#------------------------------------------------------------------------------
#$Date: 2014-12-24 13:18:19 +0200 (Wed, 24 Dec 2014) $
#$Revision: 129039 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/60/7116092.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7116092
loop_
_publ_author_name
'Gamal A. I. Moustafa'
'Yuki Saku'
'Hiroshi Aoyama'
'Takehiko Yoshimitsu'
_publ_section_title
;
 A new route to platencin via decarboxylative radical cyclization
;
_journal_name_full               Chem.Commun.
_journal_page_first              15706
_journal_paper_doi               10.1039/C4cc07316A
_journal_volume                  50
_journal_year                    2014
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C13 H18 O2'
_chemical_formula_sum            'C26 H36 O4'
_chemical_formula_weight         412.55
_chemical_melting_point          383.15
_chemical_name_systematic
'(3RS,6RS,6aRS,11bRS)-8,11-dimethoxy-6a-methyl-2-oxo-3,4,5,6,6a,7-hexahydro-2H-3,11b-methanoindeno[1,2-b]oxocin-6-yl methanesulfonate (16)'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4
_audit_creation_date             2014-06-02T15:03:07-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 90.919(14)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.001(11)
_cell_length_b                   11.207(13)
_cell_length_c                   20.96(2)
_cell_measurement_reflns_used    2531
_cell_measurement_temperature    103(2)
_cell_measurement_theta_max      27.47
_cell_measurement_theta_min      3.0498
_cell_measurement_wavelength     0.71073
_cell_volume                     2114(4)
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_reduction
'CrystalClear (Rigaku Inc., 2007), SORTAV (Blessing, 1995)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SIR92 (Giacovazzo et al, 1993)'
_diffrn_ambient_temperature      103(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 14.7059
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device       'quarter \C-circle diffractometer'
_diffrn_measurement_method       'phi or omega oscillation scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0388
_diffrn_reflns_laue_measured_fraction_full 0.988
_diffrn_reflns_laue_measured_fraction_max 0.968
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            15219
_diffrn_reflns_point_group_measured_fraction_max 0.968
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.787
_diffrn_reflns_theta_min         3.073
_diffrn_source                   'sealed x-ray tube'
_exptl_absorpt_coefficient_mu    0.085
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.296
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             896
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: n-hexane'
_exptl_crystal_size_max          0.64
_exptl_crystal_size_mid          0.37
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.947
_refine_diff_density_min         -0.512
_refine_diff_density_rms         0.112
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.594
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     136
_refine_ls_number_reflns         2429
