#------------------------------------------------------------------------------
#$Date: 2022-11-24 11:52:49 +0200 (Thu, 24 Nov 2022) $
#$Revision: 279541 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/62/8106242.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8106242
loop_
_publ_author_name
'Li, Qing-Lin'
'Li, Peng-Peng'
'Ma, Jin-Xia'
'Zhao, Ji-Xing'
'Zhao, Li'
_publ_section_title
;
 Crystal structure of
 bis{2-((E)-((4-((E)-1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2
 N,O}zinc(II), C32H30N4O4Zn
;
_journal_issue                   4
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              637
_journal_page_last               639
_journal_paper_doi               10.1515/ncrs-2017-0404
_journal_volume                  233
_journal_year                    2018
_chemical_formula_sum            'C32 H30 N4 O4 Zn'
_chemical_formula_weight         599.97
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_cell_angle_alpha                98.585(3)
_cell_angle_beta                 94.985(3)
_cell_angle_gamma                92.916(3)
_cell_formula_units_Z            2
_cell_length_a                   8.6632(8)
_cell_length_b                   12.7133(10)
_cell_length_c                   14.2719(12)
_cell_measurement_reflns_used    2849
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.35
_cell_measurement_theta_min      2.36
_cell_volume                     1545.1(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0841
_diffrn_reflns_av_unetI/netI     0.1435
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            14055
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.556
_diffrn_reflns_theta_min         2.003
_exptl_absorpt_coefficient_mu    0.836
_exptl_crystal_colour
;
;
_exptl_crystal_density_diffrn    1.290
_exptl_crystal_description
;
;
_exptl_crystal_F_000             624
_exptl_crystal_size_max          0.280
_exptl_crystal_size_mid          0.260
_exptl_crystal_size_min          0.220
_refine_diff_density_max         0.603
_refine_diff_density_min         -0.723
_refine_diff_density_rms         0.091
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     374
_refine_ls_number_reflns         7116
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.1373
_refine_ls_R_factor_gt           0.0714
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0742P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1487
_refine_ls_wR_factor_ref         0.1740
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4207
_reflns_number_total             7116
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            suppl_ncrs-2017-0404_suppl.cif
_cod_data_source_block           13_sq
_cod_database_code               8106242
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.800
_shelx_estimated_absorpt_t_max   0.838
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3484(5) 0.3871(3) 0.1006(3) 0.0288(10) Uani 1 1 d . . . . .
C2 C 0.4440(5) 0.3003(3) 0.0947(3) 0.0333(11) Uani 1 1 d . . . . .
H2 H 0.4679 0.2690 0.1486 0.040 Uiso 1 1 calc R U . . .
C3 C 0.5020(5) 0.2613(3) 0.0115(3) 0.0347(11) Uani 1 1 d . . . . .
H3 H 0.5642 0.2036 0.0097 0.042 Uiso 1 1 calc R U . . .
C4 C 0.4703(5) 0.3059(3) -0.0700(3) 0.0370(12) Uani 1 1 d . . . . .
H4 H 0.5103 0.2788 -0.1264 0.044 Uiso 1 1 calc R U . . .
C5 C 0.3781(5) 0.3910(3) -0.0659(3) 0.0351(11) Uani 1 1 d . . . . .
H5 H 0.3567 0.4215 -0.1206 0.042 Uiso 1 1 calc R U . . .
C6 C 0.3151(5) 0.4337(3) 0.0179(3) 0.0255(10) Uani 1 1 d . . . . .
C7 C 0.2253(5) 0.5250(3) 0.0107(3) 0.0266(10) Uani 1 1 d . . . . .
H7 H 0.2172 0.5480 -0.0483 0.032 Uiso 1 1 calc R U . . .
C8 C 0.0736(5) 0.6706(3) 0.0562(3) 0.0241(9) Uani 1 1 d . . . . .
C9 C 0.0571(5) 0.7042(3) -0.0311(3) 0.0300(10) Uani 1 1 d . . . . .
H9 H 0.1034 0.6683 -0.0818 0.036 Uiso 1 1 calc R U . . .
C10 C -0.0272(5) 0.7906(3) -0.0440(3) 0.0306(11) Uani 1 1 d . . . . .
H10 H -0.0371 0.8116 -0.1038 0.037 Uiso 1 1 calc R U . . .
C11 C -0.0980(5) 0.8473(3) 0.0295(3) 0.0264(10) Uani 1 1 d . . . . .
