.00429 C15 1 1.115340 0.532129 0.737023 11.00000 0.04702 0.03962 = 0.05169 -0.00263 -0.01074 0.01111 AFIX 43 H15 2 1.218254 0.595712 0.723054 11.00000 -1.20000 AFIX 0 C6 1 0.801111 0.749273 0.933894 11.00000 0.05704 0.05250 = 0.03199 -0.00986 -0.00858 0.00062 C13 1 1.028719 0.308862 0.757791 11.00000 0.09766 0.02964 = 0.04522 -0.00565 -0.02074 0.01160 AFIX 43 H13 2 1.072489 0.218881 0.757376 11.00000 -1.20000 AFIX 0 C11 1 0.751470 0.476054 0.777259 11.00000 0.05550 0.03927 = 0.05872 0.00118 -0.01191 -0.00097 AFIX 43 H11 2 0.603357 0.501640 0.790761 11.00000 -1.20000 AFIX 0 C14 1 1.179259 0.400189 0.737858 11.00000 0.05858 0.04765 = 0.06447 -0.01016 -0.01819 0.01985 AFIX 43 H14 2 1.326870 0.373161 0.724662 11.00000 -1.20000 AFIX 0 C12 1 0.818008 0.346903 0.778032 11.00000 0.06815 0.03782 = 0.07900 -0.00118 -0.01718 -0.00452 AFIX 43 H12 2 0.715593 0.283182 0.792899 11.00000 -1.20000 AFIX 0 C4 1 1.048575 0.725028 0.526906 11.00000 0.06294 0.12265 = 0.04664 0.00106 0.00614 0.01169 AFIX 137 H4A 2 1.125903 0.799861 0.540945 11.00000 -1.50000 H4B 2 1.058964 0.716557 0.456037 11.00000 -1.50000 H4C 2 1.112242 0.645801 0.558274 11.00000 -1.50000 AFIX 0 C5 1 0.715414 0.858862 0.509821 11.00000 0.12296 0.07033 = 0.05605 0.01020 -0.00649 0.03760 AFIX 137 H5A 2 0.560187 0.866715 0.528693 11.00000 -1.50000 H5B 2 0.742243 0.845644 0.439617 11.00000 -1.50000 H5C 2 0.779200 0.938562 0.524316 11.00000 -1.50000 AFIX 0 C3 1 0.695800 0.625577 0.553414 11.00000 0.11244 0.10013 = 0.05639 -0.00446 -0.02359 -0.03708 AFIX 137 H3A 2 0.771865 0.548585 0.581990 11.00000 -1.50000 H3B 2 0.688837 0.615269 0.483555 11.00000 -1.50000 H3C 2 0.549811 0.635539 0.586358 11.00000 -1.50000 AFIX 0 C7 1 1.022450 0.697020 0.949116 11.00000 0.04938 0.11772 = 0.05804 0.00671 -0.02507 0.01123 AFIX 137 H7A 2 1.047725 0.610496 0.923008 11.00000 -1.50000 H7B 2 1.039625 0.690749 1.019231 11.00000 -1.50000 H7C 2 1.126173 0.755308 0.915161 11.00000 -1.50000 AFIX 0 C8 1 0.638546 0.657992 0.978149 11.00000 0.10574 0.17861 = 0.05247 0.00790 0.01044 -0.06471 AFIX 137 H8A 2 0.662554 0.575065 0.946479 11.00000 -1.50000 H8B 2 0.493912 0.695861 0.968718 11.00000 -1.50000 H8C 2 0.652558 0.643184 1.048274 11.00000 -1.50000 AFIX 0 C9 1 0.762624 0.879227 0.980289 11.00000 0.11796 0.11444 = 0.11287 -0.01004 -0.01361 -0.00418 AFIX 137 H9A 2 0.791080 0.868478 1.049084 11.00000 -1.50000 H9B 2 0.613054 0.911843 0.976167 11.00000 -1.50000 H9C 2 0.858843 0.941421 0.945627 11.00000 -1.50000 PART AFIX 0 HKLF 