#------------------------------------------------------------------------------
#$Date: 2021-01-04 20:20:10 +0200 (Mon, 04 Jan 2021) $
#$Revision: 260474 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/77/7127762.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7127762
loop_
_publ_author_name
'Liu, Ying'
'Wang, Shuxin'
'Kang, Xi'
'Yin, Bing'
'Jin, Shan'
'Chen, Shuang'
'Zhu, Manzhou'
_publ_section_title
;
Heterogeneous metal alloy engineering: embryonic growth of M13
icosahedra in Ag-based alloy superatomic nanoclusters.
;
_journal_issue 91
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first 14203
_journal_page_last 14206
_journal_paper_doi 10.1039/d0cc05575a
_journal_volume 56
_journal_year 2020
_chemical_formula_moiety 'C280 H406 Ag48 Au3 Cl7 S28, 2(F6 Sb)'
_chemical_formula_sum 'C280 H406 Ag48 Au3 Cl7 F12 S28 Sb2'
_chemical_formula_weight 11158.01
_space_group_crystal_system monoclinic
_space_group_IT_number 15
_space_group_name_Hall '-C 2yc'
_space_group_name_H-M_alt 'C 1 2/c 1'
_atom_sites_solution_hydrogens geom
_audit_creation_date 2019-11-20
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2020-07-09 deposited with the CCDC. 2020-10-18 downloaded from the CCDC.
;
_cell_angle_alpha 90
_cell_angle_beta 108.9609(6)
_cell_angle_gamma 90
_cell_formula_units_Z 8
_cell_length_a 41.6940(5)
_cell_length_b 29.9362(4)
_cell_length_c 62.1774(9)
_cell_measurement_reflns_used 9673
_cell_measurement_temperature 296(2)
_cell_measurement_theta_max 22.66
_cell_measurement_theta_min 2.26
_cell_volume 73396.4(17)
_computing_cell_refinement 'SAINT V8.35A (?, 2016)'
_computing_data_reduction 'SAINT V8.35A (?, 2016)'
_computing_molecular_graphics 'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material 'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement 'ShelXL (Sheldrick, 2015)'
_diffrn_ambient_temperature 296.15
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type 'Bruker APEX-II CCD'
_diffrn_measurement_method '\f and \w scans'
_diffrn_radiation_type MoK\a
_diffrn_radiation_wavelength 0.71073
_diffrn_reflns_av_R_equivalents 0.0981
_diffrn_reflns_av_unetI/netI 0.1114
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max 52
_diffrn_reflns_limit_h_min -52
_diffrn_reflns_limit_k_max 37
_diffrn_reflns_limit_k_min -37
_diffrn_reflns_limit_l_max 78
_diffrn_reflns_limit_l_min -78
_diffrn_reflns_number 440232
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full 25.242
_diffrn_reflns_theta_max 26.500
_diffrn_reflns_theta_min 1.469
_exptl_absorpt_coefficient_mu 4.087
_exptl_absorpt_correction_T_max 0.7459
_exptl_absorpt_correction_T_min 0.6482
_exptl_absorpt_correction_type multi-scan
_exptl_absorpt_process_details
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0988 before and 0.0658 after correction.
The Ratio of minimum to maximum transmission is 0.8690.
The \l/2 correction factor is 0.00150.
