#------------------------------------------------------------------------------ #$Date: 2024-12-06 19:30:37 +0200 (Fri, 06 Dec 2024) $ #$Revision: 296463 $ #$URL: file:///home/coder/svn-repositories/cod/cif/7/24/93/7249336.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_7249336 loop_ _publ_author_name 'Rozhkov, Anton V.' 'Tupikina, Elena Yu.' 'Tugashov, Kirill I.' 'Kukushkin, Vadim Yu.' _publ_section_title ; Pure heterometallic spodium bonding ; _journal_issue 39 _journal_name_full CrystEngComm _journal_page_first 5607 _journal_page_last 5616 _journal_paper_doi 10.1039/D4CE00825A _journal_volume 26 _journal_year 2024 _chemical_formula_moiety 'C22 H14 F10 Hg O4 Pd' _chemical_formula_sum 'C22 H14 F10 Hg O4 Pd' _chemical_formula_weight 839.32 _space_group_crystal_system monoclinic _space_group_IT_number 12 _space_group_name_Hall '-I 2y' _space_group_name_H-M_alt 'I 1 2/m 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _audit_creation_date 2024-02-28 _audit_creation_method ; Olex2 1.5 (compiled 2023.08.24 svn.re1ec1418 for OlexSys, GUI svn.r6817) ; _audit_update_record ; 2024-04-02 deposited with the CCDC. 2024-09-13 downloaded from the CCDC. ; _cell_angle_alpha 90 _cell_angle_beta 99.161(7) _cell_angle_gamma 90 _cell_formula_units_Z 2 _cell_length_a 11.8573(9) _cell_length_b 6.2066(5) _cell_length_c 15.9257(12) _cell_measurement_reflns_used 2809 _cell_measurement_temperature 100(2) _cell_measurement_theta_max 76.4250 _cell_measurement_theta_min 4.3320 _cell_volume 1157.08(16) _computing_cell_refinement 'CrysAlisPro 1.171.41.103a (Rigaku OD, 2021)' _computing_data_collection 'CrysAlisPro 1.171.41.103a (Rigaku OD, 2021)' _computing_data_reduction 'CrysAlisPro 1.171.41.103a (Rigaku OD, 2021)' _computing_molecular_graphics 'Olex2 1.5 (Dolomanov et al., 2009)' _computing_publication_material 'Olex2 1.5 (Dolomanov et al., 2009)' _computing_structure_refinement 'SHELXL 2018/3 (Sheldrick, 2015)' _computing_structure_solution 'SHELXT 2018/2 (Sheldrick, 2018)' _diffrn_ambient_environment N~2~ _diffrn_ambient_temperature 100(2) _diffrn_detector 'Hybrid Pixel Array Detector' _diffrn_detector_area_resol_mean 10.0000 _diffrn_detector_type HyPix _diffrn_measured_fraction_theta_full 0.980 _diffrn_measured_fraction_theta_max 0.960 _diffrn_measurement_details ; List of Runs (angles in degrees, time in seconds): # Type Start End Width t~exp~ \w \q \k \f Frames #-------------------------------------------------------------------------- 1 \w 48.00 73.00 0.50 0.40 -- 47.12 76.00-114.00 50 2 \w 101.00 129.00 0.50 1.40 -- 105.95 30.00-150.00 56 3 \w 139.00 174.00 0.50 1.40 -- 105.95 30.00-150.00 70 4 \w 153.00 178.00 0.50 1.40 -- 105.95 30.00-180.00 50 5 \w 113.00 139.00 0.50 1.40 -- 105.95 30.00-180.00 52 6 \w 85.00 161.00 0.50 1.40 -- 105.95 76.00-114.00 152 7 \w 153.00 178.00 0.50 1.40 -- 105.95 45.00 150.00 50 8 \w 107.00 132.00 0.50 1.40 -- 105.95 45.00 150.00 50 9 \w 36.00 67.00 0.50 1.40 -- 105.95 -61.00 30.00 62 10 \w 33.00 95.00 0.50 1.40 -- 105.95 -76.00 118.00 124 11 \w -15.00 67.00 0.50 0.40 -- 47.12 -76.00 118.00 164 12 \w 78.00 120.00 0.50 0.40 -- 47.12 125.00 90.00 84 13 \w -67.00 -34.00 0.50 1.40 -- -105.95 61.00 30.00 66 14 \w -103.00 -70.00 0.50 1.40 -- -105.95 77.00 90.00 66 15 \w -67.00 -34.00 0.50 1.40 -- -105.95 77.00 90.00 66 16 \w -49.00 21.00 0.50 0.40 -- -47.12 76.00-114.00 140 17 \w -92.00 -43.00 0.50 1.40 -- -105.95 76.00-114.00 98 18 \w -177.00 -97.00 0.50 1.40 -- -105.95 -61.00 60.00 160 19 \w -173.00-147.00 0.50 1.40 -- -105.95 -76.00 118.00 52 20 \w -92.00 -26.00 0.50 0.40 -- -47.12 -76.00 118.00 132 ; _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'XtaLAB Synergy, Single source at home/near, HyPix' _diffrn_measurement_method '\w scans' _diffrn_orient_matrix_type 'CrysAlisPro convention (1999,Acta A55,543-557)' _diffrn_orient_matrix_UB_11 -0.0615578000 _diffrn_orient_matrix_UB_12 0.2059656000 _diffrn_orient_matrix_UB_13 0.0227878000 _diffrn_orient_matrix_UB_21 0.0768016000 _diffrn_orient_matrix_UB_22 0.0070953000 _diffrn_orient_matrix_UB_23 0.0876355000 _diffrn_orient_matrix_UB_31 0.0875952000 _diffrn_orient_matrix_UB_32 0.1379428000 _diffrn_orient_matrix_UB_33 -0.0373729000 _diffrn_radiation_monochromator mirror _diffrn_radiation_probe x-ray _diffrn_radiation_type 'Cu K\a' _diffrn_radiation_wavelength 1.54184 _diffrn_reflns_av_R_equivalents 0.0620 _diffrn_reflns_av_unetI/netI 0.0449 _diffrn_reflns_Laue_measured_fraction_full 0.980 _diffrn_reflns_Laue_measured_fraction_max 0.960 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_h_min -14 _diffrn_reflns_limit_k_max 7 _diffrn_reflns_limit_k_min -6 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_limit_l_min -19 _diffrn_reflns_number 3301 _diffrn_reflns_point_group_measured_fraction_full 0.980 _diffrn_reflns_point_group_measured_fraction_max 0.960 _diffrn_reflns_theta_full 67.684 _diffrn_reflns_theta_max 72.390 _diffrn_reflns_theta_min 4.335 _diffrn_source 'micro-focus sealed X-ray tube' _diffrn_source_type 'PhotonJet (Cu) X-ray Source' _exptl_absorpt_coefficient_mu 19.045 _exptl_absorpt_correction_T_max 1.00000 _exptl_absorpt_correction_T_min 0.20948 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; CrysAlisPro 1.171.41.103a (Rigaku Oxford Diffraction, 2021) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm. ; _exptl_crystal_colour 'clear yellow' _exptl_crystal_colour_lustre clear _exptl_crystal_colour_primary yellow _exptl_crystal_density_diffrn 2.409 _exptl_crystal_description prism _exptl_crystal_F_000 788 _exptl_crystal_size_max 0.12 _exptl_crystal_size_mid 0.04 _exptl_crystal_size_min 0.02 _refine_diff_density_max 0.236 _refine_diff_density_min -0.215 _refine_diff_density_rms 0.020 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.189 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 121 _refine_ls_number_reflns 1210 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.189 _refine_ls_R_factor_all 0.0408 _refine_ls_R_factor_gt 0.0405 _refine_ls_shift/su_max 0.003 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0787P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1134 _refine_ls_wR_factor_ref 0.1137 _reflns_Friedel_coverage 0.000 _reflns_number_gt 1172 _reflns_number_total 1210 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file d4ce00825a2.cif _cod_data_source_block 0ver0-24446_zmv-018 _cod_depositor_comments 'Adding full bibliography for 7249336--7249337.cif.' _cod_database_code 7249336 _shelx_shelxl_version_number 2018/3 _chemical_oxdiff_formula 'C22 H14 F10 Hg O4 Pd' _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_max 0.702 _shelx_estimated_absorpt_t_min 0.208 _olex2_refinement_description ; 1. Others Fixed Sof: H1A(0.5) H1B(0.5) H1C(0.5) H5A(0.5) H5B(0.5) H5C(0.5) 2.a Aromatic/amide H refined with riding coordinates: C3(H3) 2.b Idealised Me refined as rotating group: C1(H1A,H1B,H1C), C5(H5A,H5B,H5C) ; _shelx_res_file ; TITL 0ver0-24446_zmv-018_a.res in I2/m 0ver0-24446_zmv-018.res created by SHELXL-2018/3 at 22:39:59 on 28-Feb-2024 REM Old TITL 24446_ZMV-018_auto in I2 REM SHELXT solution in I2/m: R1 0.098, Rweak 0.007, Alpha 0.029 REM 0.000 for 0 systematic absences, Orientation as input REM Formula found by SHELXT: C20 O6 F10 Pd Hg CELL 1.54184 11.8573 6.2066 15.9257 90 99.161 90 ZERR 2 0.0009 0.0005 0.0012 0 0.007 0 LATT 2 SYMM -X,+Y,-Z SFAC C H F Hg O Pd UNIT 44 28 20 2 8 2 L.S. 99 PLAN 5 SIZE 0.12 0.04 0.02 TEMP -173(2) CONF BOND list 4 MORE -1 BOND $H fmap 2 53 acta OMIT -4 145 OMIT -6 4 16 OMIT 0 6 12 OMIT 2 4 0 OMIT 5 6 7 REM REM REM WGHT 0.078700 SWAT 0.927590 0.0021 FVAR 1.71140 HG1D 4 0.000000 0.500000 1.000000 10.25000 0.04108 0.03027 = 0.04677 0.00000 0.00638 0.00000 PD1 6 0.000000 0.000000 1.000000 10.25000 0.03439 0.02845 = 0.04011 0.00000 0.00316 0.00000 F1D 3 -0.037056 0.500000 0.799160 10.50000 0.04304 0.04886 = 0.05340 0.00000 -0.00053 0.00000 O1 5 0.023110 0.000000 1.126607 10.50000 0.03554 0.04253 = 0.04506 0.00000 0.00189 0.00000 F4D 3 0.421267 0.500000 0.911113 10.50000 0.04220 0.05570 = 0.06398 0.00000 0.00520 0.00000 O2 5 -0.165881 0.000000 1.007691 10.50000 0.03743 0.03388 = 0.04396 0.00000 0.00228 0.00000 F3D 3 0.339513 0.500000 0.741325 10.50000 0.05292 0.05398 = 0.06035 0.00000 0.01749 0.00000 F5D 3 0.273799 0.500000 1.024295 10.50000 0.04897 0.05728 = 0.04517 0.00000 0.00112 0.00000 F2D 3 0.110800 0.500000 0.685927 10.50000 0.05840 0.06323 = 0.04284 0.00000 0.00361 0.00000 C1 1 0.120166 0.000000 1.266600 10.50000 0.04813 0.04450 = 0.04383 0.00000 0.00344 0.00000 PART -1 AFIX 137 H1A 2 0.068746 0.113661 1.280402 10.50000 -1.50000 H1B 2 0.197376 0.026426 1.297194 10.50000 -1.50000 H1C 2 0.093010 -0.140087 1.283570 10.50000 -1.50000 AFIX 0 PART 0 C1D 1 0.114352 0.500000 0.914327 10.50000 0.04488 0.02912 = 0.04382 0.00000 0.00789 0.00000 C2 1 0.122289 0.000000 1.171286 10.50000 0.04151 0.02923 = 0.04367 0.00000 -0.00029 0.00000 C5 1 -0.363755 0.000000 0.962142 10.50000 0.03381 0.05370 = 0.05864 0.00000 0.00536 0.00000 PART -1 AFIX 137 H5A 2 -0.362623 0.043918 1.021378 10.50000 -1.50000 H5B 2 -0.396107 -0.145143 0.953667 10.50000 -1.50000 H5C 2 -0.410634 0.101225 0.924289 10.50000 -1.50000 AFIX 0 PART 0 C2D 1 0.076701 0.500000 0.828426 10.50000 0.04064 0.03116 = 0.05155 0.00000 0.00036 0.00000 C3D 1 0.150447 0.500000 0.770117 10.50000 0.05041 0.04247 = 0.04569 0.00000 0.00566 0.00000 C5D 1 0.308906 0.500000 0.884115 10.50000 0.03875 0.03770 = 0.05712 0.00000 0.00952 0.00000 C6D 1 0.231980 0.500000 0.940680 10.50000 0.04486 0.03645 = 0.05055 0.00000 -0.00027 0.00000 C3 1 0.226654 0.000000 1.142908 10.50000 0.03490 0.03936 = 0.04941 0.00000 -0.00161 0.00000 AFIX 43 H3 2 0.293193 0.000000 1.184947 10.50000 -1.20000 AFIX 0 C4D 1 0.268253 0.500000 0.797097 10.50000 0.04708 0.03407 = 0.05543 0.00000 0.01153 0.00000 C4 1 -0.242928 0.000000 0.942172 10.50000 0.03741 0.03313 = 0.05858 0.00000 0.00434 0.00000 HKLF 4 REM 0ver0-24446_zmv-018_a.res in I2/m REM wR2 = 0.1137, GooF = S = 1.189, Restrained GooF = 1.189 for all data REM R1 = 0.0405 for 1172 Fo > 4sig(Fo) and 0.0408 for all 1210 data REM 121 parameters refined using 0 restraints END WGHT 0.0787 0.0000 REM Highest difference peak 0.236, deepest hole -0.215, 1-sigma level 0.020 Q1 1 0.0247 0.5000 0.9532 10.50000 