Crystallography Open Database

Information card for entry 1556542

Preview

Coordinates	1556542.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C337 H339 Ag32 Mo4 N3 O26 P24
Calculated formula	C337 H339 Ag32 Mo4 N3 O26 P24
SMILES	c1(ccccc1)[P]1(c2ccccc2)CCCC[P]([Ag]2[P](CCCC[P](c3ccccc3)(c3ccccc3)[Ag]345[Ag]678O[Mo]9(=O)=[O][Ag]%10%11[Ag]%12%13([P](CCCC[P]2(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)[Ag]2%14%15[Ag]%16%17%12[Ag]%12%18%19%20%21%13%14[Ag]%13%14O[Mo]%22(=O)=[O][Ag]%232[Ag]6%12(O9)[Ag]261[Ag]19%127%20%23[Ag]7%20%23%24%25%26%21[Ag]%17%13O[Mo]%13(=[O][Ag]%17%10%18[Ag]%10%183[P](CCCC[P](c3ccccc3)(c3ccccc3)[Ag]([P](c3ccccc3)(c3ccccc3)CCCC[P]%16(c3ccccc3)c3ccccc3)[P](c3ccccc3)(c3ccccc3)CCCC[P](c3ccccc3)([Ag]3%16%24[Ag]%21%14%23[P](CCCC[P](c%14ccccc%14)([Ag]([P](c%14ccccc%14)(CCCC[P]%15(c%14ccccc%14)c%14ccccc%14)c%14ccccc%14)[P](c%14ccccc%14)(CCCC[P](c%14ccccc%14)(c%14ccccc%14)[Ag]%1469[Ag]%20(O%22)[Ag]69%12[O][Mo]%12(=O)=[O][Ag]%15%2089[Ag]84%11%197%10[Ag]%17%16(O%13)[Ag]%26%15(O%12)[Ag]5%188[P](c4ccccc4)(c4ccccc4)CCCC[P]([Ag]([P](CCCC[P](c4ccccc4)(c4ccccc4)[Ag]21%14%20)(c1ccccc1)c1ccccc1)[P](CCCC[P](c1ccccc1)([Ag]%253%216)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)=O)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.N(=O)(=O)[O-].N(=O)(=O)[O-].N(=O)(=O)[O-].CO
Title of publication	Oxometalate and phosphine ligand co-protected silver nanoclusters: Ag<sub>28</sub>(dppb)<sub>6</sub>(MO<sub>4</sub>)<sub>4</sub> and Ag<sub>32</sub>(dppb)<sub>12</sub>(MO<sub>4</sub>)<sub>4</sub>(NO<sub>3</sub>)<sub>4</sub>.
Authors of publication	Duan, Guang-Xiong; Han, Jun; Yang, Bao-Zhu; Xie, Yun-Peng; Lu, Xing
Journal of publication	Nanoscale
Year of publication	2020
Journal volume	12
Journal issue	3
Pages of publication	1617 - 1622
a	41.161 ± 0.003 Å
b	24.6172 ± 0.0013 Å
c	40.061 ± 0.002 Å
α	90°
β	103.141 ± 0.002°
γ	90°
Cell volume	39530 ± 4 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	7
Space group number	5
Hermann-Mauguin space group symbol	C 1 2 1
Hall space group symbol	C 2y
Residual factor for all reflections	0.0819
Residual factor for significantly intense reflections	0.0674
Weighted residual factors for significantly intense reflections	0.1802
Weighted residual factors for all reflections included in the refinement	0.1938
Goodness-of-fit parameter for all reflections included in the refinement	1.029
Diffraction radiation wavelength	0.6525 Å
Diffraction radiation type	synchrotron
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
247766 (current)	2020-02-04	cif/ Updating files of 1556541, 1556542, 1556543 Original log message: Adding full bibliography for 1556541--1556543.cif.	1556542.cif
245038	2019-12-13	cif/ Adding structures of 1556541, 1556542, 1556543 via cif-deposit CGI script.	1556542.cif