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Information card for entry 1556543
Preview
| Coordinates | 1556543.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C168 H170 Ag28 O17 P12 W4 |
|---|---|
| Calculated formula | C168 H170 Ag28 O17 P12 W4 |
| SMILES | [W]12(=[O][Ag]3456[Ag]789%10[Ag]%11%12%13%14%15%16%17[Ag]%18%19%20%21[Ag]%22%23%24%25[Ag]%26%27%28%29[Ag]%30%31%32%33%34%35%12[Ag]%12%22([Ag]%223%11([Ag]3%11%30[Ag]%30%23%26%32[Ag]%23%26%353[Ag]3%31%22([Ag]%22%31%27%23[Ag]%23%27%32([Ag]%35%36%37%38[Ag]%39%4047[Ag]3%35([Ag]35%14%34%22%37%39[Ag]457%13%24%33%27[Ag]%13%14%23([Ag]%285([Ag]5%197%14[Ag]%184([Ag]4%16%20([Ag]%15%12([Ag]69%174[P](c4ccccc4)(CCCC[P]%40(c4ccccc4)c4ccccc4)c4ccccc4)[P](c4ccccc4)(CCCC[P]%11(c4ccccc4)c4ccccc4)c4ccccc4)[P](CCCC[P]5(c4ccccc4)c4ccccc4)(c4ccccc4)c4ccccc4)O[W](O%10)(=[O][Ag]8%32%363%13)=O)[P](CCCC[P]%30(c3ccccc3)c3ccccc3)(c3ccccc3)c3ccccc3)[P](c3ccccc3)(c3ccccc3)CCCC[P]%38(c3ccccc3)c3ccccc3)[P](CCCC[P]%26(c3ccccc3)c3ccccc3)(c3ccccc3)c3ccccc3)O[W](O%31)(=O)=[O]%29)O1)O2)O[W](O%25)(=[O]%21)=O)=O.O |
| Title of publication | Oxometalate and phosphine ligand co-protected silver nanoclusters: Ag<sub>28</sub>(dppb)<sub>6</sub>(MO<sub>4</sub>)<sub>4</sub> and Ag<sub>32</sub>(dppb)<sub>12</sub>(MO<sub>4</sub>)<sub>4</sub>(NO<sub>3</sub>)<sub>4</sub>. |
| Authors of publication | Duan, Guang-Xiong; Han, Jun; Yang, Bao-Zhu; Xie, Yun-Peng; Lu, Xing |
| Journal of publication | Nanoscale |
| Year of publication | 2020 |
| Journal volume | 12 |
| Journal issue | 3 |
| Pages of publication | 1617 - 1622 |
| a | 57.246 ± 0.003 Å |
| b | 33.4588 ± 0.0016 Å |
| c | 38.553 ± 0.004 Å |
| α | 90° |
| β | 120.882 ± 0.001° |
| γ | 90° |
| Cell volume | 63375 ± 8 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.1762 |
| Residual factor for significantly intense reflections | 0.1214 |
| Weighted residual factors for significantly intense reflections | 0.3161 |
| Weighted residual factors for all reflections included in the refinement | 0.3674 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.074 |
| Diffraction radiation wavelength | 0.6525 Å |
| Diffraction radiation type | synchrotron |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 247766 (current) | 2020-02-04 | cif/ Updating files of 1556541, 1556542, 1556543 Original log message: Adding full bibliography for 1556541--1556543.cif. |
1556543.cif |
| 245038 | 2019-12-13 | cif/ Adding structures of 1556541, 1556542, 1556543 via cif-deposit CGI script. |
1556543.cif |
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Users of the data should acknowledge the original authors of the
structural data.