0.05 0.24 Q2 1 0.0000 0.3558 1.0000 10.50000 0.05 0.20 Q3 1 -0.0637 0.5000 0.9573 10.50000 0.05 0.15 Q4 1 0.0226 0.0000 0.9545 10.50000 0.05 0.14 Q5 1 0.0000 -0.1637 1.0000 10.50000 0.05 0.12 ; _shelx_res_checksum 24326 _shelx_hkl_file ; 0 -6 -8 88.06 3.30 0 -6 -10 70.73 2.67 0 -6 -12 51.78 1.88 0 -5 -5 9.95 0.95 0 -5 -7 0.21 0.43 0 -5 -9 17.72 1.34 0 -5 -11 9.77 0.94 0 -5 -13 5.66 0.66 0 -4 -4 320.42 9.90 0 -4 -6 240.31 7.82 0 -4 -8 192.09 6.60 0 -4 -10 167.68 6.01 0 -4 -12 115.07 4.44 0 -4 -14 69.01 2.87 0 -4 -16 68.17 2.48 0 -3 -9 40.88 2.09 0 -3 -11 19.72 1.43 0 -3 -13 9.88 1.03 0 -3 -15 1.54 0.51 0 -2 -2 415.29 11.97 0 -2 -4 708.59 20.77 0 -2 4 718.46 20.93 0 -2 -6 444.54 13.53 0 -2 6 434.06 13.66 0 -2 -8 303.42 10.09 0 -2 8 300.04 10.29 0 -2 -10 310.18 10.94 0 -2 -12 209.87 8.42 0 -2 -12 198.54 6.90 0 -2 -14 109.19 4.23 0 -2 16 125.19 4.35 0 -2 -16 124.83 4.31 0 -2 18 50.20 1.90 0 -2 -18 52.25 1.87 0 -1 -1 68.53 2.12 0 -1 1 71.84 2.18 0 -1 3 26.12 1.22 0 -1 5 22.23 1.34 0 -1 -5 22.93 1.30 0 -1 -7 28.36 1.76 0 -1 7 26.07 1.75 0 -1 9 66.39 3.50 0 -1 -9 71.97 3.52 0 -1 -11 25.97 2.19 0 -1 -11 25.72 1.48 0 -1 11 20.47 2.08 0 -1 -13 15.43 1.99 0 -1 -13 15.24 1.22 0 -1 17 0.39 0.39 0 -1 -17 0.16 0.36 0 -1 -19 2.88 0.36 0 -1 19 2.19 0.35 0 0 -2 515.47 14.71 0 0 -4 1136.01 32.37 0 0 6 572.60 16.82 0 0 -6 596.00 16.78 0 0 -8 402.96 13.04 0 0 8 397.08 13.02 0 0 10 360.99 13.02 0 0 -10 414.60 13.33 0 0 12 199.51 8.91 0 0 -12 259.30 9.50 0 0 -14 146.46 7.25 0 0 -18 70.78 2.74 0 1 1 79.95 2.33 0 1 1 89.43 2.43 0 1 -1 74.49 2.58 0 1 -1 64.83 2.26 0 1 3 28.30 1.32 0 1 -5 23.50 1.40 0 1 5 24.35 1.45 0 1 -7 27.52 1.67 0 1 7 28.77 1.90 0 1 -7 31.99 1.97 0 1 -9 79.45 3.88 0 1 9 68.50 3.68 0 1 11 28.96 2.47 0 1 -11 29.77 2.51 0 1 13 17.27 1.61 0 1 -13 18.92 2.35 0 1 15 1.42 0.79 0 1 17 0.27 0.41 0 1 -17 -0.04 0.45 0 1 -19 2.83 0.42 0 1 19 2.00 0.35 0 2 0 4884.89 138.62 0 2 -2 491.65 14.95 0 2 -2 480.18 14.20 0 2 2 513.76 14.46 0 2 -4 764.78 22.45 0 2 4 768.93 22.63 0 2 -6 473.11 15.43 0 2 -6 487.84 15.23 0 2 6 515.35 15.46 0 2 -8 340.96 11.83 0 2 -8 346.03 11.99 0 2 8 366.16 12.09 0 2 10 361.09 11.67 0 2 -10 356.99 13.04 0 2 10 379.63 11.88 0 2 12 213.80 8.01 0 2 -12 231.88 9.68 0 2 -14 126.31 6.81 0 2 14 122.51 4.51 0 2 14 128.73 5.23 0 2 16 133.18 5.12 0 2 -16 146.62 4.83 0 3 1 52.67 2.58 0 3 -1 54.52 2.75 0 3 -3 32.85 2.21 0 3 -5 14.31 1.10 0 3 7 5.79 0.80 0 3 -7 5.00 0.86 0 3 -7 5.61 1.29 0 3 7 6.07 0.95 0 3 -7 5.76 1.42 0 3 -9 42.28 3.04 0 3 9 47.77 2.82 0 3 11 22.29 1.86 0 3 -11 24.23 2.51 0 3 13 11.74 1.55 0 3 15 2.27 0.85 0 3 17 0.04 0.50 0 4 0 2196.30 64.62 0 4 -2 369.45 13.06 0 4 -2 362.14 11.00 0 4 -4 491.50 14.60 0 4 4 477.44 14.96 0 4 4 480.29 14.87 0 4 -4 490.36 15.63 0 4 -4 480.84 17.02 0 4 6 343.62 11.65 0 4 -6 360.99 13.79 0 4 6 338.26 11.10 0 4 -6 348.92 12.23 0 4 -8 235.44 9.96 0 4 8 251.52 8.61 0 4 8 248.94 9.18 0 4 10 205.05 8.33 0 4 10 217.69 7.96 0 4 12 150.22 6.18 0 4 14 82.06 3.72 0 4 14 80.18 3.83 0 4 16 83.23 3.29 0 5 1 38.83 1.94 0 5 1 38.22 2.35 0 5 -1 39.99 2.06 0 5 3 21.17 1.66 0 5 3 22.48 2.15 0 5 -3 20.44 2.23 0 5 3 20.45 1.30 0 5 -3 21.86 1.58 0 5 -5 14.13 2.23 0 5 5 18.14 2.01 0 5 5 16.36 1.57 0 5 -7 1.43 1.54 0 5 7 1.07 0.77 0 5 7 0.81 1.12 0 5 9 30.56 2.68 0 5 11 15.14 1.66 0 5 13 6.38 1.02 0 5 13 6.42 1.09 0 6 0 1055.17 31.46 0 6 0 1101.28 33.50 0 6 0 1046.81 33.24 0 6 2 234.47 9.83 0 6 -2 258.13 10.31 0 6 2 251.60 8.21 0 6 -2 242.94 9.71 0 6 -4 291.84 11.77 0 6 4 285.28 11.16 0 6 6 213.46 8.94 0 6 6 201.16 8.03 0 6 8 158.09 6.45 0 6 10 109.85 4.76 0 7 -1 20.55 2.89 0 7 1 20.34 2.64 0 7 3 10.03 2.04 0 7 3 7.96 1.79 0 7 -3 11.43 2.54 0 7 5 10.11 1.65 1 -6 -11 59.58 2.25 1 -6 -9 107.75 3.82 1 -6 -7 140.96 4.83 -1 -6 -7 78.37 3.01 -1 -6 -9 60.57 2.42 -1 -6 -11 64.10 2.33 1 -5 -14 6.21 0.64 1 -5 -12 11.73 1.00 1 -5 -10 21.96 1.47 1 -5 -8 0.52 0.41 1 -5 -6 27.14 1.60 1 -5 -4 12.09 0.99 -1 -5 -4 29.77 1.62 -1 -5 -6 13.60 1.14 -1 -5 -8 0.66 0.48 -1 -5 -10 3.95 0.71 -1 -5 -12 0.14 0.42 -1 -5 -14 0.62 0.29 1 -4 -15 87.99 3.30 1 -4 -11 130.59 4.93 1 -4 -9 260.03 8.59 1 -4 -7 319.07 10.10 1 -4 -5 265.88 8.43 -1 -4 -9 122.30 4.68 -1 -4 -11 123.40 4.73 -1 -4 -15 73.31 2.78 1 -3 -16 4.98 0.66 -1 -3 14 14.44 1.00 1 -3 -14 14.04 1.18 1 -3 -12 20.18 1.46 1 -3 -8 0.32 0.38 -1 -3 -12 0.43 0.52 1 -3 14 0.41 0.38 -1 -3 -14 0.47 0.50 -1 -2 17 77.18 2.86 1 -2 -17 77.78 2.84 1 -2 -15 151.08 5.40 1 -2 -15 151.16 5.17 1 -2 -13 150.11 5.45 1 -2 -13 149.38 6.81 1 -2 -11 214.59 8.32 -1 -2 11 200.95 8.32 1 -2 -11 212.84 7.08 -1 -2 9 508.12 16.50 1 -2 -9 506.51 15.33 1 -2 -9 517.61 16.39 1 -2 -7 703.87 21.27 -1 -2 7 703.03 21.42 1 -2 -5 556.45 16.49 -1 -2 5 546.51 16.58 1 -2 -3 496.62 14.57 -1 -2 1 434.72 12.54 1 -2 1 964.62 27.60 -1 -2 -5 670.52 19.90 -1 -2 -7 281.09 9.40 -1 -2 -9 191.31 7.27 -1 -2 -11 169.01 7.05 -1 -2 -13 192.70 8.37 -1 -2 -13 197.06 6.89 1 -2 13 205.01 6.62 1 -2 15 117.26 4.10 -1 -2 -15 108.22 4.17 -1 -2 -17 103.19 3.43 1 -2 17 97.63 3.44 -1 -1 18 6.78 0.70 1 -1 -18 8.34 0.72 1 -1 -16 9.24 0.87 1 -1 -14 23.54 2.43 1 -1 -14 19.86 1.42 1 -1 -12 33.65 1.82 1 -1 -12 32.93 2.74 -1 -1 12 31.70 2.67 -1 -1 10 91.02 4.45 1 -1 -10 90.34 4.36 -1 -1 8 5.35 0.90 1 -1 -8 5.80 0.86 1 -1 -6 189.87 6.37 1 -1 -4 22.57 1.16 1 -1 -2 72.98 2.42 1 -1 0 26.68 1.11 -1 -1 0 25.72 1.17 -1 -1 -2 236.21 7.40 1 -1 4 172.76 5.69 -1 -1 -4 165.80 5.91 1 -1 6 41.35 2.21 1 -1 8 33.92 2.25 -1 -1 -8 33.96 2.17 -1 -1 -10 7.23 1.16 -1 -1 -12 0.89 0.45 -1 -1 -12 1.32 0.65 1 -1 14 0.40 0.48 -1 -1 -14 0.20 0.39 -1 -1 -14 0.39 0.58 1 -1 16 1.93 0.54 1 -1 18 0.11 0.32 -1 -1 -18 0.27 0.28 1 0 -19 65.61 2.44 1 0 -17 100.68 3.80 1 0 -15 205.54 9.13 1 0 -13 220.21 9.35 -1 0 11 230.94 9.51 1 0 -11 285.56 9.97 1 0 -9 709.42 20.97 -1 0 9 633.73 20.84 1 0 -7 999.27 29.55 1 0 -5 724.49 21.33 1 0 -3 649.11 18.82 1 0 -1 668.10 18.94 1 0 -1 650.96 18.87 -1 0 -1 1211.23 34.84 1 0 3 376.17 10.69 -1 0 -3 321.50 10.88 1 0 5 876.08 23.89 -1 0 -5 768.55 23.29 1 0 7 297.26 10.37 -1 0 -7 322.50 9.56 1 0 9 227.13 8.89 -1 0 -9 268.74 9.17 1 0 11 217.84 7.67 -1 0 -11 223.96 8.86 1 0 13 253.27 8.84 -1 0 -13 250.94 10.28 -1 0 -19 77.89 2.69 1 1 -18 8.05 0.79 -1 1 18 6.28 0.66 1 1 -16 9.10 0.95 -1 1 14 27.41 1.99 1 1 -14 24.98 2.73 -1 1 12 28.71 2.58 1 1 -12 39.67 3.12 -1 1 10 96.81 4.79 1 1 -10 104.87 4.97 1 1 -8 5.33 0.93 -1 1 8 5.52 0.88 1 1 -6 180.82 6.38 1 1 -6 194.96 6.46 1 1 -4 21.98 1.19 1 1 -4 22.35 1.33 1 1 -2 71.83 2.42 1 1 0 27.85 1.20 -1 1 0 25.80 1.25 -1 1 -2 240.82 7.63 -1 1 -4 164.52 6.18 1 1 4 175.46 5.97 -1 1 -6 47.96 2.29 1 1 6 42.22 2.35 -1 1 -8 37.03 2.38 -1 1 -8 31.75 1.98 1 1 8 35.80 2.35 1 1 10 7.16 1.10 -1 1 -10 7.60 1.29 -1 1 -12 0.76 0.69 1 1 12 1.17 0.78 1 1 14 0.88 0.55 1 1 14 0.46 0.78 -1 1 -14 0.30 0.72 1 1 16 1.52 0.75 1 1 16 1.30 0.50 -1 1 -18 0.29 0.33 1 1 18 0.11 0.33 -1 2 17 87.06 3.52 -1 2 15 183.40 6.74 1 2 -15 177.09 6.24 -1 2 13 164.52 6.58 1 2 -13 185.36 8.36 -1 2 11 269.38 8.79 -1 2 11 261.50 8.91 1 2 -11 264.36 10.41 -1 2 11 245.17 10.06 1 2 -9 604.49 18.92 -1 2 9 602.25 17.52 1 2 -7 834.07 24.63 1 2 -7 758.33 24.13 -1 2 7 807.54 24.29 1 2 -5 602.37 19.00 1 2 -5 605.63 18.60 -1 2 5 652.14 18.74 1 2 -3 509.58 14.66 1 2 -3 527.84 15.36 -1 2 1 510.97 15.07 1 2 -1 503.35 15.63 -1 2 -1 1279.73 36.20 1 2 1 1222.73 35.46 -1 2 -5 681.53 21.63 -1 2 -5 728.46 21.26 -1 2 -7 317.25 10.83 1 2 9 239.02 7.99 -1 2 -9 238.68 9.02 -1 2 -9 216.53 8.61 -1 2 -11 185.63 8.29 1 2 11 199.35 7.35 1 2 13 223.12 8.02 -1 2 -13 235.59 10.02 1 2 13 212.61 7.21 1 2 15 122.43 5.03 1 2 15 123.15 4.42 1 2 17 100.34 3.88 -1 3 16 6.31 0.99 -1 3 14 18.14 1.74 1 3 -12 23.76 1.51 -1 3 12 25.25 1.97 -1 3 10 66.24 3.12 1 3 -10 64.38 4.03 -1 3 10 64.43 3.42 -1 3 8 0.87 0.64 1 3 -8 0.39 0.44 1 3 -6 100.75 4.14 1 3 -4 32.78 2.43 1 3 -2 18.47 1.69 -1 3 0 23.94 1.74 -1 3 -2 101.74 4.50 -1 3 -4 80.24 3.12 -1 3 -4 103.60 4.56 -1 3 -6 29.24 2.19 -1 3 -6 30.16 1.92 1 3 8 10.71 1.38 1 3 8 10.15 1.11 -1 3 -8 8.43 1.26 -1 3 -8 8.66 1.67 -1 3 -10 7.50 1.81 1 3 10 5.97 1.14 -1 3 -10 6.83 1.35 1 3 12 1.21 0.80 1 3 12 0.48 0.85 1 3 14 0.79 0.79 1 3 16 0.89 0.67 -1 4 15 110.85 4.43 -1 4 13 113.14 4.93 -1 4 11 176.36 6.85 -1 4 9 362.57 12.31 -1 4 9 351.21 11.74 1 4 -7 438.66 13.68 -1 4 7 450.98 14.08 -1 4 5 392.10 12.41 -1 4 5 390.01 12.35 -1 4 3 358.42 11.24 1 4 -3 355.82 10.86 -1 4 1 320.56 9.00 1 4 -1 188.91 7.58 -1 4 -1 261.41 11.19 -1 4 -1 595.28 13.59 1 4 3 237.36 8.43 -1 4 -3 260.39 8.56 -1 4 -3 219.22 9.34 -1 4 -3 247.75 7.69 1 4 3 235.32 7.40 -1 4 -5 460.84 15.25 -1 4 -5 441.07 16.48 1 4 5 456.96 14.40 1 4 5 483.19 15.11 1 4 7 217.68 7.62 -1 4 -7 209.62 8.68 1 4 7 215.46 8.27 1 4 9 158.60 6.34 1 4 9 155.71 6.82 1 4 11 149.80 6.24 1 4 13 134.99 5.70 1 4 15 79.90 3.40 -1 5 12 13.14 1.52 -1 5 10 29.07 2.23 -1 5 10 27.44 2.51 -1 5 8 0.68 1.01 -1 5 8 1.10 0.82 -1 5 6 42.30 3.01 -1 5 6 43.95 2.60 -1 5 4 19.25 1.75 1 5 -4 22.19 1.61 -1 5 4 20.09 1.70 -1 5 2 0.17 0.62 -1 5 2 2.45 0.80 1 5 -2 2.85 1.06 1 5 -2 1.77 0.73 -1 5 0 20.35 1.39 -1 5 0 18.72 1.63 1 5 0 19.30 1.36 -1 5 -2 67.76 2.94 1 5 2 68.03 3.76 1 5 2 62.31 2.69 -1 5 -2 66.87 3.78 -1 5 -4 53.11 3.56 -1 5 -4 44.83 4.47 1 5 4 51.93 2.25 -1 5 -6 22.72 2.71 1 5 6 21.80 1.96 1 5 6 23.90 2.38 1 5 8 1.24 0.89 1 5 8 0.99 1.16 1 5 10 4.41 1.10 1 5 12 0.12 0.71 1 5 12 0.14 0.83 1 5 14 0.60 0.57 -1 6 9 178.33 6.90 -1 6 7 252.26 9.87 -1 6 7 251.08 9.24 -1 6 5 221.96 9.11 1 6 -3 241.06 8.43 -1 6 3 236.96 9.63 1 6 -1 256.66 10.41 -1 6 1 266.29 10.50 1 6 -1 272.89 9.06 -1 6 -1 402.23 14.39 -1 6 -1 419.39 14.61 1 6 1 387.90 14.49 1 6 1 401.80 12.71 1 6 3 185.47 8.09 -1 6 -3 184.01 8.29 1 6 3 175.20 6.12 -1 6 -5 292.99 11.47 1 6 5 258.41 9.80 1 6 7 141.47 6.04 1 6 9 90.74 4.29 -1 7 8 0.99 0.71 -1 7 6 11.65 1.59 -1 7 4 11.44 1.83 -1 7 4 10.97 1.95 -1 7 2 0.71 1.42 -1 7 2 -0.21 1.43 -1 7 0 14.88 2.37 -1 7 -2 39.91 3.69 -1 7 -4 25.33 3.16 2 -6 -12 58.40 2.09 2 -6 -10 65.89 2.52 2 -6 -8 86.74 3.23 -2 -6 -6 125.54 4.35 -2 -6 -8 77.59 2.93 -2 -6 -10 101.08 3.45 2 -5 -15 2.65 0.36 2 -5 -13 7.30 0.75 2 -5 -11 21.62 1.42 2 -5 -9 8.38 0.93 2 -5 -7 2.58 0.59 2 -5 -5 31.35 1.70 -2 -5 -5 7.52 0.88 -2 -5 -7 14.41 1.21 -2 -5 -9 1.98 0.57 -2 -5 -11 3.64 0.63 -2 -5 -13 10.42 0.79 2 -4 -16 60.28 2.31 2 -4 -12 159.39 5.76 2 -4 -10 133.11 4.97 2 -4 -8 