;
_exptl_crystal_density_diffrn 2.020
_exptl_crystal_description block
_exptl_crystal_F_000 42848
_refine_diff_density_max 11.817
_refine_diff_density_min -6.544
_refine_diff_density_rms 0.421
_refine_ls_extinction_method none
_refine_ls_goodness_of_fit_ref 1.222
_refine_ls_hydrogen_treatment constr
_refine_ls_matrix_type fullcycle
_refine_ls_number_parameters 3746
_refine_ls_number_reflns 76000
_refine_ls_number_restraints 223
_refine_ls_restrained_S_all 3.235
_refine_ls_R_factor_all 0.1983
_refine_ls_R_factor_gt 0.1218
_refine_ls_shift/su_max 0.000
_refine_ls_shift/su_mean 0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme calc
_refine_ls_wR_factor_gt 0.3289
_refine_ls_wR_factor_ref 0.3725
_reflns_Friedel_coverage 0.000
_reflns_number_gt 41310
_reflns_number_total 76000
_reflns_threshold_expression 'I > 2\s(I)'
_cod_data_source_file d0cc05575a2.cif
_cod_data_source_block 20171119d_0ma_sq
_cod_database_code 7127762
_shelx_shelxl_version_number 2016/4
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
At 1.2 times of:
All C(H) groups, All C(H,H) groups, All C(H,H,H) groups, All C(H,H,H,H) groups
2. Restrained distances
C9QA-C1SA
1.55 with sigma of 0.02
C9QA-C3RA
1.55 with sigma of 0.02
C9QA-C2RA
1.55 with sigma of 0.02
C1SA-C5UA
1.55 with sigma of 0.02
C0VA-C9UA
1.55 with sigma of 0.02
C9UA-C5UA
1.55 with sigma of 0.02
C5UA-C8UA
1.55 with sigma of 0.02
C8UA-C7UA
1.55 with sigma of 0.02
C7UA-C217
1.55 with sigma of 0.02
C217-C0VA
1.55 with sigma of 0.02
C2RA-C0VA
1.55 with sigma of 0.02
C3RA-C7UA
1.55 with sigma of 0.02
C3RA-C9QA
1.55 with sigma of 0.02
C2RA-C9QA
1.55 with sigma of 0.02
C1SA-C9QA
1.55 with sigma of 0.02
C2RA-C1SA
2.55 with sigma of 0.02
C2RA-C3RA
2.55 with sigma of 0.02
C3RA-C1SA
2.55 with sigma of 0.02
C217-C5UA
3 with sigma of 0.02
C0VA-C8UA
3 with sigma of 0.02
C9UA-C7UA
3 with sigma of 0.02
Sb2-F75
1.815 with sigma of 0.01
F21-F75
2.63 with sigma of 0.01
F75-F22
2.345 with sigma of 0.01
F9-F75
2.602 with sigma of 0.01
F7-F75
2.563 with sigma of 0.01
C3NA-C254
1.5 with sigma of 0.01
C7NA-C254
1.5 with sigma of 0.01
C9NA-C254
1.5 with sigma of 0.01
C68-C74
1.55 with sigma of 0.01
C1UA-C0UA
1.55 with sigma of 0.01
C3UA-C0UA
1.55 with sigma of 0.01
C5RA-C2SA
1.55 with sigma of 0.01
C9JA-C9TA
1.55 with sigma of 0.01
C9JA-C3VA
1.55 with sigma of 0.01
C9JA-C8TA
1.55 with sigma of 0.01
C9TA-C0UA
1.55 with sigma of 0.01
C0UA-C1UA
1.55 with sigma of 0.01
