Crystallography Open Database

Information card for entry 7048321

Preview

Coordinates	7048321.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C55 H52 Cl4 F3 N4 O3 P2 Rh Ru S
Calculated formula	C55 H50 Cl4 F3 N4 O3 P2 Rh Ru S
Title of publication	Bis(bipyridine) ruthenium(ii) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation.
Authors of publication	Takemoto, Shin; Kitamura, Manami; Saruwatari, Shuhei; Isono, Atsutaka; Takada, Yoko; Nishimori, Rie; Tsujiwaki, Mina; Sakaue, Naoki; Matsuzaka, Hiroyuki
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2019
Journal volume	48
Journal issue	4
Pages of publication	1161 - 1165
a	10.7935 ± 0.0006 Å
b	15.5987 ± 0.0009 Å
c	17.0524 ± 0.0011 Å
α	82.036 ± 0.006°
β	88.284 ± 0.006°
γ	74.438 ± 0.005°
Cell volume	2739 ± 0.3 Å³
Cell temperature	173 K
Ambient diffraction temperature	173 K
Number of distinct elements	10
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.094
Residual factor for significantly intense reflections	0.0578
Weighted residual factors for significantly intense reflections	0.1328
Weighted residual factors for all reflections included in the refinement	0.1489
Goodness-of-fit parameter for all reflections included in the refinement	1.022
Diffraction radiation wavelength	0.71075 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
224082 (current)	2019-11-07	cif/ Updating files of 7048321, 7048322 Original log message: Adding full bibliography for 7048321--7048322.cif.	7048321.cif
212484	2018-12-08	cif/ Adding structures of 7048321, 7048322 via cif-deposit CGI script.	7048321.cif