155.39 5.52 2 -4 -6 167.86 5.71 2 -4 -4 105.04 3.75 -2 -4 -10 257.20 8.63 -2 -4 -14 105.91 3.84 2 -3 -15 7.55 0.87 2 -3 -13 19.51 1.44 2 -3 -9 15.95 1.20 2 -3 -7 0.19 0.34 -2 -3 -13 26.36 1.65 2 -3 13 23.80 1.34 -2 -3 -15 3.41 0.59 2 -2 -18 48.18 1.77 -2 -2 18 43.18 1.79 2 -2 -18 46.74 1.77 2 -2 -16 109.25 3.89 2 -2 -14 56.96 3.96 2 -2 -14 63.36 2.62 2 -2 -14 62.34 2.86 2 -2 -12 278.93 8.94 -2 -2 12 250.46 10.23 2 -2 -12 277.40 10.41 2 -2 -10 219.76 7.28 2 -2 -10 219.47 8.33 -2 -2 10 225.49 8.56 2 -2 -8 271.43 9.30 -2 -2 8 272.33 9.43 2 -2 -6 289.41 9.36 2 -2 -4 154.56 5.22 2 -2 -2 537.69 15.74 -2 -2 0 309.93 10.31 2 -2 0 359.82 10.16 -2 -2 -2 191.98 6.51 2 -2 2 202.53 6.84 -2 -2 -4 376.96 12.07 -2 -2 -8 274.61 9.60 2 -2 10 469.05 13.97 -2 -2 -10 451.59 15.52 2 -2 12 104.19 3.86 -2 -2 -12 105.08 5.26 -2 -2 -14 190.12 6.39 2 -2 14 179.91 6.14 2 -2 16 66.74 2.57 2 -2 18 49.17 1.69 -2 -1 19 1.83 0.37 2 -1 -19 1.82 0.35 2 -1 -17 4.32 0.61 2 -1 -15 11.39 1.01 -2 -1 13 29.13 2.69 2 -1 -13 33.25 2.82 2 -1 -13 30.42 1.79 2 -1 -11 57.60 2.52 -2 -1 11 53.53 3.47 2 -1 -11 58.69 3.48 2 -1 -9 33.63 2.24 2 -1 -7 1.94 0.55 2 -1 -5 164.63 5.58 2 -1 -3 73.68 2.68 2 -1 -3 70.63 2.66 2 -1 -1 1.15 0.42 2 -1 1 139.23 5.00 -2 -1 -1 135.72 4.90 -2 -1 -3 2.60 0.73 -2 -1 -5 6.80 1.05 -2 -1 -9 3.50 0.82 -2 -1 -11 13.08 1.71 -2 -1 -13 31.37 2.83 -2 -1 -13 34.00 1.88 2 -1 13 35.25 1.81 2 -1 15 4.67 0.72 2 -1 17 1.48 0.45 2 0 -20 48.82 1.75 2 0 -18 63.03 2.57 2 0 -16 143.01 5.14 2 0 -14 80.10 4.92 -2 0 12 320.78 12.43 2 0 -12 369.74 12.82 -2 0 10 274.37 10.25 2 0 -10 300.40 10.46 2 0 -8 389.30 12.69 2 0 -6 313.17 10.02 2 0 -4 156.56 5.40 2 0 -4 166.72 5.35 2 0 -2 653.36 18.82 2 0 -2 636.35 18.91 2 0 0 430.38 13.14 -2 0 -2 254.57 8.52 -2 0 -4 549.75 17.19 -2 0 -6 751.55 23.45 -2 0 -8 299.74 9.33 2 0 10 659.64 19.87 -2 0 -10 628.98 20.96 2 0 12 125.46 5.20 -2 0 -12 130.98 6.39 -2 0 -14 244.58 10.03 2 0 14 229.78 8.32 -2 0 -18 83.86 2.98 -2 1 19 1.41 0.36 2 1 -19 1.47 0.37 2 1 -17 3.82 0.67 2 1 -15 13.08 1.15 -2 1 13 30.17 2.75 2 1 -13 34.85 3.08 -2 1 11 59.58 3.72 2 1 -11 61.86 3.84 -2 1 11 64.32 2.82 2 1 -9 31.81 2.29 2 1 -7 2.35 0.62 2 1 -5 167.76 5.74 2 1 -3 69.38 2.64 2 1 -3 67.83 2.59 2 1 -1 1.11 0.46 -2 1 -1 137.94 5.10 -2 1 -3 2.06 0.78 -2 1 -5 6.65 1.10 -2 1 -7 50.34 2.64 -2 1 -9 3.58 0.81 -2 1 -9 5.14 1.01 2 1 9 2.74 0.79 2 1 11 17.25 1.57 -2 1 -11 16.00 2.02 2 1 11 17.71 1.19 2 1 13 39.97 2.47 -2 1 -13 37.75 3.32 2 1 13 35.05 1.89 2 1 15 4.21 0.72 2 1 15 4.15 1.00 2 1 17 1.61 0.44 -2 2 16 125.26 5.01 2 2 -16 134.42 4.79 2 2 -14 76.12 3.28 2 2 -14 82.40 5.36 -2 2 12 348.80 10.86 -2 2 12 324.52 10.65 2 2 -12 331.04 12.62 -2 2 10 247.38 8.29 2 2 -10 261.20 9.77 -2 2 10 257.08 9.67 2 2 -8 315.69 10.59 -2 2 8 292.70 10.45 2 2 -6 301.71 9.89 2 2 -4 158.65 5.44 2 2 -2 528.38 15.55 2 2 0 377.51 11.53 -2 2 0 389.15 11.96 2 2 2 233.75 8.20 -2 2 -2 225.46 7.70 -2 2 -4 445.88 14.39 -2 2 -6 646.85 20.51 2 2 8 342.87 10.86 -2 2 -8 310.01 11.52 -2 2 -8 334.31 11.76 2 2 10 503.30 15.97 -2 2 -10 522.17 17.57 2 2 10 530.03 15.30 2 2 10 493.70 16.18 2 2 12 113.44 5.06 2 2 12 128.54 4.55 -2 2 -12 121.64 6.48 2 2 14 196.14 7.40 2 2 14 203.50 6.74 2 2 16 78.29 3.47 -2 3 17 3.41 0.69 -2 3 15 8.58 1.20 -2 3 15 8.15 1.19 -2 3 13 22.73 1.88 -2 3 11 54.79 2.81 2 3 -11 51.84 3.90 -2 3 9 22.49 1.70 -2 3 9 20.86 1.52 2 3 -9 19.18 2.04 -2 3 9 17.83 1.90 -2 3 9 20.52 1.50 -2 3 7 1.81 0.59 2 3 -7 0.64 0.96 -2 3 7 1.04 0.53 2 3 -7 0.81 0.46 2 3 -7 0.70 0.49 -2 3 5 101.49 3.95 2 3 -5 97.08 3.98 -2 3 3 36.81 2.03 -2 3 1 9.36 1.26 -2 3 -1 88.73 4.27 -2 3 -3 14.54 1.81 -2 3 -3 10.10 0.84 -2 3 -5 8.33 0.97 -2 3 -7 34.46 2.63 2 3 7 37.26 2.47 -2 3 -7 32.08 2.40 2 3 9 2.86 0.97 -2 3 -9 2.56 0.87 -2 3 -9 3.42 1.27 2 3 11 9.85 1.38 -2 3 -11 7.58 1.88 2 3 11 9.02 1.42 2 3 13 29.80 2.16 2 3 15 3.35 0.87 -2 4 16 79.35 3.21 -2 4 14 48.82 2.74 -2 4 12 224.13 8.03 -2 4 12 210.65 7.78 -2 4 10 187.45 7.37 -2 4 8 233.87 8.23 2 4 -8 234.37 9.76 -2 4 8 229.29 8.19 -2 4 8 246.98 8.66 2 4 -6 243.18 7.90 2 4 -6 246.32 9.34 -2 4 6 244.67 8.31 2 4 -4 163.11 6.25 -2 4 4 149.08 5.50 -2 4 2 358.93 12.12 -2 4 2 348.65 11.33 2 4 -2 371.19 11.02 -2 4 0 9999.00 282.90 2 4 2 215.23 7.49 -2 4 -2 205.44 7.09 2 4 2 196.98 6.39 -2 4 -4 308.61 12.23 -2 4 -4 313.33 10.27 -2 4 -4 309.61 10.74 2 4 4 316.19 9.58 2 4 6 381.09 11.66 2 4 6 409.43 12.85 2 4 6 394.81 13.40 -2 4 -6 383.05 13.47 -2 4 -8 218.51 10.31 2 4 10 319.25 10.76 2 4 10 295.03 10.85 2 4 12 89.74 4.43 2 4 14 125.65 4.92 2 4 16 47.39 2.05 -2 5 15 3.63 0.63 -2 5 13 9.23 1.21 -2 5 11 31.42 2.27 -2 5 9 10.70 1.65 -2 5 9 12.09 1.41 2 5 -7 4.61 1.94 -2 5 7 4.09 1.03 -2 5 5 49.19 2.80 -2 5 5 49.96 2.88 2 5 -5 52.08 3.81 2 5 -3 22.53 2.17 -2 5 3 24.82 1.95 2 5 -3 26.90 1.68 -2 5 3 25.52 1.91 2 5 -3 22.15 2.39 2 5 -1 9.67 1.07 -2 5 1 9.91 1.23 2 5 -1 8.69 1.47 -2 5 -1 41.63 2.46 -2 5 -1 39.93 3.75 2 5 1 46.21 3.10 2 5 1 42.53 2.61 2 5 1 50.40 2.28 -2 5 -3 12.36 2.46 2 5 3 13.50 1.87 -2 5 -3 11.14 1.77 2 5 3 12.00 1.53 2 5 3 14.55 1.18 -2 5 -5 11.65 2.00 -2 5 -5 12.08 2.72 2 5 5 12.02 1.04 2 5 5 9.57 1.43 -2 5 -7 21.22 2.78 2 5 7 23.91 2.17 -2 5 -7 23.92 3.64 2 5 7 21.57 1.97 2 5 9 2.66 1.09 2 5 9 2.81 1.00 2 5 11 4.21 1.02 2 5 13 14.00 1.23 2 5 13 13.41 1.09 -2 6 12 96.36 3.90 -2 6 8 163.70 6.98 2 6 -6 174.27 8.58 -2 6 6 163.63 7.25 2 6 -4 139.46 5.47 2 6 -4 128.44 7.08 2 6 -2 237.54 8.26 2 6 -2 234.83 9.94 2 6 0 212.26 7.16 2 6 0 186.05 8.54 -2 6 0 194.60 8.24 2 6 2 167.39 7.83 2 6 2 171.73 6.06 -2 6 -2 178.29 7.69 2 6 4 207.54 6.77 -2 6 -4 203.01 8.87 2 6 4 191.38 8.68 2 6 6 223.36 8.53 2 6 8 130.98 5.64 -2 7 7 3.64 0.94 -2 7 5 23.28 2.06 2 7 -3 17.36 2.89 -2 7 3 15.05 2.23 -2 7 3 15.39 2.01 -2 7 1 3.69 1.59 2 7 -1 4.92 2.02 -2 7 1 3.85 1.61 2 7 1 30.20 3.00 -2 7 -1 28.77 2.94 2 7 3 7.30 1.68 -2 7 -3 10.84 2.22 2 7 5 6.08 1.34 2 7 7 5.57 1.04 2 7 7 8.27 1.11 3 -6 -11 59.61 2.20 3 -6 -9 79.29 2.94 3 -6 -7 91.91 3.34 -3 -6 -7 90.25 3.27 -3 -6 -9 74.63 2.70 3 -5 -14 0.24 0.30 3 -5 -12 3.19 0.60 3 -5 -10 13.20 1.10 3 -5 -8 11.64 1.06 3 -5 -6 34.60 1.83 -3 -5 -6 9.71 1.01 -3 -5 -8 19.37 1.39 -3 -5 -10 8.94 0.90 -3 -5 -12 17.11 1.07 -3 -5 -14 10.07 0.59 3 -4 -15 63.18 2.57 3 -4 -11 133.28 5.00 3 -4 -9 168.61 5.97 3 -4 -7 182.52 6.23 3 -4 -5 203.31 6.67 3 -4 -3 112.31 3.93 -3 -4 -11 90.72 3.71 -3 -4 -15 81.82 2.84 3 -3 -16 6.67 0.75 3 -3 -14 1.47 0.57 3 -3 -12 7.83 0.94 3 -3 -8 27.07 1.54 3 -3 -6 78.14 2.98 -3 -3 -14 29.71 1.64 3 -2 -17 53.46 2.13 3 -2 -15 106.86 3.81 3 -2 -15 98.20 3.99 3 -2 -13 21.21 1.51 3 -2 -13 20.35 2.24 3 -2 -13 24.22 1.37 -3 -2 13 19.17 2.19 3 -2 -11 228.47 7.48 -3 -2 11 220.10 8.87 3 -2 -11 218.17 7.09 3 -2 -11 225.35 8.85 3 -2 -9 283.10 8.77 3 -2 -9 289.65 9.12 3 -2 -9 302.42 10.32 3 -2 -7 343.54 11.34 3 -2 -5 460.71 14.32 3 -2 -3 176.67 5.86 3 -2 -1 567.94 16.95 3 -2 1 683.89 20.02 -3 -2 -1 631.36 20.01 3 -2 3 473.67 16.04 -3 -2 -3 512.73 15.71 -3 -2 -5 414.99 13.77 3 -2 9 239.78 7.62 -3 -2 -9 240.46 9.01 3 -2 11 130.25 4.66 -3 -2 -11 140.12 6.25 -3 -2 -13 100.64 4.01 3 -2 13 103.87 3.83 3 -2 15 140.56 4.76 -3 -2 -17 61.78 2.08 3 -2 17 56.43 2.07 3 -1 -18 5.89 0.62 3 -1 -16 9.95 0.90 3 -1 -14 2.15 0.51 -3 -1 14 2.44 0.87 3 -1 -14 2.41 0.96 3 -1 -14 2.53 0.64 -3 -1 12 9.88 1.58 3 -1 -12 12.57 0.97 3 -1 -12 12.22 1.08 3 -1 -12 12.54 1.70 3 -1 -10 29.00 1.59 3 -1 -10 33.20 2.40 3 -1 -8 47.60 2.65 3 -1 -6 170.20 6.02 3 -1 -4 34.74 1.81 3 -1 -4 35.89 1.82 3 -1 -2 7.51 0.80 3 -1 0 204.47 7.04 -3 -1 -2 11.92 1.36 -3 -1 -4 371.93 12.50 -3 -1 -6 15.92 1.74 3 -1 10 27.32 1.47 -3 -1 -10 29.34 2.44 3 -1 12 53.78 2.42 -3 -1 -12 55.51 3.79 3 -1 14 44.72 2.14 3 -1 16 4.42 0.62 -3 -1 -18 3.36 0.37 3 -1 18 3.04 0.37 3 0 -19 77.78 2.73 3 0 -19 71.18 2.68 3 0 -17 67.54 2.83 3 0 -15 132.38 7.01 3 0 -15 135.91 4.94 3 0 -13 22.91 1.42 3 0 -13 20.82 2.35 3 0 -11 291.62 10.83 3 0 -9 386.69 12.93 3 0 -7 398.70 12.77 3 0 -5 641.82 19.56 3 0 -5 664.68 19.67 3 0 -3 194.92 6.56 3 0 -3 198.13 6.46 3 0 -1 939.83 27.78 3 0 1 886.12 27.09 -3 0 -1 906.42 27.00 -3 0 -3 766.97 23.68 -3 0 -5 566.55 18.40 -3 0 -7 473.31 16.26 3 0 9 300.97 10.02 3 0 11 182.26 6.78 -3 0 -11 169.21 7.72 3 0 13 127.05 5.36 -3 0 -13 132.72 6.64 3 1 -18 6.17 0.71 -3 1 18 5.33 0.63 3 1 -16 11.67 1.06 -3 1 14 2.11 0.93 3 1 -14 3.01 0.65 3 1 -14 1.53 0.92 3 1 -12 12.40 1.02 -3 1 12 13.89 1.23 3 1 -12 12.90 1.83 -3 1 12 10.11 1.66 3 1 -10 35.43 2.63 3 1 -8 45.61 2.68 3 1 -6 159.58 5.81 3 1 -4 34.17 1.82 3 1 -4 33.81 1.84 3 1 -2 7.42 0.86 3 1 0 199.98 7.12 -3 1 -2 12.15 1.59 -3 1 -4 419.31 14.18 -3 1 -6 18.69 2.04 -3 1 -8 84.83 4.00 -3 1 -10 29.81 2.66 3 1 10 30.35 1.61 3 1 10 30.36 2.06 3 1 12 54.78 2.49 -3 1 -12 53.51 4.01 3 1 12 55.78 3.07 3 1 14 51.37 2.37 3 1 14 48.87 2.87 3 1 16 3.83 0.60 -3 1 -18 3.54 0.42 3 1 18 2.45 0.34 3 2 -15 129.99 4.83 -3 2 13 26.72 1.85 -3 2 13 22.28 2.40 3 2 -13 25.48 1.59 3 2 -13 26.43 2.88 -3 2 11 249.50 10.10 3 2 -11 267.28 10.52 3 2 -11 267.12 8.39 -3 2 11 253.16 8.62 -3 2 9 373.05 11.29 3 2 -9 347.44 12.68 -3 2 9 360.16 11.35 3 2 -7 355.86 11.96 3 2 -5 466.40 14.60 3 2 -3 190.81 6.41 3 2 -1 616.03 18.51 3 2 1 796.15 24.04 -3 2 -1 774.32 24.19 3 2 3 549.38 18.48 -3 2 -3 560.20 17.92 -3 2 -5 461.66 15.70 -3 2 -7 406.79 14.43 3 2 7 428.64 13.47 3 2 9 256.39 9.45 3 2 9 278.26 9.26 3 2 9 275.00 8.63 -3 2 -9 259.58 10.39 -3 2 -9 263.44 10.10 3 2 11 157.35 5.61 -3 2 -11 160.56 7.73 3 2 11 166.33 6.35 3 2 13 110.78 4.12 3 2 13 105.13 4.75 3 2 15 141.16 4.91 3 2 15 152.65 5.67 -3 3 16 8.09 1.03 -3 3 14 0.74 0.72 3 3 -12 9.10 0.94 -3 3 12 10.83 1.24 -3 3 10 26.36 1.81 3 3 -10 26.16 2.62 3 3 -8 30.10 1.57 -3 3 8 37.46 1.94 3 3 -8 30.68 2.69 -3 3 8 26.75 2.26 3 3 -8 34.61 2.61 -3 3 6 100.30 3.75 -3 3 4 36.32 2.16 -3 3 2 13.85 1.62 -3 3 0 139.16 6.11 -3 3 -2 19.56 2.14 3 3 2 13.21 1.32 -3 3 -4 212.44 8.47 3 3 4 168.40 7.71 -3 3 -6 16.86 2.29 3 3 6 13.64 1.36 -3 3 -6 14.21 1.70 3 3 6 14.28 2.32 -3 3 -6 12.67 1.49 -3 3 -8 46.13 3.79 3 3 8 57.65 2.92 -3 3 -8 43.57 3.29 3 3 8 53.04 2.98 3 3 8 50.31 2.05 -3 3 -10 17.01 2.33 3 3 10 19.26 1.91 3 3 12 39.55 2.56 3 3 14 33.60 2.18 3 3 16 2.69 0.67 -3 4 15 75.57 3.29 -3 4 15 70.30 3.17 -3 4 13 28.76 1.99 -3 4 13 29.62 2.11 -3 4 11 186.52 7.18 -3 4 11 182.08 6.86 -3 4 9 240.86 8.46 3 4 -7 243.63 8.15 3 4 -7 247.76 9.89 -3 4 7 