C1UA-C2UA
1.55 with sigma of 0.01
C2UA-C74
1.55 with sigma of 0.01
C74-C68
1.55 with sigma of 0.01
C68-C3UA
1.55 with sigma of 0.01
C3VA-C68
1.55 with sigma of 0.01
C3UA-C2UA
3 with sigma of 0.01
C1UA-C68
3 with sigma of 0.01
C74-C0UA
3 with sigma of 0.01
C3VA-C9TA
2.52 with sigma of 0.01
C9TA-C8TA
2.52 with sigma of 0.01
C8TA-C3VA
2.52 with sigma of 0.01
Sb4-F2
1.85 with sigma of 0.02
Sb4-F1AA
1.85 with sigma of 0.02
F2-F69
2.5 with sigma of 0.02
F2-F58
2.5 with sigma of 0.02
F1AA-F2
2.5 with sigma of 0.02
F2-F61
2.5 with sigma of 0.02
Sb3-F0AA
1.81 with sigma of 0.02
C0SA-C2SA
2.447 with sigma of 0.01
C2SA-C3SA
2.636 with sigma of 0.01
3. Restrained planarity
F13, F69, Sb4, F2, F58
with sigma of 0.1
F61, F13, Sb4, F2, F1AA
with sigma of 0.1
F0AA, Sb3, F78, F32, F95
with sigma of 0.1
C3SA, C4UA, C99, C2SA
with sigma of 0.1
C4UA, C3SA, C6UA, C0SA
with sigma of 0.1
C6UA, C0SA, C2SA, C99
with sigma of 0.1
4. Uiso/Uaniso restraints and constraints
S16 \\sim C9JA \\sim C3VA \\sim C9TA \\sim C8TA \\sim C2UA \\sim C74 \\sim C68
\\sim C3UA \\sim C0UA \\sim C1UA: within 2A with sigma of 0.001 and sigma for
terminal atoms of 0.0005
S28 \\sim C5RA \\sim C2SA \\sim C0SA \\sim C3SA \\sim C4UA \\sim C4NA \\sim
C6UA \\sim C75 \\sim C241 \\sim C99: within 2A with sigma of 0.001 and sigma
for terminal atoms of 0.0005
5. Others
Sof(Ag)=1-FVAR(1)
Sof(Ag55)=FVAR(1)
Fixed Sof: Ag3(0.5) Ag0A(0.5) Ag1(0.5) S5(0.5) Ag66(0.5) S3(0.5) S2(0.5)
S4(0.5) Sb1(0.5) Sb2(0.5) Sb3(0.5) Sb4(0.5) F11(0.5) F16(0.5) F35(0.5)
F15(0.5) F20(0.5) F32(0.5) C9OA(0.5) F58(0.5) F61(0.5) F64(0.5) F66(0.5)
F69(0.5) F71(0.5) F78(0.5) F95(0.5) C97(0.5) H97A(0.5) H97B(0.5) H0TA(0.5)
H0TB(0.5) F7(0.5) F9(0.5) C7SA(0.5) H7SA(0.5) F14(0.5) C6SA(0.5) F21(0.5)
F22(0.5) C6TA(0.5) H6TA(0.5) H6TB(0.5) C7TA(0.5) H7TA(0.5) C1TA(0.5) H1TA(0.5)
C3TA(0.5) H3TA(0.5) H3TB(0.5) C4TA(0.5) H4TA(0.5) C5TA(0.5) H5TA(0.5)
H5TB(0.5) C2TA(0.5) H2TA(0.5) C9SA(0.5) H9SA(0.5) H9SB(0.5) C8SA(0.5)
H8SA(0.5) H8SB(0.5) C61(0.5) H61(0.5) C69(0.5) H69A(0.5) H69B(0.5) C72(0.5)
H72A(0.5) H72B(0.5) F75(0.5) F13(0.5) Ag40(0.5) Ag41(0.5) S91(0.5) H3RC(0.5)
H3RD(0.5) H3RA(0.5) H3RB(0.5) C9QA(0.5) C2RA(0.5) H2RA(0.5) H2RB(0.5)
C1SA(0.5) H1SA(0.5) H1SB(0.5) C0VA(0.5) H0VA(0.5) H9UB(0.5) H9UC(0.5)
H9UA(0.5) C8UA(0.5) H8UA(0.5) H8UB(0.5) C5UA(0.5) H5UA(0.5) C217(0.5)
H21C(0.5) H21D(0.5) C2VA(0.5) C4VA(0.5) H4VA(0.5) H4VB(0.5) C5VA(0.5)