C12 C -0.0812(6) 0.8138(4) 0.1164(3) 0.0435(13) Uani 1 1 d . . . . .
H12 H -0.1277 0.8498 0.1671 0.052 Uiso 1 1 calc R U . . .
C13 C 0.0052(6) 0.7257(4) 0.1302(3) 0.0412(13) Uani 1 1 d . . . . .
H13 H 0.0161 0.7047 0.1900 0.049 Uiso 1 1 calc R U . . .
C14 C -0.2563(6) 1.0034(4) 0.0959(3) 0.0481(14) Uani 1 1 d . . . . .
H14A H -0.1735 1.0299 0.1441 0.072 Uiso 1 1 calc R U . . .
H14B H -0.3300 0.9594 0.1217 0.072 Uiso 1 1 calc R U . . .
H14C H -0.3069 1.0622 0.0746 0.072 Uiso 1 1 calc R U . . .
C15 C -0.1916(5) 0.9390(3) 0.0140(3) 0.0267(10) Uani 1 1 d . . . . .
C16 C -0.3246(6) 1.0551(4) -0.1780(3) 0.0498(15) Uani 1 1 d . . . . .
H16A H -0.2254 1.0589 -0.2030 0.075 Uiso 1 1 calc R U . . .
H16B H -0.3759 1.1192 -0.1845 0.075 Uiso 1 1 calc R U . . .
H16C H -0.3870 0.9949 -0.2127 0.075 Uiso 1 1 calc R U . . .
C17 C -0.1262(5) 0.4952(3) 0.3002(3) 0.0300(11) Uani 1 1 d . . . . .
C18 C -0.2687(6) 0.4406(3) 0.3068(3) 0.0392(12) Uani 1 1 d . . . . .
H18 H -0.3143 0.3938 0.2542 0.047 Uiso 1 1 calc R U . . .
C19 C -0.3433(6) 0.4541(4) 0.3886(4) 0.0437(13) Uani 1 1 d . . . . .
H19 H -0.4380 0.4169 0.3904 0.052 Uiso 1 1 calc R U . . .
C20 C -0.2779(6) 0.5231(4) 0.4686(3) 0.0450(14) Uani 1 1 d . . . . .
H20 H -0.3277 0.5323 0.5241 0.054 Uiso 1 1 calc R U . . .
C21 C -0.1396(6) 0.5771(4) 0.4642(3) 0.0369(12) Uani 1 1 d . . . . .
H21 H -0.0969 0.6235 0.5178 0.044 Uiso 1 1 calc R U . . .
C22 C -0.0581(6) 0.5659(3) 0.3825(3) 0.0297(10) Uani 1 1 d . . . . .
C23 C 0.0864(5) 0.6258(3) 0.3895(3) 0.0301(11) Uani 1 1 d . . . . .
H23 H 0.1144 0.6710 0.4466 0.036 Uiso 1 1 calc R U . . .
C24 C 0.3189(5) 0.6965(3) 0.3431(3) 0.0283(10) Uani 1 1 d . . . . .
C25 C 0.4595(6) 0.6628(3) 0.3148(3) 0.0340(11) Uani 1 1 d . . . . .
H25 H 0.4660 0.5925 0.2867 0.041 Uiso 1 1 calc R U . . .
C26 C 0.5894(6) 0.7315(3) 0.3275(3) 0.0334(11) Uani 1 1 d . . . . .
H26 H 0.6830 0.7063 0.3095 0.040 Uiso 1 1 calc R U . . .
C27 C 0.5841(5) 0.8385(3) 0.3668(3) 0.0283(10) Uani 1 1 d . . . . .
C28 C 0.4418(6) 0.8715(3) 0.3964(3) 0.0342(12) Uani 1 1 d . . . . .
H28 H 0.4354 0.9418 0.4243 0.041 Uiso 1 1 calc R U . . .
C29 C 0.3126(5) 0.8034(3) 0.3854(3) 0.0314(11) Uani 1 1 d . . . . .
H29 H 0.2199 0.8277 0.4058 0.038 Uiso 1 1 calc R U . . .
C30 C 0.7199(6) 0.9149(3) 0.3732(3) 0.0347(11) Uani 1 1 d . . . . .
C31 C 0.8826(6) 0.8816(4) 0.3874(4) 0.0486(14) Uani 1 1 d . . . . .