264.94 8.71 3 4 -5 312.95 10.71 3 4 -5 291.88 9.31 -3 4 3 172.31 6.29 -3 4 3 175.57 6.81 3 4 -1 374.63 12.45 -3 4 1 371.98 12.09 -3 4 1 399.46 13.40 3 4 -1 373.75 11.41 -3 4 -1 463.63 14.56 -3 4 -1 469.30 16.32 3 4 1 455.98 14.94 3 4 1 457.40 13.78 -3 4 -3 419.19 12.64 -3 4 -3 385.13 14.65 3 4 3 366.42 12.96 -3 4 -3 386.17 12.62 3 4 3 366.00 12.37 3 4 3 384.87 11.67 -3 4 -5 298.73 10.23 -3 4 -5 286.63 12.50 3 4 5 309.89 10.52 -3 4 -5 310.79 10.93 3 4 5 311.26 9.47 3 4 7 254.03 9.01 -3 4 -7 241.38 11.12 3 4 7 264.01 9.32 3 4 7 252.39 7.92 -3 4 -9 187.50 9.62 3 4 9 200.48 7.49 3 4 11 103.22 4.61 3 4 13 64.52 2.85 3 4 15 96.45 3.66 -3 5 14 0.72 0.59 -3 5 14 0.22 0.58 -3 5 12 3.40 0.89 -3 5 10 20.86 2.04 -3 5 10 20.95 1.80 3 5 -8 19.15 2.91 -3 5 8 17.11 1.92 -3 5 8 16.09 1.58 -3 5 6 55.63 3.10 -3 5 6 57.08 3.08 3 5 -6 54.35 2.79 3 5 -6 51.77 4.11 3 5 -4 30.22 2.91 -3 5 4 32.72 2.26 3 5 -2 13.03 1.91 -3 5 2 12.02 1.40 3 5 -2 12.78 1.84 3 5 -2 13.89 1.29 -3 5 0 55.14 2.98 3 5 0 61.80 3.76 3 5 0 65.06 2.78 -3 5 -2 12.29 1.65 -3 5 -2 10.86 1.27 -3 5 -2 11.73 2.26 3 5 2 12.94 1.90 -3 5 -2 14.01 1.78 3 5 2 12.93 1.55 -3 5 -4 82.73 4.37 3 5 4 74.71 4.44 3 5 4 69.91 3.78 3 5 6 13.59 1.55 -3 5 -6 14.56 2.94 3 5 6 13.04 1.69 -3 5 -6 12.81 2.18 3 5 8 27.24 2.16 3 5 8 30.31 2.47 3 5 10 10.88 1.35 3 5 12 18.78 1.45 3 5 12 21.88 1.59 -3 6 11 100.16 4.16 -3 6 9 136.85 5.89 -3 6 7 165.95 7.03 3 6 -5 211.85 9.36 -3 6 5 184.32 8.06 3 6 -3 149.18 5.67 3 6 -3 133.48 7.04 -3 6 3 143.00 5.96 -3 6 1 241.33 9.04 3 6 -1 262.75 8.69 -3 6 1 259.07 9.60 3 6 -1 247.36 10.20 3 6 1 259.88 8.67 -3 6 -1 261.35 9.95 -3 6 -3 223.48 9.42 3 6 3 244.58 7.88 3 6 5 175.74 5.81 -3 6 -5 173.44 7.80 3 6 11 47.77 2.10 -3 7 6 23.91 1.78 -3 7 6 23.36 2.24 3 7 -4 14.61 2.83 -3 7 4 16.13 1.71 -3 7 2 6.39 1.52 3 7 -2 7.97 2.24 -3 7 2 7.83 1.72 3 7 0 22.97 2.72 -3 7 0 26.85 2.53 3 7 2 6.90 1.62 -3 7 -2 9.07 1.88 3 7 4 25.79 2.22 3 7 6 8.64 1.12 4 -6 -10 63.96 2.35 4 -6 -8 64.65 2.47 -4 -6 -8 74.18 2.66 4 -5 -15 4.87 0.42 4 -5 -13 0.37 0.34 4 -5 -11 13.68 1.08 4 -5 -9 1.77 0.53 4 -5 -7 13.18 1.10 4 -5 -5 73.64 3.01 -4 -5 -9 5.89 0.78 -4 -5 -11 13.31 0.96 -4 -5 -13 0.69 0.25 4 -4 -16 60.21 2.26 4 -4 -12 49.26 2.44 4 -4 -10 155.27 5.63 4 -4 -8 133.03 4.91 4 -4 -6 305.18 9.71 4 -4 -4 195.99 6.45 -4 -4 -14 85.52 3.04 4 -3 -15 16.86 1.23 4 -3 -13 1.26 0.62 4 -3 -9 0.88 0.47 4 -3 -7 25.14 1.46 4 -3 -5 193.95 6.30 -4 -3 -13 1.44 0.50 4 -2 -18 66.42 2.26 -4 -2 18 60.88 2.27 4 -2 -16 120.73 4.17 4 -2 -16 118.06 4.14 4 -2 -14 208.72 7.27 4 -2 -14 214.21 6.94 4 -2 -12 79.76 3.09 4 -2 -12 80.04 3.41 4 -2 -12 80.20 4.63 -4 -2 12 75.66 4.58 4 -2 -10 272.44 8.50 4 -2 -10 272.77 8.85 4 -2 -10 276.61 10.24 4 -2 -8 245.98 8.98 4 -2 -6 709.24 21.82 4 -2 -4 358.10 11.39 4 -2 -2 916.15 27.13 -4 -2 0 384.80 12.68 4 -2 0 377.48 12.32 4 -2 2 512.78 16.45 -4 -2 -2 499.87 16.36 4 -2 4 249.11 9.39 -4 -2 -4 217.82 8.64 -4 -2 -6 224.65 8.90 4 -2 8 280.56 8.77 4 -2 10 141.89 4.93 -4 -2 -10 138.70 6.39 4 -2 12 45.79 2.10 -4 -2 -12 39.42 3.10 4 -2 14 144.39 4.92 -4 -2 -14 146.05 5.08 4 -2 16 68.47 2.43 4 -1 -19 1.13 0.32 -4 -1 19 1.03 0.32 4 -1 -17 2.17 0.50 4 -1 -15 29.77 1.67 4 -1 -13 2.10 0.92 4 -1 -13 2.04 0.60 4 -1 -13 2.54 0.54 -4 -1 13 1.41 0.90 4 -1 -11 53.04 2.29 4 -1 -11 56.89 2.56 4 -1 -11 58.49 3.68 4 -1 -9 1.76 0.38 4 -1 -9 0.67 0.55 4 -1 -7 46.16 2.61 4 -1 -5 453.48 14.38 4 -1 -5 461.86 14.39 4 -1 -3 138.02 5.13 4 -1 -1 61.04 2.98 4 -1 1 141.87 5.80 -4 -1 -1 139.36 5.82 -4 -1 -3 32.73 2.47 -4 -1 -5 183.65 7.64 -4 -1 -7 11.35 1.70 4 -1 9 19.97 1.25 4 -1 11 35.69 1.86 -4 -1 -11 36.06 2.96 4 -1 13 0.75 0.49 4 -1 15 0.65 0.44 4 -1 17 2.50 0.39 4 0 -18 88.50 3.28 4 0 -16 145.25 5.19 4 0 -14 277.38 8.97 4 0 -14 275.89 11.43 4 0 -12 103.58 3.85 4 0 -12 101.63 5.52 4 0 -10 350.39 10.98 4 0 -10 372.35 10.97 4 0 -10 360.70 12.74 4 0 -8 325.57 11.17 4 0 -6 978.40 28.99 4 0 -6 955.25 28.90 4 0 -4 443.32 14.10 4 0 -4 455.26 14.04 4 0 -2 1231.88 36.35 4 0 0 459.94 14.92 -4 0 -2 787.85 24.22 4 0 2 746.34 24.18 -4 0 -4 298.95 11.02 -4 0 -6 308.05 11.69 -4 0 -8 407.87 14.56 4 0 8 401.14 12.41 4 0 10 171.62 5.96 4 0 10 186.13 6.82 4 0 12 52.60 3.02 -4 0 -12 55.62 3.97 4 0 12 45.67 2.28 -4 0 -18 50.16 1.79 -4 1 19 0.67 0.30 4 1 -19 1.46 0.38 4 1 -17 2.24 0.56 4 1 -15 31.90 1.85 4 1 -13 2.11 0.58 -4 1 13 1.44 0.86 4 1 -13 2.22 1.03 -4 1 11 63.83 2.72 4 1 -11 58.20 2.52 4 1 -11 57.39 3.84 4 1 -9 1.41 0.39 4 1 -9 0.99 0.57 4 1 -7 48.35 2.77 4 1 -5 467.28 14.65 4 1 -5 456.72 14.55 4 1 -3 149.00 5.62 4 1 -1 62.49 3.23 -4 1 -1 150.04 6.36 4 1 1 145.69 6.26 -4 1 -3 34.41 2.77 -4 1 -5 192.90 8.30 -4 1 -7 9.21 1.76 4 1 9 21.72 1.35 4 1 9 20.76 1.70 4 1 11 35.49 1.91 -4 1 -11 39.53 3.31 4 1 11 34.87 2.39 4 1 13 0.36 0.82 4 1 13 0.72 0.50 4 1 15 0.42 0.41 4 1 17 2.15 0.38 -4 2 16 133.49 5.14 4 2 -16 147.26 5.06 -4 2 14 245.89 8.57 4 2 -14 259.05 8.39 4 2 -12 93.19 3.62 4 2 -12 93.06 5.53 -4 2 12 96.01 3.90 4 2 -10 316.71 10.12 -4 2 10 324.48 10.43 4 2 -10 328.08 12.24 -4 2 10 337.24 10.36 4 2 -8 276.47 10.16 4 2 -6 724.36 22.45 4 2 -4 390.13 12.55 4 2 -2 974.67 29.10 -4 2 0 498.70 16.29 4 2 0 469.78 15.60 4 2 2 579.74 19.43 -4 2 -2 598.53 19.52 -4 2 -4 269.26 10.62 4 2 4 278.34 11.25 4 2 6 258.27 8.87 -4 2 -6 263.31 10.84 -4 2 -8 365.92 12.66 4 2 8 344.13 10.52 4 2 10 170.03 5.69 -4 2 -10 171.99 7.80 4 2 10 153.92 6.25 4 2 10 147.55 5.98 -4 2 -12 44.04 3.79 4 2 12 52.29 2.37 4 2 12 45.06 2.80 4 2 14 149.08 5.04 4 2 14 139.83 5.69 -4 3 17 1.18 0.49 -4 3 13 1.52 0.73 -4 3 13 1.55 0.72 -4 3 11 43.67 2.40 4 3 -11 38.19 1.96 4 3 -11 37.34 1.98 4 3 -9 1.57 0.60 -4 3 9 1.64 0.65 4 3 -9 1.54 0.82 4 3 -7 28.19 1.43 4 3 -7 27.54 2.37 -4 3 3 79.79 4.51 -4 3 1 30.43 2.50 4 3 -1 29.62 1.81 4 3 1 64.58 3.26 -4 3 -1 61.64 3.60 -4 3 -3 32.39 3.11 -4 3 -3 23.01 2.21 4 3 3 22.97 2.34 4 3 3 30.73 1.44 4 3 5 113.57 4.53 4 3 5 102.94 6.18 -4 3 -5 101.43 4.68 4 3 7 12.12 1.36 -4 3 -7 8.88 1.96 4 3 7 9.67 2.05 -4 3 -7 9.01 1.55 4 3 7 10.14 1.41 4 3 9 15.03 1.57 4 3 9 15.35 1.80 4 3 9 13.97 1.02 4 3 11 22.97 1.89 4 3 13 0.64 0.78 4 3 15 -0.04 0.58 -4 4 16 83.67 3.22 -4 4 14 157.67 5.82 -4 4 12 71.40 3.45 -4 4 10 230.74 8.23 -4 4 10 217.61 8.00 4 4 -8 178.12 6.28 -4 4 8 196.99 6.88 4 4 -8 178.58 8.10 4 4 -6 422.22 14.49 -4 4 6 436.87 13.42 4 4 -6 409.55 12.85 -4 4 4 276.65 9.35 4 4 -4 274.60 9.77 4 4 -4 277.38 8.77 -4 4 2 559.86 18.40 -4 4 2 531.39 16.87 -4 4 0 321.36 10.64 4 4 0 286.99 10.96 -4 4 0 325.10 12.53 4 4 0 323.59 9.84 -4 4 -2 371.61 12.11 4 4 2 355.49 12.88 -4 4 -2 374.44 14.70 4 4 2 378.09 11.45 4 4 2 344.95 12.16 4 4 4 195.80 7.19 -4 4 -4 197.68 7.54 -4 4 -4 186.41 7.41 -4 4 -4 194.26 9.57 4 4 4 198.68 7.49 4 4 4 208.14 6.54 4 4 6 184.10 6.79 4 4 6 187.51 7.12 4 4 6 176.76 5.81 4 4 8 220.78 7.77 -4 4 -8 209.80 9.99 4 4 8 199.89 6.47 4 4 10 119.86 5.14 4 4 12 41.00 2.45 4 4 12 40.42 2.26 -4 5 15 7.68 0.74 -4 5 13 0.15 0.60 -4 5 11 16.24 1.67 -4 5 9 2.01 0.99 -4 5 9 2.71 0.88 4 5 -7 15.12 2.60 -4 5 7 21.41 1.82 4 5 -7 17.25 1.59 4 5 -5 112.42 4.48 4 5 -5 113.25 5.92 -4 5 5 116.21 4.98 4 5 -3 34.04 2.88 -4 5 3 36.42 2.33 -4 5 1 21.51 2.05 -4 5 1 18.36 1.72 -4 5 1 15.09 2.24 -4 5 -1 43.13 2.86 -4 5 -1 38.04 2.62 -4 5 -1 34.54 3.67 -4 5 -3 19.58 2.00 -4 5 -3 20.42 2.10 -4 5 -3 17.81 2.87 4 5 3 16.52 1.89 -4 5 -5 37.18 2.75 -4 5 -5 47.04 3.43 -4 5 -5 38.06 4.24 4 5 5 52.12 3.24 4 5 5 53.46 2.30 4 5 7 8.70 1.54 4 5 11 14.50 1.37 -4 6 12 30.37 1.62 -4 6 12 32.97 1.76 -4 6 10 118.99 4.77 -4 6 8 123.91 5.37 -4 6 8 111.56 4.70 4 6 -6 263.67 8.89 4 6 -6 232.20 10.56 4 6 -4 182.50 8.31 -4 6 4 178.48 7.00 -4 6 2 267.14 9.94 -4 6 2 287.61 10.09 4 6 -2 267.81 10.95 4 6 0 188.75 8.18 -4 6 0 198.40 7.80 4 6 0 207.24 7.07 -4 6 -2 230.38 9.19 4 6 2 249.43 8.12 4 6 4 142.48 5.01 4 6 6 114.42 3.89 4 6 8 121.14 4.93 4 6 10 63.03 2.66 -4 7 7 8.36 1.26 -4 7 5 39.97 2.83 -4 7 3 12.10 1.77 -4 7 1 7.64 1.32 -4 7 1 4.88 1.49 4 7 1 20.10 1.51 5 -6 -9 76.87 2.69 -5 -6 -7 72.38 2.54 5 -5 -14 4.99 0.48 5 -5 -12 12.37 0.94 5 -5 -10 5.44 0.71 5 -5 -8 3.88 0.67 5 -5 -6 5.91 0.77 -5 -5 -8 2.46 0.57 -5 -5 -10 1.44 0.43 -5 -5 -12 1.03 0.28 5 -4 -15 73.91 2.79 5 -4 -11 114.58 4.42 5 -4 -9 211.57 7.24 5 -4 -7 125.17 4.64 5 -4 -5 225.30 7.40 5 -4 -3 177.75 5.92 5 -3 -16 1.35 0.44 5 -3 -14 12.39 1.10 5 -3 -12 30.85 1.87 5 -3 -8 7.46 0.87 5 -3 -6 8.99 0.86 5 -3 -4 17.57 1.12 -5 -3 -14 2.88 0.47 5 -2 -17 118.20 3.95 5 -2 -15 133.10 4.89 5 -2 -15 133.43 4.62 -5 -2 13 132.79 6.87 5 -2 -13 146.99 5.43 5 -2 -13 151.73 5.07 5 -2 -13 150.18 5.08 5 -2 -13 124.70 6.74 5 -2 -11 204.60 8.69 5 -2 -11 206.12 6.77 5 -2 -11 214.02 7.20 5 -2 -9 407.40 12.78 5 -2 -9 411.02 12.35 5 -2 -9 411.86 12.41 5 -2 -9 417.93 12.43 5 -2 -9 410.10 14.28 5 -2 -5 450.78 14.45 5 -2 -3 290.84 9.79 5 -2 -1 760.52 23.37 -5 -2 1 766.26 24.14 5 -2 1 356.32 11.84 -5 -2 -1 316.31 11.91 -5 -2 -3 362.39 13.50 5 -2 3 422.04 14.07 -5 -2 -5 291.39 10.97 5 -2 5 278.07 11.44 5 -2 7 243.41 7.80 -5 -2 -7 243.21 10.13 5 -2 7 269.75 11.27 5 -2 9 160.62 5.44 5 -2 9 149.23 8.40 5 -2 11 96.29 6.52 5 -2 11 88.82 3.47 -5 -2 -11 96.54 5.11 5 -2 13 121.58 4.27 5 -2 15 95.14 3.25 5 -1 -18 2.87 0.47 5 -1 -16 2.35 0.54 5 -1 -16 2.05 0.52 5 -1 -14 23.43 1.41 -5 -1 14 19.56 2.37 5 -1 -14 20.02 1.50 5 -1 -14 21.71 2.49 5 -1 -12 50.75 2.24 5 -1 -12 46.45 2.42 5 -1 -12 48.58 3.59 5 -1 -10 23.20 1.49 5 -1 -10 23.88 1.29 5 -1 -10 22.67 1.24 5 -1 -10 19.31 2.03 5 -1 -8 11.75 1.43 5 -1 -6 10.41 1.23 5 -1 -6 12.83 1.34 5 -1 -4 28.90 1.97 5 -1 -2 1.26 0.68 5 -1 0 12.85 1.51 -5 -1 0 12.07 1.67 5 -1 2 53.99 3.54 -5 -1 -2 58.15 3.63 -5 -1 -4 55.40 3.71 5 -1 4 59.55 4.05 -5 -1 -6 5.42 1.41 -5 -1 -8 3.27 1.22 5 -1 8 1.35 0.47 5 -1 10 3.53 0.64 -5 -1 -12 3.71 1.07 5 -1 12 3.18 0.63 5 -1 14 4.53 0.64 5 -1 16 0.88 0.33 5 0 -19 56.72 2.14 5 0 -17 169.69 5.66 5 0 -17 164.25 5.63 5 0 -15 172.96 6.00 5 0 -13 195.59 6.64 5 0 -13 202.13 8.96 5 0 -11 265.28 8.54 5 0 -11 267.08 8.79 5 0 -11 270.34 8.49 5 0 -11 281.51 10.69 5 0 -9 544.90 16.35 5 0 -9 554.41 16.34 5 0 -9 571.30 18.26 5 0 -7 279.21 9.90 5 0 -5 653.90 20.02 5 0 -5 628.60 19.90 5 0 -3 349.54 11.71 5 0 -1 1153.43 34.84 -5 0 -1 429.35 14.98 5 0 1 440.18 14.93 5 0 3 583.55 18.88 -5 0 -3 508.45 18.27 -5 0 -5 352.67 13.26 5 0 7 291.01 9.31 -5 0 -7 317.44 12.25 5 0 7 307.07 10.12 5 0 9 185.68 6.32 