H5VA(0.5) C6VA(0.5) H6VA(0.5) H6VB(0.5) C7VA(0.5) C1VA(0.5) S76(0.5) C98(0.5)
F2(0.5) F1AA(0.5) F0AA(0.5)
6.a Ternary CH refined with riding coordinates:
C6(H6), C10(H10), C23(H23), C34(H34), C36(H36), C43(H43), C47(H47), C50(H50),
C54(H54), C7BA(H7BA), C0EA(H0EA), C8(H8), C7CA(H7CA), C3BA(H3BA), C9CA(H9CA),
C7AA(H7AA), C6AA(H6AA), C8AA(H8AA), C2DA(H2DA), C2BA(H2BA), C5BA(H5BA),
C5CA(H5CA), C1IA(H1IA), C3EA(H3EA), C7GA(H7GA), C6GA(H6GA), C9EA(H9EA),
C9HA(H9HA), C2FA(H2FA), C6IA(H6IA), C7FA(H7FA), C4HA(H4HA), C4IA(H4IA),
C8IA(H8IA), C6HA(H6HA), C3GA(H3GA), C2JA(H2JA), C6FA(H6FA), C4FA(H4FA),
C9FA(H9FA), C5EA(H5EA), C6EA(H6EA), C9KA(H9KA), C7JA(H7JA), C5KA(H5KA),
C0KA(H0KA), C9MA(H9MA), C37(H37), C6JA(H6JA), C1LA(H1LA), C2LA(H2LA),
C5LA(H5LA), C5NA(H5NA), C1MA(H1MA), C1PA(H1PA), C4PA(H4PA), C6RA(H6RA),
C9PA(H9PA), C6PA(H6PA), C4QA(H4QA), C0QA(H0QA), C0OA(H0OA), C77(H77),
C0TA(H0TB), C9RA(H9RA), C7SA(H7SA), C2UA(H2UA), C0UA(H0UA), C7TA(H7TA),
C1TA(H1TA), C4TA(H4TA), C2TA(H2TA), C5MA(H5MA), C5QA(H5QA), C1RA(H1RA),
C6UA(H6UA), C4UA(H4UA), C254(H254), C99(H99), C1JA(H1JA), C4OA(H4OA),
C3OA(H3OA), C2OA(H2OA), C7UA(H7UA), C0VA(H0VA), C9UA(H9UA), C5UA(H5UA),
C5VA(H5VA)
6.b Secondary CH2 refined with riding coordinates:
C1(H1A,H1B), C4(H4A,H4B), C11(H11A,H11B), C13(H13A,H13B), C16(H16A,H16B),
C17(H17A,H17B), C19(H19A,H19B), C21(H21A,H21B), C24(H24A,H24B), C26(H26A,H26B),
C29(H29A,H29B), C31(H31A,H31B), C33(H33A,H33B), C35(H35A,H35B), C39(H39A,
H39B), C40(H40A,H40B), C41(H41A,H41B), C42(H42A,H42B), C45(H45A,H45B),
C46(H46A,H46B), C48(H48A,H48B), C51(H51A,H51B), C52(H52A,H52B), C53(H53A,H53B),
C58(H58A,H58B), C60(H60A,H60B), C9BA(H9BA,H9BB), C8CA(H8CA,H8CB), C6CA(H6CA,
H6CB), C4BA(H4BA,H4BB), C1AA(H1AA,H1AB), C0AA(H0AA,H0AB), C3DA(H3DA,H3DB),
C4AA(H4AA,H4AB), C15(H15A,H15B), C3AA(H3AA,H3AB), C9AA(H9AA,H9AB), C4CA(H4CA,
H4CB), C9DA(H9DA,H9DB), C27(H27A,H27B), C2CA(H2CA,H2CB), C8BA(H8BA,H8BB),
C0DA(H0DA,H0DB), C4DA(H4DA,H4DB), C0BA(H0BA,H0BB), C1BA(H1BA,H1BB), C38(H38A,
H38B), C7DA(H7DA,H7DB), C6BA(H6BA,H6BB), C5AA(H5AA,H5AB), C2AA(H2AA,H2AB),
C5DA(H5DA,H5DB), C1DA(H1DA,H1DB), C6DA(H6DA,H6DB), C56(H56A,H56B), C57(H57A,
H57B), C3CA(H3CA,H3CB), C2EA(H2EA,H2EB), C8GA(H8GA,H8GB), C8FA(H8FA,H8FB),
C9IA(H9IA,H9IB), C7EA(H7EA,H7EB), C3IA(H3IA,H3IB), C4GA(H4GA,H4GB), C0IA(H0IA,
H0IB), C2IA(H2IA,H2IB), C0JA(H0JA,H0JB), C8HA(H8HA,H8HB), C8EA(H8EA,H8EB),
C2GA(H2GA,H2GB), C1GA(H1GA,H1GB), C7IA(H7IA,H7IB), C7HA(H7HA,H7HB), C0FA(H0FA,