4 REM mo_NP_168_0m_a.res in P-1 REM R1 = 0.0571 for 2141 Fo > 4sig(Fo) and 0.0971 for all 3205 data REM 178 parameters refined using 6 restraints END WGHT 0.0709 1.3153 REM Highest difference peak 0.866, deepest hole -0.724, 1-sigma level 0.136 Q1 1 0.8506 0.8963 0.9604 11.00000 0.05 0.87 Q2 1 0.6581 0.8527 0.9913 11.00000 0.05 0.81 Q3 1 0.9700 0.7927 0.9773 11.00000 0.05 0.59 Q4 1 0.3948 1.0035 0.7453 11.00000 0.05 0.56 Q5 1 0.5699 0.7520 0.9599 11.00000 0.05 0.51 Q6 1 0.4272 0.6720 0.4964 11.00000 0.05 0.47 Q7 1 1.3528 0.7663 0.3709 11.00000 0.05 0.46 Q8 1 0.6545 0.8255 1.0789 11.00000 0.05 0.45 Q9 1 1.0296 0.6662 0.4298 11.00000 0.05 0.45 Q10 1 0.4274 0.7841 1.0131 11.00000 0.05 0.45 Q11 1 0.8903 0.6892 0.4991 11.00000 0.05 0.45 Q12 1 0.7679 0.9166 0.4201 11.00000 0.05 0.44 Q13 1 1.0277 0.5768 1.0989 11.00000 0.05 0.44 Q14 1 0.8796 0.7574 0.5782 11.00000 0.05 0.44 Q15 1 0.8313 0.9436 0.4795 11.00000 0.05 0.43 Q16 1 0.6285 1.0551 0.6825 11.00000 0.05 0.43 Q17 1 0.3957 0.5352 0.5901 11.00000 0.05 0.42 Q18 1 0.8158 0.8524 0.8020 11.00000 0.05 0.39 Q19 1 0.7814 0.5233 0.6014 11.00000 0.05 0.38 Q20 1 0.5065 0.9037 0.7083 11.00000 0.05 0.38 ; _shelx_res_checksum 81146 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, -y, -z' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_site_symmetry_order _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_refinement_flags_adp _atom_site_disorder_assembly _atom_site_disorder_group Sn1 Sn 0.71595(9) 0.96046(5) 0.74094(4) 0.0511(2) Uani 1 1 d . . A 1 Br1 Br 0.30067(14) 0.93839(10) 0.74974(7) 0.0683(3) Uani 1 1 d . . A 1 N2 N 0.7759(10) 0.7815(5) 0.8281(4) 0.0403(14) Uani 1 1 d . . A 1 N1 N 0.7915(10) 0.7792(6) 0.6696(4) 0.0424(15) Uani 1 1 d . . A 1 C1 C 0.8238(10) 0.7101(6) 0.7508(5) 0.0336(16) Uani 1 1 d . . A 1 C10 C 0.8999(12) 0.5692(7) 0.7568(5) 0.0384(17) Uani 1 1 d . . A 1 C2 C 0.8145(13) 0.7449(8) 0.5663(5) 0.0478(19) Uani 1 1 d . . A 1 C15 C 1.1153(13) 0.5321(8) 0.7370(6) 0.0464(19) Uani 1 1 d . . A 1 H15 H 1.2183 0.5957 0.7231 0.056 Uiso 1 1 calc R U A 1 C6 C 0.8011(13) 0.7493(8) 0.9339(5) 0.0468(19) Uani 1 1 d . . A 1 C13 C 1.0287(16) 0.3089(8) 0.7578(6) 0.057(2) Uani 1 1 d . . A 1 H13 H 1.0725 0.2189 0.7574 0.069 Uiso 1 1 calc R U A 1 C11 C 0.7515(14) 0.4761(8) 0.7773(6) 0.051(2) Uani 1 1 d . . A 1 H11 H 0.6034 0.5016 0.7908 0.061 Uiso 1 1 calc R U A 1 C14 C 1.1793(14) 0.4002(8) 0.7379(6) 0.057(2) Uani 1 1 d . . A 1 H14 H 1.3269 0.3732 0.7247 0.068 Uiso 1 1 calc R U A 1 C12 C 