5 0 9 193.46 7.17 5 0 11 96.75 3.79 5 0 13 155.90 5.44 5 1 -18 2.82 0.54 5 1 -16 2.51 0.60 5 1 -14 26.18 1.57 5 1 -14 21.48 2.66 5 1 -12 59.38 2.59 5 1 -12 52.67 4.04 5 1 -10 25.43 1.41 5 1 -10 23.97 1.37 5 1 -10 23.69 2.39 5 1 -8 11.35 1.49 5 1 -6 10.50 1.32 5 1 -6 10.38 1.29 5 1 -4 30.45 2.14 5 1 -2 1.74 0.80 5 1 0 13.18 1.66 -5 1 0 12.71 1.82 -5 1 -2 67.70 4.16 5 1 2 52.78 3.77 5 1 4 62.89 4.45 -5 1 -4 68.62 4.40 -5 1 -6 5.69 1.56 5 1 8 3.14 0.89 -5 1 -8 4.82 1.56 -5 1 -8 1.53 0.93 5 1 8 2.87 0.91 5 1 8 2.41 0.57 5 1 10 3.54 1.04 5 1 10 3.33 0.68 5 1 12 3.12 1.04 -5 1 -12 3.42 1.20 5 1 12 4.33 0.72 5 1 14 5.67 0.71 5 1 16 0.70 0.32 5 2 -15 165.23 5.81 5 2 -13 188.12 6.06 -5 2 13 177.98 6.21 5 2 -11 235.15 7.78 -5 2 11 243.07 8.10 5 2 -11 234.90 10.13 -5 2 9 496.36 14.41 5 2 -9 445.62 14.20 5 2 -9 479.60 14.22 5 2 -9 477.39 16.50 5 2 -7 245.81 9.34 5 2 -5 520.33 16.81 5 2 -3 338.63 11.55 -5 2 1 993.27 28.96 5 2 -1 835.22 27.47 5 2 1 362.58 13.30 -5 2 -1 379.36 13.88 -5 2 -3 450.71 16.30 5 2 3 449.63 16.39 -5 2 -5 332.42 12.77 5 2 5 322.99 13.29 5 2 5 304.31 10.27 -5 2 -7 314.43 11.56 -5 2 -7 279.61 12.08 5 2 7 285.64 12.90 5 2 7 281.26 9.01 5 2 7 266.06 9.52 -5 2 -9 158.43 7.55 5 2 9 175.46 5.95 5 2 9 164.81 6.41 5 2 9 179.91 9.84 5 2 11 109.78 7.49 5 2 11 105.15 3.96 -5 2 -11 110.32 6.17 5 2 11 103.68 4.69 5 2 11 91.86 4.16 5 2 13 131.21 5.50 5 2 13 141.14 4.83 -5 3 16 2.18 0.68 -5 3 14 16.72 1.42 -5 3 12 46.05 2.48 5 3 -12 38.80 2.11 -5 3 10 16.61 1.40 5 3 -10 16.48 1.25 5 3 -8 8.52 0.83 -5 3 8 11.20 1.06 -5 3 6 10.89 1.05 5 3 -6 12.21 1.54 5 3 -6 9.72 0.83 -5 3 4 23.85 1.57 5 3 -4 22.65 1.21 5 3 -2 2.49 0.69 -5 3 2 1.66 1.10 5 3 -2 2.51 0.53 5 3 0 0.78 0.64 -5 3 0 1.48 0.99 5 3 2 38.61 3.13 -5 3 -2 40.74 3.36 5 3 2 47.36 2.00 5 3 4 35.78 2.35 -5 3 -4 30.66 3.05 5 3 4 28.52 3.03 5 3 4 34.88 2.14 -5 3 -6 -0.34 1.40 5 3 6 0.77 0.73 5 3 6 1.84 1.23 -5 3 -8 1.08 1.24 5 3 8 2.92 0.96 5 3 10 2.09 1.03 5 3 10 2.36 0.95 -5 3 -10 3.10 1.26 5 3 10 3.00 0.57 5 3 12 2.24 0.78 -5 4 13 123.56 4.80 -5 4 13 119.06 4.77 -5 4 11 147.36 5.75 5 4 -9 266.36 9.13 -5 4 9 284.62 9.82 5 4 -7 170.81 5.86 5 4 -7 165.62 7.42 -5 4 7 173.31 6.34 -5 4 5 298.85 10.39 5 4 -5 320.91 11.14 5 4 -5 315.89 9.86 5 4 -3 247.43 8.70 -5 4 3 233.11 8.52 -5 4 3 257.96 9.97 -5 4 1 549.90 19.55 -5 4 -1 255.73 9.15 -5 4 -1 227.05 10.97 5 4 1 249.56 8.01 -5 4 -3 273.18 9.91 -5 4 -3 255.88 11.99 5 4 3 260.27 9.61 5 4 3 273.35 8.60 -5 4 -5 182.42 9.51 5 4 5 195.31 7.00 5 4 5 195.87 6.16 -5 4 -7 185.82 9.60 5 4 7 204.01 7.18 5 4 7 182.27 6.01 5 4 9 122.52 5.26 5 4 9 125.85 4.23 5 4 11 75.21 3.51 5 4 11 68.66 3.26 -5 5 12 21.70 1.60 -5 5 12 22.56 1.67 -5 5 10 5.42 1.10 5 5 -8 5.93 1.09 -5 5 8 6.42 1.18 -5 5 8 6.36 1.10 5 5 -6 8.44 1.23 5 5 -6 8.87 1.98 5 5 -4 15.90 2.13 -5 5 4 16.06 1.62 5 5 -4 18.25 1.51 5 5 -2 1.95 1.07 -5 5 2 4.79 1.03 5 5 -2 3.32 1.31 -5 5 0 0.68 0.98 -5 5 -2 22.31 2.14 5 5 2 24.12 1.62 5 5 4 25.24 1.60 5 5 6 2.55 0.62 5 5 8 3.80 1.20 5 5 10 1.78 0.85 -5 6 11 64.89 2.84 -5 6 9 144.35 5.62 -5 6 9 138.98 5.26 -5 6 7 116.95 5.05 -5 6 7 99.56 4.36 5 6 -5 209.91 7.22 -5 6 5 187.45 7.36 -5 6 3 157.03 6.42 5 6 -3 172.12 7.40 5 6 -1 259.81 8.16 5 6 -1 250.40 9.27 5 6 1 174.07 7.00 5 6 1 170.87 6.11 5 6 3 170.77 7.09 5 6 3 181.60 6.12 5 6 5 132.85 5.66 5 6 5 133.17 4.54 5 6 9 75.06 3.03 -5 7 6 3.98 1.01 -5 7 2 2.78 1.20 5 7 0 1.15 0.77 5 7 2 10.41 0.95 6 -5 -13 3.55 0.45 6 -5 -11 2.67 0.50 6 -5 -9 0.82 0.41 6 -5 -7 4.13 0.65 6 -5 -5 4.24 0.60 -6 -5 -9 13.65 0.97 -6 -5 -11 0.48 0.25 6 -4 -16 43.43 1.60 6 -4 -12 66.18 2.86 6 -4 -10 163.01 5.81 6 -4 -8 185.86 6.47 6 -4 -6 146.85 5.25 6 -4 -4 255.10 8.24 6 -4 -2 221.84 7.16 6 -3 -15 5.77 0.72 6 -3 -13 6.89 0.88 6 -3 -9 6.53 0.86 6 -3 -7 9.22 0.92 6 -3 -5 8.40 0.83 6 -3 -3 2.21 0.48 6 -3 -1 14.80 0.99 -6 -3 -13 0.28 0.35 6 -2 -16 108.31 3.76 6 -2 -14 90.64 3.84 6 -2 -14 103.13 3.68 6 -2 -12 110.76 4.01 6 -2 -12 106.11 4.33 6 -2 -10 289.33 9.41 6 -2 -10 279.32 8.89 6 -2 -10 292.86 9.02 6 -2 -8 344.12 10.51 6 -2 -8 348.55 10.58 6 -2 -6 244.83 7.90 6 -2 -4 503.67 16.21 -6 -2 2 397.60 14.79 6 -2 -2 436.20 14.03 -6 -2 0 269.78 10.58 6 -2 0 274.87 10.09 6 -2 2 179.97 7.76 -6 -2 -2 177.59 7.89 -6 -2 -4 413.30 14.33 6 -2 4 400.85 14.53 6 -2 4 375.84 11.64 6 -2 6 253.79 11.29 6 -2 6 264.39 8.40 -6 -2 -6 285.11 11.10 6 -2 8 556.61 19.61 6 -2 8 507.16 15.49 6 -2 10 86.78 6.08 6 -2 10 97.18 3.57 -6 -2 -10 86.55 4.87 6 -2 12 137.69 4.73 6 -2 14 94.18 3.25 6 -1 -19 3.58 0.36 -6 -1 19 2.58 0.33 6 -1 -17 5.50 0.65 6 -1 -15 10.15 0.94 6 -1 -13 8.65 1.02 6 -1 -13 9.91 0.94 6 -1 -13 9.07 0.89 6 -1 -13 9.62 1.70 6 -1 -11 8.87 0.84 6 -1 -11 7.32 0.96 6 -1 -11 8.44 0.83 6 -1 -11 8.06 0.81 6 -1 -11 8.37 1.53 6 -1 -9 24.11 1.31 6 -1 -9 22.74 1.28 6 -1 -9 22.78 1.49 6 -1 -9 23.04 1.28 6 -1 -9 24.98 2.34 6 -1 -7 16.29 1.00 6 -1 -7 19.59 1.85 6 -1 -7 17.37 1.21 6 -1 -7 18.00 1.04 6 -1 -5 9.99 1.29 6 -1 -3 10.49 1.32 6 -1 -1 24.09 2.14 -6 -1 1 22.43 2.36 6 -1 1 49.93 3.45 -6 -1 -1 50.77 3.59 6 -1 3 56.02 3.94 -6 -1 -3 49.67 3.72 -6 -1 -5 26.24 2.76 6 -1 5 25.70 2.91 6 -1 5 24.56 1.36 6 -1 7 11.39 0.97 -6 -1 -7 9.44 1.82 6 -1 7 12.88 2.34 6 -1 9 45.69 2.20 6 -1 9 47.43 4.49 6 -1 11 2.52 1.32 -6 -1 -11 0.60 0.58 6 -1 11 1.13 0.52 6 -1 13 -0.03 0.41 6 -1 15 4.85 0.54 6 0 -18 78.69 2.91 6 0 -16 153.59 5.34 6 0 -14 124.58 4.59 6 0 -14 126.46 4.61 6 0 -14 117.47 6.63 6 0 -12 119.46 4.82 6 0 -12 133.81 4.72 6 0 -12 135.94 4.68 6 0 -12 129.28 6.71 6 0 -10 359.25 11.25 6 0 -10 372.92 11.60 6 0 -10 365.99 11.24 6 0 -10 365.73 13.45 6 0 -8 454.00 13.69 6 0 -8 466.63 13.70 6 0 -8 445.66 13.71 6 0 -8 479.65 15.71 6 0 -6 297.82 10.69 6 0 -4 694.17 21.91 6 0 -2 589.87 19.17 -6 0 0 317.65 12.50 6 0 0 353.19 12.46 -6 0 -2 199.84 8.94 6 0 2 207.79 8.91 -6 0 -4 583.75 20.49 6 0 4 596.40 20.86 -6 0 -6 369.79 14.55 6 0 6 369.19 15.18 6 0 6 368.77 11.51 6 0 6 386.01 12.05 6 0 8 653.04 24.22 6 0 8 652.59 19.80 6 0 10 99.36 7.08 6 0 10 110.48 4.14 6 0 12 165.38 5.73 6 1 -19 4.30 0.45 6 1 -17 7.18 0.80 6 1 -15 11.36 1.08 6 1 -13 10.59 1.01 6 1 -13 9.70 1.81 6 1 -13 10.10 1.04 6 1 -11 9.21 0.91 6 1 -11 9.68 0.92 6 1 -11 8.96 1.62 6 1 -9 24.84 1.38 6 1 -9 24.80 1.38 6 1 -9 24.44 1.39 6 1 -9 23.52 2.37 6 1 -7 17.27 1.06 6 1 -7 16.57 1.90 6 1 -7 18.68 1.14 6 1 -5 5.35 1.12 6 1 -3 11.66 1.51 -6 1 1 24.53 2.61 6 1 -1 20.91 2.13 -6 1 -1 55.18 3.96 6 1 1 45.62 3.52 -6 1 -3 64.19 4.51 6 1 3 57.56 4.29 -6 1 -5 24.43 2.94 6 1 5 26.33 3.09 6 1 5 25.75 1.46 6 1 5 25.84 1.87 6 1 5 25.08 1.90 -6 1 -7 10.91 2.12 6 1 7 11.67 2.40 6 1 7 11.90 1.04 6 1 7 12.49 1.39 6 1 9 56.33 3.21 6 1 9 57.89 2.58 6 1 9 57.40 5.18 6 1 9 51.49 2.82 6 1 11 0.23 1.06 6 1 11 1.59 0.57 6 1 13 0.10 0.43 6 1 15 5.82 0.58 6 2 -16 140.61 4.95 -6 2 14 117.30 4.54 6 2 -14 117.18 4.45 -6 2 12 130.71 4.96 6 2 -12 125.59 4.74 6 2 -10 330.64 10.30 6 2 -10 326.89 10.37 6 2 -8 379.88 11.54 6 2 -8 372.91 11.56 6 2 -6 286.31 10.39 6 2 -6 269.77 8.51 6 2 -4 563.26 18.45 6 2 -2 460.45 16.09 -6 2 2 504.89 17.52 -6 2 0 337.18 13.05 6 2 0 311.98 12.09 6 2 2 191.70 9.04 -6 2 -2 220.42 9.73 -6 2 -4 498.84 17.78 6 2 4 483.32 17.83 6 2 4 471.58 14.25 6 2 4 445.40 14.76 6 2 4 465.93 14.87 -6 2 -6 354.75 13.99 6 2 6 331.36 14.17 6 2 6 319.64 10.27 6 2 6 323.13 10.95 6 2 6 321.22 10.92 -6 2 -8 579.74 20.09 6 2 8 611.23 22.32 6 2 8 613.64 17.55 6 2 8 576.90 18.14 6 2 10 109.35 7.27 6 2 10 108.43 4.03 6 2 10 96.22 4.32 6 2 12 158.87 5.44 -6 3 13 8.84 1.11 -6 3 11 6.36 0.95 -6 3 11 5.56 0.94 6 3 -11 5.56 0.81 -6 3 9 8.04 0.99 6 3 -9 5.54 0.80 -6 3 7 12.29 1.16 6 3 -7 12.00 0.93 -6 3 5 9.59 1.07 6 3 -3 2.34 0.84 6 3 -3 2.42 0.77 -6 3 3 2.94 1.37 6 3 -3 2.38 0.55 -6 3 1 20.80 2.68 6 3 -1 20.13 1.20 6 3 -1 17.07 1.67 6 3 -1 14.71 1.75 -6 3 -1 15.61 2.35 6 3 1 15.38 1.97 6 3 3 27.77 2.93 -6 3 -3 31.09 3.29 6 3 3 33.35 2.17 -6 3 -5 22.42 3.15 6 3 5 16.32 2.48 6 3 5 15.64 1.62 6 3 7 10.81 1.54 -6 3 -7 11.42 2.28 6 3 7 9.99 1.39 6 3 9 39.57 2.62 6 3 9 40.34 1.84 6 3 9 37.09 2.48 6 3 11 0.91 0.73 6 3 11 0.73 0.75 6 3 11 1.01 0.42 -6 4 14 77.17 3.22 -6 4 12 93.99 4.02 -6 4 10 222.26 8.14 -6 4 10 238.23 8.13 6 4 -8 227.70 7.78 -6 4 8 259.81 8.48 -6 4 6 194.57 6.79 6 4 -6 183.98 6.19 -6 4 4 351.54 11.35 6 4 -4 320.85 11.42 -6 4 2 300.01 10.16 -6 4 2 263.31 11.90 6 4 -2 308.08 9.30 6 4 -2 263.92 10.03 -6 4 0 181.47 9.80 6 4 0 219.77 8.03 -6 4 -2 125.25 5.97 -6 4 -2 137.91 8.29 6 4 2 143.34 4.97 6 4 4 265.98 8.48 6 4 4 256.95 7.60 6 4 6 198.33 7.08 6 4 6 181.55 6.02 6 4 8 348.30 11.86 6 4 8 352.03 10.78 6 4 8 361.73 12.00 6 4 10 78.76 3.70 6 4 10 85.64 2.87 6 4 10 77.63 3.61 6 4 12 87.81 3.20 -6 5 13 4.76 0.70 -6 5 11 3.68 0.82 -6 5 9 1.62 0.81 6 5 -7 6.67 1.10 -6 5 7 9.46 1.31 6 5 -5 6.14 1.00 6 5 -3 1.28 0.81 6 5 -3 0.78 0.99 -6 5 3 1.27 0.82 6 5 -1 13.20 1.82 6 5 -1 15.11 1.70 6 5 1 2.99 1.36 -6 5 -1 1.75 1.16 6 5 3 24.67 1.57 6 5 3 18.59 2.14 6 5 5 8.21 0.93 6 5 7 9.06 1.43 6 5 7 8.93 0.85 6 5 9 20.50 1.63 6 5 11 0.54 0.43 -6 6 10 121.58 4.52 -6 6 8 140.83 5.32 -6 6 8 123.94 4.89 6 6 -6 130.03 4.94 -6 6 6 134.97 5.60 -6 6 6 121.51 5.11 6 6 -4 208.18 6.91 -6 6 4 173.66 7.00 6 6 -2 191.41 6.08 -6 6 2 133.06 6.05 6 6 0 143.47 5.26 6 6 2 104.63 4.01 6 6 4 178.44 6.72 6 6 4 173.77 5.79 6 6 6 132.30 4.95 6 6 6 122.00 4.00 -6 7 5 2.75 0.76 -6 7 1 6.24 1.21 6 7 1 0.34 0.54 7 -5 -12 0.56 0.28 7 -5 -10 1.73 0.43 7 -5 -8 3.98 0.59 7 -5 -6 13.94 1.02 -7 -5 -8 4.37 0.57 -7 -5 -10 10.85 0.66 7 -4 -15 37.58 1.52 7 -4 -11 131.69 4.78 7 -4 -9 98.29 3.87 7 -4 -7 149.56 5.35 7 -4 -5 123.40 4.52 7 -4 -3 183.48 6.14 -7 -4 -11 76.12 2.83 7 -3 -14 8.00 0.84 7 -3 -12 1.05 0.54 7 -3 -10 5.42 0.85 7 -3 -8 5.98 0.85 7 -3 -6 36.43 1.94 7 -3 -4 16.78 1.18 7 -3 -2 58.11 2.47 7 -3 0 27.64 1.47 7 -2 -17 63.69 2.23 7 -2 -15 74.96 2.85 7 -2 -13 98.50 3.98 7 -2 -13 98.85 3.69 7 -2 -11 243.44 7.84 7 -2 -11 248.90 8.26 7 -2 -11 237.30 7.71 7 -2 -9 171.52 5.96 7 -2 -9 161.24 5.48 7 -2 -9 166.74 5.60 7 -2 -7 272.73 9.02 7 -2 -7 283.17 8.75 7 -2 -7 278.30 8.66 7 -2 -5 186.37 7.55 7 -2 -5 191.13 6.41 7 -2 -5 191.95 6.21 7 -2 -5 192.04 6.15 -7 -2 3 314.95 12.74 7 -2 -3 322.19 11.58 7 -2 -3 333.44 10.08 7 -2 -3 329.31 10.03 7 -2 -3 325.12 10.19 7 -2 -1 458.72 14.16 7 -2 -1 509.02 16.21 -7 -2 1 481.07 17.00 7 -2 1 311.62 12.07 7 -2 1 320.27 10.02 -7 -2 -3 287.20 11.32 