H31A H 0.9489 0.9205 0.3523 0.073 Uiso 1 1 calc R U . . .
H31B H 0.8846 0.8066 0.3653 0.073 Uiso 1 1 calc R U . . .
H31C H 0.9186 0.8963 0.4539 0.073 Uiso 1 1 calc R U . . .
C32 C 0.7681(8) 1.1810(4) 0.3527(4) 0.0651(18) Uani 1 1 d . . . . .
H32A H 0.7309 1.1739 0.2866 0.098 Uiso 1 1 calc R U . . .
H32B H 0.8540 1.2334 0.3664 0.098 Uiso 1 1 calc R U . . .
H32C H 0.6862 1.2030 0.3910 0.098 Uiso 1 1 calc R U . . .
N1 N 0.1544(4) 0.5791(2) 0.0765(2) 0.0239(8) Uani 1 1 d . . . . .
N2 N -0.2111(4) 0.9562(3) -0.0716(2) 0.0323(9) Uani 1 1 d . . . . .
N3 N 0.1839(4) 0.6244(2) 0.3252(2) 0.0261(8) Uani 1 1 d . . . . .
N4 N 0.6843(5) 1.0118(3) 0.3659(3) 0.0419(10) Uani 1 1 d . . . . .
O1 O 0.2938(4) 0.4209(2) 0.1829(2) 0.0377(8) Uani 1 1 d . . . . .
O2 O -0.0619(4) 0.4777(2) 0.2201(2) 0.0379(8) Uani 1 1 d . . . . .
O3 O 0.8179(4) 1.0799(3) 0.3740(3) 0.0561(10) Uani 1 1 d . . . . .
O4 O -0.3032(4) 1.0439(2) -0.0800(2) 0.0376(8) Uani 1 1 d . . . . .
Zn2 Zn 0.14443(6) 0.52656(4) 0.20046(3) 0.02761(18) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 C6 123.2(4) . .
O1 C1 C2 118.8(4) . .
C6 C1 C2 118.1(4) . .
C3 C2 C1 121.3(4) . .
C3 C2 H2 119.3 . .
C1 C2 H2 119.3 . .
C2 C3 C4 121.2(4) . .
C2 C3 H3 119.4 . .
C4 C3 H3 119.4 . .
C5 C4 C3 118.6(4) . .
C5 C4 H4 120.7 . .
C3 C4 H4 120.7 . .
C4 C5 C6 122.3(4) . .
C4 C5 H5 118.9 . .
C6 C5 H5 118.9 . .
C5 C6 C1 118.5(4) . .
C5 C6 C7 115.2(4) . .
C1 C6 C7 126.3(4) . .
N1 C7 C6 127.9(4) . .
N1 C7 H7 116.0 . .
C6 C7 H7 116.0 . .
C13 C8 C9 118.5(4) . .
C13 C8 N1 116.4(3) . .
C9 C8 N1 125.1(4) . .
C10 C9 C8 120.6(4) . .
C10 C9 H9 119.7 . .
C8 C9 H9 119.7 . .
C9 C10 C11 122.0(4) . .
C9 C10 H10 119.0 . .
C11 C10 H10 119.0 . .
C12 C11 C10 117.3(4) . .
C12 C11 C15 121.2(4) . .
C10 C11 C15 121.4(4) . .
C11 C12 C13 121.0(4) . .
C11 C12 H12 119.5 . .
C13 C12 H12 119.5 . .
C8 C13 C12 120.6(4) . .
C8 C13 H13 119.7 . .
C12 C13 H13 119.7 . .
C15 C14 H14A 109.5 . .
C15 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C15 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
N2 C15 C11 115.4(4) . .
N2 C15 C14 124.4(4) . .
C11 C15 C14 120.1(4) . .
O4 C16 H16A 109.5 . .
O4 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
O4 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
O2 C17 C18 118.6(4) . .
O2 C17 C22 123.7(4) . .
C18 C17 C22 117.7(4) . .
C19 C18 C17 122.1(5) . .
C19 C18 H18 118.9 . .
C17 C18 H18 118.9 . .
C18 C19 C20 120.3(5) . .
C18 C19 H19 119.8 . .
C20 C19 H19 119.8 . .
C21 C20 C19 118.8(4) . .
C21 C20 H20 120.6 . .
C19 C20 H20 120.6 . .
C20 C21 C22 123.2(5) . .
C20 C21 H21 118.4 . .