0.8180(15) 0.3469(8) 0.7780(7) 0.061(2) Uani 1 1 d . . A 1 H12 H 0.7156 0.2832 0.7929 0.073 Uiso 1 1 calc R U A 1 C4 C 1.0486(15) 0.7250(12) 0.5269(6) 0.079(3) Uani 1 1 d . . A 1 H4A H 1.1259 0.7999 0.5409 0.119 Uiso 1 1 calc R U A 1 H4B H 1.0590 0.7166 0.4560 0.119 Uiso 1 1 calc R U A 1 H4C H 1.1122 0.6458 0.5583 0.119 Uiso 1 1 calc R U A 1 C5 C 0.7154(19) 0.8589(10) 0.5098(7) 0.086(3) Uani 1 1 d . . A 1 H5A H 0.5602 0.8667 0.5287 0.129 Uiso 1 1 calc R U A 1 H5B H 0.7422 0.8456 0.4396 0.129 Uiso 1 1 calc R U A 1 H5C H 0.7792 0.9386 0.5243 0.129 Uiso 1 1 calc R U A 1 C3 C 0.6958(19) 0.6256(11) 0.5534(7) 0.087(3) Uani 1 1 d . . A 1 H3A H 0.7719 0.5486 0.5820 0.131 Uiso 1 1 calc R U A 1 H3B H 0.6888 0.6153 0.4836 0.131 Uiso 1 1 calc R U A 1 H3C H 0.5498 0.6355 0.5864 0.131 Uiso 1 1 calc R U A 1 C7 C 1.0225(14) 0.6970(12) 0.9491(6) 0.075(3) Uani 1 1 d . . A 1 H7A H 1.0477 0.6105 0.9230 0.112 Uiso 1 1 calc R U A 1 H7B H 1.0396 0.6907 1.0192 0.112 Uiso 1 1 calc R U A 1 H7C H 1.1262 0.7553 0.9152 0.112 Uiso 1 1 calc R U A 1 C8 C 0.6385(19) 0.6580(14) 0.9781(7) 0.112(5) Uani 1 1 d . . A 1 H8A H 0.6626 0.5751 0.9465 0.167 Uiso 1 1 calc R U A 1 H8B H 0.4939 0.6959 0.9687 0.167 Uiso 1 1 calc R U A 1 H8C H 0.6526 0.6432 1.0483 0.167 Uiso 1 1 calc R U A 1 C9 C 0.763(2) 0.8792(13) 0.9803(9) 0.115(4) Uani 1 1 d . U A 1 H9A H 0.7911 0.8685 1.0491 0.172 Uiso 1 1 calc R U A 1 H9B H 0.6131 0.9118 0.9762 0.172 Uiso 1 1 calc R U A 1 H9C H 0.8588 0.9414 0.9456 0.172 Uiso 1 1 calc R U A 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Sn1 0.0526(4) 0.0244(3) 0.0764(5) -0.0031(2) -0.0087(3) 0.0013(2) Br1 0.0464(5) 0.0762(7) 0.0786(7) 0.0068(5) -0.0043(4) 0.0098(4) N2 0.055(4) 0.023(3) 0.044(4) -0.011(3) -0.012(3) 0.009(3) N1 0.052(4) 0.034(3) 0.038(4) 0.006(3) -0.004(3) 0.008(3) C1 0.024(4) 0.029(4) 0.049(5) -0.005(3) -0.009(3) -0.003(3) C10 0.039(4) 0.036(4) 0.041(4) -0.009(3) -0.009(3) 0.004(3) C2 0.056(5) 0.049(5) 0.037(5) 0.008(4) -0.004(4) 0.004(4) C15 0.047(5) 0.040(4) 0.052(5) -0.003(3) -0.011(4) 0.011(4) C6 0.057(5) 0.053(5) 0.032(4) -0.010(4) -0.009(4) 0.001(4) C13 0.098(8) 0.030(4) 0.045(5) -0.006(4) -0.021(5) 0.012(5) C11 0.055(5) 0.039(5) 0.059(5) 0.001(4) -0.012(4) -0.001(4) C14 0.059(6) 0.048(5) 0.064(6) -0.010(4) -0.018(4) 0.020(4) C12 0.068(6) 0.038(5) 0.079(6) -0.001(4) -0.017(5) -0.005(4) C4 0.063(6) 0.123(9) 0.047(6) 0.001(6) 0.006(5) 0.012(6) C5 0.123(9) 0.070(7) 0.056(6) 0.010(5) -0.006(6) 0.038(6) C3 0.112(9) 0.100(9) 