7 -2 3 258.24 10.93 7 -2 3 270.21 8.58 7 -2 5 318.52 13.03 7 -2 5 321.03 10.11 -7 -2 -5 337.44 13.03 -7 -2 -7 166.50 7.97 7 -2 7 156.73 8.19 7 -2 7 151.22 5.31 7 -2 9 389.61 11.97 7 -2 9 379.93 15.29 7 -2 11 113.27 4.04 7 -2 13 121.80 4.05 7 -1 -18 1.31 0.33 7 -1 -16 1.94 0.48 7 -1 -14 14.51 1.09 7 -1 -12 0.81 0.57 7 -1 -12 0.61 0.45 7 -1 -12 0.55 0.47 7 -1 -10 9.11 1.04 7 -1 -10 9.65 0.88 7 -1 -10 10.22 0.91 7 -1 -8 5.06 0.78 7 -1 -8 4.69 0.62 7 -1 -8 4.59 0.62 7 -1 -6 56.19 3.45 7 -1 -6 56.49 2.50 7 -1 -6 57.05 2.30 7 -1 -6 54.96 2.30 7 -1 -4 26.20 2.24 7 -1 -4 25.14 1.43 -7 -1 2 105.80 5.98 7 -1 -2 117.66 5.56 7 -1 0 63.94 4.01 -7 -1 0 53.87 4.05 7 -1 2 36.40 3.17 7 -1 2 31.51 1.63 -7 -1 -2 31.08 3.14 -7 -1 -4 7.79 1.73 7 -1 4 6.40 1.65 7 -1 4 7.01 0.77 7 -1 6 1.67 1.21 -7 -1 -6 1.18 1.04 7 -1 6 1.26 0.48 -7 -1 -8 11.94 2.25 7 -1 8 11.46 2.36 7 -1 8 13.44 1.10 7 -1 10 38.37 3.91 7 -1 10 34.06 1.80 7 -1 12 2.46 0.57 7 -1 14 3.38 0.47 7 0 -19 24.39 1.04 7 0 -17 97.41 3.54 7 0 -15 99.05 3.81 7 0 -13 131.27 4.81 7 0 -11 311.34 9.81 7 0 -11 312.04 9.87 7 0 -11 307.02 10.13 7 0 -9 202.11 6.61 7 0 -9 207.71 6.96 7 0 -9 193.61 6.58 7 0 -7 351.91 10.84 7 0 -7 334.47 10.49 7 0 -7 335.95 10.55 7 0 -7 369.50 12.64 7 0 -5 213.30 8.63 7 0 -5 223.82 6.91 7 0 -5 211.66 6.96 7 0 -3 446.27 15.45 -7 0 1 604.31 21.19 7 0 -1 626.17 20.73 -7 0 -1 443.03 16.12 7 0 1 415.48 15.58 -7 0 -3 340.29 13.79 7 0 3 318.94 13.44 7 0 3 324.93 10.56 -7 0 -5 405.12 15.19 7 0 5 377.62 11.66 -7 0 -7 209.84 9.88 7 0 7 181.59 9.78 7 0 7 194.50 6.58 7 0 9 452.37 18.73 7 0 9 484.29 14.70 7 0 11 127.21 4.61 7 1 -18 1.47 0.38 7 1 -16 2.34 0.60 7 1 -14 15.13 1.20 7 1 -12 0.55 0.47 7 1 -12 0.59 0.53 7 1 -10 9.82 0.95 7 1 -10 9.34 0.94 7 1 -8 5.39 0.71 7 1 -8 4.28 0.63 7 1 -6 63.08 3.84 7 1 -6 60.38 2.43 7 1 -6 56.08 2.44 7 1 -4 26.19 2.39 -7 1 2 111.79 6.44 7 1 -2 123.25 5.96 -7 1 0 67.54 4.74 7 1 0 64.07 4.36 -7 1 -2 41.52 3.83 7 1 2 37.97 3.50 7 1 2 35.74 1.87 7 1 2 36.84 2.26 7 1 4 9.24 1.27 -7 1 -4 8.08 1.94 7 1 4 7.47 1.82 7 1 4 7.14 0.83 7 1 6 1.04 1.25 -7 1 -6 0.58 1.20 7 1 6 1.31 0.55 7 1 6 0.75 0.87 -7 1 -8 12.93 1.95 7 1 8 15.59 2.79 7 1 8 13.77 1.16 7 1 8 13.27 1.46 -7 1 -8 9.68 2.28 7 1 10 43.38 4.35 7 1 10 38.11 2.01 7 1 12 2.37 0.56 7 1 14 2.86 0.47 7 2 -15 96.02 3.71 7 2 -13 118.47 4.50 -7 2 13 119.69 4.58 7 2 -11 286.13 9.17 7 2 -11 282.54 9.24 -7 2 9 183.14 6.33 7 2 -9 189.69 6.38 7 2 -9 189.11 6.32 7 2 -7 306.83 9.67 7 2 -7 307.30 9.67 7 2 -5 216.54 8.56 7 2 -5 210.77 6.54 7 2 -5 207.25 6.57 -7 2 3 401.00 14.93 7 2 -3 390.92 13.38 7 2 -3 360.41 10.99 7 2 -3 351.90 11.09 7 2 -3 355.83 11.57 7 2 -3 352.37 10.71 -7 2 1 570.77 20.54 7 2 -1 530.68 19.13 7 2 -1 571.94 17.51 7 2 1 367.58 14.37 7 2 1 363.73 11.65 7 2 1 367.67 12.19 -7 2 -3 330.18 13.44 7 2 3 297.77 12.77 7 2 3 294.28 9.74 7 2 3 310.80 10.43 7 2 5 351.98 14.92 7 2 5 360.15 11.28 7 2 5 338.70 11.87 7 2 5 349.31 11.91 -7 2 -7 212.25 9.31 -7 2 -7 192.48 9.87 7 2 7 184.59 9.90 7 2 7 197.78 6.58 7 2 7 165.83 7.06 7 2 7 185.25 7.08 7 2 9 420.77 17.29 7 2 9 446.63 13.38 7 2 9 409.21 13.78 7 2 11 134.49 4.45 7 2 11 107.58 4.39 7 2 13 130.67 4.02 -7 3 14 10.33 1.06 -7 3 12 0.11 0.58 -7 3 10 8.22 1.05 7 3 -10 5.55 0.82 -7 3 8 5.80 0.89 7 3 -8 5.18 0.79 -7 3 6 42.01 2.20 7 3 -6 33.31 1.69 -7 3 4 21.96 1.71 7 3 -4 14.17 1.82 -7 3 4 20.49 2.98 7 3 -4 16.42 1.12 -7 3 2 70.75 5.49 7 3 -2 59.36 4.02 7 3 -2 74.39 2.79 7 3 -2 70.28 3.56 -7 3 0 35.64 3.78 7 3 0 37.01 1.82 7 3 0 40.74 2.59 -7 3 -2 25.44 3.12 7 3 2 20.28 2.47 7 3 2 23.66 2.08 7 3 4 6.55 1.30 7 3 6 0.75 0.96 7 3 6 0.37 0.79 -7 3 -6 -0.75 1.43 7 3 8 9.53 1.43 7 3 8 9.70 1.41 7 3 8 9.72 0.93 7 3 10 27.41 1.35 7 3 10 25.56 1.82 7 3 12 1.53 0.31 -7 4 13 77.93 3.16 -7 4 13 78.41 3.29 -7 4 11 184.96 6.71 -7 4 9 143.52 5.56 7 4 -7 179.40 6.24 -7 4 7 202.27 6.94 7 4 -5 159.34 5.56 -7 4 3 245.16 8.48 7 4 -3 241.32 7.60 -7 4 1 306.65 10.75 7 4 -1 311.48 9.68 7 4 -1 299.91 10.65 -7 4 -1 215.10 11.29 7 4 1 241.47 8.86 -7 4 -3 206.03 10.15 7 4 3 202.38 7.22 -7 4 -5 187.22 7.83 7 4 5 204.73 6.67 -7 4 -7 152.51 5.80 7 4 7 135.35 4.77 7 4 7 139.64 5.77 7 4 9 297.72 8.94 7 4 9 287.55 9.78 7 4 11 79.48 3.01 -7 5 12 0.41 0.51 -7 5 12 0.03 0.47 -7 5 8 5.93 1.04 -7 5 8 7.83 1.14 7 5 -6 19.76 1.52 -7 5 6 23.29 1.84 7 5 -4 12.57 1.31 -7 5 2 37.96 2.73 7 5 -2 42.12 2.26 7 5 0 17.50 1.97 7 5 2 13.67 1.81 7 5 2 9.96 1.13 7 5 4 7.82 1.43 -7 5 -4 4.70 1.20 7 5 4 5.69 0.85 7 5 6 0.46 0.52 7 5 8 5.66 1.00 7 5 10 14.32 0.96 -7 6 9 64.78 2.68 -7 6 7 109.14 4.47 -7 6 5 102.92 4.27 7 6 -5 101.38 3.98 7 6 -3 140.52 4.97 -7 6 3 122.80 5.17 -7 6 1 96.62 4.77 7 6 -1 163.79 4.95 7 6 1 142.95 5.04 7 6 3 130.22 4.48 7 6 5 131.62 5.01 7 6 5 140.92 4.43 8 -5 -11 1.08 0.31 8 -5 -9 14.30 0.91 8 -5 -7 11.28 0.84 8 -5 -5 16.17 1.00 -8 -5 -7 0.51 0.31 8 -4 -12 68.93 2.72 8 -4 -10 60.14 2.61 8 -4 -8 94.18 3.68 8 -4 -6 117.12 4.33 8 -4 -4 161.83 5.56 8 -4 -2 142.89 4.91 8 -3 -15 2.82 0.46 8 -3 -13 28.01 1.58 8 -3 -9 38.21 2.07 8 -3 -7 34.68 1.93 8 -3 -5 41.90 2.11 8 -3 -3 30.95 1.70 8 -3 -1 14.34 1.08 8 -2 -16 68.08 2.42 8 -2 -14 62.34 2.68 8 -2 -14 63.08 2.52 8 -2 -12 124.07 4.66 8 -2 -12 119.44 4.35 8 -2 -10 115.79 4.53 8 -2 -10 116.83 4.12 8 -2 -10 114.96 4.23 8 -2 -8 173.32 5.73 8 -2 -8 170.93 5.82 8 -2 -6 228.20 8.96 8 -2 -6 227.95 7.53 8 -2 -6 225.69 7.28 8 -2 -6 218.99 7.19 -8 -2 4 272.12 12.02 8 -2 -4 300.72 10.85 8 -2 -4 280.91 9.18 8 -2 -4 299.71 9.07 8 -2 -4 280.27 8.97 8 -2 -2 252.91 9.70 8 -2 -2 239.43 7.90 8 -2 -2 251.03 7.82 -8 -2 0 357.14 13.74 8 -2 0 343.05 10.61 8 -2 2 252.02 10.34 8 -2 2 239.30 7.90 -8 -2 -2 246.47 10.70 8 -2 4 244.76 7.92 -8 -2 -4 255.59 10.79 8 -2 6 182.58 8.85 8 -2 6 179.41 6.11 -8 -2 -6 172.92 8.59 8 -2 8 101.09 3.81 8 -2 10 78.37 3.02 8 -2 12 68.00 2.50 8 -1 -17 4.46 0.51 8 -1 -15 6.23 0.72 8 -1 -13 40.65 2.21 8 -1 -13 46.62 2.16 8 -1 -11 5.00 0.70 8 -1 -11 3.58 0.74 8 -1 -11 4.51 0.73 8 -1 -9 59.38 2.83 8 -1 -9 62.22 2.58 8 -1 -9 59.43 2.59 8 -1 -7 62.06 3.95 8 -1 -7 61.02 2.79 8 -1 -7 62.16 2.60 8 -1 -7 61.21 2.58 8 -1 -5 66.51 4.07 8 -1 -5 67.20 2.72 8 -1 -5 68.45 2.75 8 -1 -3 40.16 3.08 8 -1 -3 43.67 1.96 -8 -1 3 44.73 3.90 8 -1 -3 42.48 2.06 8 -1 -3 40.83 1.99 8 -1 -1 30.10 2.76 8 -1 -1 26.59 1.57 -8 -1 1 27.24 3.09 -8 -1 -1 4.42 1.51 8 -1 1 3.49 1.20 8 -1 1 3.29 0.64 8 -1 3 80.04 5.36 8 -1 3 85.43 3.35 -8 -1 -3 73.42 5.37 -8 -1 -5 6.21 1.66 8 -1 5 5.11 1.54 8 -1 5 4.38 0.72 -8 -1 -7 1.61 1.13 8 -1 7 3.47 1.38 8 -1 7 3.58 0.65 8 -1 9 13.43 1.11 8 -1 11 1.99 0.52 8 -1 13 6.44 0.61 8 0 -18 46.51 1.78 8 0 -16 105.05 3.81 8 0 -14 80.52 3.29 8 0 -12 141.55 5.38 8 0 -12 151.72 5.25 8 0 -12 151.07 5.33 8 0 -10 152.86 5.67 8 0 -10 152.85 5.38 8 0 -10 156.75 5.44 8 0 -8 217.88 7.44 8 0 -8 210.89 7.12 8 0 -8 223.41 7.19 8 0 -6 318.86 11.70 8 0 -6 312.55 9.73 8 0 -6 289.53 9.39 8 0 -6 295.58 9.47 8 0 -4 371.72 13.60 8 0 -4 372.67 11.65 8 0 -4 371.00 11.37 8 0 -4 368.51 11.49 -8 0 2 321.92 13.12 8 0 -2 317.80 9.94 8 0 -2 304.24 9.66 8 0 -2 312.42 12.07 -8 0 0 496.83 18.07 8 0 0 510.96 17.43 8 0 0 454.85 14.40 -8 0 -2 292.08 12.66 8 0 2 314.98 12.55 8 0 2 287.64 9.38 -8 0 -4 305.98 13.01 8 0 4 311.61 12.98 8 0 4 291.39 9.52 -8 0 -6 214.69 10.50 8 0 6 231.91 10.82 8 0 6 213.26 7.25 -8 0 -8 118.89 7.09 8 0 8 108.59 7.02 8 0 8 108.65 4.21 8 0 10 87.22 3.45 8 0 12 71.80 2.81 8 1 -17 4.39 0.57 8 1 -15 6.99 0.82 8 1 -13 49.07 2.39 8 1 -11 4.24 0.74 8 1 -11 5.37 0.80 8 1 -9 64.46 2.75 8 1 -9 59.87 2.72 8 1 -7 59.89 4.14 8 1 -7 66.03 2.75 8 1 -7 65.10 2.79 8 1 -5 70.74 2.86 8 1 -5 73.46 2.97 -8 1 3 47.99 4.23 8 1 -3 47.00 3.54 8 1 -3 40.85 1.96 8 1 -3 44.72 2.16 -8 1 1 26.19 3.24 8 1 -1 27.32 1.72 8 1 -1 33.88 3.12 8 1 -1 30.06 2.01 -8 1 -1 1.54 1.49 8 1 1 3.36 1.33 8 1 1 3.59 0.74 -8 1 -3 84.83 6.01 8 1 3 85.19 5.82 8 1 3 82.74 3.53 8 1 3 95.42 4.10 -8 1 -5 6.29 1.77 8 1 5 4.31 1.61 8 1 5 5.22 0.82 8 1 5 5.67 1.17 -8 1 -7 3.68 1.60 8 1 7 3.64 1.56 8 1 7 3.05 0.70 8 1 7 2.94 1.00 8 1 9 14.18 1.17 8 1 11 2.29 0.57 8 1 13 6.90 0.64 8 2 -14 76.27 3.14 -8 2 12 142.99 5.27 8 2 -12 143.29 5.21 8 2 -10 139.01 4.95 8 2 -10 134.29 5.01 8 2 -8 188.17 6.46 8 2 -8 193.56 6.53 8 2 -6 243.00 10.43 8 2 -6 253.98 8.34 8 2 -6 249.09 8.37 8 2 -4 306.79 11.97 8 2 -4 314.18 9.68 8 2 -4 315.04 9.78 8 2 -4 291.58 9.22 -8 2 2 271.74 12.25 8 2 -2 267.64 10.98 8 2 -2 255.67 8.60 8 2 -2 273.63 9.18 8 2 -2 263.54 8.18 -8 2 0 448.30 17.20 8 2 0 388.89 13.00 8 2 0 403.90 15.72 8 2 0 451.25 13.72 8 2 2 252.98 11.39 8 2 2 247.54 8.53 -8 2 -4 279.22 12.70 8 2 4 272.01 12.38 8 2 4 267.32 9.11 8 2 4 289.33 9.84 -8 2 -6 199.27 10.35 8 2 6 191.98 10.21 8 2 6 211.17 7.17 8 2 6 209.01 7.71 8 2 8 107.00 4.07 8 2 8 98.22 4.36 8 2 10 94.47 3.62 8 2 12 76.57 2.55 -8 3 13 34.51 1.91 -8 3 11 3.91 0.75 -8 3 11 3.58 0.81 -8 3 9 47.91 2.38 8 3 -9 41.38 2.17 8 3 -7 37.32 1.93 8 3 -7 40.43 2.05 -8 3 5 52.92 2.75 8 3 -5 48.14 2.32 8 3 -3 36.22 2.40 8 3 -3 37.05 1.79 8 3 -1 20.74 1.33 8 3 -1 20.03 1.92 8 3 1 1.77 1.11 8 3 1 0.51 0.59 8 3 5 5.99 1.33 -8 3 -5 5.65 1.91 8 3 5 5.58 0.85 8 3 7 1.93 1.09 8 3 7 2.03 0.67 8 3 9 13.81 0.93 8 3 9 10.82 1.29 8 3 11 2.15 0.36 -8 4 12 99.49 3.91 -8 4 10 93.22 3.84 -8 4 10 95.50 4.04 -8 4 8 129.94 5.06 -8 4 6 167.70 5.90 8 4 -6 141.10 5.14 -8 4 4 228.65 8.25 -8 4 2 196.88 7.22 8 4 -2 179.38 6.94 8 4 -2 183.34 6.17 -8 4 0 274.71 10.04 -8 4 0 244.09 12.25 8 4 0 293.37 9.94 8 4 0 264.48 8.77 -8 4 -2 177.12 7.49 8 4 2 187.89 7.28 -8 4 -4 194.44 7.48 8 4 4 173.28 6.03 8 4 6 144.94 5.05 8 4 6 142.37 5.89 8 4 8 79.95 3.56 8 4 8 84.82 2.97 8 4 10 59.64 2.53 8 4 10 67.28 2.16 -8 5 11 2.21 0.60 -8 5 9 20.32 1.46 -8 5 9 24.00 1.58 -8 5 7 21.65 1.67 8 5 -5 24.81 1.59 -8 5 5 26.32 1.89 -8 5 3 24.85 2.08 8 5 -3 26.46 1.70 -8 5 -1 0.68 0.99 8 5 1 1.35 1.04 -8 5 -3 21.11 1.94 8 5 3 20.46 1.91 8 5 3 21.48 1.38 8 5 5 3.68 0.66 8 5 5 3.02 1.03 8 5 7 0.29 0.67 8 6 -4 123.63 4.41 -8 6 4 123.19 4.70 8 6 -2 112.13 4.03 -8 6 2 106.13 4.29 8 6 0 160.50 5.37 8 6 2 113.54 3.89 8 6 4 109.98 3.56 -9 -5 -6 1.33 0.29 9 -4 -13 43.73 1.71 9 -4 -11 73.58 2.80 9 -4 -9 51.87 2.28 9 -4 -7 116.23 4.22 9 -4 -5 35.05 1.77 9 -3 -14 7.04 0.65 9 -3 -10 6.93 0.86 9 -3 -8 3.24 0.64 9 -3 -6 1.82 0.55 9 -3 -4 6.00 0.77 9 -2 -15 58.03 2.14 9 -2 -13 96.89 3.63 9 -2 -13 90.69 3.38 9 -2 -11 143.77 5.09 9 -2 -11 135.90 