C22 C21 H21 118.4 . .
C21 C22 C23 116.6(4) . .
C21 C22 C17 117.8(4) . .
C23 C22 C17 125.5(4) . .
N3 C23 C22 127.3(4) . .
N3 C23 H23 116.3 . .
C22 C23 H23 116.3 . .
C25 C24 C29 118.2(4) . .
C25 C24 N3 119.8(4) . .
C29 C24 N3 121.9(4) . .
C26 C25 C24 121.0(4) . .
C26 C25 H25 119.5 . .
C24 C25 H25 119.5 . .
C25 C26 C27 121.5(4) . .
C25 C26 H26 119.3 . .
C27 C26 H26 119.3 . .
C26 C27 C28 117.1(4) . .
C26 C27 C30 121.7(4) . .
C28 C27 C30 121.1(4) . .
C29 C28 C27 121.9(4) . .
C29 C28 H28 119.1 . .
C27 C28 H28 119.1 . .
C28 C29 C24 120.3(4) . .
C28 C29 H29 119.9 . .
C24 C29 H29 119.9 . .
N4 C30 C27 113.9(4) . .
N4 C30 C31 124.3(5) . .
C27 C30 C31 121.8(4) . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
O3 C32 H32A 109.5 . .
O3 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
O3 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C7 N1 C8 119.7(3) . .
C7 N1 Zn2 119.0(3) . .
C8 N1 Zn2 121.1(3) . .
C15 N2 O4 111.6(3) . .
C23 N3 C24 119.0(4) . .
C23 N3 Zn2 121.1(3) . .
C24 N3 Zn2 119.8(3) . .
C30 N4 O3 110.8(4) . .
C1 O1 Zn2 124.4(2) . .
C17 O2 Zn2 125.7(3) . .
N4 O3 C32 106.6(4) . .
N2 O4 C16 108.1(3) . .
O1 Zn2 O2 116.94(13) . .
O1 Zn2 N1 97.69(13) . .
O2 Zn2 N1 112.63(14) . .
O1 Zn2 N3 113.33(13) . .
O2 Zn2 N3 95.67(14) . .
N1 Zn2 N3 122.01(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.324(5) .
C1 C6 1.412(5) .
C1 C2 1.410(5) .
C2 C3 1.364(6) .
C2 H2 0.9300 .
C3 C4 1.380(6) .
C3 H3 0.9300 .
C4 C5 1.375(6) .
C4 H4 0.9300 .
C5 C6 1.404(6) .
C5 H5 0.9300 .
C6 C7 1.442(5) .
C7 N1 1.298(5) .
C7 H7 0.9300 .
C8 C13 1.375(6) .
C8 C9 1.374(5) .
C8 N1 1.440(5) .
C9 C10 1.375(5) .
C9 H9 0.9300 .
C10 C11 1.389(5) .
C10 H10 0.9300 .
C11 C12 1.369(6) .
C11 C15 1.486(5) .
C12 C13 1.406(6) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 C15 1.491(6) .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 N2 1.271(5) .
C16 O4 1.425(5) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 O2 1.309(5) .
C17 C18 1.403(6) .
C17 C22 1.430(6) .
C18 C19 1.376(6) .
C18 H18 0.9300 .
C19 C20 1.390(7) .
C19 H19 0.9300 .
C20 C21 1.360(7) .
C20 H20 0.9300 .
C21 C22 1.409(6) .
C21 H21 0.9300 .
C22 C23 1.419(6) .
C23 N3 1.300(5) .
C23 H23 0.9300 .
C24 C25 1.385(6) .
C24 C29 1.408(6) .
C24 N3 1.428(6) .
C25 C26 1.370(6) .
C25 H25 0.9300 .
C26 C27 1.396(5) .
C26 H26 0.9300 .
C27 C28 1.402(6) .
C27 C30 1.475(6) .
C28 C29 1.363(6) .
C28 H28 0.9300 .
C29 H29 0.9300 .
C30 N4 1.302(5) .
C30 C31 1.498(6) .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
C32 O3 1.442(5) .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
N1 Zn2 1.989(3) .
N2 O4 1.416(4) .
N3 Zn2 2.007(3) .
N4 O3 1.395(5) .
O1 Zn2 1.917(3) .
O2 Zn2 1.919(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O1 C1 C2 C3 179.2(4) . . . .
C6 C1 C2 C3 -0.5(7) . . . .