0.056(6) -0.004(6) -0.024(6) -0.037(7) C7 0.049(6) 0.118(9) 0.058(6) 0.007(6) -0.025(4) 0.011(5) C8 0.106(9) 0.179(14) 0.052(7) 0.008(7) 0.010(6) -0.065(10) C9 0.118(5) 0.114(5) 0.113(5) -0.010(2) -0.014(2) -0.004(2) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle N1 Sn1 N2 60.2(2) N1 Sn1 Br1 93.21(16) N2 Sn1 Br1 94.35(16) N1 Sn1 C1 30.0(2) N2 Sn1 C1 30.4(2) Br1 Sn1 C1 96.19(14) C1 N2 C6 130.4(6) C1 N2 Sn1 94.0(4) C6 N2 Sn1 134.5(4) C1 N1 C2 131.9(6) C1 N1 Sn1 94.6(4) C2 N1 Sn1 133.4(5) N1 C1 N2 110.8(6) N1 C1 C10 125.1(6) N2 C1 C10 124.0(6) N1 C1 Sn1 55.4(4) N2 C1 Sn1 55.6(3) C10 C1 Sn1 176.3(5) C11 C10 C15 120.1(7) C11 C10 C1 119.4(7) C15 C10 C1 120.4(7) N1 C2 C5 106.2(7) N1 C2 C4 111.5(7) C5 C2 C4 108.3(7) N1 C2 C3 111.2(6) C5 C2 C3 109.0(8) C4 C2 C3 110.5(8) C10 C15 C14 119.0(8) C10 C15 H15 120.5 C14 C15 H15 120.5 C8 C6 C7 111.1(9) C8 C6 N2 111.3(7) C7 C6 N2 111.8(6) C8 C6 C9 110.1(9) C7 C6 C9 108.2(8) N2 C6 C9 104.0(7) C12 C13 C14 120.2(8) C12 C13 H13 119.9 C14 C13 H13 119.9 C12 C11 C10 119.9(8) C12 C11 H11 120.0 C10 C11 H11 120.0 C13 C14 C15 120.0(8) C13 C14 H14 120.0 C15 C14 H14 120.0 C13 C12 C11 120.7(8) C13 C12 H12 119.6 C11 C12 H12 119.6 C2 C4 H4A 109.5 C2 C4 H4B 109.5 H4A C4 H4B 109.5 C2 C4 H4C 109.5 H4A C4 H4C 109.5 H4B C4 H4C 109.5 C2 C5 H5A 109.5 C2 C5 H5B 109.5 H5A C5 H5B 109.5 C2 C5 H5C 109.5 H5A C5 H5C 109.5 H5B C5 H5C 109.5 C2 C3 H3A 109.5 C2 C3 H3B 109.5 H3A C3 H3B 109.5 C2 C3 H3C 109.5 H3A C3 H3C 109.5 H3B C3 H3C 109.5 C6 C7 H7A 109.5 C6 C7 H7B 109.5 H7A C7 H7B 109.5 C6 C7 H7C 109.5 H7A C7 H7C 109.5 H7B C7 H7C 109.5 C6 C8 H8A 109.5 C6 C8 H8B 109.5 H8A C8 H8B 109.5 C6 C8 H8C 109.5 H8A C8 H8C 109.5 H8B C8 H8C 109.5 C6 C9 H9A 109.5 C6 C9 H9B 109.5 H9A C9 H9B 109.5 C6 C9 H9C 109.5 H9A C9 H9C 109.5 H9B C9 H9C 109.5 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance Sn1 N1 2.168(6) Sn1 N2 2.171(6) Sn1 Br1 2.6197(13) Sn1 C1 2.624(7) N2 C1 1.329(8) N2 C6 1.496(9) N1 C1 1.314(9) N1 C2 1.477(9) C1 C10 1.499(9) C10 C11 1.381(11) C10 C15 1.382(11) C2 C5 1.502(12) C2 C4 1.516(12) C2 C3 1.512(12) C15 C14 1.392(11) C15 H15 0.9500 C6 C8 1.494(13) C6 C7 1.484(12) C6 C9 1.515(14) C13 C12 1.357(12) C13 C14 1.376(12) C13 H13 0.9500 C11 C12 1.368(11) C11 H11 0.9500 C14 H14 0.9500 C12 H12 0.9500 C4 H4A 0.9800 C4 H4B 0.9800 C4 H4C 0.9800 C5 H5A 0.9800 C5 H5B 0.9800 C5 H5C 0.9800 C3 H3A 0.9800 C3 H3B 0.9800 C3 H3C 0.9800 C7 H7A 0.9800 C7 H7B 0.9800 C7 H7C 0.9800 C8 H8A 0.9800 C8 H8B 0.9800 C8 H8C 0.9800 C9 H9A 0.9800 C9 H9B 0.9800 C9 H9C 0.9800