4.63 9 -2 -11 130.49 4.74 9 -2 -9 88.57 3.37 9 -2 -9 92.26 3.51 9 -2 -7 191.22 6.76 9 -2 -7 196.19 6.45 9 -2 -7 199.77 6.56 -9 -2 5 36.79 3.97 9 -2 -5 42.29 3.23 9 -2 -5 53.80 2.45 9 -2 -5 49.77 2.25 9 -2 -5 50.73 2.22 -9 -2 3 270.24 12.07 9 -2 -3 283.76 10.83 9 -2 -3 280.54 9.00 9 -2 -3 275.07 8.81 -9 -2 1 279.71 12.04 9 -2 -1 284.86 10.96 9 -2 -1 267.66 8.73 9 -2 1 99.92 3.84 -9 -2 -1 108.69 6.45 -9 -2 -3 105.62 6.30 9 -2 3 90.30 5.62 9 -2 3 101.42 3.90 -9 -2 -5 72.09 5.13 9 -2 5 71.27 5.02 9 -2 5 77.98 3.17 9 -2 7 121.48 4.40 9 -2 9 73.94 2.87 9 -2 11 64.64 2.36 9 -1 -16 12.21 0.82 9 -1 -14 12.39 0.97 9 -1 -12 47.40 2.37 9 -1 -12 46.87 2.13 9 -1 -12 45.19 2.19 9 -1 -10 10.34 1.10 9 -1 -10 9.87 0.95 9 -1 -10 10.48 0.99 9 -1 -8 4.17 0.78 9 -1 -8 3.67 0.66 9 -1 -8 2.99 0.62 9 -1 -6 2.99 1.03 9 -1 -6 2.23 0.55 9 -1 -6 2.31 0.58 9 -1 -4 16.30 2.04 -9 -1 4 13.75 2.53 9 -1 -4 13.05 1.13 9 -1 -4 13.82 1.07 9 -1 -4 14.27 1.11 -9 -1 2 30.69 3.54 9 -1 -2 34.84 3.09 9 -1 -2 36.80 1.90 -9 -1 0 13.77 2.49 9 -1 0 13.26 1.15 9 -1 0 12.31 1.96 -9 -1 -2 24.51 3.15 9 -1 2 22.57 2.78 9 -1 2 26.97 1.65 -9 -1 -4 25.06 3.12 9 -1 4 24.66 2.98 9 -1 4 25.67 1.61 -9 -1 -6 1.82 1.28 9 -1 6 2.54 1.24 9 -1 6 3.24 0.70 9 -1 8 15.39 1.19 9 -1 10 16.87 1.13 9 -1 12 2.80 0.44 9 0 -17 48.63 1.88 9 0 -15 88.78 3.35 9 0 -13 124.51 4.57 9 0 -11 171.53 5.97 9 0 -11 176.60 6.07 9 0 -9 115.83 4.54 9 0 -9 115.00 4.30 9 0 -9 113.69 4.32 9 0 -7 260.72 10.40 9 0 -7 246.32 8.24 9 0 -7 238.69 7.94 9 0 -7 241.38 8.00 9 0 -5 54.37 3.89 9 0 -5 56.16 2.44 9 0 -5 50.57 2.43 -9 0 3 347.29 14.60 9 0 -3 381.01 13.70 9 0 -3 349.92 10.84 9 0 -3 334.03 10.94 -9 0 1 338.87 14.30 9 0 -1 355.53 13.55 9 0 -1 330.95 10.80 -9 0 -1 114.33 7.21 9 0 1 123.02 6.85 9 0 1 115.76 4.53 -9 0 -3 113.17 7.16 9 0 3 120.29 7.06 9 0 3 117.37 4.53 -9 0 -5 84.08 6.05 9 0 5 93.81 6.26 9 0 5 93.72 3.80 -9 0 -7 157.55 8.43 9 0 7 160.92 8.51 9 0 7 149.07 5.44 9 0 9 87.20 3.46 9 0 11 78.41 3.00 9 1 -16 14.00 0.94 9 1 -14 15.64 1.17 9 1 -12 52.41 2.42 9 1 -12 51.49 2.46 9 1 -10 11.47 1.08 9 1 -10 10.24 1.03 9 1 -8 3.22 0.68 9 1 -8 4.06 0.74 9 1 -6 2.41 1.08 9 1 -6 2.85 0.61 9 1 -6 2.92 0.67 -9 1 4 13.79 2.64 9 1 -4 11.75 1.94 9 1 -4 12.87 1.06 9 1 -4 14.41 1.21 -9 1 2 32.38 3.83 9 1 -2 39.99 3.56 9 1 -2 34.22 1.97 -9 1 0 16.29 2.76 9 1 0 14.47 1.29 9 1 0 12.19 2.15 -9 1 -2 26.39 3.49 9 1 2 27.20 3.27 9 1 2 27.30 1.80 -9 1 -4 23.34 3.26 9 1 4 25.36 3.21 9 1 4 24.93 1.69 -9 1 -6 3.71 1.61 9 1 6 1.62 1.22 9 1 6 3.92 0.77 9 1 8 18.94 1.36 9 1 10 15.36 1.13 9 1 12 2.48 0.44 9 2 -13 117.23 4.31 9 2 -11 150.80 5.38 9 2 -11 157.34 5.52 9 2 -9 101.95 3.93 9 2 -9 101.61 3.99 9 2 -7 220.09 7.46 9 2 -7 226.95 7.49 -9 2 5 51.36 4.99 9 2 -5 51.78 4.06 9 2 -5 58.69 2.58 9 2 -5 55.29 2.60 -9 2 3 331.84 14.02 9 2 -3 309.05 12.29 9 2 -3 297.89 9.64 9 2 -3 291.35 9.08 -9 2 1 331.77 14.38 9 2 -1 291.09 12.62 9 2 -1 313.85 10.16 9 2 -1 336.84 10.80 9 2 -1 303.32 9.61 -9 2 -1 123.21 7.76 9 2 1 113.41 4.64 9 2 1 117.62 6.90 9 2 1 122.28 5.13 -9 2 -3 117.26 7.53 9 2 3 97.62 6.61 9 2 3 113.80 4.54 9 2 3 116.56 4.97 -9 2 -5 86.96 6.30 9 2 5 82.33 6.06 9 2 5 88.85 3.71 9 2 5 85.34 4.06 9 2 7 151.83 5.23 9 2 7 128.61 5.38 9 2 9 85.36 3.32 9 2 11 75.22 2.52 -9 3 12 33.19 1.85 -9 3 10 9.51 0.99 -9 3 8 3.54 0.76 -9 3 6 2.04 0.74 9 3 -6 1.32 0.48 -9 3 4 9.90 1.33 9 3 -4 6.90 0.86 9 3 -4 8.24 0.84 9 3 -2 26.79 2.09 9 3 -2 26.35 1.46 9 3 0 7.16 0.90 9 3 0 8.88 0.97 9 3 0 10.09 1.50 9 3 2 25.97 1.52 9 3 2 26.45 2.14 9 3 4 19.34 1.88 9 3 6 3.31 0.67 9 3 6 2.03 1.01 9 3 8 13.42 1.24 9 3 8 14.91 0.96 9 3 10 12.14 0.69 -9 4 13 67.96 2.56 -9 4 11 105.01 4.03 -9 4 9 75.48 3.23 -9 4 7 151.37 5.62 9 4 -5 46.36 2.14 -9 4 3 218.69 7.95 -9 4 1 227.92 8.25 9 4 -1 220.59 7.99 9 4 -1 212.84 7.17 9 4 1 98.91 4.42 9 4 1 90.29 3.60 -9 4 -3 112.74 4.83 9 4 3 88.07 4.30 -9 4 -5 97.15 4.03 9 4 5 74.87 3.01 9 4 7 97.99 4.12 9 4 7 114.04 3.67 9 4 9 59.95 2.01 -9 5 10 5.27 0.72 -9 5 8 2.78 0.69 -9 5 8 2.55 0.60 -9 5 6 1.63 0.71 9 5 -4 3.45 0.72 -9 5 4 4.85 0.91 -9 5 2 17.48 1.67 9 5 -2 17.91 1.30 9 5 2 16.70 1.53 -9 5 -4 14.48 1.33 9 5 4 11.19 1.25 -9 6 3 109.89 3.96 9 6 -3 108.23 3.69 9 6 -1 129.09 4.26 9 6 1 67.61 2.42 10 -4 -10 68.74 2.55 10 -4 -8 88.16 3.22 10 -3 -13 2.30 0.41 10 -3 -9 1.41 0.50 10 -3 -7 24.61 1.50 10 -3 -5 0.42 0.42 10 -2 -14 33.08 1.38 10 -2 -12 99.67 3.59 10 -2 -12 88.22 3.31 10 -2 -10 132.25 4.80 10 -2 -10 130.49 4.43 10 -2 -10 127.81 4.53 10 -2 -8 147.67 5.02 10 -2 -8 147.58 5.13 10 -2 -6 145.98 6.90 -10 -2 6 139.62 8.37 10 -2 -6 155.17 5.49 10 -2 -6 154.62 5.21 10 -2 -6 150.30 5.27 10 -2 -4 18.22 2.19 -10 -2 4 16.59 2.69 10 -2 -4 22.12 1.32 -10 -2 2 185.28 9.59 10 -2 -2 190.65 8.40 10 -2 -2 197.32 6.51 -10 -2 0 126.97 7.30 10 -2 0 121.83 6.26 10 -2 0 118.01 4.39 -10 -2 -2 120.63 7.07 10 -2 2 133.95 4.73 10 -2 2 113.88 6.39 10 -2 4 195.47 6.60 10 -2 6 145.92 5.08 10 -2 8 89.10 3.25 10 -2 10 102.83 3.38 10 -1 -15 1.42 0.37 10 -1 -13 3.81 0.60 10 -1 -11 8.35 0.96 10 -1 -11 9.64 0.90 10 -1 -11 9.68 0.93 10 -1 -9 2.60 0.67 10 -1 -9 3.12 0.62 10 -1 -9 3.62 0.65 10 -1 -7 41.04 2.18 10 -1 -7 39.16 1.99 10 -1 -7 41.25 2.04 -10 -1 5 -0.21 1.18 10 -1 -5 1.21 0.84 10 -1 -5 0.86 0.49 10 -1 -5 0.32 0.49 -10 -1 3 3.06 1.55 10 -1 -3 4.19 1.25 10 -1 -3 5.14 0.79 -10 -1 1 4.95 1.84 10 -1 -1 2.69 1.11 10 -1 -1 4.43 0.78 -10 -1 -1 62.36 5.09 10 -1 1 63.34 2.88 10 -1 1 57.01 4.44 -10 -1 -3 65.77 5.15 10 -1 3 69.11 4.99 10 -1 3 72.36 3.16 10 -1 5 2.87 0.67 10 -1 7 3.54 0.66 10 -1 9 14.84 1.04 10 -1 11 0.63 0.32 10 0 -16 59.82 2.21 10 0 -14 50.09 2.18 10 0 -12 123.00 4.39 10 0 -12 121.30 4.45 10 0 -10 171.87 5.91 10 0 -10 170.38 5.94 10 0 -8 182.87 6.20 10 0 -8 173.83 6.13 -10 0 6 173.04 9.91 10 0 -6 196.74 8.87 10 0 -6 192.52 6.59 10 0 -6 201.04 6.70 10 0 -4 20.52 2.52 -10 0 4 19.32 3.07 10 0 -4 22.28 1.42 10 0 -4 20.26 1.44 -10 0 2 261.84 12.23 10 0 -2 259.37 11.01 10 0 -2 253.87 8.51 -10 0 0 154.42 8.82 10 0 0 149.93 5.55 10 0 0 142.63 7.70 -10 0 -2 139.97 8.44 10 0 2 158.59 8.26 10 0 2 160.55 5.80 -10 0 -4 212.97 10.74 10 0 4 218.89 10.55 10 0 4 235.27 7.81 10 0 6 179.17 6.29 10 0 8 101.72 3.86 10 0 10 128.82 4.40 10 1 -15 1.51 0.43 10 1 -13 3.75 0.67 10 1 -11 9.92 0.99 10 1 -11 8.33 0.95 10 1 -9 2.82 0.68 10 1 -9 2.83 0.69 10 1 -7 38.97 3.52 10 1 -7 41.32 2.15 10 1 -7 39.72 2.08 -10 1 5 0.91 1.55 10 1 -5 0.15 0.71 10 1 -5 0.54 0.50 10 1 -5 1.05 0.60 -10 1 3 8.05 2.15 10 1 -3 5.25 1.44 10 1 -3 5.39 0.89 -10 1 1 4.79 1.81 10 1 -1 2.89 1.24 10 1 -1 3.95 0.84 -10 1 -1 68.90 5.63 10 1 1 62.08 3.02 10 1 1 62.97 4.93 -10 1 -3 73.44 5.69 10 1 3 69.48 5.30 10 1 3 76.25 3.39 10 1 5 3.53 0.78 10 1 7 3.37 0.70 10 1 9 15.51 1.08 10 1 11 0.73 0.33 10 2 -12 112.19 4.11 10 2 -10 152.04 5.30 10 2 -10 151.78 5.37 10 2 -8 164.33 5.73 10 2 -8 164.10 5.77 10 2 -6 152.08 7.97 -10 2 6 146.64 9.17 10 2 -6 170.10 5.90 10 2 -6 172.44 5.89 10 2 -4 17.52 2.53 -10 2 4 16.58 3.16 10 2 -4 22.54 1.49 10 2 -4 18.73 1.08 -10 2 2 226.64 11.39 10 2 -2 210.35 9.73 10 2 -2 221.25 7.32 10 2 -2 206.74 6.72 -10 2 0 130.83 8.34 10 2 0 126.93 7.34 10 2 0 138.53 5.16 10 2 0 138.84 4.70 -10 2 -2 139.46 8.33 10 2 2 138.97 5.22 10 2 2 127.54 7.42 10 2 4 221.71 7.59 10 2 6 165.75 5.82 10 2 10 124.15 3.88 -10 3 11 7.77 0.87 -10 3 9 2.59 0.62 -10 3 5 0.67 0.66 -10 3 3 6.49 1.26 10 3 -3 4.00 0.68 10 3 -1 4.06 0.71 10 3 1 51.73 2.96 10 3 1 50.64 2.24 10 3 3 55.55 2.38 10 3 5 3.00 0.93 10 3 7 3.46 0.55 10 3 9 12.42 0.67 -10 4 12 66.81 2.45 -10 4 10 98.96 3.74 -10 4 8 118.61 4.39 -10 4 6 120.08 4.59 -10 4 4 29.97 1.97 -10 4 2 174.32 6.51 -10 4 0 119.32 4.77 10 4 0 101.89 3.83 10 4 2 100.67 4.39 10 4 2 110.12 3.85 -10 4 -4 198.56 6.50 10 4 4 163.26 5.55 10 4 6 129.46 4.17 10 4 8 72.76 2.32 -10 5 9 1.04 0.42 -10 5 7 16.85 1.16 -10 5 5 0.62 0.54 -10 5 3 3.00 0.75 10 5 -1 3.21 0.62 -10 5 1 4.15 0.92 -10 5 1 2.31 0.67 10 5 1 31.88 1.49 -10 5 -3 34.11 1.81 10 5 3 33.48 1.45 10 5 5 1.38 0.29 11 -2 -11 78.43 2.85 11 -2 -9 135.57 4.50 11 -2 -9 133.62 4.60 11 -2 -7 119.60 4.16 11 -2 -5 191.94 6.31 11 -2 -3 152.19 5.20 11 -2 -1 193.09 6.40 11 -2 1 70.72 2.87 11 -2 3 209.86 6.84 11 -2 5 142.92 4.88 11 -2 5 145.10 4.84 11 -2 7 122.73 4.07 11 -2 7 122.06 4.03 11 -2 9 48.29 1.65 11 -1 -14 2.14 0.38 11 -1 -12 5.65 0.63 11 -1 -12 4.90 0.62 11 -1 -10 0.37 0.41 11 -1 -10 0.66 0.41 11 -1 -8 3.99 0.66 11 -1 -8 4.21 0.67 11 -1 -6 59.60 2.60 11 -1 -6 57.22 2.56 -11 -1 4 4.16 1.73 11 -1 -4 3.24 1.10 11 -1 -4 4.17 0.75 -11 -1 2 5.60 1.77 11 -1 -2 6.20 1.41 11 -1 -2 6.61 0.85 11 -1 0 4.27 1.25 11 -1 0 5.99 0.84 11 -1 2 2.61 0.67 11 -1 4 10.17 1.02 11 -1 6 2.16 0.57 11 -1 8 7.74 0.72 11 -1 10 2.26 0.34 11 0 -15 49.74 1.88 11 0 -13 93.69 3.40 11 0 -11 102.75 3.78 11 0 -11 104.66 3.85 11 0 -9 176.20 5.87 11 0 -9 165.40 5.84 11 0 -7 160.15 5.44 11 0 -7 143.71 5.30 -11 0 5 232.54 11.72 11 0 -5 226.09 10.05 11 0 -5 237.80 7.83 11 0 -5 241.49 7.92 -11 0 3 172.54 9.76 11 0 -3 188.67 8.80 11 0 -3 193.04 6.57 -11 0 1 238.54 11.67 11 0 -1 228.13 10.41 11 0 -1 246.72 8.13 -11 0 -1 78.71 5.95 11 0 1 85.85 3.64 11 0 1 79.32 5.33 11 0 1 88.13 3.59 11 0 3 266.24 8.84 11 0 5 176.52 6.14 11 0 7 155.92 5.35 11 0 9 75.59 2.77 11 1 -14 2.64 0.46 11 1 -12 5.38 0.66 11 1 -12 5.53 0.70 11 1 -10 0.26 0.44 11 1 -10 0.52 0.50 11 1 -8 5.11 0.78 11 1 -8 4.28 0.74 11 1 -6 60.66 2.79 11 1 -6 62.11 2.75 -11 1 4 2.48 1.50 11 1 -4 3.69 1.27 11 1 -4 3.13 0.73 -11 1 2 5.21 1.82 11 1 -2 4.96 1.46 11 1 -2 5.37 0.89 11 1 0 5.00 1.43 11 1 0 5.53 0.90 11 1 2 3.17 0.77 11 1 4 10.75 1.09 11 1 6 2.74 0.63 11 1 8 8.43 0.78 11 1 10 3.01 0.37 11 1 10 2.70 0.30 11 2 -9 152.35 5.25 11 2 -9 155.21 5.34 11 2 -7 133.16 4.79 -11 2 5 222.75 7.44 11 2 -5 212.74 7.26 11 2 -3 160.75 5.70 11 2 -1 222.71 7.22 11 2 -1 205.93 6.64 11 2 1 89.40 3.55 11 2 1 84.45 3.13 11 2 3 251.09 8.28 11 2 3 255.56 7.91 11 2 5 158.27 5.56 11 2 5 170.83 5.34 11 2 9 72.87 2.36 -11 3 10 1.11 0.48 -11 3 8 3.57 0.59 -11 3 4 3.19 0.80 -11 3 2 5.76 1.18 11 3 0 6.19 0.67 11 3 2 2.21 0.55 11 3 4 7.49 0.69 11 3 8 5.62 0.41 -11 4 9 98.56 3.56 -11 4 7 91.24 3.39 -11 4 5 136.04 4.86 -11 4 3 129.92 4.82 -11 4 1 173.85 6.20 -11 4 -1 76.96 3.16 11 4 1 63.24 2.45 11 4 3 176.80 5.52 -11 4 -5 124.27 4.15 11 4 5 119.42 3.79 -11 5 6 19.75 1.05 -11 5 4 2.13 0.49 11 5 0 2.98 0.42 -11 5 0 3.41 0.54 12 -2 -10 84.90 2.84 