H0FB), C1HA(H1HA,H1HB), C3HA(H3HA,H3HB), C0HA(H0HA,H0HB), C5GA(H5GA,H5GB),
C2HA(H2HA,H2HB), C5IA(H5IA,H5IB), C4EA(H4EA,H4EB), C3FA(H3FA,H3FB), C5HA(H5HA,
H5HB), C0GA(H0GA,H0GB), C5FA(H5FA,H5FB), C1FA(H1FA,H1FB), C0LA(H0LA,H0LB),
C4JA(H4JA,H4JB), C3MA(H3MA,H3MB), C8MA(H8MA,H8MB), C6LA(H6LA,H6LB), C1KA(H1KA,
H1KB), C0NA(H0NA,H0NB), C3KA(H3KA,H3KB), C1NA(H1NA,H1NB), C25(H25A,H25B),
C3LA(H3LA,H3LB), C6KA(H6KA,H6KB), C9LA(H9LA,H9LB), C7MA(H7MA,H7MB), C4LA(H4LA,
H4LB), C6NA(H6NA,H6NB), C2KA(H2KA,H2KB), C0MA(H0MA,H0MB), C5JA(H5JA,H5JB),
C2NA(H2NA,H2NB), C8KA(H8KA,H8KB), C8JA(H8JA,H8JB), C7NA(H7NA,H7NB), C2MA(H2MA,
H2MB), C7KA(H7KA,H7KB), C4KA(H4KA,H4KB), C2PA(H2PA,H2PB), C0PA(H0PA,H0PB),
C7RA(H7RA,H7RB), C1QA(H1QA,H1QB), C5PA(H5PA,H5PB), C4RA(H4RA,H4RB), C7PA(H7PA,
H7PB), C0RA(H0RA,H0RB), C2QA(H2QA,H2QB), C9NA(H9NA,H9NB), C3QA(H3QA,H3QB),
C8PA(H8PA,H8PB), C63(H63A,H63B), C65(H65A,H65B), C97(H97A,H97B), C4SA(H4SA,
H4SB), C5SA(H5SA,H5SB), C8RA(H8RA,H8RB), C1UA(H1UA,H1UB), C6TA(H6TA,H6TB),
C3TA(H3TA,H3TB), C5TA(H5TA,H5TB), C8TA(H8TA,H8TB), C9SA(H9SA,H9SB), C8SA(H8SA,
H8SB), C69(H69A,H69B), C72(H72A,H72B), C9TA(H9TA,H9TB), C7OA(H7OA,H7OB),
C8OA(H8OA,H8OB), C7QA(H7QA,H7QB), C6QA(H6QA,H6QB), C125(H12A,H12B), C8QA(H8QA,
H8QB), C8NA(H8NA,H8NB), C148(H14A,H14B), C0SA(H0SA,H0SB), C2SA(H2SA,H2SB),
C3SA(H3SA,H3SB), C4NA(H4NA,H4NB), C75(H75A,H75B), C241(H24C,H24D), C6MA(H6MA,
H6MB), C5OA(H5OA,H5OB), C1OA(H1OA,H1OB), C6OA(H6OA,H6OB), C3PA(H3PA,H3PB),
C8LA(H8LA,H8LB), C3RA(H3RC,H3RD), C3RA(H3RA,H3RB), C2RA(H2RA,H2RB), C1SA(H1SA,
H1SB), C9UA(H9UB,H9UC), C8UA(H8UA,H8UB), C217(H21C,H21D), C4VA(H4VA,H4VB),
C6VA(H6VA,H6VB)
6.c Aromatic/amide H refined with riding coordinates:
C3NA(H3NA), C0TA(H0TA), C61(H61)
;
_shelx_res_file
;
TITL 20171119d_0ma in C2/c #15
20171119d_0ma_sq.res created by SHELXL-2016/4 at 21:27:44 on 20-Nov-2019
REM reset to C2/c #15
CELL 0.71073 41.694 29.9362 62.17742 90 108.9609 90
ZERR 8 0.0005 0.0004 0.00094 0 0.0006 0
LATT 7
SYMM -X,+Y,0.5-Z
SFAC C H Ag Au Cl F S Sb
UNIT 2240 3248 384 24 56 96 224 16
DFIX 1.55 C9QA C1SA
DFIX 1.55 C9QA C3RA
DFIX 1.55 C9QA C2RA
DFIX 1.55 C1SA C5UA
DFIX 1.55 C0VA C9UA
DFIX 1.55 C9UA C5UA
DFIX 1.55 C5UA C8UA
DFIX 1.55 C8UA C7UA
DFIX 1.55 C7UA C217
DFIX 1.55 C217 C0VA
DFIX 1.55 C2RA C0VA
DFIX 1.55 C3RA C7UA
DFIX 1.55 C3RA C9QA
DFIX 1.55 C2RA C9QA
DFIX 1.55 C1SA C9QA
DFIX 2.55 C2RA C1SA
DFIX 2.55 C2RA C3RA
DFIX 2.55 C3RA C1SA
