Crystallography Open Database

Information card for entry 7705318

Preview

Coordinates	7705318.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C19 H42 Si5
Calculated formula	C19 H42 Si5
Title of publication	Pentamethylcyclopentadienyl-substituted hypersilylsilylene: reversible and irreversible activation of C[double bond, length as m-dash]C double bonds and dihydrogen.
Authors of publication	Leszczyńska, Kinga I; Deglmann, Peter; Präsang, Carsten; Huch, Volker; Zimmer, Michael; Schweinfurth, David; Scheschkewitz, David
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2020
Journal volume	49
Journal issue	38
Pages of publication	13218 - 13225
a	9.0809 ± 0.0007 Å
b	9.9667 ± 0.0009 Å
c	14.8247 ± 0.0013 Å
α	89.447 ± 0.002°
β	89.918 ± 0.002°
γ	87.141 ± 0.002°
Cell volume	1340 ± 0.2 Å³
Cell temperature	152 ± 2 K
Ambient diffraction temperature	152 ± 2 K
Number of distinct elements	3
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0586
Residual factor for significantly intense reflections	0.0497
Weighted residual factors for significantly intense reflections	0.129
Weighted residual factors for all reflections included in the refinement	0.1327
Goodness-of-fit parameter for all reflections included in the refinement	1.078
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
258861 (current)	2020-11-06	cif/ Updating files of 7705318, 7705319, 7705320, 7705321 Original log message: Adding full bibliography for 7705318--7705321.cif.	7705318.cif
255731	2020-08-29	cif/ Adding structures of 7705318, 7705319, 7705320, 7705321 via cif-deposit CGI script.	7705318.cif