12 -2 -8 119.87 3.95 12 -2 -6 95.72 3.37 12 -2 -4 114.15 3.96 12 -2 -2 162.78 5.36 12 -2 0 110.40 3.85 12 -2 2 104.64 3.63 12 -2 4 101.20 3.42 12 -2 6 52.29 1.85 12 -1 -11 6.87 0.61 12 -1 -11 6.51 0.64 12 -1 -9 2.76 0.52 12 -1 -7 12.73 0.97 12 -1 -5 3.47 0.63 12 -1 -3 3.87 0.69 12 -1 -1 3.68 0.69 12 -1 1 7.01 0.81 12 -1 3 0.35 0.45 12 -1 5 0.95 0.40 12 -1 7 2.08 0.38 12 0 -12 116.02 3.94 12 0 -10 119.68 4.06 12 0 -10 112.29 4.07 12 0 -8 160.95 5.37 12 0 -8 153.40 5.37 12 0 -6 120.74 4.42 12 0 -4 139.56 5.01 12 0 -2 200.03 6.76 12 0 0 142.21 5.10 12 0 2 139.66 4.98 12 0 4 130.83 4.60 12 0 6 67.48 2.63 12 0 8 79.59 2.71 12 1 -11 7.27 0.68 12 1 -11 7.21 0.70 12 1 -9 3.10 0.60 12 1 -7 13.73 1.09 12 1 -5 3.49 0.73 12 1 -3 3.08 0.69 12 1 -1 4.24 0.78 12 1 1 7.75 0.90 12 1 3 0.14 0.50 12 1 5 0.46 0.42 12 1 7 1.88 0.39 12 1 7 2.67 0.34 12 2 -6 103.06 3.76 -12 2 4 137.07 4.91 12 2 -4 132.06 4.72 12 2 -2 182.72 6.13 12 2 0 129.63 4.58 12 2 2 123.36 4.27 12 2 2 120.01 3.96 12 2 4 122.20 3.93 12 2 6 68.58 2.30 -12 3 9 1.59 0.44 -12 3 7 8.58 0.72 -12 3 5 2.94 0.57 -12 3 3 2.24 0.63 -12 3 1 4.25 0.86 -12 3 -1 6.90 1.04 -12 3 -3 0.55 0.66 12 3 3 0.48 0.33 -12 3 -5 0.85 0.48 12 3 5 0.64 0.28 -12 4 8 74.68 2.62 -12 4 6 67.06 2.45 -12 4 4 87.54 3.17 -12 4 2 133.90 4.58 -12 4 0 101.15 3.66 -12 4 -2 89.05 3.19 13 -2 -7 68.32 2.33 13 -2 -5 71.57 2.49 13 -2 -3 97.63 3.27 13 -2 -1 80.89 2.78 13 -2 1 85.83 2.87 13 -2 3 59.07 2.00 13 -1 -10 0.49 0.26 13 -1 -8 10.62 0.74 13 -1 -6 10.88 0.81 13 -1 -4 0.65 0.41 13 -1 -2 2.15 0.50 13 -1 0 0.23 0.38 13 -1 2 2.75 0.47 13 -1 4 3.23 0.43 13 -1 6 0.32 0.18 13 0 -9 69.66 2.55 13 0 -7 94.33 3.38 13 0 -5 90.80 3.36 13 0 -3 114.22 4.07 13 0 -1 100.14 3.66 13 0 1 111.60 3.92 13 0 3 87.28 3.12 13 0 5 99.99 3.33 13 0 7 92.42 2.88 13 1 -10 0.13 0.31 13 1 -8 11.19 0.82 13 1 -6 11.82 0.91 13 1 -4 0.89 0.47 13 1 -2 2.03 0.52 13 1 0 0.41 0.41 13 1 2 2.93 0.51 13 1 4 3.40 0.46 13 1 6 0.37 0.20 -13 2 3 96.37 3.46 -13 3 2 1.42 0.42 -13 3 0 0.13 0.39 -13 3 -2 2.10 0.46 14 -1 -7 2.31 0.32 14 -1 -5 6.61 0.52 14 -1 -3 0.03 0.26 14 -1 -1 7.39 0.56 14 -1 1 5.48 0.45 14 0 -8 63.42 2.19 14 0 -6 61.89 2.23 14 0 -4 90.34 3.10 14 0 -2 109.64 3.66 14 0 0 74.50 2.60 14 0 2 77.47 2.60 14 1 -9 0.24 0.18 14 1 -7 2.91 0.37 14 1 -5 7.59 0.59 14 1 -3 0.23 0.30 -14 1 1 5.88 0.58 14 1 -1 8.35 0.61 14 1 1 5.84 0.48 14 1 3 9.43 0.51 0 0 0 0.00 0.00 TITL 24446_ZMV-018_auto in I2 REM I2 (#5 in standard setting) CELL 1.54184 11.857328 6.206602 15.925747 90.0000 99.1610 90.0000 ZERR 2.00 0.000882 0.000464 0.001179 0.0000 0.0071 0.0000 LATT -2 SYMM -x, y,-z SFAC C H O F Pd Hg UNIT 44.00 28.00 8.00 20.00 2.00 2.00 REM CrysAlisPro recorded range (K): Min=100.0; max=100.0; aver:100.0 TEMP -173 TREF HKLF 4 END _computing_structure_solution 'SHELXT 2018/2 (Sheldrick, 2018)' ; _shelx_hkl_checksum 19464 _olex2_submission_special_instructions 'No special instructions were received' _oxdiff_exptl_absorpt_empirical_details ; Empirical correction (ABSPACK) includes: - Absorption correction using spherical harmonics - Frame scaling ; _oxdiff_exptl_absorpt_empirical_full_max 4.670 _oxdiff_exptl_absorpt_empirical_full_min 0.400 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y, -z' 'x+1/2, y+1/2, z+1/2' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z' '-x+1/2, -y+1/2, -z+1/2' 'x+1/2, -y+1/2, z+1/2' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_site_symmetry_order _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_refinement_flags_adp _atom_site_refinement_flags_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Hg1D Hg 0.000000 0.500000 1.000000 0.0394(11) Uani 1 4 d S T P . . Pd1 Pd 0.000000 0.000000 1.000000 0.0346(11) Uani 1 4 d S T P . . F1D F -0.0371(4) 0.500000 0.7992(3) 0.0493(15) Uani 1 2 d S T P . . O1 O 0.0231(4) 0.000000 1.1266(3) 0.0415(15) Uani 1 2 d S T P . . F4D F 0.4213(4) 0.500000 0.9111(3) 0.0543(15) Uani 1 2 d S T P . . O2 O -0.1659(4) 0.000000 1.0077(3) 0.0389(14) Uani 1 2 d S T P . . F3D F 0.3395(5) 0.500000 0.7413(4) 0.0548(18) Uani 1 2 d S T P . . F5D F 0.2738(4) 0.500000 1.0243(3) 0.0512(16) Uani 1 2 d S T P . . F2D F 0.1108(4) 0.500000 0.6859(3) 0.0553(15) Uani 1 2 d S T P . . C1 C 0.1202(7) 0.000000 1.2666(4) 0.0459(19) Uani 1 2 d S T P . . H1A H 0.068746 0.113661 1.280402 0.069 Uiso 0.5 1 calc R U P A -1 H1B H 0.197376 0.026426 1.297194 0.069 Uiso 0.5 1 calc R U P A -1 H1C H 0.093010 -0.140087 1.283570 0.069 Uiso 0.5 1 calc R U P A -1 C1D C 0.1144(6) 0.500000 0.9143(4) 0.0392(17) Uani 1 2 d S T P . . C2 C 0.1223(6) 0.000000 1.1713(4) 0.0389(17) Uani 1 2 d S T P . . C5 C -0.3638(6) 0.000000 0.9621(5) 0.049(2) Uani 1 2 d S T P . . H5A H -0.362623 0.043918 1.021378 0.073 Uiso 0.5 1 calc R U P B -1 H5B H -0.396107 -0.145143 0.953667 0.073 Uiso 0.5 1 calc R U P B -1 H5C H -0.410634 0.101225 0.924289 0.073 Uiso 0.5 1 calc R U P B -1 C2D C 0.0767(6) 0.500000 0.8284(4) 0.0419(18) Uani 1 2 d S T P . . C3D C 0.1504(9) 0.500000 0.7701(6) 0.046(2) Uani 1 2 d S T P . . C5D C 0.3089(6) 0.500000 0.8841(5) 0.0443(19) Uani 1 2 d S T P . . C6D C 0.2320(6) 0.500000 0.9407(5) 0.0448(18) Uani 1 2 d S T P . . C3 C 0.2267(6) 0.000000 1.1429(5) 0.0421(18) Uani 1 2 d S T P . . H3 H 0.293193 0.000000 1.184947 0.051 Uiso 1 2 calc R U P . . C4D C 0.2683(6) 0.500000 0.7971(5) 0.0452(18) Uani 1 2 d S T P . . C4 C -0.2429(6) 0.000000 0.9422(5) 0.0434(19) Uani 1 2 d S T P . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Hg1D 0.0411(11) 0.0303(11) 0.0468(11) 0.000 0.0064(3) 0.000 Pd1 0.0344(11) 0.0285(12) 0.0401(12) 0.000 0.0032(3) 0.000 F1D 0.043(2) 0.049(3) 0.053(3) 0.000 -0.0005(16) 0.000 O1 0.036(2) 0.043(3) 0.045(3) 0.000 0.0019(17) 0.000 F4D 0.042(2) 0.056(3) 0.064(3) 0.000 0.0052(18) 0.000 O2 0.037(2) 0.034(3) 0.044(2) 0.000 0.0023(17) 0.000 F3D 0.053(3) 0.054(4) 0.060(3) 0.000 0.017(2) 0.000 F5D 0.049(3) 0.057(3) 0.045(2) 0.000 0.0011(18) 0.000 F2D 0.058(3) 0.063(3) 0.043(2) 0.000 0.0036(17) 0.000 C1 0.048(4) 0.045(4) 0.044(4) 0.000 0.003(3) 0.000 C1D 0.045(3) 0.029(4) 0.044(3) 0.000 0.008(2) 0.000 C2 0.042(3) 0.029(3) 0.044(3) 0.000 0.000(2) 0.000 C5 0.034(3) 0.054(5) 0.059(4) 0.000 0.005(3) 0.000 C2D 0.041(3) 0.031(4) 0.052(4) 0.000 0.000(3) 0.000 C3D 0.050(5) 0.042(5) 0.046(4) 0.000 0.006(3) 0.000 C5D 0.039(3) 0.038(4) 0.057(4) 0.000 0.010(3) 0.000 C6D 0.045(4) 0.036(4) 0.051(4) 0.000 0.000(3) 0.000 C3 0.035(3) 0.039(4) 0.049(4) 0.000 -0.002(2) 0.000 C4D 0.047(4) 0.034(4) 0.055(4) 0.000 0.012(3) 0.000 C4 0.037(3) 0.033(4) 0.059(4) 0.000 0.004(3) 0.000 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Hg Hg -4.2923 7.6849 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pd Pd 0.1215 3.9337 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag Pd1 Hg1D Pd1 180.0 . 1_565 ? C1D Hg1D Pd1 90.000(2) 5_567 . ? C1D Hg1D Pd1 90.000(1) . 1_565 ? C1D Hg1D Pd1 90.000(1) . . ? C1D Hg1D Pd1 90.000(2) 5_567 1_565 ? C1D Hg1D C1D 180.0 . 5_567 ? Hg1D Pd1 Hg1D 180.0 . 1_545 ? O1 Pd1 Hg1D 90.000(1) 5_557 1_545 ? O1 Pd1 Hg1D 90.000(1) 5_557 . ? O1 Pd1 Hg1D 90.000(1) . 1_545 ? O1 Pd1 Hg1D 90.000(1) . . ? O1 Pd1 O1 180.0 . 5_557 ? O2 Pd1 Hg1D 90.000(1) 5_557 1_545 ? O2 Pd1 Hg1D 90.000(1) 5_557 . ? O2 Pd1 Hg1D 90.000(1) . 1_545 ? O2 Pd1 Hg1D 90.000(1) . . ? O2 Pd1 O1 94.84(18) 5_557 . ? O2 Pd1 O1 94.84(18) . 5_557 ? O2 Pd1 O1 85.16(18) . . ? O2 Pd1 O1 85.16(18) 5_557 5_557 ? O2 Pd1 O2 180.0 5_557 . ? C2 O1 Pd1 122.1(4) . . ? C4 O2 Pd1 122.5(5) . . ? H1A C1 H1B 109.5 . . ? H1A C1 H1C 109.5 . . ? H1B C1 H1C 109.5 . . ? C2 C1 H1A 109.5 . . ? C2 C1 H1B 109.5 . . ? C2 C1 H1C 109.5 . . ? C2D C1D Hg1D 121.0(5) . . ? C2D C1D C6D 116.9(6) . . ? C6D C1D Hg1D 122.1(5) . . ? O1 C2 C1 113.4(6) . . ? O1 C2 C3 127.7(6) . . ? C3 C2 C1 118.9(6) . . ? H5A C5 H5B 109.5 . . ? H5A C5 H5C 109.5 . . ? H5B C5 H5C 109.5 . . ? C4 C5 H5A 109.5 . . ? C4 C5 H5B 109.5 . . ? C4 C5 H5C 109.5 . . ? F1D C2D C1D 119.5(6) . . ? F1D C2D C3D 118.3(7) . . ? C1D C2D C3D 122.3(7) . . ? F2D C3D C2D 120.9(8) . . ? F2D C3D C4D 118.7(8) . . ? C2D C3D C4D 120.4(8) . . ? F4D C5D C6D 121.3(7) . . ? F4D C5D C4D 119.4(6) . . ? C6D C5D C4D 119.3(7) . . ? F5D C6D C1D 119.5(7) . . ? F5D C6D C5D 117.9(7) . . ? C5D C6D C1D 122.6(7) . . ? C2 C3 H3 117.1 . . ? C2 C3 C4 125.8(6) . 5_557 ? C4 C3 H3 117.1 5_557 . ? F3D C4D C3D 120.7(7) . . ? F3D C4D C5D 120.8(7) . . ? C5D C4D C3D 118.5(7) . . ? O2 C4 C5 114.0(7) . . ? O2 C4 C3 127.0(7) . 5_557 ? C3 C4 C5 118.9(6) 5_557 . ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Hg1D Pd1 3.1033(3) . ? Hg1D Pd1 3.1033(3) 1_565 ? Hg1D C1D 2.071(7) . ? Hg1D C1D 2.071(7) 5_567 ? Pd1 O1 1.991(5) . ? Pd1 O1 1.991(5) 5_557 ? Pd1 O2 1.990(5) . ? Pd1 O2 1.990(5) 5_557 ? F1D C2D 1.355(8) . ? O1 C2 1.274(8) . ? F4D C5D 1.333(8) . ? O2 C4 1.273(9) . ? F3D C4D 1.320(10) . ? F5D C6D 1.345(9) . ? F2D C3D 1.348(11) . ? C1 H1A 0.9800 . ? C1 H1B 0.9800 . ? C1 H1C 0.9800 . ? C1 C2 1.522(9) . ? C1D C2D 1.370(10) . ? C1D C6D 1.391(10) . ? C2 C3 1.383(10) . ? C5 H5A 0.9800 . ? C5 H5B 0.9800 . ? C5 H5C 0.9800 . ? C5 C4 1.516(10) . ? C2D C3D 1.373(13) . ? C3D C4D 1.395(13) . ? C5D C6D 1.380(11) . ? C5D C4D 1.393(11) . ? C3 H3 0.9500 . ? C3 C4 1.399(11) 5_557 ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag Hg1D C1D C2D F1D 0.000(3) . . . . ? Hg1D C1D C2D C3D 180.000(3) . . . . ? Hg1D C1D C6D F5D 0.000(3) . . . . ? Hg1D C1D C6D C5D 180.000(3) . . . . ? Pd1 O1 C2 C1 180.000(3) . . . . ? Pd1 O1 C2 C3 0.000(4) . . . . ? Pd1 O2 C4 C5 180.000(2) . . . . ? Pd1 O2 C4 C3 0.000(4) . . . 5_557 ? F1D C2D C3D F2D 0.000(4) . . . . ? F1D C2D C3D C4D 180.000(3) . . . . ? O1 C2 C3 C4 0.000(5) . . . 5_557 ? F4D C5D C6D F5D 0.000(4) . . . . ? F4D C5D C6D C1D 180.000(3) . . . . ? F4D C5D C4D F3D 0.000(4) . . . . ? F4D C5D C4D C3D 180.000(3) . . . . ? F2D C3D C4D F3D 0.000(3) . . . . ? F2D C3D C4D C5D 180.000(3) . . . . ? C1 C2 C3 C4 180.000(4) . . . 5_557 ? C1D C2D C3D F2D 180.000(2) . . . . ? C1D C2D C3D C4D 0.000(4) . . . . ? C2D C1D C6D F5D 180.000(2) . . . . ? C2D C1D C6D C5D 0.000(4) . . . . ? C2D C3D C4D F3D 180.000(4) . . . . ? C2D C3D C4D C5D 0.000(4) . . . . ? C6D C1D C2D F1D 180.000(2) . . . . ? C6D C1D C2D C3D 0.000(4) . . . . ? C6D C5D C4D F3D 180.000(3) . . . . ? C6D C5D C4D C3D 0.000(4) . . . . ? C4D C5D C6D F5D 180.000(2) . . . . ? C4D C5D C6D C1D 0.000(4) . . . . ?