Crystallography Open Database

Information card for entry 7249445

Preview

Coordinates	7249445.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C79 H85 B2 Cl6 N8 Pt2 Rh S2
Calculated formula	C76 H79 B2 N8 Pt2 Rh S2
Title of publication	Restriction of reaction sites on metal-sulfide cores induced by steric repulsion of bis-N-heterocyclic carbene ligands in trinuclear complexes bearing triply bridging sulfide ligands.
Authors of publication	Yabune, Natsuki; Nakajima, Hiroshi; Nishioka, Takanori
Journal of publication	RSC advances
Year of publication	2024
Journal volume	14
Journal issue	40
Pages of publication	29355 - 29367
a	17.827 ± 0.004 Å
b	25.802 ± 0.004 Å
c	13.476 ± 0.003 Å
α	90°
β	128.641 ± 0.005°
γ	90°
Cell volume	4841.6 ± 1.7 Å³
Cell temperature	193 ± 2 K
Ambient diffraction temperature	193.35 K
Number of distinct elements	8
Space group number	8
Hermann-Mauguin space group symbol	C 1 m 1
Hall space group symbol	C -2y
Residual factor for all reflections	0.0447
Residual factor for significantly intense reflections	0.0399
Weighted residual factors for significantly intense reflections	0.0958
Weighted residual factors for all reflections included in the refinement	0.102
Goodness-of-fit parameter for all reflections included in the refinement	0.8978
Diffraction radiation wavelength	0.71075 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
295082 (current)	2024-10-06	cif/ Adding structures of 7249439, 7249440, 7249441, 7249442, 7249443, 7249444, 7249445, 7249446 via cif-deposit CGI script.	7249445.cif