DFIX 3 C217 C5UA
DFIX 3 C0VA C8UA
DFIX 3 C9UA C7UA
DFIX 1.815 0.01 Sb2 F75
DFIX 2.63 0.01 F21 F75
DFIX 2.345 0.01 F75 F22
DFIX 2.602 0.01 F9 F75
DFIX 2.563 0.01 F7 F75
DFIX 1.5 0.01 C3NA C254
DFIX 1.5 0.01 C7NA C254
DFIX 1.5 0.01 C9NA C254
DFIX 1.55 0.01 C68 C74
DFIX 1.55 0.01 C1UA C0UA
DFIX 1.55 0.01 C3UA C0UA
DFIX 1.55 0.01 C5RA C2SA
DFIX 1.55 0.01 C9JA C9TA
DFIX 1.55 0.01 C9JA C3VA
DFIX 1.55 0.01 C9JA C8TA
DFIX 1.55 0.01 C9TA C0UA
DFIX 1.55 0.01 C0UA C1UA
DFIX 1.55 0.01 C1UA C2UA
DFIX 1.55 0.01 C2UA C74
DFIX 1.55 0.01 C74 C68
DFIX 1.55 0.01 C68 C3UA
DFIX 1.55 0.01 C3VA C68
DFIX 3 0.01 C3UA C2UA
DFIX 3 0.01 C1UA C68
DFIX 3 0.01 C74 C0UA
DFIX 2.52 0.01 C3VA C9TA
DFIX 2.52 0.01 C9TA C8TA
DFIX 2.52 0.01 C8TA C3VA
DFIX 1.85 Sb4 F2
DFIX 1.85 Sb4 F1AA
DFIX 2.5 F2 F69
DFIX 2.5 F2 F58
DFIX 2.5 F1AA F2
DFIX 2.5 F2 F61
DFIX 1.81 Sb3 F0AA
DFIX 2.447 0.01 C0SA C2SA
DFIX 2.636 0.01 C2SA C3SA
FLAT F13 F69 Sb4 F2 F58
FLAT F61 F13 Sb4 F2 F1AA
FLAT F0AA Sb3 F78 F32 F95
FLAT C3SA C4UA C99 C2SA
FLAT C4UA C3SA C6UA C0SA
FLAT C6UA C0SA C2SA C99
SIMU 0.001 0.0005 2 S16 C9JA C3VA C9TA C8TA C2UA C74 C68 C3UA C0UA C1UA
SIMU 0.001 0.0005 2 S28 C5RA C2SA C0SA C3SA C4UA C4NA C6UA C75 C241 C99
L.S. 10
PLAN 20
TEMP 23
bloc 1
bloc 1
ABIN
fmap 2
ACTA
OMIT 0 53
OMIT 8 0 6
OMIT -5 1 6
OMIT 3 1 1
OMIT -2 4 4
OMIT -5 1 7
OMIT 9 1 0
OMIT -6 2 2
OMIT 3 1 8
OMIT -8 2 2
OMIT -7 3 6
OMIT 1 1 1
OMIT 0 0 2
OMIT -1 1 2
OMIT 1 1 0
OMIT -2 0 2
OMIT -1 1 1
OMIT 2 0 0
OMIT -4 2 4
OMIT 4 2 9
OMIT -3 5 8
OMIT -2 4 10
OMIT 4 0 6
OMIT 2 0 4
OMIT 0 2 6
OMIT -8 2 13
OMIT -4 4 6
OMIT 1 5 2
OMIT -4 4 12
OMIT 9 3 0
OMIT 2 2 4
OMIT 1 5 8
OMIT 1 1 8
OMIT -6 0 10
OMIT -10 4 8
OMIT -1 1 3
OMIT -3 1 4
OMIT -5 5 9
OMIT 4 6 4
OMIT 3 1 2
OMIT 6 0 4
OMIT 4 0 4
OMIT -1 3 7
OMIT -4 0 6
OMIT 2 4 3
OMIT -2 2 4
OMIT 8 0 4
OMIT 4 0 2
OMIT 1 1 2
OMIT -7 1 9
OMIT -2 2 8
OMIT 5 1 3
OMIT -4 2 1
OMIT -5 3 1
OMIT 5 1 0
OMIT -2 0 6
OMIT 1 5 4
OMIT -2 2 10
OMIT -4 2 5
OMIT 1 3 9
OMIT 3 3 5
OMIT 1 1 6
OMIT 2 2 1
OMIT 3 3 1
OMIT 0 4 6
OMIT 4 4 1
OMIT -3 1 8
OMIT -1 3 3
OMIT 2 2 9
OMIT 3 1 5
OMIT -5 1 8
OMIT 0 0 6
OMIT -2 2 9
OMIT -6 0 2
OMIT 1 5 0
OMIT 6 0 2
OMIT -3 1 2
OMIT 0 2 5
OMIT 1 5 5
OMIT 0 2 7
OMIT 1 3 3
OMIT 1 3 6
OMIT -3 1 7
OMIT -5 1 4
OMIT -5 1 1
OMIT -3 7 2
OMIT -6 2 12
OMIT 5 1 11
OMIT 1 3 1
OMIT -3 5 2
OMIT -1 1 7
OMIT -1 7 1
OMIT 3 5 4
OMIT -4 4 3
OMIT 0 2 8
OMIT -2 2 17
OMIT -1 3 2
OMIT 7 7 0
OMIT -1 5 9
OMIT -2 0 10
OMIT -1 5 7
REM
REM
REM