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.594
_refine_ls_R_factor_all          0.1542
_refine_ls_R_factor_gt           0.1327
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3926
_refine_ls_wR_factor_ref         0.4116
_reflns_number_gt                1853
_reflns_number_total             2429
_reflns_threshold_expression     'I > 2\s(I)'
_[local]_cod_data_source_file    c4cc07316a2.cif
_[local]_cod_data_source_block   c13h18o2
_[local]_cod_cif_authors_sg_H-M  'C 2/c'
_cod_database_code               7116092
_diffrn_reflns_point_group_measured_fraction_ful 0.988
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 -x,y,1/2-z
3 1/2+x,1/2+y,z
4 1/2-x,1/2+y,1/2-z
5 -x,-y,-z
6 x,-y,1/2+z
7 1/2-x,1/2-y,-z
8 1/2+x,1/2-y,1/2+z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
C1 C 0.1188(4) 0.6033(3) 0.86651(18) 0.0315(9) Uani 1 d
C2 C 0.0825(4) 0.7294(3) 0.83975(19) 0.0323(9) Uani 1 d
H2 H 0.0063 0.719 0.805 0.039 Uiso 1 calc
C3 C 0.0121(4) 0.8039(3) 0.89155(19) 0.0339(9) Uani 1 d
C4 C 0.3566(4) 0.6966(3) 0.8192(2) 0.0385(10) Uani 1 d
H4 H 0.4488 0.7326 0.8015 0.046 Uiso 1 calc
C5 C -0.0218(4) 0.5492(3) 0.89314(19) 0.0350(9) Uani 1 d
H5A H -0.0936 0.5358 0.8576 0.042 Uiso 1 calc
H5B H 0.0026 0.4705 0.912 0.042 Uiso 1 calc
C6 C -0.1279(4) 0.7497(3) 0.9178(2) 0.0357(9) Uani 1 d
H6 H -0.167 0.8009 0.9528 0.043 Uiso 1 calc
C7 C 0.2233(4) 0.7814(3) 0.8089(2) 0.0396(10) Uani 1 d
H7A H 0.205 0.793 0.7626 0.048 Uiso 1 calc
H7B H 0.2463 0.8601 0.828 0.048 Uiso 1 calc
C8 C -0.0944(4) 0.6254(3) 0.9430(2) 0.0399(10) Uani 1 d
H8A H -0.0278 0.6314 0.9809 0.048 Uiso 1 calc
H8B H -0.188 0.587 0.9564 0.048 Uiso 1 calc
C9 C 0.1802(5) 0.5282(3) 0.8126(2) 0.0411(10) Uani 1 d
H9A H 0.1977 0.4459 0.8281 0.049 Uiso 1 calc
H9B H 0.1058 0.5243 0.7773 0.049 Uiso 1 calc
C10 C 0.2419(4) 0.6163(3) 0.91758(19) 0.0367(9) Uani 1 d
H10A H 0.2052 0.6644 0.9537 0.044 Uiso 1 calc
H10B H 0.2705 0.5367 0.934 0.044 Uiso 1 calc
C11 C 0.3747(4) 0.6764(3) 0.8889(2) 0.0382(9) Uani 1 d
C12 C 0.3239(5) 0.5785(3) 0.7875(2) 0.0445(11) Uani 1 d
H12A H 0.4062 0.522 0.7964 0.053 Uiso 1 calc
H12B H 0.3154 0.5895 0.7407 0.053 Uiso 1 calc
C13 C 0.0677(5) 0.9028(3) 0.9170(2) 0.0473(11) Uani 1 d
H13A H 0.0195 0.9398 0.9518 0.057 Uiso 1 calc
H13B H 0.1558 0.9367 0.9004 0.057 Uiso 1 calc
O1 O 0.4871(3) 0.6998(2) 0.92049(15) 0.0432(8) Uani 1 d
O2 O -0.2353(3) 0.7429(3) 0.86608(15) 0.0451(8) Uani 1 d
H2A H -0.1978 0.7071 0.835 0.068 Uiso 1 calc
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.0320(18) 0.0257(15) 0.037(2) 0.0005(12) 0.0075(16) -0.0028(11)
C2 0.038(2) 0.0285(16) 0.031(2) 0.0055(12) 0.0062(16) 0.0003(12)
C3 0.038(2) 0.0311(16) 0.033(2) 0.0021(12) 0.0030(17) -0.0056(13)
C4 0.030(2) 0.051(2) 0.035(2) 0.0021(15) 0.0067(17) -0.0001(14)
C5 0.0332(19) 0.0320(17) 0.040(2) 0.0022(13) 0.0033(16) -0.0072(13)
C6 0.0323(19) 0.0361(18) 0.039(2) 0.0034(14) 0.0083(17) 0.0010(13)
C7 0.039(2) 0.0372(18) 0.043(3) 0.0045(14) 0.0089(19) -0.0051(14)
C8 0.036(2) 0.0381(19) 0.046(3) 0.0032(14) 0.0048(18) -0.0113(14)
C9 0.042(2) 0.0400(19) 0.041(2) -0.0043(14) 0.0061(18) 0.0092(15)