C1 C2 C3 C4 0.4(7) . . . .
C2 C3 C4 C5 0.0(7) . . . .
C3 C4 C5 C6 -0.2(7) . . . .
C4 C5 C6 C1 0.1(7) . . . .
C4 C5 C6 C7 178.1(4) . . . .
O1 C1 C6 C5 -179.5(4) . . . .
C2 C1 C6 C5 0.3(6) . . . .
O1 C1 C6 C7 2.8(7) . . . .
C2 C1 C6 C7 -177.5(4) . . . .
C5 C6 C7 N1 179.7(4) . . . .
C1 C6 C7 N1 -2.5(8) . . . .
C13 C8 C9 C10 -0.6(7) . . . .
N1 C8 C9 C10 177.6(4) . . . .
C8 C9 C10 C11 0.3(7) . . . .
C9 C10 C11 C12 -0.2(7) . . . .
C9 C10 C11 C15 -178.7(4) . . . .
C10 C11 C12 C13 0.4(7) . . . .
C15 C11 C12 C13 178.8(5) . . . .
C9 C8 C13 C12 0.8(7) . . . .
N1 C8 C13 C12 -177.6(4) . . . .
C11 C12 C13 C8 -0.7(8) . . . .
C12 C11 C15 N2 -173.5(4) . . . .
C10 C11 C15 N2 4.9(6) . . . .
C12 C11 C15 C14 6.2(7) . . . .
C10 C11 C15 C14 -175.4(4) . . . .
O2 C17 C18 C19 179.6(4) . . . .
C22 C17 C18 C19 0.6(6) . . . .
C17 C18 C19 C20 -0.4(7) . . . .
C18 C19 C20 C21 0.3(7) . . . .
C19 C20 C21 C22 -0.5(7) . . . .
C20 C21 C22 C23 -178.6(4) . . . .
C20 C21 C22 C17 0.8(6) . . . .
O2 C17 C22 C21 -179.7(4) . . . .
C18 C17 C22 C21 -0.8(6) . . . .
O2 C17 C22 C23 -0.4(6) . . . .
C18 C17 C22 C23 178.5(4) . . . .
C21 C22 C23 N3 176.7(4) . . . .
C17 C22 C23 N3 -2.7(7) . . . .
C29 C24 C25 C26 0.0(6) . . . .
N3 C24 C25 C26 177.3(4) . . . .
C24 C25 C26 C27 -1.8(6) . . . .
C25 C26 C27 C28 2.6(6) . . . .
C25 C26 C27 C30 -174.7(4) . . . .
C26 C27 C28 C29 -1.6(6) . . . .
C30 C27 C28 C29 175.7(4) . . . .
C27 C28 C29 C24 -0.1(6) . . . .
C25 C24 C29 C28 1.0(6) . . . .
N3 C24 C29 C28 -176.3(4) . . . .
C26 C27 C30 N4 148.1(4) . . . .
C28 C27 C30 N4 -29.1(6) . . . .
C26 C27 C30 C31 -32.3(6) . . . .
C28 C27 C30 C31 150.5(4) . . . .
C6 C7 N1 C8 178.2(4) . . . .
C6 C7 N1 Zn2 -7.0(6) . . . .
C13 C8 N1 C7 -178.1(4) . . . .
C9 C8 N1 C7 3.6(6) . . . .
C13 C8 N1 Zn2 7.2(5) . . . .
C9 C8 N1 Zn2 -171.1(3) . . . .
C11 C15 N2 O4 179.2(3) . . . .
C14 C15 N2 O4 -0.5(6) . . . .
C22 C23 N3 C24 175.5(4) . . . .
C22 C23 N3 Zn2 -2.6(5) . . . .
C25 C24 N3 C23 140.9(4) . . . .
C29 C24 N3 C23 -41.9(5) . . . .
C25 C24 N3 Zn2 -41.0(5) . . . .
C29 C24 N3 Zn2 136.2(3) . . . .
C27 C30 N4 O3 179.1(3) . . . .
C31 C30 N4 O3 -0.5(6) . . . .
C6 C1 O1 Zn2 7.1(6) . . . .
C2 C1 O1 Zn2 -172.7(3) . . . .
C18 C17 O2 Zn2 -170.4(3) . . . .
C22 C17 O2 Zn2 8.6(5) . . . .
C30 N4 O3 C32 172.7(4) . . . .
C15 N2 O4 C16 -177.7(4) . . . .