C10 0.032(2) 0.0374(18) 0.040(2) 0.0044(14) -0.0026(17) -0.0026(13)
C11 0.0288(19) 0.045(2) 0.041(2) 0.0040(15) 0.0059(17) -0.0012(14)
C12 0.043(2) 0.049(2) 0.042(3) -0.0037(16) 0.0125(19) 0.0078(16)
C13 0.056(3) 0.0373(19) 0.049(3) -0.0072(15) 0.006(2) -0.0092(16)
O1 0.0303(16) 0.0576(17) 0.0415(19) 0.0059(12) -0.0035(13) -0.0073(11)
O2 0.0381(17) 0.0587(17) 0.0385(19) 0.0031(12) 0.0004(14) 0.0080(12)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C5 C1 C9 111.6(3)
C5 C1 C10 112.2(3)
C9 C1 C10 107.7(3)
C5 C1 C2 109.0(3)
C9 C1 C2 108.2(3)
C10 C1 C2 108.1(3)
C3 C2 C7 116.5(3)
C3 C2 C1 109.3(3)
C7 C2 C1 109.0(3)
C3 C2 H2 107.2
C7 C2 H2 107.2
C1 C2 H2 107.2
C13 C3 C6 120.2(4)
C13 C3 C2 126.1(4)
C6 C3 C2 113.5(3)
C11 C4 C12 108.5(3)
C11 C4 C7 107.7(3)
C12 C4 C7 109.4(4)
C11 C4 H4 110.4
C12 C4 H4 110.4
C7 C4 H4 110.4
C8 C5 C1 113.7(3)
C8 C5 H5A 108.8
C1 C5 H5A 108.8
C8 C5 H5B 108.8
C1 C5 H5B 108.8
H5A C5 H5B 107.7
O2 C6 C3 107.5(3)
O2 C6 C8 109.9(3)
C3 C6 C8 109.5(3)
O2 C6 H6 110
C3 C6 H6 110
C8 C6 H6 110
C4 C7 C2 110.5(3)
C4 C7 H7A 109.6
C2 C7 H7A 109.6
C4 C7 H7B 109.6
C2 C7 H7B 109.6
H7A C7 H7B 108.1
C5 C8 C6 111.3(3)
C5 C8 H8A 109.4
C6 C8 H8A 109.4
C5 C8 H8B 109.4
C6 C8 H8B 109.4
H8A C8 H8B 108
C12 C9 C1 112.0(3)
C12 C9 H9A 109.2
C1 C9 H9A 109.2
C12 C9 H9B 109.2
C1 C9 H9B 109.2
H9A C9 H9B 107.9
C11 C10 C1 109.5(3)
C11 C10 H10A 109.8
C1 C10 H10A 109.8
C11 C10 H10B 109.8
C1 C10 H10B 109.8
H10A C10 H10B 108.2
O1 C11 C4 125.0(4)
O1 C11 C10 122.2(4)
C4 C11 C10 112.7(3)
C4 C12 C9 109.7(3)
C4 C12 H12A 109.7
C9 C12 H12A 109.7
C4 C12 H12B 109.7
C9 C12 H12B 109.7
H12A C12 H12B 108.2
C3 C13 H13A 120
C3 C13 H13B 120
H13A C13 H13B 120
C6 O2 H2A 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 C5 1.517(5)
C1 C9 1.521(5)
C1 C10 1.535(5)
C1 C2 1.553(5)
C2 C3 1.517(5)
C2 C7 1.546(5)
C2 H2 1
C3 C13 1.324(5)
C3 C6 1.511(5)
C4 C11 1.485(6)
C4 C12 1.508(6)
C4 C7 1.543(6)
C4 H4 1
C5 C8 1.507(5)
C5 H5A 0.99
C5 H5B 0.99
C6 O2 1.443(5)
C6 C8 1.519(5)
C6 H6 1
C7 H7A 0.99
C7 H7B 0.99
C8 H8A 0.99
C8 H8B 0.99
C9 C12 1.513(6)
C9 H9A 0.99
C9 H9B 0.99
C10 C11 1.506(5)
C10 H10A 0.99
C10 H10B 0.99
C11 O1 1.228(5)
C12 H12A 0.99
C12 H12B 0.99
C13 H13A 0.95
C13 H13B 0.95
O2 H2A 0.84
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C5 C1 C2 C3 55.1(4)
C9 C1 C2 C3 176.5(3)
C10 C1 C2 C3 -67.1(4)
C5 C1 C2 C7 -176.6(3)
C9 C1 C2 C7 -55.1(4)
C10 C1 C2 C7 61.2(4)
C7 C2 C3 C13 -7.1(6)
C1 C2 C3 C13 116.9(4)
C7 C2 C3 C6 177.9(3)
C1 C2 C3 C6 -58.1(4)
C9 C1 C5 C8 -175.2(3)
C10 C1 C5 C8 63.8(4)
C2 C1 C5 C8 -55.8(4)
C13 C3 C6 O2 122.2(4)
C2 C3 C6 O2 -62.5(4)
C13 C3 C6 C8 -118.4(4)
C2 C3 C6 C8 56.9(4)
C11 C4 C7 C2 -56.1(4)
C12 C4 C7 C2 61.7(4)
C3 C2 C7 C4 119.7(4)
C1 C2 C7 C4 -4.5(4)
C1 C5 C8 C6 55.8(4)
O2 C6 C8 C5 64.2(4)
C3 C6 C8 C5 -53.7(4)
C5 C1 C9 C12 -177.6(3)
C10 C1 C9 C12 -54.0(4)
C2 C1 C9 C12 62.6(4)
C5 C1 C10 C11 -177.0(3)
C9 C1 C10 C11 59.9(4)
C2 C1 C10 C11 -56.8(4)
C12 C4 C11 O1 120.7(4)
C7 C4 C11 O1 -120.9(4)
C12 C4 C11 C10 -56.0(4)
C7 C4 C11 C10 62.4(4)
C1 C10 C11 O1 178.2(3)
C1 C10 C11 C4 -5.1(4)
C11 C4 C12 C9 61.6(4)
C7 C4 C12 C9 -55.6(5)
C1 C9 C12 C4 -5.7(5)